JPS5851926A - Method for thickening emulsion - Google Patents
Method for thickening emulsionInfo
- Publication number
- JPS5851926A JPS5851926A JP56149095A JP14909581A JPS5851926A JP S5851926 A JPS5851926 A JP S5851926A JP 56149095 A JP56149095 A JP 56149095A JP 14909581 A JP14909581 A JP 14909581A JP S5851926 A JPS5851926 A JP S5851926A
- Authority
- JP
- Japan
- Prior art keywords
- emulsion
- acid
- oil
- viscosity
- polyhydric alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims abstract description 8
- 230000008719 thickening Effects 0.000 title claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 12
- 229930195729 fatty acid Natural products 0.000 claims abstract description 12
- 239000000194 fatty acid Substances 0.000 claims abstract description 12
- -1 fatty acid ester Chemical class 0.000 claims abstract description 12
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 9
- 230000002378 acidificating effect Effects 0.000 claims abstract description 8
- 239000008346 aqueous phase Substances 0.000 claims abstract description 5
- 229930006000 Sucrose Natural products 0.000 claims description 9
- 239000005720 sucrose Substances 0.000 claims description 9
- 239000007764 o/w emulsion Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 abstract description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract description 6
- 239000007787 solid Substances 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract description 4
- 150000001413 amino acids Chemical class 0.000 abstract description 3
- 239000006071 cream Substances 0.000 abstract description 3
- 235000019260 propionic acid Nutrition 0.000 abstract description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 abstract description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- 238000010979 pH adjustment Methods 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- QNAYBMKLOCPYGJ-UHFFFAOYSA-N Alanine Chemical compound CC([NH3+])C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 229940024606 amino acid Drugs 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- OIKBVOIOVNEVJR-UHFFFAOYSA-N hexadecyl 6-methylheptanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCC(C)C OIKBVOIOVNEVJR-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 229940032094 squalane Drugs 0.000 description 2
- QIJRTFXNRTXDIP-UHFFFAOYSA-N (1-carboxy-2-sulfanylethyl)azanium;chloride;hydrate Chemical compound O.Cl.SCC(N)C(O)=O QIJRTFXNRTXDIP-UHFFFAOYSA-N 0.000 description 1
- QZNNVYOVQUKYSC-JEDNCBNOSA-N (2s)-2-amino-3-(1h-imidazol-5-yl)propanoic acid;hydron;chloride Chemical compound Cl.OC(=O)[C@@H](N)CC1=CN=CN1 QZNNVYOVQUKYSC-JEDNCBNOSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- QIZPVNNYFKFJAD-UHFFFAOYSA-N 1-chloro-2-prop-1-ynylbenzene Chemical compound CC#CC1=CC=CC=C1Cl QIZPVNNYFKFJAD-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000283153 Cetacea Species 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical class NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 1
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 description 1
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 description 1
- QIVBCDIJIAJPQS-VIFPVBQESA-N L-tryptophane Chemical compound C1=CC=C2C(C[C@H](N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-VIFPVBQESA-N 0.000 description 1
- KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- AYFVYJQAPQTCCC-UHFFFAOYSA-N Threonine Natural products CC(O)C(N)C(O)=O AYFVYJQAPQTCCC-UHFFFAOYSA-N 0.000 description 1
- 239000004473 Threonine Substances 0.000 description 1
- QIVBCDIJIAJPQS-UHFFFAOYSA-N Tryptophan Natural products C1=CC=C2C(CC(N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-UHFFFAOYSA-N 0.000 description 1
- KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Natural products CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 description 1
- KGUHOFWIXKIURA-VQXBOQCVSA-N [(2r,3s,4s,5r,6r)-6-[(2s,3s,4s,5r)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy-3,4,5-trihydroxyoxan-2-yl]methyl dodecanoate Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](COC(=O)CCCCCCCCCCC)O[C@@H]1O[C@@]1(CO)[C@@H](O)[C@H](O)[C@@H](CO)O1 KGUHOFWIXKIURA-VQXBOQCVSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- IWWCATWBROCMCW-UHFFFAOYSA-N batyl alcohol Natural products CCCCCCCCCCCCCCCCCCOC(O)CO IWWCATWBROCMCW-UHFFFAOYSA-N 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000008278 cosmetic cream Substances 0.000 description 1
