JPS5911860A - Production of solid aromatic composition - Google Patents
Production of solid aromatic compositionInfo
- Publication number
- JPS5911860A JPS5911860A JP57120270A JP12027082A JPS5911860A JP S5911860 A JPS5911860 A JP S5911860A JP 57120270 A JP57120270 A JP 57120270A JP 12027082 A JP12027082 A JP 12027082A JP S5911860 A JPS5911860 A JP S5911860A
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- castor oil
- mixture
- fragrance
- acid amide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000003118 aryl group Chemical group 0.000 title claims description 15
- 239000000203 mixture Substances 0.000 title claims description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000007787 solid Substances 0.000 title claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 42
- 239000000194 fatty acid Substances 0.000 claims description 42
- 229930195729 fatty acid Natural products 0.000 claims description 42
- 150000004665 fatty acids Chemical class 0.000 claims description 40
- -1 terpene hydrocarbons Chemical class 0.000 claims description 27
- 239000004359 castor oil Substances 0.000 claims description 18
- 235000019438 castor oil Nutrition 0.000 claims description 18
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 18
- 235000007586 terpenes Nutrition 0.000 claims description 16
- 239000004698 Polyethylene Substances 0.000 claims description 11
- 229920000573 polyethylene Polymers 0.000 claims description 11
- 229920001971 elastomer Polymers 0.000 claims description 9
- 239000005060 rubber Substances 0.000 claims description 9
- 239000003205 fragrance Substances 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 239000004793 Polystyrene Substances 0.000 claims description 6
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 6
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 239000010779 crude oil Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000002360 explosive Substances 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 239000002966 varnish Substances 0.000 claims 1
- 150000003505 terpenes Chemical class 0.000 description 13
- 239000001993 wax Substances 0.000 description 9
- XMGQYMWWDOXHJM-JTQLQIEISA-N D-limonene Natural products CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
- 235000015278 beef Nutrition 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- 229920003049 isoprene rubber Polymers 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 235000021357 Behenic acid Nutrition 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229940116226 behenic acid Drugs 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000004203 carnauba wax Substances 0.000 description 2
- 235000013869 carnauba wax Nutrition 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- 125000000545 (4R)-limonene group Chemical group 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 1
- WCOXQTXVACYMLM-UHFFFAOYSA-N 2,3-bis(12-hydroxyoctadecanoyloxy)propyl 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC(O)CCCCCC)COC(=O)CCCCCCCCCCC(O)CCCCCC WCOXQTXVACYMLM-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 125000003447 alpha-pinene group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000006701 autoxidation reaction Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003172 expectorant agent Substances 0.000 description 1
