JPS5516024A - Preparation of polyester - Google Patents
Preparation of polyesterInfo
- Publication number
- JPS5516024A JPS5516024A JP8835678A JP8835678A JPS5516024A JP S5516024 A JPS5516024 A JP S5516024A JP 8835678 A JP8835678 A JP 8835678A JP 8835678 A JP8835678 A JP 8835678A JP S5516024 A JPS5516024 A JP S5516024A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- glycol
- titanium
- millimol
- lactam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Polyesters Or Polycarbonates (AREA)
Abstract
PURPOSE: To obtain a high-quality polyester with little softening point drop, good appearance, and useful for fibers, etc., by direct esterification between terephthalic acid and a glycol in the presence of a specific lactam and an organo-titanium compound followed by carrying out polycondensation.
CONSTITUTION: A direct esterification is carried out between terephthalic acid (along with a dicarboxylic acid such as adipic acid, sebacic acid, isophthalic acid, etc.) and a glycol such as ethylene glycol, 1,3-propanediol, neopentyl glycol, etc., in the presence of a lactam of formula (X is 3W5C alkylene, R is H or 1W4C alkyl), e.g. a pyrrolidone, ε-caprolactam, etc., and an organotitanium compound such as a titanium carboxylate, etc., in amounts of 5W100 millimol %, 0.5W50 millimol % (calculated and as titanium atom), both based on the dicarboxylic acid, respectively. The reaction product obtained above is subsequently subjected to polycondensation.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8835678A JPS5516024A (en) | 1978-07-21 | 1978-07-21 | Preparation of polyester |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8835678A JPS5516024A (en) | 1978-07-21 | 1978-07-21 | Preparation of polyester |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5516024A true JPS5516024A (en) | 1980-02-04 |
Family
ID=13940526
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8835678A Pending JPS5516024A (en) | 1978-07-21 | 1978-07-21 | Preparation of polyester |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5516024A (en) |
-
1978
- 1978-07-21 JP JP8835678A patent/JPS5516024A/en active Pending
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