JPS5628468A - Lithium-iodine complex solid electrolyte battery - Google Patents
Lithium-iodine complex solid electrolyte batteryInfo
- Publication number
- JPS5628468A JPS5628468A JP10372879A JP10372879A JPS5628468A JP S5628468 A JPS5628468 A JP S5628468A JP 10372879 A JP10372879 A JP 10372879A JP 10372879 A JP10372879 A JP 10372879A JP S5628468 A JPS5628468 A JP S5628468A
- Authority
- JP
- Japan
- Prior art keywords
- iodine
- lithium
- monomer
- battery
- active material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007784 solid electrolyte Substances 0.000 title abstract 2
- YFXWODPYUNGUEE-UHFFFAOYSA-N [I].[Li] Chemical compound [I].[Li] YFXWODPYUNGUEE-UHFFFAOYSA-N 0.000 title 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 5
- 229910052740 iodine Inorganic materials 0.000 abstract 5
- 239000011630 iodine Substances 0.000 abstract 5
- 239000000178 monomer Substances 0.000 abstract 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 239000008187 granular material Substances 0.000 abstract 3
- 229910052744 lithium Inorganic materials 0.000 abstract 3
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical group [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000007774 positive electrode material Substances 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- 108091006149 Electron carriers Proteins 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011149 active material Substances 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000006866 deterioration Effects 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 229910002027 silica gel Inorganic materials 0.000 abstract 1
- 239000000741 silica gel Substances 0.000 abstract 1
- 229960001866 silicon dioxide Drugs 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
PURPOSE:To obtain a battery which has good shelfing properties by usng a negative electrode of lithium and a positive electrode made of a mixture of iodine monomer and an electron carrier complex consisting of iodine and an organic aromatic hetero- ring compound, and by specifying the diameter of the granules of iodine monomer contained in the positive electrode. CONSTITUTION:A battery is formed of a negative electrode 1 of lithium, a positive active material 2, and a solid electrolyte 3 whose main component is lithium iodide that will be formed on the active surface of the contact between the negative electrode 1 and the positve active material 2; the positive active material is made of a mixture of iodine monomer, which is in the form of a powder granule with a maximum diameter of not more than 77mum, and a charge transfer complex consisting of iodine and an organic aromatic hetero-ring compound. 1-Alkylpyridinium iodide is preferred as the organic aromatic hetero-ring compound, and a silicagel powder may be mixed with that. Through the means mentioned above, pitlike corrosions produced on the surface of the lithium negative-electrode in contact with iodine- monomer granules, can be uniformed, thus obtaining a battery without any deterioration in its discharge performance during storage, as well as any minute internal short-circuit.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10372879A JPS5628468A (en) | 1979-08-15 | 1979-08-15 | Lithium-iodine complex solid electrolyte battery |
US06/175,734 US4315975A (en) | 1979-08-15 | 1980-08-06 | Solid-state lithium-iodine primary battery |
GB8025949A GB2056756B (en) | 1979-08-15 | 1980-08-08 | Solid-state lithium-iodine primary battery |
DE3030542A DE3030542C2 (en) | 1979-08-15 | 1980-08-13 | Galvanic lithium-iodine cell |
CH6117/80A CH651966A5 (en) | 1979-08-15 | 1980-08-13 | LITHIUM-IODINE SOLID PRIMARY CELL. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10372879A JPS5628468A (en) | 1979-08-15 | 1979-08-15 | Lithium-iodine complex solid electrolyte battery |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5628468A true JPS5628468A (en) | 1981-03-20 |
JPS616503B2 JPS616503B2 (en) | 1986-02-27 |
Family
ID=14361707
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10372879A Granted JPS5628468A (en) | 1979-08-15 | 1979-08-15 | Lithium-iodine complex solid electrolyte battery |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5628468A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58158885A (en) * | 1982-03-16 | 1983-09-21 | 三洋電機株式会社 | Induction heating cooking device |
JPS58158886A (en) * | 1982-03-16 | 1983-09-21 | 三洋電機株式会社 | Induction heating cooking device |
-
1979
- 1979-08-15 JP JP10372879A patent/JPS5628468A/en active Granted
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58158885A (en) * | 1982-03-16 | 1983-09-21 | 三洋電機株式会社 | Induction heating cooking device |
JPS58158886A (en) * | 1982-03-16 | 1983-09-21 | 三洋電機株式会社 | Induction heating cooking device |
Also Published As
Publication number | Publication date |
---|---|
JPS616503B2 (en) | 1986-02-27 |
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