JPS586724B2 - Now that you know it, it's time to move on. - Google Patents
Now that you know it, it's time to move on.Info
- Publication number
- JPS586724B2 JPS586724B2 JP49126632A JP12663274A JPS586724B2 JP S586724 B2 JPS586724 B2 JP S586724B2 JP 49126632 A JP49126632 A JP 49126632A JP 12663274 A JP12663274 A JP 12663274A JP S586724 B2 JPS586724 B2 JP S586724B2
- Authority
- JP
- Japan
- Prior art keywords
- inert gas
- concentration
- distillation
- gas
- know
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011261 inert gas Substances 0.000 claims description 13
- 238000004821 distillation Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000003208 petroleum Substances 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 238000007664 blowing Methods 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 6
- 238000009835 boiling Methods 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 238000001256 steam distillation Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Description
【発明の詳細な説明】
本発明は濃縮または蒸留を効果的に行なう方法に関する
ものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for effectively carrying out concentration or distillation.
従来、高沸点を有する物質または熱的に不安定な物質の
濃縮及び蒸留には、減圧蒸留または水蒸気蒸留などの方
法が用いられてきた。Conventionally, methods such as vacuum distillation or steam distillation have been used to concentrate and distill substances with high boiling points or thermally unstable substances.
しかし、水分を嫌う物質を含有する場合や親水性の強い
物質を含む場合には水蒸気蒸留法は使用できす、また、
減圧蒸留法は、装置が複雑となること、排気ガス中に被
蒸留物の一部が混入し、これらが大気中に逸散し環境汚
染を来たす等の欠点がある。However, steam distillation cannot be used when containing substances that dislike moisture or containing highly hydrophilic substances.
The vacuum distillation method has drawbacks such as a complicated apparatus and a part of the distillate mixed into the exhaust gas, which is dissipated into the atmosphere and causes environmental pollution.
本発明者らは、例えば、石油留分を重合して得る、高沸
点分を含む石油樹脂留分を濃縮または蒸留して石油樹脂
を得る方法として、これらの欠点のない方法を種々検討
した結果、濃縮または蒸留の系内に不活性ガスを循環さ
せ、かつ濃縮缶または蒸留缶の底部より該不活性ガスを
吹込みながら濃縮または蒸留を行なうことにより、効率
良く濃縮または蒸留をなし得ることを見出した。The present inventors have investigated various methods that do not have these drawbacks, for example, as a method for obtaining petroleum resin by concentrating or distilling a petroleum resin fraction containing high boiling points obtained by polymerizing petroleum fractions. It has been shown that concentration or distillation can be carried out efficiently by circulating an inert gas in the concentration or distillation system and performing concentration or distillation while blowing the inert gas into the bottom of the concentration or distillation can. I found it.
以下、図面により本発明をさらに詳細に説明する。Hereinafter, the present invention will be explained in more detail with reference to the drawings.
第１図は、本発明の一実施態様に用いる回分式濃縮装置
の経路図である。FIG. 1 is a route diagram of a batch concentrator used in one embodiment of the present invention.
原料仕込管１により濃縮搭２に一定量の原料を仕込み、
ガス吹込ノズル３より不活性ガスを吹込む。A certain amount of raw material is charged into the concentration tower 2 through the raw material supply pipe 1,
Inert gas is blown from the gas blowing nozzle 3.
不活性ガスは、用いる原料に不活性なガスで通常窒素ガ
スが用いられる。The inert gas is a gas inert to the raw materials used, and nitrogen gas is usually used.
凝縮器４で留出物を凝縮し、受槽５で不活性ガスと留出
物を分離して、留出液ポンプ６で留出物抜出管７から留
出物を抜き出す。The distillate is condensed in a condenser 4, the inert gas and the distillate are separated in a receiver tank 5, and the distillate is extracted from a distillate extraction pipe 7 with a distillate pump 6.
一方不活性ガスは、循環管８を通して循環し調圧弁９で
圧調整を行う、もし設定圧以下になれば不活性ガスを吹
込みつ匁、循環ポンプ１０で不活性ガスを送り、設定圧
以上になった場合は調圧弁１１でガスをパージし、流量
調節弁１２で不活性ガスの流量を調節する。On the other hand, the inert gas is circulated through the circulation pipe 8 and the pressure is adjusted by the pressure regulating valve 9. If the pressure is below the set pressure, inert gas is blown in and the circulation pump 10 is used to send the inert gas so that the pressure is higher than the set pressure. If this occurs, the pressure regulating valve 11 purges the gas, and the flow rate regulating valve 12 regulates the flow rate of the inert gas.
また循環ガスは加熱器１３で温度を調節してノズル３よ
り吹込む。Further, the temperature of the circulating gas is adjusted by a heater 13 and then blown through the nozzle 3.
搭の温度は加熱器１４で調節し、缶部が所定の濃度にな
ったらタップ配管１５よりタップする。The temperature of the tower is adjusted by a heater 14, and when the can part reaches a predetermined concentration, it is tapped from a tap pipe 15.
