JPS56156222A - Preparation of alkylbiphenyl rich in m- and p- substitution product - Google Patents
Preparation of alkylbiphenyl rich in m- and p- substitution productInfo
- Publication number
- JPS56156222A JPS56156222A JP5951580A JP5951580A JPS56156222A JP S56156222 A JPS56156222 A JP S56156222A JP 5951580 A JP5951580 A JP 5951580A JP 5951580 A JP5951580 A JP 5951580A JP S56156222 A JPS56156222 A JP S56156222A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- alumina
- rich
- silica
- zeolite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain the titled substance rich in m- and p- substitution products, simply without problems of corrosion of apparatuses and pollution, by reacting biphenyl with a lower olefin in the presence of a catalyst, e.g. silica -alumina or zeolite, under given conditions.
CONSTITUTION: One mole biphenyl is reacted with 0.5W5mol lower olefin in the presence of a catalyst, e.g. silica-alumina or zeolite, at 180°C or above, to give an alkylbiphenyl rich in the m- and p- substitution products. The silica-alumina catalyst has an alumina content of 10W30wt%, and the zeolite catalyst is any of the natural or synthetic ones and may be used alone or in a mixture. The particle diameter of the catalyst is most preferably 20W150μ, and the catalyst is activated by calcining in the air at 400W850°C. The amount of the catalyst is 0.5W10wt%, preferably 1W5wt%, based on the biphenyl.
USE: An electrical insulating oil, a solvent for pressure-sensitive paper and a heating medium oil.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5951580A JPS56156222A (en) | 1980-05-07 | 1980-05-07 | Preparation of alkylbiphenyl rich in m- and p- substitution product |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5951580A JPS56156222A (en) | 1980-05-07 | 1980-05-07 | Preparation of alkylbiphenyl rich in m- and p- substitution product |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS56156222A true JPS56156222A (en) | 1981-12-02 |
Family
ID=13115466
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5951580A Pending JPS56156222A (en) | 1980-05-07 | 1980-05-07 | Preparation of alkylbiphenyl rich in m- and p- substitution product |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS56156222A (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4699658A (en) * | 1986-05-02 | 1987-10-13 | Kureha Kagaku Kogyo Kabushiki Kaisha | Solvent for chromogenic dye-precursor material for pressure-sensitive recording paper sheet and pressure-sensitive recording paper sheet prepared by using the solvent |
JPS63122645A (en) * | 1986-11-11 | 1988-05-26 | Kureha Chem Ind Co Ltd | Production of biphenyl-4,4'-dicarboxylic acid |
JPS63227529A (en) * | 1987-03-13 | 1988-09-21 | Kureha Chem Ind Co Ltd | Selective alkylation of biphenyl |
US4774136A (en) * | 1986-05-02 | 1988-09-27 | Kureha Kagaku Kogyo Kabushiki Kaisha | Solvent for the chromogenic dye-precursor material for a pressure-sensitive recording paper sheet and a pressure-sensitive recording paper sheet prepared by using the solvent |
US4795493A (en) * | 1986-01-07 | 1989-01-03 | Kureha Kagaku Kogyo Kabushiki Kaisha | Solvent for chromogenic dye-precursor material for pressure-sensitive recording paper sheet and pressure-sensitive recording paper sheet prepared by using the solvent |
US4891448A (en) * | 1987-11-23 | 1990-01-02 | The Dow Chemical Company | Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers |
US4943553A (en) * | 1986-12-25 | 1990-07-24 | Nippon Steel Chemical Co., Ltd. | Method of making ethylbiphenyls |
US5015797A (en) * | 1987-11-23 | 1991-05-14 | The Dow Chemical Company | Alkylation of polycyclic aromatic compounds to alkylates enriched in the linear- and near linear-substituted isomers |
US5198595A (en) * | 1987-11-23 | 1993-03-30 | The Dow Chemical Company | Alkylation of aromatic compounds |
US5243116A (en) * | 1987-11-23 | 1993-09-07 | The Dow Chemical Company | Alkylation of aromatic compounds |
US7205445B2 (en) | 2002-08-30 | 2007-04-17 | Nippon Petrochemicals, Co., Ltd. | Method of continuous production of polyalkylbiphenyls |
-
1980
- 1980-05-07 JP JP5951580A patent/JPS56156222A/en active Pending
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4795493A (en) * | 1986-01-07 | 1989-01-03 | Kureha Kagaku Kogyo Kabushiki Kaisha | Solvent for chromogenic dye-precursor material for pressure-sensitive recording paper sheet and pressure-sensitive recording paper sheet prepared by using the solvent |
US4774136A (en) * | 1986-05-02 | 1988-09-27 | Kureha Kagaku Kogyo Kabushiki Kaisha | Solvent for the chromogenic dye-precursor material for a pressure-sensitive recording paper sheet and a pressure-sensitive recording paper sheet prepared by using the solvent |
US4699658A (en) * | 1986-05-02 | 1987-10-13 | Kureha Kagaku Kogyo Kabushiki Kaisha | Solvent for chromogenic dye-precursor material for pressure-sensitive recording paper sheet and pressure-sensitive recording paper sheet prepared by using the solvent |
US4822767A (en) * | 1986-05-02 | 1989-04-18 | Kureha Kagaku Kogyo Kabushiki Kaisha | Solvent for chromogenic dye-precursor material for pressure-sensitive recording paper sheet and pressure-sensitive recording paper sheet prepared by using the solvent |
JPS63122645A (en) * | 1986-11-11 | 1988-05-26 | Kureha Chem Ind Co Ltd | Production of biphenyl-4,4'-dicarboxylic acid |
JPH0531536B2 (en) * | 1986-11-11 | 1993-05-12 | Kureha Chemical Ind Co Ltd | |
US4970338A (en) * | 1986-11-11 | 1990-11-13 | Kureha Kagaku Kogyo K.K. | Preparation process of biphenyl-4,4'-dicarboxylic acid |
US4943553A (en) * | 1986-12-25 | 1990-07-24 | Nippon Steel Chemical Co., Ltd. | Method of making ethylbiphenyls |
EP0285280A1 (en) * | 1987-03-13 | 1988-10-05 | Kureha Kagaku Kogyo Kabushiki Kaisha | Process for selectively alkylating biphenyl |
US4982037A (en) * | 1987-03-13 | 1991-01-01 | Kureha Kagaku Kogyo Kabushiki Kaisha | Process for selectively alkylating biphenyl |
JPS63227529A (en) * | 1987-03-13 | 1988-09-21 | Kureha Chem Ind Co Ltd | Selective alkylation of biphenyl |
US4891448A (en) * | 1987-11-23 | 1990-01-02 | The Dow Chemical Company | Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers |
US5015797A (en) * | 1987-11-23 | 1991-05-14 | The Dow Chemical Company | Alkylation of polycyclic aromatic compounds to alkylates enriched in the linear- and near linear-substituted isomers |
US5198595A (en) * | 1987-11-23 | 1993-03-30 | The Dow Chemical Company | Alkylation of aromatic compounds |
US5243116A (en) * | 1987-11-23 | 1993-09-07 | The Dow Chemical Company | Alkylation of aromatic compounds |
US7205445B2 (en) | 2002-08-30 | 2007-04-17 | Nippon Petrochemicals, Co., Ltd. | Method of continuous production of polyalkylbiphenyls |
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