- 230000003419 expectorant effect Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 150000002889 oleic acids Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 208000023504 respiratory system disease Diseases 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は消臭才たは発香を目的とした同型芳主体とする
場合は吸引去痰剤あるいは動物の呼吸器疾患の治療用揮
発性組成、物の製法に関する。従来より揮発性テルペン
炭化水素（以下単にテルペンと言う）を主体とする芳香
成分をポリエチレンおよびまたはヒマシ油類等により固
型化し、更に、その際生ゴムおよびまたは高級脂肪族ア
ルコールを添加し７たり、脂肪酸類及びまたは、ワック
ス類を添加する方法は見い出されている。（特公昭５７
−１．５９０３号、特開昭５３−１４５９３１号）しか
し上記方法により固型化されたものは硬度が十分ではな
く、容器の強度が弱い時や、あやまって落した時などは
くずれてし甘う場合があった。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a volatile composition and a method for producing a product for use as a suction expectorant or for the treatment of respiratory diseases in animals, when the composition is based on the same type of aroma for deodorizing or scenting purposes. Conventionally, aromatic components mainly composed of volatile terpene hydrocarbons (hereinafter simply referred to as terpenes) are solidified with polyethylene and/or castor oil, etc., and raw rubber and/or higher aliphatic alcohols are added at that time. Methods have been found to add fatty acids and/or waxes. (Tokuko Showa 57
(No. 1.5903, Japanese Unexamined Patent Publication No. 53-145931) However, the hardness of the solidified product by the above method is not sufficient, and if the container is weak or accidentally dropped, it will collapse and become soft. There were cases where
本発明は、かかる芳香成型物の改良を研究し、新しいポ
リエチレンとして市販されている、中低圧型合法直鎖状
ポリエチレン（以下ＬＬＤＰＥという）、ポリプロピレ
ン、脂肪酸アマイド等を芳香成分に添加することによっ
て非常に硬度がありしかも離漿の全くない生成物を得る
ことに成功ｔ、たもので、本発明は揮発性テルペン炭化
水素を主体とする芳香成分と下記■または■または１■
とを加熱混合【７冷却することを特徴とする固型発香組
成物の製法である。The present invention has researched the improvement of such aromatic molded products, and by adding medium-low pressure type legal linear polyethylene (hereinafter referred to as LLDPE), polypropylene, fatty acid amide, etc., which are commercially available as new polyethylene, to the aromatic component. The present invention has succeeded in obtaining a product that has a hardness and no syneresis, and the present invention has been developed by combining an aromatic component mainly composed of volatile terpene hydrocarbons and the following ■ or ■ or 1
This is a method for producing a solid fragrance composition characterized by heating and mixing [7] and cooling.
１、（ｉ）ＬＬＤＰＥ
（１１）ポリプロピレン
（ｉｉｉ）脂肪酸アマイド
（ｉｖ）脂肪酸アマイドとポリエチレンの混合物上記（
１）〜（ｉｖ）から選ばれる一種。1, (i) LLDPE (11) polypropylene (iii) fatty acid amide (iv) mixture of fatty acid amide and polyethylene (
A type selected from 1) to (iv).
Ｉｌ、ＬＬＤＰＥと下記（ａ）〜（１）から選ばれる一
種または二種以上との混合物。Il, a mixture of LLDPE and one or more selected from the following (a) to (1).
（ａ）ヒマシ油、（ｈ）ヒマシ油誘導体、（ｃ）硬化油
、（ｄ）脂肪酸、（ｅ）蒸留脂肪酸、（ｆ）脂肪酸のエ
ステル化物、（ｇ’）脂肪酸の金属塩、（ｈ）高級脂肪
族アルコール、（ｉ）生ゴム、（ｊ）ポリスチロール、
（ｋ）植物系天然ワックス、（１）脂肪酸アマイドＩ１
１．ポリプロピレンと下Ｍｅ （ａ）〜（ｒ＋１）から
選ばれる一種寸たけ二種以上との混合物。(a) castor oil, (h) castor oil derivative, (c) hydrogenated oil, (d) fatty acid, (e) distilled fatty acid, (f) esterified fatty acid, (g') metal salt of fatty acid, (h) Higher aliphatic alcohol, (i) raw rubber, (j) polystyrene,
