JPH1199866A - Laminate material for vehicle seat, and its manufacture - Google Patents
Laminate material for vehicle seat, and its manufactureInfo
- Publication number
- JPH1199866A JPH1199866A JP10182682A JP18268298A JPH1199866A JP H1199866 A JPH1199866 A JP H1199866A JP 10182682 A JP10182682 A JP 10182682A JP 18268298 A JP18268298 A JP 18268298A JP H1199866 A JPH1199866 A JP H1199866A
- Authority
- JP
- Japan
- Prior art keywords
- conductive
- vehicle seat
- weight
- parts
- conductive adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002648 laminated material Substances 0.000 title claims abstract description 37
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000000853 adhesive Substances 0.000 claims abstract description 58
- 230000001070 adhesive effect Effects 0.000 claims abstract description 58
- 239000012790 adhesive layer Substances 0.000 claims abstract description 37
- 239000007787 solid Substances 0.000 claims abstract description 22
- 239000003063 flame retardant Substances 0.000 claims description 43
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 39
- 229910052698 phosphorus Inorganic materials 0.000 claims description 30
- 239000011574 phosphorus Substances 0.000 claims description 30
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 28
- 239000011231 conductive filler Substances 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 9
- 229910052736 halogen Inorganic materials 0.000 claims description 9
- 150000002367 halogens Chemical class 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 238000010030 laminating Methods 0.000 claims description 4
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 1
- 230000000149 penetrating effect Effects 0.000 claims 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract description 25
- 239000006260 foam Substances 0.000 abstract description 24
- 239000004744 fabric Substances 0.000 abstract description 22
- 239000000839 emulsion Substances 0.000 abstract description 15
- 239000006229 carbon black Substances 0.000 abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 11
- 239000000203 mixture Substances 0.000 abstract description 11
- 238000001035 drying Methods 0.000 abstract description 4
- 230000035939 shock Effects 0.000 abstract description 2
- 239000008247 solid mixture Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 16
- 230000000694 effects Effects 0.000 description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 8
- 230000005611 electricity Effects 0.000 description 8
- 230000003068 static effect Effects 0.000 description 8
- 239000000567 combustion gas Substances 0.000 description 7
- 230000006870 function Effects 0.000 description 7
- -1 polyethylene Polymers 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 5
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 4
- 235000011007 phosphoric acid Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229920000388 Polyphosphate Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 239000006261 foam material Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910000039 hydrogen halide Inorganic materials 0.000 description 2
- 239000012433 hydrogen halide Substances 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 2
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- PQYJRMFWJJONBO-UHFFFAOYSA-N Tris(2,3-dibromopropyl) phosphate Chemical compound BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr PQYJRMFWJJONBO-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- RAYIMXZLSRHMTK-UHFFFAOYSA-N bis(2,3-dibromopropyl) 2,3-dichloropropyl phosphate Chemical compound ClCC(Cl)COP(=O)(OCC(Br)CBr)OCC(Br)CBr RAYIMXZLSRHMTK-UHFFFAOYSA-N 0.000 description 1
- GPZPNAVMOODHSK-UHFFFAOYSA-N bis(3-chloropropyl) octyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCCl)OCCCCl GPZPNAVMOODHSK-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000007770 graphite material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000002917 halogen containing inorganic group Chemical group 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 235000014786 phosphorus Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- JZZBTMVTLBHJHL-UHFFFAOYSA-N tris(2,3-dichloropropyl) phosphate Chemical compound ClCC(Cl)COP(=O)(OCC(Cl)CCl)OCC(Cl)CCl JZZBTMVTLBHJHL-UHFFFAOYSA-N 0.000 description 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 description 1
- GTRSAMFYSUBAGN-UHFFFAOYSA-N tris(2-chloropropyl) phosphate Chemical compound CC(Cl)COP(=O)(OCC(C)Cl)OCC(C)Cl GTRSAMFYSUBAGN-UHFFFAOYSA-N 0.000 description 1
- LKOCAGKMEUHYBV-UHFFFAOYSA-N tris(3-bromo-3-chloropropyl) phosphate Chemical compound ClC(Br)CCOP(=O)(OCCC(Cl)Br)OCCC(Cl)Br LKOCAGKMEUHYBV-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Seats For Vehicles (AREA)
- Laminated Bodies (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、車両シートに着座
した者が低電位物に触れたときの静電気による電撃感を
抑えるための車両シート用ラミネート材及びその製法に
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a laminated material for a vehicle seat for suppressing an electric shock due to static electricity when a person sitting on the vehicle seat touches a low-potential object, and a method of manufacturing the same.
【0002】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
自動車等の車両用シートは降車時の静電気発生に伴う不
快感(電撃感)を緩和するため、静電気防止用界面活性
剤の噴霧等、数々の静電気防止処置がなされてきた。2. Description of the Related Art
In order to alleviate the discomfort (electric shock) caused by the generation of static electricity when getting off the vehicle, various antistatic treatments such as spraying of a surfactant for preventing static electricity have been taken.
【0003】現在、最も有効とされるのは、導電糸を織
り込んだシート表皮の裏面を導電バッキング材でコーテ
ィングした上で、シートパッドとしてのウレタンフォー
ムに接着剤により接着するか又はフレームラミネートす
る(ウレタンフォームを炎で溶かして積層する)ことに
より得られる車両シート用ラミネート材である。ここ
で、導電バッキング材とは、アクリル樹脂などの樹脂成
分中に、カーボンなどの導電性物質のほか、シート表皮
を燃えにくくするための三酸化アンチモンなどの難燃剤
が含有されたものをいう。At present, the most effective method is to coat the back surface of the sheet skin in which the conductive yarn is woven, with a conductive backing material, and then bond it to urethane foam as a seat pad with an adhesive or frame laminate ( This is a laminate material for a vehicle seat obtained by melting and laminating urethane foam with a flame. Here, the conductive backing material refers to a material in which a resin component such as an acrylic resin contains, in addition to a conductive material such as carbon, a flame retardant such as antimony trioxide for making the skin of the sheet difficult to burn.
【0004】しかし、導電バッキング材の樹脂成分は専
らバインダとして用いられるため少量含有されているに
過ぎず、このためシート表皮にはカーボンや難燃剤のゴ
ワゴワした風合いが出てしまうという問題がある。ま
た、シート表皮に導電バッキング材をコーティングする
工程が増えるため、生産工程が多くなり、コスト的に高
価になるという問題もある。However, since the resin component of the conductive backing material is used exclusively as a binder, it is contained only in a small amount, and there is a problem that a rough texture of carbon or a flame retardant appears on the sheet skin. In addition, since the number of steps for coating the sheet skin with the conductive backing material increases, there is a problem that the number of production steps increases and the cost increases.
