JPS5712008A - Aromatic vinyl polymer having novel functional group and production thereof - Google Patents
Aromatic vinyl polymer having novel functional group and production thereofInfo
- Publication number
- JPS5712008A JPS5712008A JP8656980A JP8656980A JPS5712008A JP S5712008 A JPS5712008 A JP S5712008A JP 8656980 A JP8656980 A JP 8656980A JP 8656980 A JP8656980 A JP 8656980A JP S5712008 A JPS5712008 A JP S5712008A
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- functional group
- formula
- arom
- vinyl polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000000524 functional group Chemical group 0.000 title abstract 4
- 229920002554 vinyl polymer Polymers 0.000 title abstract 4
- 125000003118 aryl group Chemical group 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 abstract 4
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 102000004190 Enzymes Human genes 0.000 abstract 2
- 108090000790 Enzymes Proteins 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 abstract 1
- TXNSZCSYBXHETP-UHFFFAOYSA-N 2-chloro-n-(hydroxymethyl)acetamide Chemical compound OCNC(=O)CCl TXNSZCSYBXHETP-UHFFFAOYSA-N 0.000 abstract 1
- 241000894006 Bacteria Species 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- -1 acryl Chemical group 0.000 abstract 1
- 239000003463 adsorbent Substances 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PURPOSE: To obtain the titled polymer which can be converted into a polymer useful for adsorption, ion exchange, enzyme immobilization, etc., by reacting a specified insolubilized arom. vinyl polymer with a haloacetamidomethylating agent.
CONSTITUTION: A (co)polymer of an arom. vinyl monomer such as styrene which is used as a starting material, is reacted with a haloacetamidomethylating agent (e.g. N-methylolchloroacetamide) of formula I (wherein X is halogen; R', R" are each H, lower alkyl, aryl, aralkyl; Y is H, lower alkyl, acryl) in the presence of formaldehyde, a swelling agent (e.g. nitropropane) and an acid catalyst (e.g. sulfuric acid), to produce an arom. vinyl polymer having a functional group of formula II. The halogen of the functional group of formula II can easily be substituted with other functional groups, e.g. amino group to produce a polymer having a group of formula III. This polymer exhibits excellent performance in immobilization of enzymes and bacteria, or as an adsorbent for macromolecular compds.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8656980A JPS5712008A (en) | 1980-06-27 | 1980-06-27 | Aromatic vinyl polymer having novel functional group and production thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8656980A JPS5712008A (en) | 1980-06-27 | 1980-06-27 | Aromatic vinyl polymer having novel functional group and production thereof |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1297689A Division JPH01279908A (en) | 1989-01-21 | 1989-01-21 | Aromatic vinyl polymer having new functional group and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5712008A true JPS5712008A (en) | 1982-01-21 |
| JPH031324B2 JPH031324B2 (en) | 1991-01-10 |
Family
ID=13890639
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8656980A Granted JPS5712008A (en) | 1980-06-27 | 1980-06-27 | Aromatic vinyl polymer having novel functional group and production thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5712008A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60197703A (en) * | 1984-03-19 | 1985-10-07 | Toray Ind Inc | Polymer excellent in endotoxin adsorptivity and its molding |
| WO2011055852A1 (en) * | 2009-11-06 | 2011-05-12 | セーレン株式会社 | Rubbing cloth |
-
1980
- 1980-06-27 JP JP8656980A patent/JPS5712008A/en active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60197703A (en) * | 1984-03-19 | 1985-10-07 | Toray Ind Inc | Polymer excellent in endotoxin adsorptivity and its molding |
| JPH0356741B2 (en) * | 1984-03-19 | 1991-08-29 | ||
| WO2011055852A1 (en) * | 2009-11-06 | 2011-05-12 | セーレン株式会社 | Rubbing cloth |
| JP5855461B2 (en) * | 2009-11-06 | 2016-02-09 | セーレン株式会社 | Rubbing cloth |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH031324B2 (en) | 1991-01-10 |
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