(k) Plant-based natural wax, (1) Fatty acid amide I1
1. A mixture of polypropylene and at least one type selected from Me (a) to (r+1).
（ａ）ヒマシ油、（ｂ）ヒマシ油誘導体、（ｃ）硬化油
、（ｄ）脂肪酸、（ｅ）蒸留１折肪酸、（ｆ）脂肪酸の
エステル化物、（ｇ）脂肪酸の金属塩、（ｈ）高級脂肪
族アルコール、（ｉ）生ゴム、（ｊ）ポリスチロール、
（ｌｃ）植物系天然ワックス、（１）脂肪酸アマイド、
ｆｌｌ）ポリエチレン
本発明組成物の主体であるテルペンは揮発性を有するも
のであればよく、揮発性のあるものは一般に芳香を有し
ているものである。かかるものとしてα−ピネンを主成
分とするもの、ｄ−リモネンを主成分とするもの、その
他種々のテルペンが上げられるが、これらのうち特にり
七ネンは、去痰作用及び動物の呼吸器疾患の治療効果を
有するものであり、本発明にかかる組成物はそれらの効
果も期待できるものである。かかるテルペンの選択ｒ４
．産出状況、使用目的及び芳香の好みによって任意に定
められるものである。またテルペンｈａ金物として産出
し、取り扱われることが多いが、本発明においては混合
物であっても良い。さらにテルペン中には天然にあるい
は自動酸化等によってアルコール、アルデヒド、ケトン
、カルボン酸等の酸素化合物を含有することが多いが、
これらを含んでいても良い０更にテルペンに適当量好ま
しくは、１０重量％（以下％ｔま重量％を示す）以下の
調合香料または香料原油を添加して芳香を強めることも
できる。１だテルペンにアレスリン、ＤＤＶＰ等の揮発
性殺虫剤の適当量好ましくは３０チ以下を添加しても良
い。捷だ製造工程および貯蔵期間中におけるテルペンの
酸化を防止するために必侠に応じて酸化防止剤を添加す
ることが好ましい。かかる酸化防止剤は慣用されている
いずれのものでも良く、例えばアルキルフェノール類ヲ
あげることができる。以上種々の場合を述べたが、テル
ペンは少なくとも芳香成分中６０％以上存在し、芳香成
分の主体をなすものでおる。(a) castor oil, (b) castor oil derivative, (c) hydrogenated oil, (d) fatty acid, (e) distilled mono-fold fatty acid, (f) esterified product of fatty acid, (g) metal salt of fatty acid, ( h) higher aliphatic alcohol, (i) raw rubber, (j) polystyrene,
(lc) plant-based natural wax, (1) fatty acid amide,
fll) Polyethylene The terpene which is the main component of the composition of the present invention may be any terpene as long as it is volatile, and volatile terpenes generally have an aroma. Examples of such terpenes include those whose main component is α-pinene, those whose main component is d-limonene, and various other terpenes. It has therapeutic effects, and the composition according to the present invention can be expected to have these effects as well. Selection of such terpenes r4
．． It is determined arbitrarily depending on the production situation, purpose of use, and fragrance preference. Further, although terpene ha is often produced and handled as a metal product, it may be used as a mixture in the present invention. Furthermore, terpenes often contain oxygen compounds such as alcohols, aldehydes, ketones, and carboxylic acids, either naturally or through autoxidation.
Furthermore, a suitable amount of a blended fragrance or fragrance crude oil, preferably 10% by weight (hereinafter referred to as %t) or less, may be added to the terpene to intensify the aroma. An appropriate amount of a volatile insecticide such as allethrin or DDVP, preferably 30 or less, may be added to the terpene. It is preferable to add an antioxidant according to necessity in order to prevent oxidation of terpenes during the fermentation process and storage period. Such antioxidants may be any commonly used antioxidants, such as alkylphenols. Although various cases have been described above, terpenes are present in at least 60% or more of the aromatic components, and are the main component of the aromatic components.
