JPS5618611A - Production of diallyldialkylammonium chloride - Google Patents
Production of diallyldialkylammonium chlorideInfo
- Publication number
- JPS5618611A JPS5618611A JP9323679A JP9323679A JPS5618611A JP S5618611 A JPS5618611 A JP S5618611A JP 9323679 A JP9323679 A JP 9323679A JP 9323679 A JP9323679 A JP 9323679A JP S5618611 A JPS5618611 A JP S5618611A
- Authority
- JP
- Japan
- Prior art keywords
- chloride
- temperature
- carbon radicals
- initiator
- considered
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title abstract 4
- 150000001723 carbon free-radicals Chemical class 0.000 abstract 3
- 239000003999 initiator Substances 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- -1 oxygen radicals Chemical class 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
Landscapes
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PURPOSE: To obtain a high-molecular diallyldialky1ammonium chloride polymer, by polymerizing diallyldialky1ammomium chloride at a specific temperature in the presence of a water-soluble azo initiator.
CONSTITUTION: A diallyldialky1ammonium chloride is polymerized at a temperature lower than 55°C, by use of 0.2W1.5wt%, based on the monomer, of a water- soluble initiator. The necessity to set the polymerization temperature at below 55°C is considered to be attributable to the specificity of carbon radicals generated by the decomposition of the azoinitiator. Generally, compared with carbon radicals, oxygen radicals from a peroxide type initiator show higher ability to initiate the reaction and as well, act strongly upon the termination reaction. The similar effect is possible also in case of carbon radicals when the temperature is high, and this is considered to be the reason for an unsatisfactorily low molecular weight.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9323679A JPS5618611A (en) | 1979-07-24 | 1979-07-24 | Production of diallyldialkylammonium chloride |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9323679A JPS5618611A (en) | 1979-07-24 | 1979-07-24 | Production of diallyldialkylammonium chloride |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5618611A true JPS5618611A (en) | 1981-02-21 |
| JPS625163B2 JPS625163B2 (en) | 1987-02-03 |
Family
ID=14076887
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9323679A Granted JPS5618611A (en) | 1979-07-24 | 1979-07-24 | Production of diallyldialkylammonium chloride |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5618611A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6323911A (en) * | 1986-07-02 | 1988-02-01 | サンド アクチエンゲゼルシヤフト | Method for polymerizing diarylamine and its derivative and polymer |
| US5248744A (en) * | 1992-04-20 | 1993-09-28 | Nalco Chemical Company | Process of polymerizing diallyldialkyl ammonium compounds with azo catalyst |
| US5422408A (en) * | 1992-04-20 | 1995-06-06 | Nalco Chemical Company | Polymerization of diallyldialkyl ammonium halide compounds with azo compound and inorganic salt |
| CN1051323C (en) * | 1993-06-10 | 2000-04-12 | 诺尔科化学公司 | Hydrophobic dispersants used in forming polymer dispersions |
| JP2001521890A (en) * | 1997-11-05 | 2001-11-13 | ジェルテックス ファーマシューティカルズ，インコーポレイテッド | Method for treating hypercholesterolemia using unsubstituted polydiallylamine |
| JP2004167465A (en) * | 2002-11-18 | 2004-06-17 | Kaya Frock Kk | Sludge dehydrating agent |
| CN100357501C (en) * | 2006-04-21 | 2007-12-26 | 北京科技大学 | Poly-diallyldimethyl ammonium chloride single-chain single crystal and method for preparing same |
| CN102858818A (en) * | 2010-04-19 | 2013-01-02 | 日东纺织株式会社 | Method for producing diallylamine acetate polymer |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5035279A (en) * | 1973-06-12 | 1975-04-03 | ||
| JPS5157793A (en) * | 1974-11-15 | 1976-05-20 | Nitto Boseki Co Ltd | JIARIRUAMIN JUDOTAINO JUGOTAIO SEIZOSURU HOHO |
-
1979
- 1979-07-24 JP JP9323679A patent/JPS5618611A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5035279A (en) * | 1973-06-12 | 1975-04-03 | ||
| JPS5157793A (en) * | 1974-11-15 | 1976-05-20 | Nitto Boseki Co Ltd | JIARIRUAMIN JUDOTAINO JUGOTAIO SEIZOSURU HOHO |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6323911A (en) * | 1986-07-02 | 1988-02-01 | サンド アクチエンゲゼルシヤフト | Method for polymerizing diarylamine and its derivative and polymer |
| US5248744A (en) * | 1992-04-20 | 1993-09-28 | Nalco Chemical Company | Process of polymerizing diallyldialkyl ammonium compounds with azo catalyst |
| US5422408A (en) * | 1992-04-20 | 1995-06-06 | Nalco Chemical Company | Polymerization of diallyldialkyl ammonium halide compounds with azo compound and inorganic salt |
| CN1051323C (en) * | 1993-06-10 | 2000-04-12 | 诺尔科化学公司 | Hydrophobic dispersants used in forming polymer dispersions |
| JP2001521890A (en) * | 1997-11-05 | 2001-11-13 | ジェルテックス ファーマシューティカルズ，インコーポレイテッド | Method for treating hypercholesterolemia using unsubstituted polydiallylamine |
| JP2004167465A (en) * | 2002-11-18 | 2004-06-17 | Kaya Frock Kk | Sludge dehydrating agent |
| CN100357501C (en) * | 2006-04-21 | 2007-12-26 | 北京科技大学 | Poly-diallyldimethyl ammonium chloride single-chain single crystal and method for preparing same |
| CN102858818A (en) * | 2010-04-19 | 2013-01-02 | 日东纺织株式会社 | Method for producing diallylamine acetate polymer |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS625163B2 (en) | 1987-02-03 |
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