【0005】一方、その他の従来例として、例えば特開
平63−194940号公報には、クッション材(シー
トパッド)に導電性物質を含浸させ、これを導電性を有
する表皮材本体と接着させることにより静電防止機能を
付与させた表皮材が開示されている。しかし、この場合
には、シートパッドに導電性物質を含浸させる工程が増
えるため、生産工程が多くなり、製造コストが高くなる
という問題がある。On the other hand, as another conventional example, for example, Japanese Patent Application Laid-Open No. 63-194940 discloses that a cushioning material (seat pad) is impregnated with a conductive substance and adhered to a conductive skin material body. A skin material having an antistatic function is disclosed. However, in this case, the number of steps for impregnating the sheet pad with the conductive substance increases, so that there is a problem that the number of production steps increases and the manufacturing cost increases.
【0006】また、特開平1−171936号公報には
導電性繊維を混入させた編布に導電性発泡材(シートパ
ッド)を貼付した立毛調静電気防止編布が開示されてい
る。しかし、この場合には、シートパッドとして、ポリ
ウレタンやポリエチレンなどの樹脂をベースに導電性粒
子例えばカーボン粒子や金属粒子を混入させて発泡した
ものを用いるが、導電性が不均一になりやすく、性能が
ばらつきやすいという問題がある。Japanese Unexamined Patent Publication (Kokai) No. 1-171936 discloses a napped fabric antistatic knitted fabric in which a conductive foam material (sheet pad) is adhered to a knitted fabric mixed with conductive fibers. However, in this case, as the seat pad, a foam made by mixing conductive particles such as carbon particles or metal particles based on a resin such as polyurethane or polyethylene is used, but the conductivity tends to be nonuniform, and the performance is high. There is a problem that is easy to vary.
【0007】本発明は上記課題に鑑みなされたものであ
り、静電気ショックを防止する機能を安定に備え、低コ
ストで製造できソフトな風合いが得られる車両シート用
ラミネート材及びその製法を提供することを目的とす
る。The present invention has been made in view of the above problems, and provides a laminate material for a vehicle seat, which has a function of preventing electrostatic shock stably, can be manufactured at low cost, and has a soft feel, and a method for producing the same. With the goal.
【0008】[0008]
【課題を解決するための手段、発明の実施の形態及び発
明の効果】上記課題を解決するため、本発明の車両シー
ト用ラミネート材は、導電繊維を用いて形成したシート
表皮と、クッション性を有するシートパッドと、導電性
フィラーを含み、前記シート表皮と前記シートパッドと
を接着する導電性接着層とを備えたことを特徴とする。Means for Solving the Problems, Embodiments of the Invention and Effects of the Invention In order to solve the above-mentioned problems, a laminate material for a vehicle seat of the present invention provides a seat skin formed using conductive fibers and a cushioning property. And a conductive adhesive layer including a conductive filler and bonding the sheet skin and the sheet pad.
【0009】かかる車両シート用ラミネート材では、シ
ート表皮の表面に発生した電荷はシート表皮の導電繊維
又は導電性接着層中の導電性フィラーに集められ、広範
囲に分散されることにより又は自己放電により除電され
る。このため、車両シートに着座した者が低電位物に触
れたときの静電気による電撃感を抑えることができると
いう効果が得られる。In such a laminate material for a vehicle seat, electric charges generated on the surface of the seat skin are collected in conductive fibers or conductive fillers in the conductive adhesive layer of the seat skin and dispersed over a wide range or by self-discharge. Static electricity is removed. For this reason, the effect of being able to suppress the sense of electric shock due to static electricity when a person sitting on the vehicle seat touches a low-potential object is obtained.
【0010】また、従来例である特開平1−17193
6号ではシートパッドに導電性粒子を均一に混入させる
ことが難しいため、シートパッドのうちシート表皮側に
導電性粒子が十分分布せず、電撃感防止機能が安定して
得られないおそれがあったが、本発明ではシート表皮と
シートパッドの間に導電性フィラーを有する導電性接着
層を設けたため、電撃感防止機能が安定して得られる。[0010] Japanese Patent Laid-Open Publication No.
In No. 6, since it is difficult to uniformly mix the conductive particles into the seat pad, the conductive particles are not sufficiently distributed on the skin side of the seat pad, and there is a possibility that the function of preventing a sense of electric shock cannot be stably obtained. However, in the present invention, since the conductive adhesive layer having the conductive filler is provided between the sheet skin and the seat pad, the function of preventing electric shock is stably obtained.
【0011】更に、従来は導電バッキング材をシート表
皮裏面にコーティングしていたためその導電バッキング
材によって風合いが悪化するという問題があったが、本
発明では導電バッキング材を使用しないため、そのよう
な問題がなく、風合いが良好になるという効果が得られ
る更にまた、シート表皮とシートパッドとを導電性接着
剤で接着するという1つの工程で製造されるため、多工
程を有する場合に比べて生産コストが低いという効果が
得られる。Further, conventionally, there has been a problem that the conductive backing material is coated on the back surface of the sheet skin, so that the conductive backing material deteriorates the texture. However, the present invention does not use the conductive backing material. And the effect of improving the feeling is obtained. Furthermore, since it is manufactured in a single step of bonding the sheet skin and the seat pad with a conductive adhesive, the production cost is higher than in the case of having multiple steps. Is low.
【0012】本発明において、導電性接着剤に含まれる
導電性フィラーとしては、銀・銅・鉄等の金属類・金属
酸化物類、カーボンブラック・グラファイト等のカーボ
ン類等の粉末や繊維状のものがあげられる。このうちカ
ーボン類は、金属類・金属酸化物類に比べて、接着剤
の接着性能阻害が低い、低添加量で良好な導電効果が
得られる、比重が低く分散性に優れる、等の点から好
ましい。In the present invention, the conductive filler contained in the conductive adhesive includes powders such as metals and metal oxides such as silver, copper and iron, carbons such as carbon black and graphite, and fibrous materials. There are things. Among them, carbons are lower in adhesion performance of the adhesive than in the case of metals and metal oxides, a good conductive effect can be obtained with a small amount of addition, and low in specific gravity and excellent in dispersibility. preferable.
【0013】導電性接着剤の接着剤としては、ホットメ
ルト、エポキシ・ウレタン等の油溶性、酢ビ・アクリル
・エチレン・スチレン等の共重合体及び又は単量体及び
又は混合体の水性、クロロプレン・SBR等の溶剤系が
あるが、これらは必ずしも油溶性・水性・溶剤系に限ら
ず例えば、クロロプレン・SBR等の水性であっても、
エポキシ・ウレタン等の溶剤系であってもかまわない。Examples of the adhesive for the conductive adhesive include oil-soluble materials such as hot melt, epoxy and urethane, copolymers such as vinyl acetate, acryl, ethylene and styrene and / or aqueous and chloroprene monomers and / or mixtures. There are solvent systems such as SBR, but these are not necessarily limited to oil-soluble, aqueous and solvent systems.
Solvents such as epoxy and urethane may be used.
