JPS5895899A - Plastic housing with electromagnetic shielding characteristic - Google Patents
Plastic housing with electromagnetic shielding characteristicInfo
- Publication number
- JPS5895899A JPS5895899A JP19483481A JP19483481A JPS5895899A JP S5895899 A JPS5895899 A JP S5895899A JP 19483481 A JP19483481 A JP 19483481A JP 19483481 A JP19483481 A JP 19483481A JP S5895899 A JPS5895899 A JP S5895899A
- Authority
- JP
- Japan
- Prior art keywords
- conductive
- electromagnetic shielding
- layer
- core layer
- plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004033 plastic Substances 0.000 title claims description 15
- 229920003023 plastic Polymers 0.000 title claims description 15
- 239000010410 layer Substances 0.000 claims description 15
- 239000012792 core layer Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 230000000694 effects Effects 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 3
- -1 flakes Substances 0.000 claims description 3
- 239000011231 conductive filler Substances 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 239000004020 conductor Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 8
- 239000007787 solid Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000011162 core material Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004616 structural foam Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
この発明は、電磁波シールド効果を有するプラスチック
製筐体に関するものであって、産業用、事務用、家庭用
、その他の電子機器を収容するハウジング材として、電
磁波遮蔽効果を有するプラスチック製筐体を提供するこ
とを目的としてなされたものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a plastic housing having an electromagnetic wave shielding effect, which can be used as a housing material for accommodating industrial, office, household, and other electronic devices. The purpose of this invention is to provide a plastic casing that has the following characteristics.
プラスチック成形筐体は、従来の板金、グイキャスト等
の金属製品に比して、軽量、耐蝕性であること、外観、
感触の良いこと、機器の発する騒音を吸収すること、生
、産コストの低いこと、及び成形の自由性によって、内
部に装着する機器部品の組付、筐体相互の組′立てか自
由にデザインされることによる生産性の向上等多くの特
長を有する為に、その需要は拡大しつつある。Compared to conventional metal products such as sheet metal and guicast, plastic molded casings are lighter, more corrosion resistant, and have better appearance and
Due to its good feel, ability to absorb noise emitted by equipment, low production costs, and freedom of molding, it is possible to freely design the assembly of equipment parts to be installed inside and the assembly of the casing with each other. The demand for it is increasing because it has many features such as improved productivity by being
然し乍ら、プラスチック成形筐体は、電磁波に対する透
過性を有するために、内部の電子機器か発生する電磁波
を透過して、この電磁波による障害を外部に及はす。However, since the plastic molded casing is transparent to electromagnetic waves, the electromagnetic waves generated by the internal electronic equipment are transmitted through it, and the interference caused by the electromagnetic waves is caused to the outside.
又外部からの電磁波を通して、内部の機器に悪影響を受
けることがある。Also, internal equipment may be adversely affected by electromagnetic waves from outside.
又プラスチックは電気絶縁性であるために、静電気が蓄
積し、機器の正常な動作を妨害する等の問題がある。Furthermore, since plastic is electrically insulating, static electricity accumulates, which can interfere with the normal operation of equipment.
現在一般に実施されている電磁波をシールドする方法と
しては、筐体内面のアルミニュームを主とする真空蒸着
、スパッタリング、イオンブレーティング等によるメタ
ライジング。銀、銅、ニッケル等による電解メッキ。亜
鉛を主とする金属溶射によるメタライジング、或は銀、
銅、ニッケル、グラファイト、カーボンブラング等の電
導性粉末を多量に混合した導電性塗料による筐体内面の
塗装等が行われているが、これ等は何れも、導電性表層
を2次的にプラスチック筐体表面に形成させる方法であ
って、これ等の方法は、シールド処理が成形工程と別工
程となり、高価な設備や特殊技術が要求されるばかりで
なく、特に形状が複雑化するにつれて、生産性が低下し
、著しいコストの上昇を来たす。Currently, methods for shielding electromagnetic waves that are generally practiced include metallizing the inner surface of the housing using aluminum, mainly by vacuum evaporation, sputtering, ion blasting, etc. Electrolytic plating with silver, copper, nickel, etc. Metallizing by metal spraying mainly consisting of zinc, or silver,
The inner surface of the casing is coated with a conductive paint containing a large amount of conductive powder such as copper, nickel, graphite, carbon bran, etc. However, in all of these methods, the conductive surface layer is These methods require shielding treatment to be a separate process from the molding process, and not only require expensive equipment and special techniques, but also as the shape becomes more complex. Productivity decreases and costs rise significantly.