固型化剤としてのＬＬＤＰＥに密度（Ｌ９１５〜０．９
４のものでろって中低圧法により溶ｔ［を重合法あるい
は気相重合法によって作られたエチレンとα−オレフィ
ンとの共直合体をいう。例えば三井石油化学工業社製の
ウルトゼツクスをあげることができる。ポリプロピレン
ｔ６↓市販のいず九でもよいが溶融時に流動性のあるも
のが好ましい。脂肪酸アマイドとしてＯまエチレンビス
アマイド、ステアロアマイド、オレイン酸アマイド、メ
チレンビスステアロアマイト等があげられる。またポリ
エチレンは如何なるものでもよいが低密度又は中低密度
ポリエチレンが好ｔ Ｉ、い。ヒマシ油は市販されてい
るもののいずれでもよく、ヒマシ油誘導体としては、セ
バシン酸、セバシン酸エステル、脱水ヒマシ油、水嵩添
加ヒマシ油、ヒマシ油エステル化物（メチルリシルレー
ト、エチルリシノＬ／−）、、イングロビルリシル−ト
等）、ロート油、吹込ヒマシ油、カスターワックス等が
上げられる。また硬化油としては牛脂硬化油、魚油硬化
油、菜種硬化油、硬化ロウ、ダイヤモンドワックス等が
上げられる。また脂肪酸としてはステアリン酸、分解脂
肪酸（ヤシ硬化脂肪酸、ヤシ脂肪酸、牛脂脂肪酸、大豆
脂肪酸等）、オレイン酸等の炭素数１６以上のものが上
けられ、蒸留脂肪酸にはカプロン酸、カプリル酸、カプ
リン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ベ
ヘニン酸等の炭素数８以上のものがあげられる。°又、
脂肪酸のエステル化物とし２ては、脂肪酸の低級アルキ
ルエステル化物例えばメチルエステル化物を言う。脂肪
酸の金属塩としては高級脂肪酸アルミニウム塩、高級脂
肪酸ナトリウム塩等が上げられる。高級脂肪族アルコー
ルとして、モテルアルコール、ラウリルアルコール、ス
テアリルアルコール等、常温で固型のものであれば良い
。生ゴムとしては、エチレンプロピレンゴム（ＥＰＴ）
、クロロプレンゴム（ＣＲ）、スチレンブタジェンゴム
（ＳＢＲ）、イソプレンゴム（ＩＲ）、ブタジェンゴム
（ＢＲ）、インブチレンイソプレンゴム（ＩＩＲ）、ス
チレンゴム（ＳＲ）、クロロプレンニトリルゴムその他
種々の合成ゴムおよびベールクレープ、スモークドシー
ト、塩化ゴム等の天然または変性天然ゴム′ｆ：あげる
ことができる。ポリスチロールもどのようなものでも良
い。また植物系天然ワックスとしては木ロウ、キャンデ
ラワックス、カルナバワックス等が上げられる。Density (L915 ~ 0.9
4 refers to a copolymer of ethylene and α-olefin produced by polymerizing molten t[alpha] by a medium-low pressure method or by a gas phase polymerization method. For example, Urtozex manufactured by Mitsui Petrochemical Industries, Ltd. can be mentioned. Commercially available polypropylene t6↓ may be used, but one that is fluid when melted is preferred. Examples of the fatty acid amide include ethylene bisamide, stearamide, oleic acid amide, methylene bis stearamide, and the like. Any type of polyethylene may be used, but low density or medium-low density polyethylene is preferred. Any commercially available castor oil may be used, and examples of castor oil derivatives include sebacic acid, sebacic acid ester, dehydrated castor oil, bulked castor oil, castor oil esters (methyl lysyllate, ethyl lysino L/-), Inglobillysilte, etc.), funnel oil, blown castor oil, castor wax, etc. Examples of the hydrogenated oil include hydrogenated beef tallow oil, hydrogenated fish oil, hydrogenated rapeseed oil, hydrogenated wax, and diamond wax. Fatty acids include stearic acid, decomposed fatty acids (hardened coconut fatty acids, coconut fatty acids, beef tallow fatty acids, soybean fatty acids, etc.), and oleic acids with carbon atoms of 16 or more, and distilled fatty acids include caproic acid, caprylic acid, Examples include those having 8 or more carbon atoms, such as capric acid, lauric acid, myristic acid, palmitic acid, and behenic acid. °Also,
The esterified fatty acid 2 refers to a lower alkyl esterified fatty acid, such as a methyl esterified product. Examples of the metal salts of fatty acids include higher fatty acid aluminum salts and higher fatty acid sodium salts. The higher aliphatic alcohol may be one that is solid at room temperature, such as motel alcohol, lauryl alcohol, and stearyl alcohol. As raw rubber, ethylene propylene rubber (EPT)
, chloroprene rubber (CR), styrene butadiene rubber (SBR), isoprene rubber (IR), butadiene rubber (BR), inbutylene isoprene rubber (IIR), styrene rubber (SR), chloroprene nitrile rubber and other various synthetic rubbers and veils. Natural or modified natural rubber such as crepe, smoked sheet, chlorinated rubber, etc. can be mentioned. Any type of polystyrene may be used. Further, examples of plant-based natural waxes include wood wax, candela wax, carnauba wax, and the like.
