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JPS56156222A - Preparation of alkylbiphenyl rich in m- and p- substitution product - Google Patents

Preparation of alkylbiphenyl rich in m- and p- substitution product

Info

Publication number
JPS56156222A
JPS56156222A JP5951580A JP5951580A JPS56156222A JP S56156222 A JPS56156222 A JP S56156222A JP 5951580 A JP5951580 A JP 5951580A JP 5951580 A JP5951580 A JP 5951580A JP S56156222 A JPS56156222 A JP S56156222A
Authority
JP
Japan
Prior art keywords
catalyst
alumina
rich
silica
zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5951580A
Other languages
Japanese (ja)
Inventor
Mamoru Yamane
Yutaka Mukai
Yasukazu Sato
Hiromi Ozaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Mining Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Mining Co Ltd filed Critical Nippon Mining Co Ltd
Priority to JP5951580A priority Critical patent/JPS56156222A/en
Publication of JPS56156222A publication Critical patent/JPS56156222A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain the titled substance rich in m- and p- substitution products, simply without problems of corrosion of apparatuses and pollution, by reacting biphenyl with a lower olefin in the presence of a catalyst, e.g. silica -alumina or zeolite, under given conditions.
CONSTITUTION: One mole biphenyl is reacted with 0.5W5mol lower olefin in the presence of a catalyst, e.g. silica-alumina or zeolite, at 180°C or above, to give an alkylbiphenyl rich in the m- and p- substitution products. The silica-alumina catalyst has an alumina content of 10W30wt%, and the zeolite catalyst is any of the natural or synthetic ones and may be used alone or in a mixture. The particle diameter of the catalyst is most preferably 20W150μ, and the catalyst is activated by calcining in the air at 400W850°C. The amount of the catalyst is 0.5W10wt%, preferably 1W5wt%, based on the biphenyl.
USE: An electrical insulating oil, a solvent for pressure-sensitive paper and a heating medium oil.
COPYRIGHT: (C)1981,JPO&Japio
JP5951580A 1980-05-07 1980-05-07 Preparation of alkylbiphenyl rich in m- and p- substitution product Pending JPS56156222A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5951580A JPS56156222A (en) 1980-05-07 1980-05-07 Preparation of alkylbiphenyl rich in m- and p- substitution product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5951580A JPS56156222A (en) 1980-05-07 1980-05-07 Preparation of alkylbiphenyl rich in m- and p- substitution product

Publications (1)

Publication Number Publication Date
JPS56156222A true JPS56156222A (en) 1981-12-02

Family

ID=13115466

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5951580A Pending JPS56156222A (en) 1980-05-07 1980-05-07 Preparation of alkylbiphenyl rich in m- and p- substitution product

Country Status (1)

Country Link
JP (1) JPS56156222A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4699658A (en) * 1986-05-02 1987-10-13 Kureha Kagaku Kogyo Kabushiki Kaisha Solvent for chromogenic dye-precursor material for pressure-sensitive recording paper sheet and pressure-sensitive recording paper sheet prepared by using the solvent
JPS63122645A (en) * 1986-11-11 1988-05-26 Kureha Chem Ind Co Ltd Production of biphenyl-4,4'-dicarboxylic acid
JPS63227529A (en) * 1987-03-13 1988-09-21 Kureha Chem Ind Co Ltd Selective alkylation of biphenyl
US4774136A (en) * 1986-05-02 1988-09-27 Kureha Kagaku Kogyo Kabushiki Kaisha Solvent for the chromogenic dye-precursor material for a pressure-sensitive recording paper sheet and a pressure-sensitive recording paper sheet prepared by using the solvent
US4795493A (en) * 1986-01-07 1989-01-03 Kureha Kagaku Kogyo Kabushiki Kaisha Solvent for chromogenic dye-precursor material for pressure-sensitive recording paper sheet and pressure-sensitive recording paper sheet prepared by using the solvent
US4891448A (en) * 1987-11-23 1990-01-02 The Dow Chemical Company Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers
US4943553A (en) * 1986-12-25 1990-07-24 Nippon Steel Chemical Co., Ltd. Method of making ethylbiphenyls
US5015797A (en) * 1987-11-23 1991-05-14 The Dow Chemical Company Alkylation of polycyclic aromatic compounds to alkylates enriched in the linear- and near linear-substituted isomers
US5198595A (en) * 1987-11-23 1993-03-30 The Dow Chemical Company Alkylation of aromatic compounds
US5243116A (en) * 1987-11-23 1993-09-07 The Dow Chemical Company Alkylation of aromatic compounds
US7205445B2 (en) 2002-08-30 2007-04-17 Nippon Petrochemicals, Co., Ltd. Method of continuous production of polyalkylbiphenyls

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4795493A (en) * 1986-01-07 1989-01-03 Kureha Kagaku Kogyo Kabushiki Kaisha Solvent for chromogenic dye-precursor material for pressure-sensitive recording paper sheet and pressure-sensitive recording paper sheet prepared by using the solvent
US4774136A (en) * 1986-05-02 1988-09-27 Kureha Kagaku Kogyo Kabushiki Kaisha Solvent for the chromogenic dye-precursor material for a pressure-sensitive recording paper sheet and a pressure-sensitive recording paper sheet prepared by using the solvent
US4699658A (en) * 1986-05-02 1987-10-13 Kureha Kagaku Kogyo Kabushiki Kaisha Solvent for chromogenic dye-precursor material for pressure-sensitive recording paper sheet and pressure-sensitive recording paper sheet prepared by using the solvent
US4822767A (en) * 1986-05-02 1989-04-18 Kureha Kagaku Kogyo Kabushiki Kaisha Solvent for chromogenic dye-precursor material for pressure-sensitive recording paper sheet and pressure-sensitive recording paper sheet prepared by using the solvent
JPS63122645A (en) * 1986-11-11 1988-05-26 Kureha Chem Ind Co Ltd Production of biphenyl-4,4'-dicarboxylic acid
JPH0531536B2 (en) * 1986-11-11 1993-05-12 Kureha Chemical Ind Co Ltd
US4970338A (en) * 1986-11-11 1990-11-13 Kureha Kagaku Kogyo K.K. Preparation process of biphenyl-4,4'-dicarboxylic acid
US4943553A (en) * 1986-12-25 1990-07-24 Nippon Steel Chemical Co., Ltd. Method of making ethylbiphenyls
EP0285280A1 (en) * 1987-03-13 1988-10-05 Kureha Kagaku Kogyo Kabushiki Kaisha Process for selectively alkylating biphenyl
US4982037A (en) * 1987-03-13 1991-01-01 Kureha Kagaku Kogyo Kabushiki Kaisha Process for selectively alkylating biphenyl
JPS63227529A (en) * 1987-03-13 1988-09-21 Kureha Chem Ind Co Ltd Selective alkylation of biphenyl
US4891448A (en) * 1987-11-23 1990-01-02 The Dow Chemical Company Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers
US5015797A (en) * 1987-11-23 1991-05-14 The Dow Chemical Company Alkylation of polycyclic aromatic compounds to alkylates enriched in the linear- and near linear-substituted isomers
US5198595A (en) * 1987-11-23 1993-03-30 The Dow Chemical Company Alkylation of aromatic compounds
US5243116A (en) * 1987-11-23 1993-09-07 The Dow Chemical Company Alkylation of aromatic compounds
US7205445B2 (en) 2002-08-30 2007-04-17 Nippon Petrochemicals, Co., Ltd. Method of continuous production of polyalkylbiphenyls

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