JPS5659722A - Oxidation of olefin - Google Patents
Oxidation of olefinInfo
- Publication number
- JPS5659722A JPS5659722A JP13564579A JP13564579A JPS5659722A JP S5659722 A JPS5659722 A JP S5659722A JP 13564579 A JP13564579 A JP 13564579A JP 13564579 A JP13564579 A JP 13564579A JP S5659722 A JPS5659722 A JP S5659722A
- Authority
- JP
- Japan
- Prior art keywords
- olefin
- oxide
- compound
- pref
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To prepare an olefin oxide having an unsaturated bond, without generation of CO2 gas, at low temperature, in high yield, by oxidizing an olefin having the same carbon number as that of the objective oxide with molecular oxygen in the presence of an aqueous solution of an Mo compound and a Pd catalyst.
CONSTITUTION: A 3W6C olefin, e.g. propylene or 1-butene, is oxidized with molecular oxygen in the presence of an aqueous solution of an Mo compound, e.g. a molybdenum oxide, heteropolymolybdic acid, etc. pref. molybdenum trioxide, etc., and a Pd catalyst, to obtain an oxide of the olefin, having an unsaturated bond and the same carbon number as that of the olefin, e.g. an α, β-unsaturated carboxylic acid. The concentration of the Mo compound in the solution is pref. 1W60g/l. The Pd catalyst is pref. a lower oxide of an intermetallic compound of Pd and other metals such as Pb and Bi.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54135645A JPS6033369B2 (en) | 1979-10-19 | 1979-10-19 | Olefin oxidation method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54135645A JPS6033369B2 (en) | 1979-10-19 | 1979-10-19 | Olefin oxidation method |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5659722A true JPS5659722A (en) | 1981-05-23 |
JPS6033369B2 JPS6033369B2 (en) | 1985-08-02 |
Family
ID=15156638
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP54135645A Expired JPS6033369B2 (en) | 1979-10-19 | 1979-10-19 | Olefin oxidation method |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6033369B2 (en) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4612301A (en) * | 1985-04-17 | 1986-09-16 | The Standard Oil Company | Metal coordination complexes of heteropolyacids as catalysts for alcohol conversion |
US5596111A (en) * | 1995-06-05 | 1997-01-21 | North Dakota State University | Method for preparation of carboxylic acids |
WO2004037411A1 (en) * | 2002-10-28 | 2004-05-06 | Mitsubishi Rayon Co., Ltd. | CATALYST FOR α,ß-UNSATURATED CARBOXYLIC ACID PRODUCTION, PROCESS FOR PRODUCING THE SAME, AND PROCESS FOR PRODUCING α,ß-UNSATURATED CARBOXYLIC ACID |
JP2005218952A (en) * | 2004-02-05 | 2005-08-18 | Mitsubishi Rayon Co Ltd | Method for producing noble metal-containing catalyst |
JP2007152152A (en) * | 2005-11-30 | 2007-06-21 | Mitsubishi Rayon Co Ltd | Palladium-containing supported catalyst and method for producing α, β-unsaturated carboxylic acid using the same |
JP2007203284A (en) * | 2006-01-04 | 2007-08-16 | Mitsubishi Rayon Co Ltd | Palladium-supported catalyst and method for producing the same |
JP2008212817A (en) * | 2007-03-02 | 2008-09-18 | Mitsubishi Rayon Co Ltd | Palladium-containing catalyst, method for producing the same, and method for producing α, β-unsaturated carboxylic acid |
US7446223B2 (en) | 2004-06-04 | 2008-11-04 | Mitsubishi Rayon Co., Ltd. | Palladium-containing catalyst and method for producing same |
JP2009029729A (en) * | 2007-07-25 | 2009-02-12 | Mitsubishi Rayon Co Ltd | Process for producing α, β-unsaturated carboxylic acid |
JP2009050749A (en) * | 2007-08-23 | 2009-03-12 | Mitsubishi Rayon Co Ltd | Palladium-containing catalyst, method for producing the same, and method for producing α, β-unsaturated carboxylic acid |
JP2009279575A (en) * | 2008-04-22 | 2009-12-03 | Mitsubishi Rayon Co Ltd | Palladium-containing catalyst |