【0014】導電性フィラーの添加量については、バイ
ンダーである接着剤の固形分100重量部に対し導電性
フィラーを0.1〜200重量部添加することが好まし
い。添加量が0.1重量部を下回ると導電効果がほとん
どなくなるため好ましくなく、200重量部を越えると
接着性が低下し、コストが上昇し、風合いが硬化する傾
向にあるため好ましくない。更に、2〜30重量部添加
することがより好ましく、この場合、電撃感の抑制効
果、接着性、風合いが極めて優れている。The amount of the conductive filler is preferably 0.1 to 200 parts by weight based on 100 parts by weight of the solid content of the adhesive as a binder. If the amount is less than 0.1 part by weight, the conductive effect is almost completely lost, which is not preferable. If the amount exceeds 200 parts by weight, the adhesiveness is reduced, the cost is increased, and the hand tends to be hardened, which is not preferable. Further, it is more preferable to add 2 to 30 parts by weight. In this case, the effect of suppressing the electric shock feeling, the adhesiveness, and the feeling are extremely excellent.
【0015】なお、導電性接着剤には所望により、ロジ
ン樹脂や石油樹脂などの粘着付与樹脂、酸化チタンや酸
化鉄などの顔料、炭酸カルシウムやクレーなどの充填
材、酸化亜鉛やフェノール誘導体などの老化防止剤、ポ
リオキシエチレン誘導体やラウリル硫酸ナトリウムなど
の界面活性剤等の添加を行ってもよい。As the conductive adhesive, if desired, tackifying resins such as rosin resin and petroleum resin, pigments such as titanium oxide and iron oxide, fillers such as calcium carbonate and clay, and zinc oxide and phenol derivatives. Antioxidants, surfactants such as polyoxyethylene derivatives and sodium lauryl sulfate may be added.
【0016】シート表皮としては、導電繊維を用いて形
成したものであれば特に限定されず、例えば導電糸織り
込み済みの織物、編み物などのほか、車両シートの表皮
として適しているものならば使用可能である。シートパ
ッドとしては、クッション性を有するものであれば特に
限定されず、例えば多孔性物質であるウレタンフォーム
などのほか、他の発泡材やフェルト、不織布なども使用
可能である。The seat skin is not particularly limited as long as it is formed using conductive fibers. For example, a woven fabric or a knitted fabric in which conductive yarn has been woven can be used as long as it is suitable as a skin of a vehicle seat. It is. The seat pad is not particularly limited as long as it has a cushioning property. For example, in addition to urethane foam which is a porous substance, other foam materials, felts, nonwoven fabrics and the like can be used.
【0017】本発明の車両シート用ラミネート材におい
ては、導電性接着層は5〜100g/m2 であることが
接着性・導電性を良好に得るうえで好ましい。5g/m
2 未満では接着性・導電性が低くなる傾向にあるため好
ましくなく、また100g/m2 を超えると風合いが硬
くなる傾向にあるため好ましくない。In the laminate material for a vehicle seat of the present invention, the conductive adhesive layer is preferably 5 to 100 g / m 2 in order to obtain good adhesiveness and conductivity. 5g / m
Not preferable because there is a tendency that the adhesion-conductive lower is less than 2, is not preferable because there is a tendency that the texture exceeds 100 g / m 2 becomes hard.
【0018】本発明の車両シート用ラミネート材におい
ては、導電性接着層の一部はシート表皮及び/シートパ
ッドに滲み込んだ状態で存在していてもよい。シート表
皮が導電繊維を用いて形成されているため通常は導電性
接着剤が浸透しやすく、またシートパッドとして例えば
多孔性物質や不織布などを用いた場合には同様に導電性
接着剤が浸透しやすいため、結果的に導電性接着層の一
部がこれらに滲み込んだ状態で存在する。このように導
電性接着層の一部がシート表皮及び/又はシートパッド
に滲み込んだ状態で存在する場合には、導電性接着層の
使用量が5〜100g/m2 のとき、その導電性接着層
の厚さはシート表皮及び/又はシートパッドに滲み込ん
だ部分も含めると5〜1000μmとなる。In the laminate material for a vehicle seat of the present invention, a part of the conductive adhesive layer may be present in a state of seeping into the seat skin and / or the seat pad. Since the sheet skin is formed using conductive fibers, the conductive adhesive usually penetrates easily, and when the sheet pad is made of, for example, a porous substance or a nonwoven fabric, the conductive adhesive similarly penetrates. As a result, a part of the conductive adhesive layer is present in a state of seeping into these. As described above, when a part of the conductive adhesive layer is present in a state of seeping into the sheet skin and / or the seat pad, when the amount of the conductive adhesive layer used is 5 to 100 g / m 2 , The thickness of the adhesive layer is 5 to 1000 μm including the portion that has permeated into the sheet skin and / or the sheet pad.
【0019】本発明の車両シート用ラミネート剤におい
ては、導電性接着層は、リン系難燃剤を含んでいること
が好ましい。導電性フィラー(特にカーボン)を含むラ
ミネート材では、リン系難燃剤以外の難燃剤(例えばハ
ロゲン系難燃剤や無機金属化合物系難燃剤)を用いた場
合、燃焼過程で導電性フィラーがろうそくの芯のように
なり火が燃え続けるいわゆるろうそく現象を抑制でき
ず、長期間燃焼し続けるという問題がある。これに対し
て、リン系難燃剤を用いた場合、このようなろうそく現
象を抑制し、迅速に燃焼をストップさせることができる
ので好ましい。なお、このリン系難燃剤の難燃化機構に
ついては一般に次のごとく説明される。即ち、リン系難
燃剤は火災に晒されたとき、リン化合物→リン酸→メタ
リン酸→ポリメタリン酸と順次分解し、生成したリン酸
層が不揮発性の保護皮膜を形成し、また、ポリメタリン
酸による脱水作用が有機物を炭化の方向に進め、炭化皮
膜を形成し、物理的に酸素の供給を遮断し、難燃作用を
与える。In the vehicle seat laminate of the present invention, the conductive adhesive layer preferably contains a phosphorus-based flame retardant. In a laminate material containing a conductive filler (particularly carbon), when a flame retardant other than a phosphorus-based flame retardant (for example, a halogen-based flame retardant or an inorganic metal compound-based flame retardant) is used, the conductive filler becomes a candle core during the burning process. Thus, there is a problem that the so-called candle phenomenon in which the fire keeps burning cannot be suppressed, and the burning continues for a long time. On the other hand, the use of a phosphorus-based flame retardant is preferable because such a candle phenomenon can be suppressed and combustion can be stopped quickly. The flame retarding mechanism of the phosphorus-based flame retardant is generally described as follows. That is, when the phosphorus-based flame retardant is exposed to a fire, the phosphorus compound is sequentially decomposed in the order of a phosphorus compound → phosphoric acid → metaphosphoric acid → polymetaphosphoric acid, and the generated phosphoric acid layer forms a non-volatile protective film. The dehydration function advances the organic matter in the direction of carbonization, forms a carbonized film, physically shuts off the supply of oxygen, and provides a flame retardant effect.
