JPS553870A - Sulfurous acid method for eluting iodine - Google Patents
Sulfurous acid method for eluting iodineInfo
- Publication number
- JPS553870A JPS553870A JP7774278A JP7774278A JPS553870A JP S553870 A JPS553870 A JP S553870A JP 7774278 A JP7774278 A JP 7774278A JP 7774278 A JP7774278 A JP 7774278A JP S553870 A JPS553870 A JP S553870A
- Authority
- JP
- Japan
- Prior art keywords
- iodine
- eluted
- sulfurous acid
- adsorbed
- elution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 title abstract 8
- 229910052740 iodine Inorganic materials 0.000 title abstract 8
- 239000011630 iodine Substances 0.000 title abstract 8
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 6
- 238000010828 elution Methods 0.000 abstract 3
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 3
- 239000006227 byproduct Substances 0.000 abstract 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 150000008065 acid anhydrides Chemical class 0.000 abstract 1
- 239000003957 anion exchange resin Substances 0.000 abstract 1
- 239000012267 brine Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 1
- 239000012609 strong anion exchange resin Substances 0.000 abstract 1
Landscapes
- Treatment Of Water By Ion Exchange (AREA)
Abstract
PURPOSE: To simplify and rationalize the separation and refinement of iodine in the subsequent process while saving chemical and energy costs elution of iodine from a strong basic anion exchange resin with iodine adsorbed employing sulfurous acid.
CONSTITUTION: A molecular iodine is eluted by a solution containing sulfurous acid from an iodine-adsorbed resin in which strong anion exchange resin adsorbs iodine from a brine containing iodine. In addition, ionic iodine is eluted using a by-product sulfuric acid. Aus acid anhydride is introduced into a solution after iodine ion is eluted with a sulfuric acid by this method to dissolve a molecular iodine from the afore-mentioned iodine adsorbed resin with the sulfurous acid contact of about 0.5 to 6.0% by weight in terms of SO2. With such an arrangement, the elution (formula I) of the molecular iodine with sulfurous acid proceeds at a normal temperature. No huminic organic substance if adsorbed wot's be eluted. The by-product sulfuric acid is applicable to the elution formula X of iodine ion.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7774278A JPS553870A (en) | 1978-06-27 | 1978-06-27 | Sulfurous acid method for eluting iodine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7774278A JPS553870A (en) | 1978-06-27 | 1978-06-27 | Sulfurous acid method for eluting iodine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS553870A true JPS553870A (en) | 1980-01-11 |
| JPS6234681B2 JPS6234681B2 (en) | 1987-07-28 |
Family
ID=13642353
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7774278A Granted JPS553870A (en) | 1978-06-27 | 1978-06-27 | Sulfurous acid method for eluting iodine |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS553870A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100434725B1 (en) * | 2001-10-25 | 2004-06-07 | 니카코리아 (주) | Recovery of Iodine by Ion Exchange Resin |
| CN100345751C (en) * | 2005-04-29 | 2007-10-31 | 贵州宏福实业开发有限总公司 | Process of extracting iodine from dilute phosphoric acid produced in iodine-containing phosphate ore production |
| JP2009142764A (en) * | 2007-12-14 | 2009-07-02 | Japan Organo Co Ltd | Iodine recovery method and iodine recovery device from iodine-containing waste liquid |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5571416B2 (en) | 2010-03-17 | 2014-08-13 | Ｊｘ日鉱日石金属株式会社 | Copper sulfide ore leaching method |
| WO2011145688A1 (en) | 2010-05-19 | 2011-11-24 | Jx日鉱日石金属株式会社 | Method for processing acidic solution that contains iodide ions and iron ions |
-
1978
- 1978-06-27 JP JP7774278A patent/JPS553870A/en active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100434725B1 (en) * | 2001-10-25 | 2004-06-07 | 니카코리아 (주) | Recovery of Iodine by Ion Exchange Resin |
| CN100345751C (en) * | 2005-04-29 | 2007-10-31 | 贵州宏福实业开发有限总公司 | Process of extracting iodine from dilute phosphoric acid produced in iodine-containing phosphate ore production |
| JP2009142764A (en) * | 2007-12-14 | 2009-07-02 | Japan Organo Co Ltd | Iodine recovery method and iodine recovery device from iodine-containing waste liquid |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6234681B2 (en) | 1987-07-28 |
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