JPS58224438A - Magnetic recording medium - Google Patents
Magnetic recording mediumInfo
- Publication number
- JPS58224438A JPS58224438A JP57106782A JP10678282A JPS58224438A JP S58224438 A JPS58224438 A JP S58224438A JP 57106782 A JP57106782 A JP 57106782A JP 10678282 A JP10678282 A JP 10678282A JP S58224438 A JPS58224438 A JP S58224438A
- Authority
- JP
- Japan
- Prior art keywords
- magnetic recording
- lubricant
- recording medium
- pinholes
- durability
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000314 lubricant Substances 0.000 claims abstract description 15
- 239000010409 thin film Substances 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000010408 film Substances 0.000 abstract description 6
- 229920001296 polysiloxane Polymers 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000000956 alloy Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000696 magnetic material Substances 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 206010041235 Snoring Diseases 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
- G11B5/62—Record carriers characterised by the selection of the material
- G11B5/72—Protective coatings, e.g. anti-static or antifriction
- G11B5/725—Protective coatings, e.g. anti-static or antifriction containing a lubricant, e.g. organic compounds
- G11B5/7253—Fluorocarbon lubricant
Landscapes
- Magnetic Record Carriers (AREA)
- Lubricants (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は金属薄膜型磁気記録媒体に関する0将来の高密
度磁気記録媒体として、メッキ、真空蒸着法、スパッタ
法等によりfjiil造される磁性金属又は合金薄膜が
有望視されている。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to metal thin film magnetic recording media. Magnetic metal or alloy thin films produced by plating, vacuum evaporation, sputtering, etc. are considered to be promising as future high-density magnetic recording media. ing.
金属薄膜としてはFe、NI、Coの合金、これらとc
r等の合金など種々の合金組成のものが提案されている
のまたスパッタ法により製造したC・−Or合金f#膜
は膜面に対して垂直方向1c強い磁気果方性を持つこと
から、原理的にDJ2磁界による記録密度の制限がない
画期的な磁気記録方式である垂直磁気記録(特開11i
352−134706号)に用いる媒体として、早期実
用化の為の研究が各方面で精力的に行なわれている。Metal thin films include alloys of Fe, NI, Co, and c
Various alloy compositions have been proposed, such as alloys such as r, and the C--Or alloy f# film produced by sputtering has a strong magnetic orientation in the direction perpendicular to the film surface. Perpendicular magnetic recording (Unexamined Japanese Patent Publication No. 11i
No. 352-134706), research is being actively conducted in various fields for its early practical application.
しかしながら、これらの金属′NI模型磁気記録媒体は
、記録再生に用いる磁気ヘッドを接触させて相対的に移
動させた場合、摩擦係数が大きい為スティック−スリッ
プ現象が発生する、耐久力がない等の欠陥を有するもの
であった。However, these metal NI model magnetic recording media have problems such as a stick-slip phenomenon occurring due to the large coefficient of friction when the magnetic head used for recording and reproduction is brought into contact and moved relative to each other, and lacks durability. It was defective.
本発明は、係る状況に鑑みて為されたものであり、金属
薄膜型磁気記録媒体に表面で測って、直径φ(1m)と
単位面積当たりの個数N(個/μ−)との積が、CLO
5(μm−(固/μm2)からl15(μm・個/μm
m )の範囲にある微小なピンホールを形成し、該ピン
ホールに醐滑剤を充填したことを特徴とするものである
。本発明によると金属薄膜型磁気記録媒体の耐久性が飛
躍的に向上する。The present invention was made in view of the above situation, and the product of the diameter φ (1 m) and the number N (pieces/μ−) per unit area when measured at the surface of a metal thin film magnetic recording medium is , C.L.O.
5(μm-(solid/μm2) to l15(μm・pieces/μm
It is characterized by forming minute pinholes in the range of m) and filling the pinholes with a lubricant. According to the present invention, the durability of metal thin film magnetic recording media is dramatically improved.
後で詳しく述べるように、ビンホールの直径(平均直径
のこと、以下同じ)と単位面積(μm11当りの個数と
の積が上記範囲にあるときに最良の記録媒体が得られる
ことが分った。上記の積がα05μm個/μml以下の
場合には磁気ヘッドに対する摩擦・摩耗が大きくなり耐
久性が小さくなる。一方、この積が15μm個/μm1
以上になると磁性体に対する非磁性体(i%il滑剤)
の面積比が大きくなりすぎ好ましくない。又ピンホール
の最大径は記録波長よりも十分に小さい必要があり、1
2μm以下にすべきである。As will be described in detail later, it has been found that the best recording medium can be obtained when the product of the diameter (average diameter, same hereinafter) of the via holes and the number of holes per unit area (μm 11) is within the above range. If the above product is less than α05 μm pieces/μml, friction and wear on the magnetic head will increase and durability will decrease.On the other hand, if this product is 15 μm pieces/μm1
Above that, the non-magnetic material (i%il lubricant) against the magnetic material
The area ratio becomes too large, which is not preferable. Also, the maximum diameter of the pinhole must be sufficiently smaller than the recording wavelength, and 1
It should be 2 μm or less.
