JPS56115733A - Decoloring method of dihydroxydiphenylmethane - Google Patents
Decoloring method of dihydroxydiphenylmethaneInfo
- Publication number
- JPS56115733A JPS56115733A JP1924780A JP1924780A JPS56115733A JP S56115733 A JPS56115733 A JP S56115733A JP 1924780 A JP1924780 A JP 1924780A JP 1924780 A JP1924780 A JP 1924780A JP S56115733 A JPS56115733 A JP S56115733A
- Authority
- JP
- Japan
- Prior art keywords
- dihydroxydiphenylmethane
- colored
- boron hydride
- sodium boron
- decolored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PVAONLSZTBKFKM-UHFFFAOYSA-N diphenylmethanediol Chemical compound C=1C=CC=CC=1C(O)(O)C1=CC=CC=C1 PVAONLSZTBKFKM-UHFFFAOYSA-N 0.000 title abstract 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- MOOAHMCRPCTRLV-UHFFFAOYSA-N boron sodium Chemical compound [B].[Na] MOOAHMCRPCTRLV-UHFFFAOYSA-N 0.000 abstract 3
- 235000006408 oxalic acid Nutrition 0.000 abstract 2
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain the titled decolored compound, useful as a raw material for an epoxy resin not colored even in an oxidizing atmosphere for a long time readily, by heat-treating colored dihydroxydiphenylmethane solution at a low temperature with sodium boron hydride and oxalic acid.
CONSTITUTION: A solution of colored dihydroxydiphenylmethane (A) in an organic solvent, e.g. epichlorophdrin or benzene, is heated 0W150°C, preferably 0W100°C, in the presence of sodium boron hydride in an amount of 0.001W1wt% based on (A) and oxalic acid in an amount of 1.5 times that of the sodium boron hydride as an anhydride by weight, usually for 1W2hr, to give decolored dihydroxydiphenylmethane.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1924780A JPS6052738B2 (en) | 1980-02-20 | 1980-02-20 | Method for decolorizing dihydroxydiphenylmethane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1924780A JPS6052738B2 (en) | 1980-02-20 | 1980-02-20 | Method for decolorizing dihydroxydiphenylmethane |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS56115733A true JPS56115733A (en) | 1981-09-11 |
JPS6052738B2 JPS6052738B2 (en) | 1985-11-21 |
Family
ID=11994075
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1924780A Expired JPS6052738B2 (en) | 1980-02-20 | 1980-02-20 | Method for decolorizing dihydroxydiphenylmethane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6052738B2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5202505A (en) * | 1992-03-24 | 1993-04-13 | Hoechst Celanese Corporation | Purification of hydroxyphenyl alkanes |
US5756781A (en) * | 1995-09-29 | 1998-05-26 | General Electric Company | Method for making tris(hydroxyphenyl) compounds using ion exchange |
JPWO2020189201A1 (en) * | 2019-03-18 | 2020-09-24 |
-
1980
- 1980-02-20 JP JP1924780A patent/JPS6052738B2/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5202505A (en) * | 1992-03-24 | 1993-04-13 | Hoechst Celanese Corporation | Purification of hydroxyphenyl alkanes |
US5756781A (en) * | 1995-09-29 | 1998-05-26 | General Electric Company | Method for making tris(hydroxyphenyl) compounds using ion exchange |
JPWO2020189201A1 (en) * | 2019-03-18 | 2020-09-24 | ||
WO2020189201A1 (en) * | 2019-03-18 | 2020-09-24 | 三菱ケミカル株式会社 | Method for producing bisphenol and method for producing polycarbonate resin |
Also Published As
Publication number | Publication date |
---|---|
JPS6052738B2 (en) | 1985-11-21 |
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