JPS556423A - Production of benzthiazolylsulfenamide - Google Patents
Production of benzthiazolylsulfenamideInfo
- Publication number
- JPS556423A JPS556423A JP7704978A JP7704978A JPS556423A JP S556423 A JPS556423 A JP S556423A JP 7704978 A JP7704978 A JP 7704978A JP 7704978 A JP7704978 A JP 7704978A JP S556423 A JPS556423 A JP S556423A
- Authority
- JP
- Japan
- Prior art keywords
- primary
- water
- alkyl groups
- secondary amine
- benzthiazolylsulfenamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
PURPOSE: To virtually eliminate disposition problems of soiled water and waste water and produce the captioned amide by causing direct electrolytic oxidation crosscoupling of the specific primary or secondary amine and 2-mercaptobenzthiazole or bisbenzthiazole disulfide.
CONSTITUTION: The primary or secondary amine expressed by H2NR or HNR'R" (R is alkyl groups of straight-chain-, branch-or ring-form of C3 to C8, R', R" are similar alkyl groups of C2 thru C8 and indicate the groups forming rings with R', R") and MBT or MBTS are electrolytically oxidized and crosscoupled in the single or mixed solvent selected from aprotic polar solvents such as acetonitrile, nitrobenzene or other, protic solvents such as of alcohols, primary or secondary amines or other and water, without particularly adding supporting salt, whereby the benzthiazolylsulfenamide shown by formula I or II is directly produced.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7704978A JPS556423A (en) | 1978-06-27 | 1978-06-27 | Production of benzthiazolylsulfenamide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7704978A JPS556423A (en) | 1978-06-27 | 1978-06-27 | Production of benzthiazolylsulfenamide |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS556423A true JPS556423A (en) | 1980-01-17 |
Family
ID=13622915
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7704978A Pending JPS556423A (en) | 1978-06-27 | 1978-06-27 | Production of benzthiazolylsulfenamide |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS556423A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6536449B1 (en) | 1997-11-17 | 2003-03-25 | Mattson Technology Inc. | Downstream surface cleaning process |
CN104109879A (en) * | 2014-07-21 | 2014-10-22 | 河南省科学院高新技术研究中心 | Process for synthesizing rubber vulcanization accelerator TBBS by electrolytic method in water phase |
CN104109878A (en) * | 2014-07-21 | 2014-10-22 | 河南省科学院高新技术研究中心 | Process for synthesizing rubber vulcanization accelerator CBS by electrolytic method in water phase |
CN108727302A (en) * | 2017-10-23 | 2018-11-02 | 科迈化工股份有限公司 | A kind of environment-friendly type N tert butyl benzothiazole 2 sulfenamide(NS)Synthesis technology |
-
1978
- 1978-06-27 JP JP7704978A patent/JPS556423A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6536449B1 (en) | 1997-11-17 | 2003-03-25 | Mattson Technology Inc. | Downstream surface cleaning process |
CN104109879A (en) * | 2014-07-21 | 2014-10-22 | 河南省科学院高新技术研究中心 | Process for synthesizing rubber vulcanization accelerator TBBS by electrolytic method in water phase |
CN104109878A (en) * | 2014-07-21 | 2014-10-22 | 河南省科学院高新技术研究中心 | Process for synthesizing rubber vulcanization accelerator CBS by electrolytic method in water phase |
CN108727302A (en) * | 2017-10-23 | 2018-11-02 | 科迈化工股份有限公司 | A kind of environment-friendly type N tert butyl benzothiazole 2 sulfenamide(NS)Synthesis technology |
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