[go: up one dir, main page]

JPS55129294A - Preparation of s-aryl o,o-dialkyl phosphorothioate - Google Patents

Preparation of s-aryl o,o-dialkyl phosphorothioate

Info

Publication number
JPS55129294A
JPS55129294A JP3721179A JP3721179A JPS55129294A JP S55129294 A JPS55129294 A JP S55129294A JP 3721179 A JP3721179 A JP 3721179A JP 3721179 A JP3721179 A JP 3721179A JP S55129294 A JPS55129294 A JP S55129294A
Authority
JP
Japan
Prior art keywords
aryl
group
phosphorothioate
substituted
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3721179A
Other languages
Japanese (ja)
Other versions
JPS6312070B2 (en
Inventor
Mitsuaki Mukoyama
Yutaka Watanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Chemiphar Co Ltd
Original Assignee
Nippon Chemiphar Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Chemiphar Co Ltd filed Critical Nippon Chemiphar Co Ltd
Priority to JP3721179A priority Critical patent/JPS55129294A/en
Publication of JPS55129294A publication Critical patent/JPS55129294A/en
Publication of JPS6312070B2 publication Critical patent/JPS6312070B2/ja
Granted legal-status Critical Current

Links

Abstract

PURPOSE: To obtain a phosphorothioate having different alkyl groups in high yield, by reacting a readily available S,S-diaryl O-alkyl phosphorodithioate with a trialkyltin salt of various alcohols.
CONSTITUTION: An S,S-diaryl O-alkyl phosphorodithioate of formula II: (R1 is aryl group which may be substituted by a halogen or alkyl group; R2 is straight or branched chain cycloalkyl group which may be substituted by an aryl or heterocyclic group) is reacted with an alkoxytrialkyl-stannan of formula III (R3 is straight, branched chain, or cycloalkyl group which may be substituted by an aryl or heterocyclic group; R4 is lower alkyl group) to give an S-aryl O,O-dialkyl phosphorothioate of formula I, e.g. S-p-chlorophenyl O-ethyl O-tetrahydrofuryl phosphorothioate in an 80% yield.
COPYRIGHT: (C)1980,JPO&Japio
JP3721179A 1979-03-29 1979-03-29 Preparation of s-aryl o,o-dialkyl phosphorothioate Granted JPS55129294A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3721179A JPS55129294A (en) 1979-03-29 1979-03-29 Preparation of s-aryl o,o-dialkyl phosphorothioate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3721179A JPS55129294A (en) 1979-03-29 1979-03-29 Preparation of s-aryl o,o-dialkyl phosphorothioate

Publications (2)

Publication Number Publication Date
JPS55129294A true JPS55129294A (en) 1980-10-06
JPS6312070B2 JPS6312070B2 (en) 1988-03-17

Family

ID=12491249

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3721179A Granted JPS55129294A (en) 1979-03-29 1979-03-29 Preparation of s-aryl o,o-dialkyl phosphorothioate

Country Status (1)

Country Link
JP (1) JPS55129294A (en)

Also Published As

Publication number Publication date
JPS6312070B2 (en) 1988-03-17

Similar Documents

Publication Publication Date Title
ATE1242T1 (en) PROCESS FOR THE PREPARATION OF 3-AMINO-1-HYDROXYPROPAN-1,1-DIPHOSPHONIC ACID.
JPS55129294A (en) Preparation of s-aryl o,o-dialkyl phosphorothioate
JPS565492A (en) Organic phosphate derivative, its preparation, and insecticide, acaricide, and nematocide comprising it
GB1507950A (en) Pyrimidine(4,6)diyl-bis-(thiono)(thiol)-phosphoric(phosphonic)acid esters process for their preparation and their use as insecticides or acaricides
JPS54129127A (en) Herbicidal composition
GB929099A (en) Thiolo- and thiolothiono-phosphoric, phosphonic and phosphinic acid esters
US3787539A (en) Thionothiolphosphoric acid o,s-diester amides
US3228999A (en) Alkoxy carbonyl, amino carbonyl and cyano derivatives of alkyl or aryl mercapto, sulphono or sulphoxido ethyl esters of thio-phosphorus acids
US3402224A (en) Diacid ester dimethyl thioether diphosphorus compounds
US3408425A (en) S-phenylmercaptocyanomethyl phosphoric-onic or-inic acid esters
GB1512179A (en) Thionobenzenephosphonic acid 0,0-diesters and their use as insecticides and acaricides
GB1272160A (en) Novel phosphorus-containing pyrazolyl esters, a process for their preparation, and their use as insecticides and acaricides
GB1509660A (en) O-pyrazolo-pyrimidinethionothiolphosphoric acid esters and their use as insecticides acaricides and nematicides
GB1315888A (en) Pyrazolo-thiono-phosphoric phosphonic acid esters
JPS56166197A (en) O-alkyl s-alkyl or -aryl thiophosphoric chloride
JPS5612398A (en) Organic phosphate derivative, its preparation, and germicide, insecticide and acaricide containing it
JPS55104294A (en) Thio- or dithiophosphoric acid ester, its preparation, and insecticide, miticide, and menatocide containing the compound as effective component
ES8607975A1 (en) Esters from the family of the N-phosphonomethylglycine and their use for the preparation of known herbicides.
JPS57139086A (en) Ethylene glycol derivative
FR2255307A1 (en) Insecticidal and acaricidal agents - comprising acyl 2-oxo-tetrahydrofuranyl (thiono) thiophosphonic acid esters
JPS5511514A (en) Preparation of colloidal solution of organic phosphorus- containing zirconium salt
DE3572667D1 (en) Process for the preparation of o-alkyl 5-(alpha ramified alkyl)alkyl phosphonothioates
DE3061105D1 (en) Pyrazolin-5-on-yl-methyl-(di)thiophosphoric acid esters, process for their preparation and their use as pesticides
GB1529781A (en) (thiono)(thiol)-pyridazinephosphoric(phosphonic)acid esters and ester-amides and their use as insecticides and acaricides
ES471749A1 (en) Pyridazinon(thiono)-phosphoric acid esters, process for their preparation and their use as insecticides and acaricides.