JPS57139106A - Polymerization of olefin - Google Patents
Polymerization of olefinInfo
- Publication number
- JPS57139106A JPS57139106A JP2421981A JP2421981A JPS57139106A JP S57139106 A JPS57139106 A JP S57139106A JP 2421981 A JP2421981 A JP 2421981A JP 2421981 A JP2421981 A JP 2421981A JP S57139106 A JPS57139106 A JP S57139106A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- halogen
- olefin
- ethylene
- reaction product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001336 alkenes Chemical class 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 3
- 239000005977 Ethylene Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 150000002901 organomagnesium compounds Chemical class 0.000 abstract 2
- 239000004711 α-olefin Substances 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 150000002366 halogen compounds Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 150000004291 polyenes Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- 150000003682 vanadium compounds Chemical class 0.000 abstract 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
PURPOSE: To obtain a polymer in high catalytic efficiencies even at high temperatures with good process ecomomy, by copolymerizing ethylene with an α- olefin by use of a specified catalyst containing a reaction product between an organomagnesium compound and a halogen compound.
CONSTITUTION: Ethylene is copolymerized with an α-olefin other than ethylene or a polyene at a temperature ≥120°C in one or more of reaction zones in the presence of (A) a catalyst component prepared by contacting a titanium compound and a vanadium compound with a reaction product between a hydrocarbon solvent-soluble organomagnesium compound represented by formulaI, wherein M is a GroupIWIII metal of the periodic table, α, p, q, r and s are each ≥0 and satisfy relationships (II) and (III), wherein m is the valence of M, t≥0, R1 and R2 are each a 1W20C hydrocarbyl, X1 and X2 are each H, a halogen, oxygen or the like and D is an electron-donating organic compound, and at least one member selected from the group consisting of hydrogen chloride, organic halides, boron, aluminum and silicon and (B) an organoaluminum compound represented by formula IV, wherein R3 is 1W20C hydrocarbyl group, X3 is a halogen or the like and 2<n<3.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2421981A JPS57139106A (en) | 1981-02-23 | 1981-02-23 | Polymerization of olefin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2421981A JPS57139106A (en) | 1981-02-23 | 1981-02-23 | Polymerization of olefin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS57139106A true JPS57139106A (en) | 1982-08-27 |
Family
ID=12132168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2421981A Pending JPS57139106A (en) | 1981-02-23 | 1981-02-23 | Polymerization of olefin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57139106A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7320756B2 (en) * | 2001-05-05 | 2008-01-22 | Debasish Mukhopadhyay | Method and apparatus for treatment of feedwaters by membrane separation under acidic conditions |
-
1981
- 1981-02-23 JP JP2421981A patent/JPS57139106A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7320756B2 (en) * | 2001-05-05 | 2008-01-22 | Debasish Mukhopadhyay | Method and apparatus for treatment of feedwaters by membrane separation under acidic conditions |
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