更に導電層の剥離、脱落等による内部電子機器の短絡等
の危険性、シールド効果の経年低下、或いは工場作業に
おける労働安室衛生面で好ましくない等多くの問題があ
る。Furthermore, there are many other problems, such as the danger of short-circuiting of internal electronic equipment due to peeling or falling off of the conductive layer, deterioration of shielding effectiveness over time, and undesirable sanitary conditions in labor safety rooms during factory work.
又他方に於て、導電性の繊維、フレーク、粒子、 等
を多量に充填した熱硬化性コンパウンドを用いたSMC
,BMC等による圧縮成形品や、熱可塑性成形材料を用
いた導電性成形品も開発されていて、これ等の成形品は
、成形品自体が導電化されているので、2次的な導電化
処理が不要であるから、生産性は向上するが、一方圧綿
成形による筐体は成形技術上形状に制約があり、熱可塑
性コンパウンドの射出成形に比較して極めて非能率的で
あって、特殊な用途の場合に限定される。On the other hand, SMC using a thermosetting compound filled with a large amount of conductive fibers, flakes, particles, etc.
, Compression molded products using BMC, etc., and conductive molded products using thermoplastic molding materials have also been developed, and since the molded products themselves are electrically conductive, these molded products cannot be made secondary to electrical conductivity. Since no processing is required, productivity is improved, but on the other hand, the shape of the casing made by compression molding is limited due to the molding technology, and it is extremely inefficient compared to injection molding of thermoplastic compound, and special limited to specific uses.
又、通常の熱可塑性射出成形品は、生産性に優れ安価に
量産されるが、筐体のような大型成形品は、反り、歪み
が生じ易く、特にリブやボスの存在する形状においては
、ひけによる外観の不良化が避けられない。この為大型
筐体には、低発泡射出成形法による構造用発泡体(S、
F)が採用される。In addition, normal thermoplastic injection molded products have excellent productivity and can be mass-produced at low cost, but large molded products such as housings are prone to warping and distortion, especially in shapes with ribs and bosses. Poor appearance due to sink marks is unavoidable. For this reason, the large casing is made of structural foam (S,
F) is adopted.
この成形法は材料の発泡によりキャビティを充たし、同
時にキャビティ表面にインテグラルスキン層を形成させ
る方法であるから、型内圧か低く、成形品のひけ、歪み
等は防止できるが、この方法による発泡成形品の表面は
発泡模様を帯びた肌の粗い幾分多孔質となり、然も全体
に導電材料を多量含有させた場合は著しく外観を損い、
仕上塗装を必須とする。更に上記いづれの成形法も筐体
全体に多量の導電材料を混入したコンパウンドを使用す
るために、コスト高、機械的強度の低下を免れない。This molding method fills the cavity by foaming the material and at the same time forms an integral skin layer on the cavity surface, so the pressure inside the mold is low and it is possible to prevent sink marks and distortion of the molded product. The surface of the product becomes rough and somewhat porous with a foam pattern, and if the entire product contains a large amount of conductive material, the appearance will be significantly impaired.
Finish painting is required. Furthermore, in any of the above-mentioned molding methods, a compound containing a large amount of conductive material is used for the entire casing, resulting in high costs and a decrease in mechanical strength.
以−ヒが従来法の技術的概要であるが、この発明は、上
記の様な従来法の欠点を解決することによって、優れた
電磁波シールド特性を有すると共に、極めて生産性の高
いプラスチック筐体を完成したものである。The following is a technical overview of the conventional method. By solving the above-mentioned drawbacks of the conventional method, this invention provides a plastic casing that has excellent electromagnetic shielding properties and is highly productive. It is completed.
以下この発明の構成を詳しく説明する。The configuration of this invention will be explained in detail below.
この発明に係る電磁波シールド特性を有するプラスチッ
ク筐体は、図面に示すように、導電材料を含まない非発
泡(ソリッド状)のスキン層lをもって導電材料を多量
に含有し1.05〜1.5倍に発泡させたコア層2の全
表面を被覆した構造を有するものであって、ソリッドス
キン層1、発泡コア層2、共に熱可塑性プラスチックよ
りなるものである。As shown in the drawings, the plastic casing having electromagnetic shielding properties according to the present invention has a non-foamed (solid) skin layer l that does not contain any conductive material, and contains a large amount of conductive material with a thickness of 1.05 to 1.5. It has a structure in which the entire surface of a core layer 2 which has been foamed to double its original size is covered, and both the solid skin layer 1 and the foamed core layer 2 are made of thermoplastic plastic.