JP2010209063A (en) * | 2009-02-16 | 2010-09-24 | Mitsubishi Rayon Co Ltd | METHOD FOR PRODUCING alpha,beta-UNSATURATED CARBOXYLIC ACID |
US7884239B2 (en) | 2004-02-10 | 2011-02-08 | Mitsubishi Rayon Co., Ltd. | Catalyst for producing α,β-unsaturated carboxylic acid and method for preparation thereof, and method for producing α,β-unsaturated carboxylic acid |
US8088945B2 (en) | 2005-02-18 | 2012-01-03 | Mitsubishi Rayon Co., Ltd. | Palladium-containing catalyst, method for producing same, and method for producing α,β-unsaturated carboxylic acid |
JP2012017315A (en) * | 2010-06-11 | 2012-01-26 | Mitsubishi Rayon Co Ltd | METHOD FOR PRODUCING α,β-UNSATURATED CARBOXYLIC ACID |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0371377U (en) * | 1989-11-17 | 1991-07-18 | ||
JPH0411575U (en) * | 1990-05-21 | 1992-01-30 |
-
1979
- 1979-10-19 JP JP54135645A patent/JPS6033369B2/en not_active Expired
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4612301A (en) * | 1985-04-17 | 1986-09-16 | The Standard Oil Company | Metal coordination complexes of heteropolyacids as catalysts for alcohol conversion |
US5596111A (en) * | 1995-06-05 | 1997-01-21 | North Dakota State University | Method for preparation of carboxylic acids |
WO2004037411A1 (en) * | 2002-10-28 | 2004-05-06 | Mitsubishi Rayon Co., Ltd. | CATALYST FOR α,ß-UNSATURATED CARBOXYLIC ACID PRODUCTION, PROCESS FOR PRODUCING THE SAME, AND PROCESS FOR PRODUCING α,ß-UNSATURATED CARBOXYLIC ACID |
JP2005218952A (en) * | 2004-02-05 | 2005-08-18 | Mitsubishi Rayon Co Ltd | Method for producing noble metal-containing catalyst |
US7884239B2 (en) | 2004-02-10 | 2011-02-08 | Mitsubishi Rayon Co., Ltd. | Catalyst for producing α,β-unsaturated carboxylic acid and method for preparation thereof, and method for producing α,β-unsaturated carboxylic acid |
US7446223B2 (en) | 2004-06-04 | 2008-11-04 | Mitsubishi Rayon Co., Ltd. | Palladium-containing catalyst and method for producing same |
US8389760B2 (en) | 2005-02-18 | 2013-03-05 | Mitsubishi Rayon Co., Ltd. | Palladium-containing catalyst, method for producing same, and method for producing α, β-unsaturated carboxylic acid |
US8088945B2 (en) | 2005-02-18 | 2012-01-03 | Mitsubishi Rayon Co., Ltd. | Palladium-containing catalyst, method for producing same, and method for producing α,β-unsaturated carboxylic acid |
JP2007152152A (en) * | 2005-11-30 | 2007-06-21 | Mitsubishi Rayon Co Ltd | Palladium-containing supported catalyst and method for producing α, β-unsaturated carboxylic acid using the same |
JP2007203284A (en) * | 2006-01-04 | 2007-08-16 | Mitsubishi Rayon Co Ltd | Palladium-supported catalyst and method for producing the same |
JP2008212817A (en) * | 2007-03-02 | 2008-09-18 | Mitsubishi Rayon Co Ltd | Palladium-containing catalyst, method for producing the same, and method for producing α, β-unsaturated carboxylic acid |
JP2009029729A (en) * | 2007-07-25 | 2009-02-12 | Mitsubishi Rayon Co Ltd | Process for producing α, β-unsaturated carboxylic acid |
JP2009050749A (en) * | 2007-08-23 | 2009-03-12 | Mitsubishi Rayon Co Ltd | Palladium-containing catalyst, method for producing the same, and method for producing α, β-unsaturated carboxylic acid |
JP2009279575A (en) * | 2008-04-22 | 2009-12-03 | Mitsubishi Rayon Co Ltd | Palladium-containing catalyst |
JP2010209063A (en) * | 2009-02-16 | 2010-09-24 | Mitsubishi Rayon Co Ltd | METHOD FOR PRODUCING alpha,beta-UNSATURATED CARBOXYLIC ACID |
JP2012017315A (en) * | 2010-06-11 | 2012-01-26 | Mitsubishi Rayon Co Ltd | METHOD FOR PRODUCING α,β-UNSATURATED CARBOXYLIC ACID |
Also Published As
Publication number | Publication date |
---|---|
JPS6033369B2 (en) | 1985-08-02 |
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