- 229960001305 cysteine hydrochloride Drugs 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229950010030 dl-alanine Drugs 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000003084 food emulsifier Nutrition 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- 235000006109 methionine Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- 235000008729 phenylalanine Nutrition 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940032085 sucrose monolaurate Drugs 0.000 description 1
- 229940035023 sucrose monostearate Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/41—Emulsifying
- B01F23/4105—Methods of emulsifying
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Colloid Chemistry (AREA)
Abstract
Description
【発明の詳細な説明】
本発明はショ糖脂肪酸エステルを含む水中油型エマルシ
ョンの増粘方法に関する０
シヨ糖脂肪酸エステルは食品用乳化剤として広く使用さ
れている。しかしショ糖脂肪酸エステルの乳化力は既存
の合成乳化剤と比較して著しくその性能が劣るため、安
全性が保証されているにもかかわらず食品用途以外には
ほとんど使用されることがない。最近、このようなショ
糖脂肪酸エステルの欠点を解消しつる新しい乳化法が開
発された（特開昭５５−８４５ｓ ２ ）−。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for thickening oil-in-water emulsions containing sucrose fatty acid esters.Sucrose fatty acid esters are widely used as food emulsifiers. However, the emulsifying power of sucrose fatty acid ester is significantly inferior to that of existing synthetic emulsifiers, so it is rarely used for purposes other than food, even though its safety is guaranteed. Recently, a new emulsification method has been developed that overcomes the drawbacks of sucrose fatty acid esters (Japanese Patent Application Laid-Open No. 55-845S2).
この技術の出現により、安全性のすぐれたエマルション
があらゆる分野で製造可能となった。With the advent of this technology, emulsions with excellent safety can be produced in all fields.
この技術は、ショ糖脂肪酸エステル、多価アルコールお
よび油を使用して多価アルコール中油型エマルションを
作シ、これに水相成分を加えて水中油型エマルションと
する方法である。この方法は安全性の高いエマルション
が得られることはもちろん、従来技術に比べ少い乳化剤
量で、微細で均質なエマルションが得られるという特徴
をもっている。しかし、この技術を化粧品に適用してク
リームを作る場合、エマルションが増粘しにくく、クリ
ーム様の形態を得ることが非常にむずかしい。これは、
この技術によって得られるエマルションが非常に微細な
エマルションであること、ショ糖脂肪酸ニステルト多価
アルコールの作る構造が、固形脂の結晶防止作用を有す
ること、および従来の界面活性剤のように水中で界面活
性剤−高級アルコールによる液晶生成が紹められないこ
とに起因するものと思われる。This technique uses sucrose fatty acid ester, polyhydric alcohol, and oil to prepare an oil-in-polyhydric alcohol emulsion, and then adds an aqueous phase component to this to form an oil-in-water emulsion. This method has the characteristic that not only a highly safe emulsion can be obtained, but also a fine and homogeneous emulsion can be obtained with a smaller amount of emulsifier than conventional techniques. However, when this technology is applied to cosmetics to make creams, the emulsion is difficult to thicken and it is extremely difficult to obtain a cream-like form. this is,
The emulsion obtained by this technology is a very fine emulsion, the structure created by the sucrose fatty acid nistert polyhydric alcohol has the effect of preventing crystallization of solid fat, and unlike conventional surfactants, it can be used as an emulsion in water. This is thought to be due to the fact that liquid crystal formation using an activator-higher alcohol is not introduced.
杢糸萌者らは、このような欠点を解消すべく鋭意研知を
重ねたところ、エマルションの粘度を高め、クリーム様
の形態を得る新たな増粘方法を見いだした。即ち本発明
は、ショ糖脂肪酸エステル、多価アルコールおよび油よ
り得られる１ｉｆｆｉアルコール中油型エマルシヨンに
水相成分を加えて水中油型エマジョンを製造するに際し
て、有機酸、無機酸、アミノ酸−等の酸性物質を加え、
ｐ）Ｉを４．５〜６．６に調整することにより、エマル
ションを増粘するものである。ｐＨを４．５〜６．６に
調整すると、エマ尤゛ジョンの粘性は著しく上昇［２、
固形脂の少ない系においてもクリーム様の粘性を得るこ
とができる。In order to overcome these drawbacks, Mokuito Moesha and his colleagues worked diligently to find a new thickening method to increase the viscosity of the emulsion and obtain a cream-like form. That is, the present invention involves adding an aqueous phase component to an oil-in-alcohol emulsion obtained from a sucrose fatty acid ester, a polyhydric alcohol, and an oil to produce an oil-in-water emulsion. add the substance,
p) The emulsion is thickened by adjusting I to 4.5 to 6.6. When the pH was adjusted to 4.5-6.6, the viscosity of the emulsion increased significantly [2,
Cream-like viscosity can be obtained even in systems with low solid fat content.