【0020】リン系難燃剤としては、無機リン系難燃
剤、有機リン系難燃剤のいずれでも使用でき、無機リン
系難燃剤は例えばリンのほか、リン酸、オルトリン酸、
メタリン酸、ポリリン酸及びそれらの塩などが挙げられ
る。有機リン系難燃剤としては例えばホスフェート類、
ホスホネート類、ホスファイト類、含リンポリオール
類、ホスフォネート型ポリオール類、ホスフェート型ポ
リオール類などが挙げられる。このうちホスフェート類
としては、トリメチルホスフェート、トリエチルホスフ
ェート、トリブチルホスフェート、トリオクチルホスフ
ェート、トリブトキシエチルホスフェート、トリフェニ
ルホスフェート、トリクレジルホスフェート、クレジル
ジフェニルホスフェート、オクチルジフェニルホスフェ
ートなどの非含ハロゲン化合物や、トリス(クロロエチ
ル)ホスフェート、トリス(2−クロロプロピル)ホス
フェート、トリス(2,3−ジクロロプロピル)ホスフ
ェート、トリス(2,3−ジブロモプロピル)ホスフェ
ート、トリス(ブロモクロロプロピル)ホスフェート、
ビス(2,3−ジブロモプロピル)−2,3−ジクロロ
プロピルホスフェート、ビス(クロロプロピル)モノオ
クチルホスフェート、ポリホスホネート、ポリホスフェ
ート、芳香族ポリホスフェートなどの含ハロゲン化合物
が挙げられる。これらのリン系難燃剤は単独で使用して
も、二種類以上の併用であってもよい。As the phosphorus-based flame retardant, any of inorganic phosphorus-based flame retardants and organic phosphorus-based flame retardants can be used. The inorganic phosphorus-based flame retardant is, for example, phosphorus, phosphoric acid, orthophosphoric acid, or the like.
Examples include metaphosphoric acid, polyphosphoric acid, and salts thereof. As the organic phosphorus-based flame retardant, for example, phosphates,
Examples include phosphonates, phosphites, phosphorus-containing polyols, phosphonate-type polyols, and phosphate-type polyols. Among them, as the phosphates, non-halogen-containing compounds such as trimethyl phosphate, triethyl phosphate, tributyl phosphate, trioctyl phosphate, tributoxyethyl phosphate, triphenyl phosphate, tricresyl phosphate, cresyl diphenyl phosphate, octyl diphenyl phosphate, Tris (chloroethyl) phosphate, tris (2-chloropropyl) phosphate, tris (2,3-dichloropropyl) phosphate, tris (2,3-dibromopropyl) phosphate, tris (bromochloropropyl) phosphate,
Halogen-containing compounds such as bis (2,3-dibromopropyl) -2,3-dichloropropyl phosphate, bis (chloropropyl) monooctyl phosphate, polyphosphonate, polyphosphate, and aromatic polyphosphate. These phosphorus-based flame retardants may be used alone or in combination of two or more.
【0021】リン系難燃剤のうちハロゲンを含むものに
ついては、燃焼時にハロゲン化水素を含むガスが放出さ
れるので環境上好ましくなく、この点を考慮すれば非含
ハロゲンのリン系難燃剤が好ましい。リン系難燃剤の添
加比率については、バインダである接着剤の固形分10
0重量部に対しリン系難燃剤を1〜200重量部添加す
るのが好ましい。添加量が1重量部を下回ると難燃効果
が十分得られないため好ましくなく、200重量部を越
えると接着性が低下したりコストが上昇したり風合いが
硬化したりするため好ましくない。また、5〜50重量
部添加することがより好ましく、この場合、難燃効果、
接着性、風合いが極めて優れている。Of the phosphorus-based flame retardants, those containing halogen are not environmentally preferable because a gas containing hydrogen halide is released during combustion, and in view of this, a halogen-free phosphorus-based flame retardant is preferred. . Regarding the addition ratio of the phosphorus-based flame retardant, the solid content of the adhesive as a binder was 10%.
It is preferable to add 1 to 200 parts by weight of a phosphorus-based flame retardant to 0 parts by weight. If the amount is less than 1 part by weight, the flame-retardant effect cannot be sufficiently obtained, so that it is not preferable. If the amount exceeds 200 parts by weight, the adhesiveness is reduced, the cost is increased, and the texture is hardened. Further, it is more preferable to add 5 to 50 parts by weight, in this case, a flame retardant effect,
Excellent adhesion and texture.
【0022】本発明の車両シート用ラミネート材の製法
は、導電繊維を用いて形成したシート表皮とクッション
性を有するシートパッドとを導電性フィラーを含む導電
性接着剤で接着する工程を含む。ここで、接着剤の塗布
方法としては、塗布面(シート表皮の裏面又はシートパ
ッドの表面)の全面に塗布してもよいが、線状・格子状
又は点状に塗布した場合には全面塗布に比べて接着剤の
目付量を低減させることができるうえ、得られるラミネ
ート材の風合いを柔らかくすることができるので好まし
い。The method of manufacturing a laminate material for a vehicle seat according to the present invention includes a step of bonding a seat skin formed using conductive fibers and a seat pad having a cushioning property with a conductive adhesive containing a conductive filler. Here, as a method of applying the adhesive, the adhesive may be applied to the entire surface to be applied (the back surface of the sheet skin or the surface of the sheet pad). This is preferable because the weight per unit area of the adhesive can be reduced and the texture of the obtained laminate can be softened.
【0023】この製法においては、シートパッドに導電
性接着剤を塗布し、その塗布面にシート表皮を載せて接
着することが好ましい。通常、シートパッドはシート表
皮よりも厚いため作業性が良く、また車両シート用ラミ
ネート材がシート表皮、接着層、シートパッド、接着
層、裏基布というラミネート構造の場合には、シートパ
ッドの表裏両面に接着剤を塗布することにより接着工程
を1つにまとめることができるので好ましい。In this manufacturing method, it is preferable that a conductive adhesive is applied to the sheet pad, and that the surface of the sheet is placed on the applied surface and bonded. Normally, the seat pad is thicker than the seat skin, so workability is good. Also, when the vehicle seat laminate has a laminated structure of the seat skin, adhesive layer, seat pad, adhesive layer, backing fabric, the front and back of the seat pad It is preferable to apply an adhesive to both surfaces so that the bonding process can be integrated into one.
【0024】また、この製法においては、導電性フィラ
ーはカーボン類であること、導電性接着剤は接着剤固形
分100重量部に対し導電性フィラーを0.1〜200
重量部含むこと、導電性接着剤の使用量は固形分換算で
5〜100g/m2 であることが好ましいが、これらが
好ましい理由については既述したとおりである。In this production method, the conductive filler is carbon, and the conductive adhesive is 0.1 to 200 parts by weight based on 100 parts by weight of the solid content of the adhesive.