上記した固型化物の添加量゛ハ芳香成分１００重蓋部（
以下部は重量部を示す）に対して５〜３０部あれば充分
である。Addition amount of the above-mentioned solidified material: 100 parts of aromatic components (
5 to 30 parts by weight (the following parts are parts by weight) is sufficient.
上記した芳香成分と固型化物は夫々の成分に適した温度
例えば８０〜１４０℃にて加熱混合し、溶解あるいは均
一化した後常温まで冷却すれば良い○
以下実施例を挙げて具体的に説明するが、本発明はこれ
に限定されるものではない。The above-mentioned aromatic components and solidified products may be heated and mixed at a temperature suitable for each component, for example, 80 to 140°C, dissolved or homogenized, and then cooled to room temperature. ○ The following is a concrete explanation with examples. However, the present invention is not limited thereto.
実施例に使用したＬＬＤＰＥｉｆ三井石油化学工業のウ
ルトゼツクス２０２００Ｊであり、ポリエチレンは密度
０．９１〜０．９３、分子量１５００のものでめり、ポ
リプロピレンは三井石油化学工業の５Ｊ５１０である。The LLDPE used in the examples is Ultzex 20200J manufactured by Mitsui Petrochemical Industries, the polyethylene has a density of 0.91 to 0.93 and a molecular weight of 1500, and the polypropylene is 5J510 manufactured by Mitsui Petrochemical Industries.
また、各種固型化物は表−１のとおりである。Moreover, various solidified products are as shown in Table-1.
甘だ芳香成分は表−２のとおりである。The sweet aroma components are shown in Table 2.
表−１固型化物
Ａ、ヒマシ油
Ｂ、ヒマシ油誘導体として水素添加ヒマシ油Ｃ０硬化油
として牛脂硬化油
り、脂肪酸としてステアリン酸
Ｅ、蒸留脂肪酸としてベヘニン酸
Ｆ、脂肪酸のエステル化物として牛脂硬化メチルエステ
ル
Ｇ、脂肪酸の金属塩としてステアリン酸ＮａＨ０高級脂
肪族アルコールとしてラウリルアルコール
■、生ゴムとしてＩＲ日本ゼオン製２２００Ｊ、ポリス
チロール
に、植物系天然ワックスとしてカルナバワックスＬ１月
旨訪酸アマイドとしてエチレンビスアマイド表−２芳香
成分
実施例 １〜５純度９５％のｄ −ＩＪモネンｌ ６
〜１０ １ ８５％
ｌ １１〜１５ ＃ ９５チのｄ−リモネンに５
％のレモン系香料配合
ｌ １６〜２０１８５％のｄ−リモネンに５％のレモン
系香料配合
１ ２１〜２５ １ ９５％のｄ−リモネンにＤＤＶ
Ｐ２％配合
尚、次表における固型物の硬さは、直径１１ａ＋ｆｆｌ
。Table-1 Solidified product A, castor oil B, hydrogenated castor oil C as castor oil derivative, hydrogenated beef tallow as hydrogenated oil, stearic acid E as fatty acid, behenic acid F as distilled fatty acid, hydrogenated beef tallow methyl as esterified fatty acid Ester G, NaH stearate as metal salt of fatty acid, lauryl alcohol as higher aliphatic alcohol, IR Nippon Zeon 2200J as raw rubber, polystyrene as carnauba wax L1 as vegetable natural wax, ethylene bisamide as acid amide. -2 Aromatic component examples 1-5 95% purity d-IJ monene l 6
~10 1 85% l 11~15 #5 to 95 d-limonene
% lemon flavoring 16-20 185% d-limonene and 5% lemon flavoring 1 21-25 1 95% d-limonene and DDV
Contains 2% P.The hardness of the solid in the following table is 11a+ffl.
