JPS5510421A - Treating method for waste sulfuric acid containing toluene sulfonic acid derivative - Google Patents
Treating method for waste sulfuric acid containing toluene sulfonic acid derivativeInfo
- Publication number
- JPS5510421A JPS5510421A JP8175678A JP8175678A JPS5510421A JP S5510421 A JPS5510421 A JP S5510421A JP 8175678 A JP8175678 A JP 8175678A JP 8175678 A JP8175678 A JP 8175678A JP S5510421 A JPS5510421 A JP S5510421A
- Authority
- JP
- Japan
- Prior art keywords
- soln
- sulfuric acid
- sulfonic acid
- toluene sulfonic
- contg
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title abstract 10
- NIXKBAZVOQAHGC-UHFFFAOYSA-N phenylmethanesulfonic acid Chemical class OS(=O)(=O)CC1=CC=CC=C1 NIXKBAZVOQAHGC-UHFFFAOYSA-N 0.000 title abstract 3
- 239000002699 waste material Substances 0.000 title abstract 3
- -1 isopropyl alcohol Chemical class 0.000 abstract 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 2
- JTZLIGVBEAGAFZ-UHFFFAOYSA-N 5-chloro-4-methyl-2-nitrobenzenesulfonic acid Chemical class CC1=CC([N+]([O-])=O)=C(S(O)(=O)=O)C=C1Cl JTZLIGVBEAGAFZ-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 235000011114 ammonium hydroxide Nutrition 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 1
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 150000004292 cyclic ethers Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
Landscapes
- Physical Water Treatments (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To recover sulfuric acid from a waste sulfuric acid soln. contg. toluene sulfonic acid derivatives by adding a specified org. solvent to the soln. and by simultaneously converting sulfuric acid contained into its ammonium salt to separate the soln. into two layers.
CONSTITUTION: To a waste sulfuric acid soln. contg. toluene sulfonic acid derivatives such as isomers of 6-chloro-3-nitrotoluene-4-sulfonic acid is added about 2W 100, pref. 10W60 vol% of one or more kinds of solvents selected from 2W6C alcohols such as isopropyl alcohol, 2W4C ketones such as acetone, 2W4C aliph. esters such as methyl acetate, 3W8C aliph. carboxylic acids such as butyric acid, and 5- and 6-membered cyclic ethers such as dixoane. After adding ammonia gas or ammonia water furthermore, the soln. is allowed to stand, thus being separated into an org. solvent layer contg. the derivatives and an aq. soln. layer contg. ammonium sulfate. The layers are then taken out separately.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8175678A JPS5510421A (en) | 1978-07-05 | 1978-07-05 | Treating method for waste sulfuric acid containing toluene sulfonic acid derivative |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8175678A JPS5510421A (en) | 1978-07-05 | 1978-07-05 | Treating method for waste sulfuric acid containing toluene sulfonic acid derivative |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5510421A true JPS5510421A (en) | 1980-01-24 |
| JPS614770B2 JPS614770B2 (en) | 1986-02-13 |
Family
ID=13755277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8175678A Granted JPS5510421A (en) | 1978-07-05 | 1978-07-05 | Treating method for waste sulfuric acid containing toluene sulfonic acid derivative |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5510421A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4608245A (en) * | 1985-10-17 | 1986-08-26 | Gaddy James L | Method of separation of sugars and concentrated sulfuric acid |
| JPH0452967U (en) * | 1990-09-13 | 1992-05-06 | ||
| JP2021020832A (en) * | 2019-07-30 | 2021-02-18 | Ｊｆｅスチール株式会社 | Cleaning method of mother liquid of ammonium sulfate, and cleaning apparatus of mother liquid of ammonium sulfate |
-
1978
- 1978-07-05 JP JP8175678A patent/JPS5510421A/en active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4608245A (en) * | 1985-10-17 | 1986-08-26 | Gaddy James L | Method of separation of sugars and concentrated sulfuric acid |
| JPH0452967U (en) * | 1990-09-13 | 1992-05-06 | ||
| JP2021020832A (en) * | 2019-07-30 | 2021-02-18 | Ｊｆｅスチール株式会社 | Cleaning method of mother liquid of ammonium sulfate, and cleaning apparatus of mother liquid of ammonium sulfate |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS614770B2 (en) | 1986-02-13 |
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