It is preferable to include the parts by weight and the amount of the conductive adhesive to be used is 5 to 100 g / m 2 in terms of the solid content.
【0025】更に、この製法においては、導電性接着剤
はリン系難燃剤を含むこと、特にそのリン系難燃剤を1
〜200重量部含むこと、リン系難燃剤としては非含ハ
ロゲンであることが好ましいが、これらが好ましい理由
については詳述したとおりである。Further, in this manufacturing method, the conductive adhesive contains a phosphorus-based flame retardant.
It is preferable that the phosphorus-containing flame retardant is non-halogen-containing as the phosphorus-containing flame retardant.
【0026】[0026]
[実施例1]アクリルエマルジョン系接着剤(アイカ工
業製アイカアイボンRA−233、固形分含有率55重
量%、以下同じ)に、その固形分100重量部に対しカ
ーボンブラック15重量部を添加し、均一に分散した状
態となるまで攪拌した。この接着剤をウレタンフォーム
の片面に格子状塗布形式のグラビアロールで固形分換算
で50g/m2 塗布し(膜厚50μm)、直ちにウレタ
ンフォームの接着剤塗布面にニットファブリック(導電
糸を折り込み済みのもの、(株)セーレン製の商品名グ
ランスE、以下同じ)を重ね合わせ、圧力をかけながら
100℃乾燥炉中で2分間乾燥し、実施例1の車両シー
ト用ラミネート材を得た。Example 1 15 parts by weight of carbon black was added to 100 parts by weight of a solid content of an acrylic emulsion-based adhesive (Aika Aibon RA-233 manufactured by Aika Kogyo, solid content 55% by weight, the same applies hereinafter). The mixture was stirred until a uniform dispersion was obtained. The adhesive is applied to one surface of the urethane foam with a gravure roll of a grid-like application type at a solid content of 50 g / m 2 (film thickness: 50 μm), and a knit fabric (with conductive yarn folded immediately) is applied to the adhesive application surface of the urethane foam. And Glance E (trade name; manufactured by Seiren Co., Ltd .; the same applies hereinafter)) and dried in a drying oven at 100 ° C. for 2 minutes while applying pressure to obtain a laminate material for vehicle seats of Example 1.
【0027】この車両シート用ラミネート材は、図1に
示すとおり、シート表皮であるニットファブリック11
と、シートパッドであるウレタンフォーム13と、両者
を接着する導電性接着層15とを備えている。このうち
導電性接着層15は、図2に示すように格子状であり、
カーボンブラック17を含み、その一部がニットファブ
リック11及びウレタンフォーム13に滲み込んでい
る。この導電性接着層15の厚さ(滲み込んだ部分を含
む)は373μmであった。As shown in FIG. 1, the laminated material for a vehicle seat is a knit fabric 11 which is a seat skin.
And a urethane foam 13 serving as a seat pad, and a conductive adhesive layer 15 for bonding the two. Among them, the conductive adhesive layer 15 has a lattice shape as shown in FIG.
The carbon black 17 is contained, and a part of the carbon black 17 is seeped into the knit fabric 11 and the urethane foam 13. The thickness of the conductive adhesive layer 15 (including the seepage portion) was 373 μm.
【0028】[実施例2]カーボンブラック15重量部
の代わりに酸化亜鉛30重量部を添加した以外は、実施
例1と同様にして車両シート用ラミネート材を得た。こ
の車両シート用ラミネート材は、実施例1と同様、図
1、2に示す構造であり、導電性接着層の厚さ(滲み込
んだ部分を含む)は345μmであった。Example 2 A laminate for a vehicle seat was obtained in the same manner as in Example 1 except that 30 parts by weight of zinc oxide was added instead of 15 parts by weight of carbon black. This laminate material for vehicle seats has the structure shown in FIGS. 1 and 2 as in Example 1, and the thickness of the conductive adhesive layer (including the portion that has permeated) is 345 μm.
【0029】[実施例3]接着剤をウレタンフォームの
片面に面状塗布形式のロールコーターで固形分換算で5
0g/m2 塗布し、直ちにウレタンフォームの接着剤塗
布面にニットファブリックを重ね合わせた以外は、第1
実施例と同様にして車両シート用ラミネート材を得た。
この車両シート用ラミネート材は、実施例1と同様、図
1、2に示す構造であり、導電性接着層の厚さ(滲み込
んだ部分を含む)は288μmであった。Example 3 An adhesive was applied to one surface of a urethane foam by a roll coater of a planar application type in terms of solid content of 5%.
0 g / m 2 , and the knit fabric was immediately superimposed on the adhesive-coated surface of the urethane foam.
A laminate for a vehicle seat was obtained in the same manner as in the example.
This laminated material for vehicle seats has the structure shown in FIGS. 1 and 2 as in Example 1, and the thickness of the conductive adhesive layer (including the seepage portion) was 288 μm.
【0030】[実施例4]アクリルエマルジョン系接着
剤の代わりにエチレン・酢ビエマルジョン系接着剤(ア
イカ工業製アイカアイボンAE−21、固形分含有率5
5重量%、以下同じ)を用いた以外は、実施例1と同様
にして車両シート用ラミネート材を得た。この車両シー
ト用ラミネート材は、実施例1と同様、図1、2に示す
構造であり、導電性接着層の厚さ(滲み込んだ部分を含
む)は318μmであった。Example 4 Instead of an acrylic emulsion adhesive, an ethylene / vinyl acetate emulsion adhesive (Aika Aibon AE-21 manufactured by Aika Kogyo, solid content 5
5% by weight (the same applies hereinafter)) to obtain a laminate for a vehicle seat in the same manner as in Example 1. This laminate material for vehicle seats has the structure shown in FIGS. 1 and 2 as in Example 1, and the thickness of the conductive adhesive layer (including the portion that has penetrated) was 318 μm.
【0031】[実施例5]アクリルエマルジョン系接着
剤に、その固形分100重量部に対しトリブチルホスフ
ェート30重量部を更に添加した以外は、実施例1と同
様にして車両シート用ラミネート材を得た。Example 5 A laminated material for a vehicle seat was obtained in the same manner as in Example 1, except that 30 parts by weight of tributyl phosphate was further added to 100 parts by weight of the solid content of the acrylic emulsion-based adhesive. .
【0032】[実施例6]アクリルエマルジョン系接着
剤に、その固形分100重量部に対しトリフェニルホス
フェート30重量部を更に添加した以外は、実施例1と
同様にして車両シート用ラミネート材を得た。Example 6 A laminated material for a vehicle seat was obtained in the same manner as in Example 1, except that 30 parts by weight of triphenyl phosphate was further added to 100 parts by weight of the solid content of the acrylic emulsion-based adhesive. Was.
【0033】[実施例7]アクリルエマルジョン系接着
剤に、その固形分100重量部に対しポリリン酸アンモ
ニウム30重量部を更に添加した以外は、実施例1と同
様にして車両シート用ラミネート材を得た。Example 7 A laminated material for a vehicle seat was obtained in the same manner as in Example 1, except that 30 parts by weight of ammonium polyphosphate was further added to 100 parts by weight of the solid content of the acrylic emulsion-based adhesive. Was.