第１図は回分式濃縮搭を示したものであるがこれと同様
の装置を数段直列に繋ぐことにより多段式連続濃縮を行
うことも可能である。Although FIG. 1 shows a batch type concentrator, it is also possible to perform multistage continuous concentration by connecting several stages of similar equipment in series.
又、不活性ガスの流量を精密に制御すること及び循環ガ
ス濃度を精密に制御することにより糸外に循環ガスを放
出することなく経済的運転が可能である。Furthermore, by precisely controlling the flow rate of the inert gas and the concentration of the circulating gas, economical operation is possible without releasing the circulating gas outside the yarn.
本発明は被濃縮物または被蒸留物の性質を損なうことな
く濃縮または蒸留を行うことができる。The present invention allows concentration or distillation to be performed without impairing the properties of the concentrate or distillate.
又、おおむね密閉系で行うため例えば有機低沸点物など
が大気中に逸散することがない。Furthermore, since the process is generally carried out in a closed system, organic low-boiling substances, for example, do not escape into the atmosphere.
次に実施例で本発明を詳述する。Next, the present invention will be explained in detail with reference to Examples.
実施例、比較例
樹脂濃度５７．８％（他は石油成分）の石油樹脂重合液
の濃縮を第１図に示した装置を用いて行った。Examples and Comparative Examples A petroleum resin polymer solution having a resin concentration of 57.8% (the rest being petroleum components) was concentrated using the apparatus shown in FIG.
重合液５００ｇを濃縮缶に仕込み、マントルヒーターで
加熱した。500 g of the polymerization liquid was placed in a concentrator and heated with a mantle heater.
一方、２００℃に保った窒素ガスをガス吹込ノズルから
５１．５ｇ−ｍｏｌ／時の速度で濃縮缶に吹込み、重合
液をパブリングしながら７０分間濃縮した。On the other hand, nitrogen gas maintained at 200° C. was blown into the concentrator at a rate of 51.5 g-mol/hour from a gas blowing nozzle, and the polymerization solution was concentrated for 70 minutes while bubbling.
搭頂、搭底の温度及び缶の重合液の樹脂濃度の経時変化
を表−１に示した。Table 1 shows the changes in temperature at the top and bottom and the resin concentration of the polymerization liquid in the can over time.
又比較例として、加熱窒素ガスの代りに水蒸気（２００
℃）を用いて行った結果を同表に示した。In addition, as a comparative example, water vapor (200
The results were shown in the same table.
又、濃縮物は、ガードナー色相計で測定した結果いずれ
も５であった。The concentrates were all rated at 5 when measured using a Gardner hue meter.
この結果から、通常、水蒸気蒸留にて行う物質について
本発明の方法で行えば、これと同等の品質が簡便に得ら
れることが判る。This result shows that the same quality can be easily obtained by using the method of the present invention for substances that are normally subjected to steam distillation.
Claims (1)
または蒸留をおこなうに当り、濃縮缶または蒸留缶の底
部より不活性ガスを吹込みながら、かつ系内を該不活性
ガスで置換し、該不活性ガスを循環させてこれを行うこ
とを特徴とする濃縮または蒸留方法。1. When concentrating or distilling a petroleum resin solution obtained by polymerizing petroleum fractions, while blowing an inert gas from the bottom of the concentrator or distillation can, and replacing the inside of the system with the inert gas, A concentration or distillation method characterized in that this is carried out by circulating the inert gas.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP49126632A JPS586724B2 (en) | 1974-11-05 | 1974-11-05 | Now that you know it, it's time to move on. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP49126632A JPS586724B2 (en) | 1974-11-05 | 1974-11-05 | Now that you know it, it's time to move on. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5152981A JPS5152981A (en) | 1976-05-11 |
| JPS586724B2 true JPS586724B2 (en) | 1983-02-05 |
Family
ID=14939983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP49126632A Expired JPS586724B2 (en) | 1974-11-05 | 1974-11-05 | Now that you know it, it's time to move on. |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS586724B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS589667B2 (en) * | 1977-04-13 | 1983-02-22 | ヤマサ醤油株式会社 | How to make rich soy sauce |
| JPS59209601A (en) * | 1983-05-16 | 1984-11-28 | Kuri Kagaku Sochi Kk | Evaporative distillation apparatus using inert gas |
| JPS6090002A (en) * | 1983-10-24 | 1985-05-21 | Mitsui Toatsu Chem Inc | Distillating method |
| HUP1100435A2 (en) * | 2011-08-12 | 2013-04-29 | Hyd Rakkutato Es Gyogyszerfejlesztoe Kft | Apparatus and method for distillation of liquids with different boiling point |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US310510A (en) * | 1885-01-06 | Toggle |
-
1974
- 1974-11-05 JP JP49126632A patent/JPS586724B2/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US310510A (en) * | 1885-01-06 | Toggle |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5152981A (en) | 1976-05-11 |
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