この電磁波シールド特性を有する筐体の製造は、例えば
Battenfeld Maschienenfab
riken’GmbH(西ドイツ)社製の多成分射出成
形機を用い、ソリッドスキン用材料として着色または非
着色の熱可塑性材料と、コア材料として発泡剤を含むか
あるいは含まない熱可塑性材料に導電性効果の高い充填
剤を混練したものを用い、表面をソリッドスキン層で被
覆し、内部を導電性を有するコアとする断面サンドイッ
チ状の成形を行うことによって可能となる。The manufacture of the housing having this electromagnetic shielding property is carried out by, for example, Battenfeld Maschienenfab.
Using a multicomponent injection molding machine manufactured by Riken'GmbH (West Germany), conductive effects were applied to colored or unpigmented thermoplastic materials as solid skin materials and thermoplastic materials with or without blowing agents as core materials. This is made possible by using a material kneaded with a filler having a high viscosity, covering the surface with a solid skin layer, and molding it into a cross-sectional sandwich shape with a conductive core inside.
この場合2成分の射出はスキン、コアを逐次的に行うこ
とも、僅かにスキンを先行射出しその後2成分を同時射
出することも任意であるっ尚サンドイッチ状構成の成形
機並ひに成形技術については、既に例えは MODER
N PLASTIC■NTERNATIONAL6〔7
〕42−44(1976)。In this case, the injection of the two components may be carried out sequentially for the skin and the core, or it is optional to inject the skin slightly first and then inject the two components simultaneously. Regarding MODER, we have already given an example.
N PLASTIC■NTERNATIONAL6 [7
] 42-44 (1976).
同じ< 10 (3) 18−21 (1980)、
JOURNALOF CELLULARPLASTIC
5、March/ Apri194−97 (1979
)、 PLASTIC5MACHINERY& EQU
IPMENT’9 (2) 9−17 (1980)、
等の刊行物文献に記載されて公知である。Same < 10 (3) 18-21 (1980),
JOURNAL OF CELLULAR PLASTIC
5, March/Apri194-97 (1979
), PLASTIC5MACHINERY & EQU
IPMENT'9 (2) 9-17 (1980),
It is described in publications such as et al.
ここに、ソリッドスキン層形成材料としては、低発泡コ
ア層材料と接着性があって硬化収縮挙動が類似したもの
であり、射出成形に適する熱可塑性樹脂ならば可であっ
て、ポリカーボネート、変性PPO、ポリアミド、等の
エンジニアリングプラスチックから、汎用のポリオレフ
ィン、ポリスチレン等まで各種のものが実用されるが、
外観の美しさ、機械的強度、化学耐性、電気特性等を勘
案し用途に応じて選択することが出来る。Here, the material for forming the solid skin layer may be any thermoplastic resin that has adhesive properties and similar curing shrinkage behavior to the material for the low foam core layer and is suitable for injection molding, including polycarbonate and modified PPO. Various materials are used in practical use, from engineering plastics such as , polyamide, etc. to general-purpose polyolefins, polystyrene, etc.
It can be selected depending on the application, taking into consideration the beauty of appearance, mechanical strength, chemical resistance, electrical properties, etc.
又低発泡コア層成形材料としては、スキン層材料と接着
性がよく、混和される導電材料とよく混合し導電性を良
くする樹脂を用いる。As the material for forming the low-foam core layer, a resin is used that has good adhesion to the skin layer material and mixes well with the conductive material to be mixed to improve conductivity.
低発泡コア層に混合充填される導電性材料としては、ア
ルミニューム、銅、ニッケル、等の金属繊維、金属フレ
ーク、金属粒子、金属コートガラス繊維、グラファイト
、カーボンブランク、等を使用することが出来る。As the conductive material mixed and filled in the low foam core layer, metal fibers such as aluminum, copper, nickel, etc., metal flakes, metal particles, metal coated glass fibers, graphite, carbon blank, etc. can be used. .
これらは、導電材料の種類、発泡倍率及び電磁界強度の
減衰率を考慮して、コンパウンド中に20−60%を充
填する。These are filled in the compound at 20-60%, taking into account the type of conductive material, the expansion ratio and the attenuation rate of the electromagnetic field strength.
以上述べた様に、2成分射出成形法によって成形され、
上記の様な構造をもつ電磁波シールド特性を有するプラ
スチック筐体は、通常の1成分射出成形品と同様に、表
面卑情でピンホール、気泡等がなく、しかもひけ、反り
、歪み等がなく、更にソリッドスキン層には、導電性材
料を含有しないから、導電性材料に基づく着色、変色等
が無い。As mentioned above, it is molded by two-component injection molding method,
The plastic casing, which has electromagnetic shielding properties and has the structure described above, has a smooth surface with no pinholes or bubbles, and is free from sink marks, warping, distortion, etc., just like ordinary one-component injection molded products. Furthermore, since the solid skin layer does not contain a conductive material, there is no coloring or discoloration caused by the conductive material.