【0034】[実施例8]アクリルエマルジョン系接着
剤に、その固形分100重量部に対しトリブチルホスフ
ェート30重量部を更に添加した以外は、実施例2と同
様にして車両シート用ラミネート材を得た。Example 8 A laminated material for a vehicle seat was obtained in the same manner as in Example 2 except that 30 parts by weight of tributyl phosphate was further added to 100 parts by weight of the solid content of the acrylic emulsion-based adhesive. .
【0035】[実施例9]エチレン・酢ビエマルジョン
系接着剤に、その固形分100重量部に対しトリブチル
ホスフェート30重量部を更に添加した以外は、実施例
4と同様にして車両シート用ラミネート材を得た。Example 9 A laminate material for a vehicle seat was prepared in the same manner as in Example 4 except that 30 parts by weight of tributyl phosphate was further added to 100 parts by weight of the solid content of the ethylene-vinyl acetate emulsion-based adhesive. I got
【0036】[比較例1]アクリルエマルジョン系接着
剤に、カーボンブラック30重量部を添加しなかった以
外は、実施例1と同様にして車両シート用ラミネート材
を得た。この車両シート用ラミネート材は、実施例1と
同様、図1、2に示す構造であり(但し、カーボンブラ
ック17は含まない)、導電性接着層の厚さ(滲み込ん
だ部分を含む)は216μmであった。Comparative Example 1 A laminate for a vehicle seat was obtained in the same manner as in Example 1 except that 30 parts by weight of carbon black was not added to the acrylic emulsion-based adhesive. This vehicle seat laminate has the structure shown in FIGS. 1 and 2 (but does not include the carbon black 17) as in Example 1, and the thickness of the conductive adhesive layer (including the seepage portion) is It was 216 μm.
【0037】[比較例2]アクリルエマルジョン系接着
剤をウレタンフォームの片面に格子状塗布形式のグラビ
アロールで固形分換算で50g/m2 塗布し、直ちにウ
レタンフォームの接着剤塗布面に静電防止用界面活性剤
(主成分として界面活性剤を含むもの)の噴霧がなされ
たニットファブリックを重ね合わせ、圧力をかけながら
100℃乾燥炉中で2分間乾燥した。これにより比較例
2の車両シート用ラミネート材を得た。[Comparative Example 2] An acrylic emulsion-based adhesive was applied to one surface of urethane foam with a gravure roll of a grid-like application type at a solid content of 50 g / m 2 , and immediately the antistatic surface was applied to the adhesive-applied surface of the urethane foam. The knit fabric sprayed with the surfactant for use (containing a surfactant as a main component) was overlapped, and dried in a drying oven at 100 ° C. for 2 minutes while applying pressure. As a result, a laminate for a vehicle seat of Comparative Example 2 was obtained.
【0038】[比較例3]アクリルエマルジョン系接着
剤をウレタンフォームの片面に格子状塗布形式のグラビ
アロール100g/m2 塗布し、直ちにウレタンフォー
ムの接着剤塗布面に導電バッキング材(カーボンブラッ
クを10重量部、難燃剤としての三酸化アンチモンを4
0重量部含むアクリル樹脂)で裏面コーティングしたニ
ットファブリックを重ね合わせ、圧力をかけながら10
0℃乾燥炉中で2分間乾燥した。これにより比較例3の
車両シート用ラミネート材を得た。Comparative Example 3 An acrylic emulsion-based adhesive was applied to one side of urethane foam in the form of a gravure roll in the form of a grid, at 100 g / m 2 , and immediately a conductive backing material (10 carbon black) was applied to the adhesive-applied surface of the urethane foam. 4 parts by weight of antimony trioxide as a flame retardant
Knit fabric coated on the back with acrylic resin containing 0 parts by weight)
It was dried in a 0 ° C. drying oven for 2 minutes. As a result, a laminate for a vehicle seat of Comparative Example 3 was obtained.
【0039】[比較例4]カーボンブラック15重量部
を添加しなかった以外は、実施例5と同様にして車両シ
ート用ラミネート材を得た。 [比較例5]トリブチルホスフェート30重量部の代わ
りに、三酸化アンチモンとデカブロモジフェニルエーテ
ルの混合物(難燃剤)30重量部を更に添加した以外
は、実施例5と同様にして車両シート用ラミネート材を
得た。Comparative Example 4 A laminated material for a vehicle seat was obtained in the same manner as in Example 5, except that 15 parts by weight of carbon black was not added. Comparative Example 5 A vehicle seat laminate was prepared in the same manner as in Example 5 except that 30 parts by weight of a mixture of antimony trioxide and decabromodiphenyl ether (flame retardant) was further added instead of 30 parts by weight of tributyl phosphate. Obtained.
【0040】[比較例6]ニットファブリックの裏面
に、導電バッキング材(カーボンブラック10重量部、
三酸化アンチモンとデカブロモジフェニルエーテルの混
合物(難燃剤)40重量部を含むアクリル樹脂)をコー
ティングし、これとウレタンフォームとをフレームラミ
ネートにて接着することにより、車両シート用ラミネー
ト材を得た。Comparative Example 6 A conductive backing material (10 parts by weight of carbon black,
A mixture of antimony trioxide and decabromodiphenyl ether (an acrylic resin containing 40 parts by weight of a flame retardant) was coated, and this was adhered to a urethane foam by frame lamination to obtain a laminate material for a vehicle seat.
【0041】[評価試験]上記各実施例、各比較例で製
造した車両シート用ラミネート材を室温で7日間静置
し、下記の評価試験に供した。 導電性テスト(接着層の電気抵抗値) 電池式絶縁抵抗計にて接着剤皮膜の抵抗値を測定した。 人体帯電圧(電撃感) 測定する車両シート用ラミネート材を被せたシートに規
定の衣類を着用し着座して摩擦運動した後の帯電圧(電
撃感)を測定した。 接着性テスト(はくり接着強さ) 車両シート用ラミネート材を試験片として25mm×2
00mmに調製し、23℃雰囲気下で引っ張り試験機に
てはくり強度を測定した。 燃焼試験 車両シート用ラミネート材を試験片として100mm×
350mmに調製し、この試験片をU字型保持具に水平
に取り付け、ガスバーナーにて燃焼したときの燃焼速度
を測定した。 燃焼ガス試験 燃焼ガス分析を行い、ハロゲン化水素を検知したかどう
かをチェックした。 風合い 複数の車両シート用ラミネート材を同一条件下で手によ
る触感にて比較し確認した。[Evaluation Test] The laminates for vehicle seats produced in the above Examples and Comparative Examples were allowed to stand at room temperature for 7 days and subjected to the following evaluation tests. Conductivity test (electrical resistance value of adhesive layer) The resistance value of the adhesive film was measured by a battery-type insulation resistance meter. Human body voltage (electric shock) The charged voltage (electric shock) was measured after wearing a specified garment on a seat covered with a laminate material for a vehicle seat to be measured and sitting and frictionally moving. Adhesion test (stripping adhesion strength) 25mm x 2
The thickness was adjusted to 00 mm, and the peel strength was measured with a tensile tester in an atmosphere at 23 ° C. Combustion test 100mm x laminate sheet for vehicle seat
The test piece was adjusted to 350 mm, the test piece was mounted horizontally on a U-shaped holder, and the burning rate when burning with a gas burner was measured. Combustion gas test Combustion gas analysis was performed to check whether hydrogen halide was detected. Texture A plurality of laminated materials for vehicle seats were compared and confirmed by the tactile sensation by hand under the same conditions.
