JPS57140628A - Catalytic reductive decomposition of nitrogen oxides - Google Patents
Catalytic reductive decomposition of nitrogen oxidesInfo
- Publication number
- JPS57140628A JPS57140628A JP56025304A JP2530481A JPS57140628A JP S57140628 A JPS57140628 A JP S57140628A JP 56025304 A JP56025304 A JP 56025304A JP 2530481 A JP2530481 A JP 2530481A JP S57140628 A JPS57140628 A JP S57140628A
- Authority
- JP
- Japan
- Prior art keywords
- nox
- carried out
- synthetic zeolite
- type synthetic
- hydrogen type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000354 decomposition reaction Methods 0.000 title abstract 2
- 230000002829 reductive effect Effects 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000007789 gas Substances 0.000 abstract 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000010457 zeolite Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
Landscapes
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
Abstract
PURPOSE: To remove nitrogen oxides from an exhaust gas, especially, a high temp. exhaust gas in good efficiency by utilizing such a phenomenon that, if hydrogen type synthetic zeolite is used as a catalyst, an extremely high denitrating ratio is obtained in a high temp. range of 500W700°C.
CONSTITUTION: By using a hydrogen type synthetic zeolite as a catalyst, the reductive decomposition reaction of NOx is carried out under a reaction temp. condition of 500W700°C, pref., 500W650°C while GHSV of NOx containing gas is adjusted to about 100W150,000hr-1, pref., about 10,000W100,000hr-1. In this case, an addition amount of ammonia basing on NOx contained in said gas may be a stoichiometric amount or more but, when denitration is carried out at a high temp. exceeding 600°C, use of an excessive amt. is preferred. Generally, the reaction is carried out so as to adjust a molar ratio of NH3/NOx to about 1.0W1.5 and, as the hydrogen type synthetic zeolite, one having an avaliable fine pore size of 8W12Å is used.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56025304A JPS57140628A (en) | 1981-02-23 | 1981-02-23 | Catalytic reductive decomposition of nitrogen oxides |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56025304A JPS57140628A (en) | 1981-02-23 | 1981-02-23 | Catalytic reductive decomposition of nitrogen oxides |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS57140628A true JPS57140628A (en) | 1982-08-31 |
Family
ID=12162268
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56025304A Pending JPS57140628A (en) | 1981-02-23 | 1981-02-23 | Catalytic reductive decomposition of nitrogen oxides |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57140628A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59230642A (en) * | 1983-06-15 | 1984-12-25 | Toyo Soda Mfg Co Ltd | Selective reducing and denitrating catalyst and denitration method of gas using the same |
JPS6022922A (en) * | 1983-07-20 | 1985-02-05 | Babcock Hitachi Kk | Denitration method by reduction with ammonia and its apparatus |
US5271913A (en) * | 1989-12-28 | 1993-12-21 | Mitsubishi Jukogyo Kabushiki Kaisha | Denitration catalyst for high-temperature exhaust gas |
-
1981
- 1981-02-23 JP JP56025304A patent/JPS57140628A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59230642A (en) * | 1983-06-15 | 1984-12-25 | Toyo Soda Mfg Co Ltd | Selective reducing and denitrating catalyst and denitration method of gas using the same |
JPH0417096B2 (en) * | 1983-06-15 | 1992-03-25 | Tosoh Corp | |
JPS6022922A (en) * | 1983-07-20 | 1985-02-05 | Babcock Hitachi Kk | Denitration method by reduction with ammonia and its apparatus |
JPH0417083B2 (en) * | 1983-07-20 | 1992-03-25 | Babcock Hitachi Kk | |
US5271913A (en) * | 1989-12-28 | 1993-12-21 | Mitsubishi Jukogyo Kabushiki Kaisha | Denitration catalyst for high-temperature exhaust gas |
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