.
厚さ１０ｆｌの円盤状のものに、２ Ｋ９の分銅をのせ
た時全くこわれないものを充分とした。A 10fl thick disc-shaped material that would not break at all when a 2 K9 weight was placed on it was considered sufficient.
実施例 １２３４５６７８
芳香成分１００１００１００１００１００１００１００
１００ＬＬＤＰＥ １０ １０ ８ １５ １０
− − ５ボｌＪ７’ｉ：＋ヒＬり／ −
−−−−−２０１０Ａ−５−−−−−−−
Ｂ−−５−−〜 −５
Ｃ−−−１０−−−−
Ｄ −−−−−１０１５−−硬 さ 充分
充分 充分 充分 充分 充分 充分 充分実施例
９ １０ １１ １２ １３ １４ １５ １６芳香成
分１．００１００１００１００１００１００１００１０
０ＬＬＤＰＥ ５ ８ １０ ５ ５ −
− ５ポリフ゛ロヒ１イｙ −−−−５１
０１０５Ｅ １０ − − −−
５ − −− −−Ｆ
−７−−−１０−−−
Ｇ −−１０−−−５−
Ｈ−−−−１５−−−−７
硬 さ 充分 充分 充分 充分 充分 充分 充分
充分実施例 １７１８１９２０２１２２２３２４２５
芳香成分１００１００１００１００１００１００１００
１００１００ＬＬＤＰＥ ７ １０ １０ １０
８ − − ５ −ボリフｂビンン −
−−−−−−１０１０−５Ｂ −−−
−−−−−−−５５Ｉ ２−−− −
− −− − −Ｊ −５−−−−−
７−−
Ｋ ５−一一一一−Ｌ
−−−−５−５−−−−−ポリエチレン −−−
−−７−−−−５５硬 さ 充分 充分 充分 充
分 充分 充分 充分 ブ紛 充外上記各固型化物は全
（離漿現象がみられず適当な揮発速度を有［７，２０℃
の室温に２０日間以上放置した後においても尚充分な芳
香を有していた。Example 12345678 Aromatic component 100100100100100100100
100LLDPE 10 10 8 15 10
- - 5volJ7'i:+HiLri/-
-------2010A-5------ B---5---~ -5 C---10--- D------1015---Hardness Sufficient Sufficient Sufficient Sufficient Sufficient sufficient sufficient example
9 10 11 12 13 14 15 16 Aromatic component 1.0010010010010010010010
0LLDPE 5 8 10 5 5 −
- 5 Polymorphy 1 ----51
0105E 10 - - --
5 - - - -F
-7--10--- G--10--5- H----15--7 Hardness Sufficient Sufficient Sufficient Sufficient Sufficient Sufficient Sufficient Example 171819202122232425
Aromatic ingredients 100100100100100100100
100100LLDPE 7 10 10 10
8 - - 5 - Borif b binn -
------1010-5B ---
---------55I 2-----
− −− − −J −5−−−−−
7-- K 5-1111-L
-----5-5----Polyethylene ---
--7-----55 Hardness Sufficient Sufficient Sufficient Sufficient Sufficient Sufficient Bladder All of the above solidified products (no syneresis phenomenon and appropriate volatilization rate [7, 20℃
Even after being left at room temperature for 20 days or more, it still had a sufficient aroma.