【0042】これらの結果を表1及び表2に示す。The results are shown in Tables 1 and 2.
【0043】[0043]
【表1】 [Table 1]
【0044】[0044]
【表2】 [Table 2]
【0045】[各実施例の評価結果] 1)実施例1では、導電性、人体帯電圧、接着性、風合
いのいずれも極めて良好な結果が得られた。また、生産
工程は一工程でよいため低コスト化が図れた。 2)実施例2は、導電性フィラーとして酸化亜鉛を用
い、その使用量を実施例1のカーボンブラックの2倍量
とした以外は実施例1と同様にして製造したものである
が、実施例1に比べて導電性、接着性が僅かに劣るもの
の全体として良好な結果が得られた。この実施例1、2
の比較から、導電性フィラーとしては金属粉よりもカー
ボン類の方が優れているといえる。 3)実施例3は、接着剤を面状に塗布した以外は実施例
1と同様にして製造したものであるが、実施例1に比べ
て風合いが僅かに劣るものの全体としては極めて良好な
結果が得られた。この実施例1、2の比較から、接着剤
は全面塗布よりも格子状に塗布した方が風合いの点で有
利といえる。 4)実施例4は、接着剤としてエチレン・酢ビエマルジ
ョン系を使用した以外は実施例1と同様にして製造した
ものであるが、接着性が僅かに劣るものの全体としては
極めて良好な結果が得られた。この実施例1、2の比較
から、エチレン・酢ビエマルジョン系よりもアクリルエ
マルジョン系の方が接着性の面で有利といえる。 5)実施例5、6は、導電性接着剤組成に非含ハロゲン
の有機リン系難燃剤を加えた以外は実施例1と同様にし
て製造したものであり、実施例7は導電性接着剤組成に
非含ハロゲンの無機リン系難燃剤を加えた以外は実施例
1と同様に製造したものであるが、これらはいずれも実
施例1とほぼ同等の効果を奏したうえ、更に良好な難燃
性を示し、また燃焼ガスによる環境への影響は小さいと
いう効果が得られることがわかった。 6)実施例8は、導電性接着剤組成に非含ハロゲンの有
機リン系難燃剤を加えた以外は実施例2と同様にして製
造したものであるが、この場合実施例2とほぼ同等の効
果を奏したうえ、更に良好な難燃性を示し、また燃焼ガ
スによる環境への影響は小さいという効果が得られるこ
とがわかった。 7)実施例9は、導電性接着剤組成に非含ハロゲンの有
機リン系難燃剤を加えた以外は実施例4と同様にして製
造したものであるが、この場合、実施例4とほぼ同等の
効果を奏したうえ、更に良好な難燃性を示し、また燃焼
ガスによる環境への影響は小さいという効果が得られる
ことがわかった。[Evaluation Results of Each Example] 1) In Example 1, extremely good results were obtained in all of conductivity, human body voltage, adhesiveness, and hand. In addition, since the production process requires only one process, cost reduction can be achieved. 2) Example 2 was manufactured in the same manner as in Example 1 except that zinc oxide was used as the conductive filler, and the amount used was twice that of the carbon black of Example 1. Although the conductivity and adhesion were slightly inferior to those of No. 1, good results were obtained as a whole. Examples 1 and 2
From the comparison, it can be said that carbons are more excellent as conductive fillers than metal powders. 3) Example 3 was manufactured in the same manner as in Example 1 except that the adhesive was applied in the form of a sheet. However, although the texture was slightly inferior to that of Example 1, the overall result was extremely good. was gotten. From the comparison between Examples 1 and 2, it can be said that the application of the adhesive in a lattice form is more advantageous than that of the entire surface in terms of texture. 4) Example 4 was produced in the same manner as in Example 1 except that an ethylene-vinyl acetate emulsion was used as the adhesive. However, although the adhesiveness was slightly inferior, extremely good results were obtained as a whole. Obtained. From the comparison of Examples 1 and 2, it can be said that the acrylic emulsion is more advantageous than the ethylene / vinyl acetate emulsion in terms of adhesiveness. 5) Examples 5 and 6 were produced in the same manner as in Example 1 except that a halogen-free organic phosphorus-based flame retardant was added to the conductive adhesive composition. Example 7 was a conductive adhesive. Except that a non-halogen-containing inorganic phosphorus-based flame retardant was added to the composition, it was produced in the same manner as in Example 1. It was found that the fuel gas showed flammability and the effect of combustion gas on the environment was small. 6) Example 8 was manufactured in the same manner as in Example 2 except that a halogen-free organic phosphorus-based flame retardant was added to the conductive adhesive composition. It has been found that, in addition to the effect, the flame retardancy is further improved, and the effect of the combustion gas on the environment is small. 7) Example 9 was produced in the same manner as in Example 4 except that a non-halogen-containing organophosphorus flame retardant was added to the conductive adhesive composition. It has been found that, in addition to the effect described above, the effect of exhibiting even better flame retardancy and the effect of the combustion gas on the environment is small.
【0046】なお、実施例1〜9ではシート表皮である
ニットファブリック11とシートパッドであるウレタン
フォーム13との間にカーボンブラック17を有する導
電性接着層15を設けたため、電撃感防止機能が安定し
て得られた。これに対して、従来例である特開平1−1
71936号ではシートパッドに導電性粒子を均一に混
入させることが難しいため、シートパッドのうちシート
表皮側に導電性粒子が十分分布せず、電撃感防止機能が
安定して得られないおそれがある。In Examples 1 to 9, since the conductive adhesive layer 15 having carbon black 17 was provided between the knit fabric 11 as the seat skin and the urethane foam 13 as the seat pad, the function of preventing the sense of electric shock was stable. Was obtained. On the other hand, Japanese Patent Laid-Open No. 1-1
According to 71936, it is difficult to uniformly mix conductive particles into the seat pad, so that the conductive particles are not sufficiently distributed on the seat skin side of the seat pad, and there is a possibility that the function of preventing electric shock is not stably obtained. .