従って外観に全く影響を与えることなく、シールド効果
を発揮させることが出来、仕上塗装等の2次処理を要求
されてコストアップに連ることか無い。Therefore, the shielding effect can be exerted without affecting the appearance at all, and there is no need for secondary treatment such as finish painting, which would lead to an increase in cost.
又、導電層か内部コア層に限定され、表面に露出しない
ために、導電層の酸化による電磁波シールド効果の経年
低下を起すことが無く、2次的に付着させた導電層の様
に剥離脱落によって内部機器回路の短絡等を惹起する恐
れもない。。In addition, since the conductive layer is limited to the inner core layer and is not exposed to the surface, the electromagnetic shielding effect does not deteriorate over time due to oxidation of the conductive layer, and it does not peel off like a secondary conductive layer. Therefore, there is no risk of short-circuiting of internal equipment circuits. .
又コスト高の導電性材料の使用量か、コア層のみに限定
されるので大巾に削減される。Furthermore, the amount of expensive conductive material used is limited to only the core layer, which greatly reduces the amount of use.
更に内部に有効な導電層を有しているから、端子を用い
て接地することが容易となる。Furthermore, since it has an effective conductive layer inside, it is easy to ground it using a terminal.
即ち以上の様な数々の特長を有するプラスチック筐体が
、2成分射出成形法を用いてl工程によって極めて高い
生産性の下に製造されることか本発明の特徴とするとこ
ろである。That is, a feature of the present invention is that the plastic casing having the numerous features described above can be manufactured in one step with extremely high productivity using the two-component injection molding method.
本発明に係る電磁波シールド特性を有するプラスチック
筐体の縦断面斜視図である。
図中
1・・・ソリッドスキン層、
2・・・導電材料を充填した発泡コア層。
図 面
1FIG. 1 is a vertical cross-sectional perspective view of a plastic casing having electromagnetic shielding properties according to the present invention. In the figure, 1: Solid skin layer, 2: Foamed core layer filled with conductive material. Drawing surface 1
Claims (1)
り被覆した構造を有するプラスチック成形筐体において
、前記コア層に、繊維状、フレーク状又は、粒状等の導
電性充填剤を含有した材料を用い、全コア層を導電層と
し電磁波シールド効果を賦与したプラスチック成形筐体
。In a plastic molded casing having a structure in which the entire surface is covered with a foamed core layer with a non-foamed skin layer, the core layer is made of a material containing a conductive filler in the form of fibers, flakes, or granules. , a plastic molded casing whose entire core layer is a conductive layer, giving it an electromagnetic shielding effect.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19483481A JPS5895899A (en) | 1981-12-02 | 1981-12-02 | Plastic housing with electromagnetic shielding characteristic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19483481A JPS5895899A (en) | 1981-12-02 | 1981-12-02 | Plastic housing with electromagnetic shielding characteristic |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5895899A true JPS5895899A (en) | 1983-06-07 |
Family
ID=16331034
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP19483481A Pending JPS5895899A (en) | 1981-12-02 | 1981-12-02 | Plastic housing with electromagnetic shielding characteristic |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5895899A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60138997A (en) * | 1983-12-26 | 1985-07-23 | 三菱電線工業株式会社 | Composition for shielding electromagnetic wave |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5473300A (en) * | 1977-11-24 | 1979-06-12 | Toray Industries | Radio shield material |
JPS5825098B2 (en) * | 1974-03-22 | 1983-05-25 | ロ−ム アンド ハ−ス カンパニ− | Polyene Kabinyl Foam Fragile Polyene Kabinyl Foam Oshidashihou Oyobi Fragile Polyene Kabinyl Foam |
-
1981
- 1981-12-02 JP JP19483481A patent/JPS5895899A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5825098B2 (en) * | 1974-03-22 | 1983-05-25 | ロ−ム アンド ハ−ス カンパニ− | Polyene Kabinyl Foam Fragile Polyene Kabinyl Foam Oshidashihou Oyobi Fragile Polyene Kabinyl Foam |
JPS5473300A (en) * | 1977-11-24 | 1979-06-12 | Toray Industries | Radio shield material |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60138997A (en) * | 1983-12-26 | 1985-07-23 | 三菱電線工業株式会社 | Composition for shielding electromagnetic wave |
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