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JPS5622745A - Preparation of carboxylic acid - Google Patents

Preparation of carboxylic acid

Info

Publication number
JPS5622745A
JPS5622745A JP9881579A JP9881579A JPS5622745A JP S5622745 A JPS5622745 A JP S5622745A JP 9881579 A JP9881579 A JP 9881579A JP 9881579 A JP9881579 A JP 9881579A JP S5622745 A JPS5622745 A JP S5622745A
Authority
JP
Japan
Prior art keywords
carboxylic acid
carbon monoxide
amount
base
iii
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP9881579A
Other languages
Japanese (ja)
Other versions
JPS6244534B2 (en
Inventor
Hirosuke Wada
Akio Baba
Noboru Wada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Priority to JP9881579A priority Critical patent/JPS5622745A/en
Publication of JPS5622745A publication Critical patent/JPS5622745A/en
Publication of JPS6244534B2 publication Critical patent/JPS6244534B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To obtain a carboxylic acid advantageously, by isomerizing a formate in the presence of a catalyst consisting of (a) metal palladium or palladium compound, (b) an alkyl halide or hydrogen halide, and (c) a base, and carbon monoxide.
CONSTITUTION: A formate shown by the formula HCOOR(R is straight-chain or branched-chain alkyl, etc.) is isomerized in the presence of a catalyst consisting of (i) metal palladium or palladium compound, (ii) alkyl halide or halogenated hydrocarbon, and (iii) a base (e.g., an organic base, e.g., amine, amide, phosphine, etc.) and carbon monoxide preferably at 150W250°C and under a carbon monoxide partial pressure of 30W150kg/cm2 to give a carboxylic acid shown by the formula RCOOH in high conversion and high selectivity by using the relatively inexpensive catalyst. Preferably an amount of (i) calculated as Pd is 1W50mg atom per mole of the raw material, and an amount of (ii) is 1W100mol and an amount of (iii) is 1W1000mol per g atom of (i) respectively.
COPYRIGHT: (C)1981,JPO&Japio
JP9881579A 1979-08-02 1979-08-02 Preparation of carboxylic acid Granted JPS5622745A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9881579A JPS5622745A (en) 1979-08-02 1979-08-02 Preparation of carboxylic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9881579A JPS5622745A (en) 1979-08-02 1979-08-02 Preparation of carboxylic acid

Publications (2)

Publication Number Publication Date
JPS5622745A true JPS5622745A (en) 1981-03-03
JPS6244534B2 JPS6244534B2 (en) 1987-09-21

Family

ID=14229812

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9881579A Granted JPS5622745A (en) 1979-08-02 1979-08-02 Preparation of carboxylic acid

Country Status (1)

Country Link
JP (1) JPS5622745A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3333317A1 (en) * 1983-09-15 1985-03-28 Chemische Werke Hüls AG, 4370 Marl CATALYTIC SYSTEM AND METHOD FOR PRODUCING ACETIC ACID BY CATALYTIC REVERSE OF METAL METALYLATE
JPS6460460A (en) * 1987-12-24 1989-03-07 Isuzu Motors Ltd Braking force holding device
JPH0578274A (en) * 1991-03-22 1993-03-30 Dalian Kagaku Kogyo Kofun Yugenkoshi Process for producing acetic acid

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS493513A (en) * 1972-03-13 1974-01-12
JPS5016773A (en) * 1973-06-13 1975-02-21

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS493513A (en) * 1972-03-13 1974-01-12
JPS5016773A (en) * 1973-06-13 1975-02-21

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3333317A1 (en) * 1983-09-15 1985-03-28 Chemische Werke Hüls AG, 4370 Marl CATALYTIC SYSTEM AND METHOD FOR PRODUCING ACETIC ACID BY CATALYTIC REVERSE OF METAL METALYLATE
JPS6460460A (en) * 1987-12-24 1989-03-07 Isuzu Motors Ltd Braking force holding device
JPH0578274A (en) * 1991-03-22 1993-03-30 Dalian Kagaku Kogyo Kofun Yugenkoshi Process for producing acetic acid

Also Published As

Publication number Publication date
JPS6244534B2 (en) 1987-09-21

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