本発明で使用される酸性物質はきわめて少量の添加で効
果が発揮され、多過ぎると粘性灯かえって減少してしま
う０シヨ糖脂肪酸エステルは、酸性領域（ｐＨ４以下）
で凝集し、その界面活性を失うことが知られているが、
本発明では通常系に対して０．０１％〜０．５％程度の
少量の酸性物質を添加してｐＨを４．５〜６．６の弱酸
性に一調整増粘せしめるものであり、ショ糖脂肪酸エス
テ・ルの性能になんら悪影Ｗを及はすものではナイ。従
って本発明のｐＨ領域では、エマルション粒径に太き表
変化は認められない。The acidic substance used in the present invention is effective when added in a very small amount, and if it is added in too much, the viscosity decreases.
is known to aggregate and lose its surface activity.
In the present invention, a small amount of an acidic substance of about 0.01% to 0.5% is added to a normal system to adjust the pH to a weak acidity of 4.5 to 6.6 and increase the viscosity. It should not have any negative impact on the performance of the sugar fatty acid ester. Therefore, in the pH range of the present invention, no change in emulsion particle size is observed.
本発明に使用される酸性物質としては、有機酸、無機酸
、アミノ酸があり、有機酸としては、酢酸、プロピオン
酸、酪酸、リンゴ酸、乳酸、酒石酸、クエン酸、−コハ
ク酸、アクリル酸、ポリアクリル酸などとそれらの酸性
塩があげられ、無機酸としては、￥ｉ酸、硫酸などとそ
れらの酸性塩があげられ、アミノ酸としてはグルタミン
酸、ヒスチジン塩酸塩、ＤＬアラニン、グリシン、スレ
オニン、バリン、トリプトファン、メチオニン、フェニ
ルアラニン、アスパラギン酸、システィン塩酸塩、リジ
ン塩ｆｌＩ／塩などおよびそれらの酸性塩があげられる
。Acidic substances used in the present invention include organic acids, inorganic acids, and amino acids, and organic acids include acetic acid, propionic acid, butyric acid, malic acid, lactic acid, tartaric acid, citric acid, -succinic acid, acrylic acid, Examples include polyacrylic acid and their acid salts; inorganic acids include \i acid, sulfuric acid, and their acid salts; amino acids include glutamic acid, histidine hydrochloride, DL alanine, glycine, threonine, and valine. , tryptophan, methionine, phenylalanine, aspartic acid, cysteine hydrochloride, lysine salt flI/salt, and acid salts thereof.
本発明により増粘されたエマルションは固形脂が少量で
もクリーム様の粘性が得られるため、従来のクリームの
ようにエマルション中の固形脂の結晶化による経時的な
外観、粘性変化が生じないという特徴をもっている。
□以下本発明を実施例について説明する。The emulsion thickened according to the present invention has a cream-like viscosity even with a small amount of solid fat, so unlike conventional creams, the appearance and viscosity do not change over time due to crystallization of the solid fat in the emulsion. have.
□The present invention will be described below with reference to Examples.
実施例１
下記に示す処方にてｆＡＪの多価アルコール中油型エマ
ルションに（Ｂｌの水相成分を加えて水中油型エマルシ
ョ“ンを作シ、之に各種酸性物質を夫々添加した場合の
エマルションの粘性とエマルションの状態を表−１に示
す。表−１よシ酸性物質を０．０１％程度添加すること
によシエマルション粘性が著しく増加することがわかる
。Example 1 An oil-in-water emulsion was prepared by adding an aqueous phase component of fAJ (Bl) to an oil-in-water emulsion of polyhydric alcohol according to the formulation shown below. The viscosity and the state of the emulsion are shown in Table 1.Table 1 shows that the viscosity of the emulsion increases significantly by adding about 0.01% of the acidic substance.