使用する潤滑剤はフッ素系樹脂が好ましいが、他の高分
子系潤滑剤例えばシリコン系潤滑剤を用いても良い。The lubricant used is preferably a fluororesin, but other polymeric lubricants such as silicone lubricants may also be used.
以下、実施例に閑連して本発明の詳細な説明する。Hereinafter, the present invention will be explained in detail with reference to Examples.
ト
実施例1
表面に′FjL径α1μmのピンホールが、1鼾が当た
り1個の割合で存在する高分子基体上に、スパッタ法に
より厚さ[L5μmの垂直員方性C9−Cr膜全形成し
た。C@−Cr膜表面には、基体表面のピンホールが反
訣されて、直径ct1μmのものが1個/μm8の割合
で存在した。Example 1 A vertically oriented C9-Cr film with a thickness of [L5 μm] was completely formed by sputtering on a polymer substrate in which pinholes with a diameter α1 μm were present on the surface at a ratio of one pinhole per snore. did. On the surface of the C@-Cr film, pinholes on the substrate surface were repelled, and pinholes with a diameter ct1 μm were present at a ratio of 1/μm8.
該ピンホールにフッ素系潤滑剤を充填した後、打ち抜き
により、フレ午シプルディスクを作成した。After filling the pinhole with a fluorine-based lubricant, a flexible disk was produced by punching.
フレキシブルディスク耐久性試験機により、磁気ヘッド
との接触走行耐久性を評価したところ、10ロ0万バス
後にも、出力低下、エラーの増加がまったく見られない
という極めて良好な結果を得た。When the durability of the disk in contact with a magnetic head was evaluated using a flexible disk durability tester, very good results were obtained, with no decrease in output or increase in errors observed even after 1,000,000 busses.
比較例
意図的にピンホールを形成しないでCo−Crスパッタ
膜(厚さa5(μm))t−作成し、表面にフッ素系潤
滑剤を塗布して、フレ午シブルディスク耐久性試験を行
な、つたところ、100ロ万パス、平均出力は、およそ
20%減衰し、エラーは104倍に増加した。Comparative Example A Co-Cr sputtered film (thickness a5 (μm)) was prepared without intentionally forming pinholes, a fluorine-based lubricant was applied to the surface, and a flexible disk durability test was conducted. After 1 million passes, the average output attenuated by approximately 20% and the error increased by a factor of 104.
実施例2
直径φ(μm)と単位面積当たりの個数N(個/μmm
)の積を種々変化させて耐久性を評価したところ、図1
に示す結果を得たO
φN>0.05(Jim、個/μm”) テ急激tC
耐久性が向上していることが判るq
φN>[L’5(μm−個/ tt wr ” )
テハ、耐久Th ハ良好であるが、磁性体に対する非磁
性体(illl滑剤)の面積比率が大きくなりすぎ、実
用上好ましくなかった。Example 2 Diameter φ (μm) and number per unit area N (pieces/μmm
) The durability was evaluated by varying the product of Fig. 1.
Obtained the results shown in O φN>0.05 (Jim, pieces/μm") Te sudden tC
It can be seen that the durability has improved q φN>[L'5 (μm-pcs/tt wr ”)
The surface area and durability Th were good, but the area ratio of the non-magnetic material (ill lubricant) to the magnetic material was too large, which was not desirable for practical use.
図面はピンホール直径とその個数密度との積が耐久性に
及ばず影11ヲ示すグラフである。
;吠菖(−=°≦k)The drawing is a graph showing a shadow 11 in which the product of the pinhole diameter and the number density does not reach the durability. ; iris (-=°≦k)
Claims (2)
ったときに直径φ(μm)と単位面積当りの個数N(個
/μml) との積φNが0.05〜CL 5μm個
/μm” の範囲にあるピンホールを形成し、該ピン
ホールに潤滑剤を充填したことを特徴とする磁気記録媒
体。(1) The product φN of the diameter φ (μm) and the number N per unit area (pieces/μml) when measured at the surface of the magnetic layer of the metal thin film magnetic recording material is 0.05 to CL 5 μm pieces/μm. 1. A magnetic recording medium characterized in that a pinhole in the range of 10 μm is formed and the pinhole is filled with a lubricant.
磁気記録媒体〇(2) The magnetic recording medium according to item 1 above, wherein the lubricant is a fluorine-based lubricant.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57106782A JPS58224438A (en) | 1982-06-23 | 1982-06-23 | Magnetic recording medium |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57106782A JPS58224438A (en) | 1982-06-23 | 1982-06-23 | Magnetic recording medium |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS58224438A true JPS58224438A (en) | 1983-12-26 |
Family
ID=14442466
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57106782A Pending JPS58224438A (en) | 1982-06-23 | 1982-06-23 | Magnetic recording medium |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS58224438A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4675075A (en) * | 1983-06-22 | 1987-06-23 | Fujitsu Limited | Magnetic recording production processes |
-
1982
- 1982-06-23 JP JP57106782A patent/JPS58224438A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4675075A (en) * | 1983-06-22 | 1987-06-23 | Fujitsu Limited | Magnetic recording production processes |
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