JPS56115774A - N-substituted-3-alkenyl-6-halocarbazole and its preparation - Google Patents
N-substituted-3-alkenyl-6-halocarbazole and its preparationInfo
- Publication number
- JPS56115774A JPS56115774A JP1853280A JP1853280A JPS56115774A JP S56115774 A JPS56115774 A JP S56115774A JP 1853280 A JP1853280 A JP 1853280A JP 1853280 A JP1853280 A JP 1853280A JP S56115774 A JPS56115774 A JP S56115774A
- Authority
- JP
- Japan
- Prior art keywords
- halocarbazole
- substituted
- alkenyl
- formula
- formyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 abstract 4
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 abstract 2
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 2
- XEKOUTJATPGANW-UHFFFAOYSA-N 3-bromo-9-dodecyl-6-ethenylcarbazole Chemical compound C=CC1=CC=C2N(CCCCCCCCCCCC)C3=CC=C(Br)C=C3C2=C1 XEKOUTJATPGANW-UHFFFAOYSA-N 0.000 abstract 1
- CWDJTDJQVUXQEA-UHFFFAOYSA-N CC=[PH3] Chemical compound CC=[PH3] CWDJTDJQVUXQEA-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920000547 conjugated polymer Polymers 0.000 abstract 1
- CEOCUCXOSQUXGV-UHFFFAOYSA-N methanidylphosphanium Chemical compound [PH3]=C CEOCUCXOSQUXGV-UHFFFAOYSA-N 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 150000004714 phosphonium salts Chemical class 0.000 abstract 1
Landscapes
- Indole Compounds (AREA)
Abstract
NEW MATERIAL:An N-substituted -3-alkenyl-6-halocarbazole expressed by formula I (R is 1W16C alkyl, alkyloxyalkyl or aralkyl; R1 and R2 are H or CH3; X is Br or I).
EXAMPLE: 3-Bromo-6-vinyl-9-n-dodecylcarbazole.
USE: A synthetic intermediate for a photoconductive material or a monomer for preparing a conjugated polymer to be a photoconductive material. Useful as a photosensitive material for electrophotography.
PROCESS: The formyl group or acetyl group of an N-substituted -3-formyl(or acetyl)- 6-halocarbazole expressed by formula II (Y is formyl or acetyl) is reacted with methylenephosphorane or ethylidenephosphorane generated from a phosphonium salt under anhydrous or phase transfer conditions and converted into an alkenyl group and give the compound of formula I.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1853280A JPS56115774A (en) | 1980-02-19 | 1980-02-19 | N-substituted-3-alkenyl-6-halocarbazole and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1853280A JPS56115774A (en) | 1980-02-19 | 1980-02-19 | N-substituted-3-alkenyl-6-halocarbazole and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56115774A true JPS56115774A (en) | 1981-09-11 |
| JPH0215536B2 JPH0215536B2 (en) | 1990-04-12 |
Family
ID=11974230
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1853280A Granted JPS56115774A (en) | 1980-02-19 | 1980-02-19 | N-substituted-3-alkenyl-6-halocarbazole and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS56115774A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003050086A1 (en) * | 2001-12-12 | 2003-06-19 | The University Of Sheffield | 2, 7 - substituted carbazoles and oligomers, polymers and co-polymers thereof |
-
1980
- 1980-02-19 JP JP1853280A patent/JPS56115774A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003050086A1 (en) * | 2001-12-12 | 2003-06-19 | The University Of Sheffield | 2, 7 - substituted carbazoles and oligomers, polymers and co-polymers thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0215536B2 (en) | 1990-04-12 |
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