＋Ａｌシヨ糖モノラウリン酸エステル ７．５ｗｔ％
バチルアルコール １．０
グリセリン １５．０
［Ｂｌスクワラン １６．０牛脂脂肪酸トリ
グリセライド ５．０密口９ ５．
０
イソオクタン酸セチル ５．０
セタノール ２．０
イオン交換水で １００
５−
表 −１
＊ 単位センチボイズ、２５Ｃで測定
＊＊ ◎：非常に良好、○；良好
＝ ６−
実施例２
下記に示す処方にてｆＡ＋の多価アルコール中油型エマ
ルションに（Ｂｌを加えて化粧用クリームを作り、酸性
物質添加によるエマルションの粘性変化を調べた０即ち
下記の処方で得られたクリームの粘度は７２００ｃｐ（
ｐＨ７，０）であるが、これにクエン酸を０．０５％添
加してｐＨ６，０としたものは２３０００ｃｐと非常に
粘度が大きくなった。また固形脂が少いため、外観、粘
性に経時変化が認められなかった。+Al sucrose monolaurate 7.5wt%
Batyl alcohol 1.0 Glycerin 15.0 [Bl squalane 16.0 Tallow fatty acid triglyceride 5.0 Close mouth 9 5.
0 Cetyl isooctanoate 5.0 Cetanol 2.0 With ion-exchanged water 100 5- Table 1 * Unit centivoise, measured at 25C ** ◎: Very good, ○: Good = 6- Example 2 For the formulation shown below A cosmetic cream was made by adding (Bl) to an oil-in-polyhydric alcohol emulsion of fA+, and the change in viscosity of the emulsion due to the addition of an acidic substance was investigated.
However, when the pH was adjusted to 6.0 by adding 0.05% citric acid to it, the viscosity became extremely high at 23,000 cp. In addition, since there was little solid fat, no changes in appearance or viscosity over time were observed.
ａ）ホホバ油 １０ｗｔ％ スクワラン １０ イソオクタン酸セチル １０ 鯨ロウ ５ ステアリン酸 １ パチルアルコール １ ショ糖モノステアリン酸エステル ５ シヨ糖モノオレイン酸エステル １ グリセリン ６ （Ｂｌイオン交換水 ５３ ７− １１５−a) Jojoba oil 10wt% Squalane 10 Cetyl isooctanoate 10 Whale wax 5 Stearic acid 1 Patyl alcohol 1 Sucrose monostearate 5 Sucrose monooleic acid ester 1 Glycerin 6 (Bl ion exchange water 53 7- 115-
Claims (1)
られる多価アルコール中油型エマルションに水相成分を
加えて水中油型エマルションを製造するに際して、酸性
物質を添加しエマルションのｐＨを４．５〜６．６に調
整して増粘せしめることを特徴とするエマルションの増
粘方法０Sucrose fatty acid ester, polyhydric alcohol, and oil When producing an oil-in-water emulsion by adding an aqueous phase component to the obtained oil-in-polyhydric alcohol emulsion, an acidic substance is added to adjust the pH of the emulsion to 4.5 to 6. A method for thickening an emulsion characterized by adjusting the viscosity to .6 and increasing the viscosity 0
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56149095A JPS5851926A (en) | 1981-09-21 | 1981-09-21 | Method for thickening emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56149095A JPS5851926A (en) | 1981-09-21 | 1981-09-21 | Method for thickening emulsion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5851926A true JPS5851926A (en) | 1983-03-26 |
Family
ID=15467581
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56149095A Pending JPS5851926A (en) | 1981-09-21 | 1981-09-21 | Method for thickening emulsion |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5851926A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100633022B1 (en) * | 1999-11-15 | 2006-10-11 | 가부시키가이샤 시세이도 | Oil-in-polyhydric alcohol thermal base |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5821086A (en) * | 1981-07-29 | 1983-02-07 | 住友電気工業株式会社 | Composite body of pipe and cable |
-
1981
- 1981-09-21 JP JP56149095A patent/JPS5851926A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5821086A (en) * | 1981-07-29 | 1983-02-07 | 住友電気工業株式会社 | Composite body of pipe and cable |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100633022B1 (en) * | 1999-11-15 | 2006-10-11 | 가부시키가이샤 시세이도 | Oil-in-polyhydric alcohol thermal base |
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