出願人 タカビシ化学株式会社 代理人 滝 川 敏 雄Applicant: Takabishi Chemical Co., Ltd. Agent Toshio Takigawa
Claims (1)
下記Ｉまたは■または川とを加熱混合し冷却することを
特徴とする固型発番組成物の製法。 １、 （ｉ） 中低圧型合法直鎖状ポリエチレン（以
下ＬＬＤＰＥという） （１１）ポリプロピレン （面脂肪酸アマイド （（ｉ
ｖ）脂肪酸アマイドとポリエチレンの混合物 上記（ｉ）〜（１ｖ）から選ばれる一種。
（Ｉｌ、ＬＬＤＰＥと下記（ａ）〜（１）から選ばレル
一種またに二種以上との混合物。 （ａ）ヒマシ油、（ｂ）ヒマシ油誘導体、（ｃ）硬化油
、 ３、（ｄ）脂肪酸、（ｅ）蒸留脂肪酸、（ｆ）Ｊ脂
肪酸のニス族アルコール、（ｉ）生ゴム、（ｊ）ポリス
チロール、（ｋｌ Ｍ物系天然ワックス、（１）脂肪酸
アマイド ■、ポリプロピレンと下記（ａ）〜−から選ばれる一種
または二種以上との混合物。 （ａ）ヒマシ油、（ｂ）ヒマシ油誘導体、（ｃ）硬化油
、（ｄ）脂肪酸、（ｅ）蒸留脂肪酸、（ｆ）脂肪酸のエ
ステル化物、（ロ））脂肪酸の金属塩、（ｈ）高級脂肪
族アルコール、（ｉ）生ゴム、（Ｊ）ポリスチロール、
（ｋ）他物系天然ワックス、（１）脂肪酸アマイド、（
ホ）ポリエチレン ２）芳香成分に調合香料または香料原油が含有されてい
る特許請求の範囲第１項記載の固型発番組成物の製法。 ３）芳香成分に揮発性殺虫剤が含有されている特許請求
の範囲第１項または第２項記載の固型発香組成物の製法
。[Scope of Claims] (1) A method for producing a solid explosive product, which comprises heating and mixing an aromatic component mainly consisting of volatile terpene hydrocarbons with the following I, (2) or (2), and then cooling the mixture. 1. (i) Medium and low pressure type legal linear polyethylene (hereinafter referred to as LLDPE) (11) Polypropylene (plane fatty acid amide ((i)
v) Mixture of fatty acid amide and polyethylene A type selected from the above (i) to (1v).
(Il, a mixture of LLDPE and one or more compounds selected from the following (a) to (1). (a) Castor oil, (b) Castor oil derivative, (c) Hydrogenated oil, 3, (d) Fatty acid, (e) distilled fatty acid, (f) J fatty acid varnish group alcohol, (i) crude rubber, (j) polystyrene, (kl M-based natural wax, (1) fatty acid amide ■, polypropylene and the following (a) A mixture with one or more selected from - (a) castor oil, (b) castor oil derivative, (c) hydrogenated oil, (d) fatty acid, (e) distilled fatty acid, (f) ester of fatty acid (b) Metal salts of fatty acids, (h) higher aliphatic alcohols, (i) crude rubber, (J) polystyrene,
(k) Other natural wax, (1) Fatty acid amide, (
e) Polyethylene 2) The method for producing a solid extrusion product according to claim 1, wherein the aromatic component contains a blended fragrance or a fragrance crude oil. 3) A method for producing a solid fragrance composition according to claim 1 or 2, wherein the fragrance component contains a volatile insecticide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57120270A JPS5911860A (en) | 1982-07-09 | 1982-07-09 | Production of solid aromatic composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57120270A JPS5911860A (en) | 1982-07-09 | 1982-07-09 | Production of solid aromatic composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5911860A true JPS5911860A (en) | 1984-01-21 |
| JPH0337948B2 JPH0337948B2 (en) | 1991-06-07 |
Family
ID=14782061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57120270A Granted JPS5911860A (en) | 1982-07-09 | 1982-07-09 | Production of solid aromatic composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5911860A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59115347U (en) * | 1983-01-24 | 1984-08-03 | ジエコ−株式会社 | Drive wheel tachometer |
-
1982
- 1982-07-09 JP JP57120270A patent/JPS5911860A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59115347U (en) * | 1983-01-24 | 1984-08-03 | ジエコ−株式会社 | Drive wheel tachometer |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0337948B2 (en) | 1991-06-07 |
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