【0047】[各比較例の評価結果] 1)比較例1は導電性フィラーを添加しなかった以外は
実施例1と同様にして製造したものであるが、導電性、
人体帯電圧が共に大きく、静電気による電撃感も強かっ
た。 2)比較例2は導電性フィラーを含まない接着剤を用い
たこと及び静電防止用の界面活性剤を噴霧したこと以外
は実施例1と同様にして製造したものであるが、導電
性、人体帯電圧はやや効果が見られたものの実施例1に
比べて不十分であり、また接着性能の低下も見られた。
更に噴霧工程が一つ増えるため生産性・コスト面でも劣
った。 3)比較例3は導電性フィラーを含まない接着剤を用い
たこと及び導電バッキング材をニットファブリックの裏
面にコーティングしたこと以外は実施例1と同様にして
製造したものであるが、風合いが劣り、また導電バッキ
ング材をコーティングする工程が増えるため生産性・コ
スト面でも劣った。 4)比較例4は導電性フィラーを添加しなかった以外は
実施例5と同様にして製造したものであるが、良好な難
燃性を示し、また燃焼ガスによる環境への影響も小さい
ものの、導電性、人体帯電圧が共に大きく、静電気によ
る電撃感も強かった。 5)比較例5は難燃剤として含ハロゲン難燃剤を添加し
た以外は実施例5と同様にして製造したものであり、比
較例6は難燃剤として含ハロゲン難燃剤を添加した導電
バッキング材をニットファブリックの裏面にコーティン
グしてフレームラミネートによりウレタンフォームに接
着したこと以外は実施例5と同様にして製造したもので
あるが、いずれも実施例5に比べて、風合いが劣り、難
燃性が不十分であり、また燃焼ガスによる環境への影響
が懸念された。[Evaluation Results of Comparative Examples] 1) Comparative Example 1 was produced in the same manner as in Example 1 except that no conductive filler was added.
Both human body voltages were large and the sense of electric shock due to static electricity was strong. 2) Comparative Example 2 was manufactured in the same manner as in Example 1 except that an adhesive containing no conductive filler was used and a surfactant for preventing static electricity was sprayed. Although the human body voltage was slightly effective, it was insufficient compared to Example 1, and the adhesion performance was also reduced.
In addition, productivity and cost were inferior because one spraying step was added. 3) Comparative Example 3 was produced in the same manner as in Example 1 except that an adhesive containing no conductive filler was used and a conductive backing material was coated on the back surface of the knit fabric, but the texture was inferior. In addition, productivity and cost were inferior because the number of steps of coating the conductive backing material increased. 4) Comparative Example 4 was produced in the same manner as in Example 5 except that the conductive filler was not added, but showed good flame retardancy and the effect of the combustion gas on the environment was small. Both conductivity and human body voltage were large, and the sense of electric shock due to static electricity was strong. 5) Comparative Example 5 was produced in the same manner as in Example 5 except that a halogen-containing flame retardant was added as a flame retardant. Comparative Example 6 was formed by knitting a conductive backing material to which a halogen-containing flame retardant was added as a flame retardant. The fabric was manufactured in the same manner as in Example 5 except that the back surface of the fabric was coated and adhered to the urethane foam by frame lamination. However, in all cases, the texture was inferior to Example 5, and the flame retardancy was poor. It was sufficient, and there was concern about the impact of combustion gases on the environment.
【0048】尚、上記実施例では図1に示すようにニッ
トファブリック11、導電性接着層15、ウレタンフォ
ーム13というラミネート構造であったが、図3に示す
ように、更にウレタンフォーム13の裏面側に接着層1
8、裏基布19を積層したラミネート構造としてもよ
い。このとき、接着層18は特に導電性接着層である必
要はない。但し、接着層18を導電性接着層とする場合
には、ウレタンフォーム13の表裏両面に一度に導電性
接着剤を塗布すればよいため、接着工程が簡略化され
る。In the above embodiment, the laminated structure of the knit fabric 11, the conductive adhesive layer 15, and the urethane foam 13 was used as shown in FIG. 1, but as shown in FIG. Adhesive layer 1
8. A laminated structure in which the backing base cloth 19 is laminated may be used. At this time, the adhesive layer 18 does not need to be a conductive adhesive layer. However, when the adhesive layer 18 is a conductive adhesive layer, a conductive adhesive may be applied to both the front and back surfaces of the urethane foam 13 at one time, and thus the bonding process is simplified.
【図1】 実施例1の車両シート用ラミネート材の構造
を示す説明図である。FIG. 1 is an explanatory view showing a structure of a laminate material for a vehicle seat according to a first embodiment.
【図2】 図1のA−A断面図である。FIG. 2 is a sectional view taken along line AA of FIG.
【図3】 実施例1とは異なる車両シート用ラミネート
材の構造を示す説明図である。FIG. 3 is an explanatory view showing a structure of a laminate material for a vehicle seat different from that of the first embodiment.
11・・・ニットファブリック、13・・・ウレタンフ
ォーム、15・・・導電性接着層、17・・・カーボン
ブラック、18・・・接着層、19・・・裏基布。11: knit fabric, 13: urethane foam, 15: conductive adhesive layer, 17: carbon black, 18: adhesive layer, 19: backing fabric.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 村上 靖志 愛知県豊田市山之手5−128 豊田通商株 式会社内 (72)発明者 松本 康弘 愛知県豊田市山之手5−128 豊田通商株 式会社内 (72)発明者 海老原 健治 愛知県海部郡甚目寺町大字上萱津字深見24 番地 アイカ工業株式会社内 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Yasushi Murakami 5-128 Yamanote, Toyota City, Aichi Prefecture Inside Toyota Tsusho Corporation (72) Inventor Yasuhiro Matsumoto 5-128 Yamanote, Toyota City, Aichi Prefecture Inside Toyota Tsusho Corporation ( 72) Inventor Kenji Ebihara 24, Fukami, Kamikatsu, Oji, Jimaji-cho, Kaifu-gun, Aichi Prefecture Inside Aika Kogyo Co., Ltd.
Claims (16)
と、 クッション性を有するシートパッドと、 導電性フィラーを含み、前記シート表皮と前記シートパ
ッドとを接着する導電性接着層とを備えたことを特徴と
する車両シート用ラミネート材。1. A sheet skin formed using conductive fibers, a seat pad having a cushioning property, and a conductive adhesive layer including a conductive filler and bonding the seat skin and the sheet pad. A laminate material for a vehicle seat, characterized in that:
ことを特徴とする請求項1記載の車両シート用ラミネー
ト材。2. The vehicle seat laminate according to claim 1, wherein the conductive filler is carbon.
0重量部に対し、前記導電性フィラーを0.1〜200
重量部含むことを特徴とする請求項1又は2記載の車両
シート用ラミネート材。3. The conductive adhesive layer has an adhesive solid content of 10.
0.1 to 200 parts by weight of the conductive filler with respect to 0 parts by weight.
The laminating material for a vehicle seat according to claim 1, wherein the laminating material includes a weight part.
2 であることを特徴とする請求項1〜3のいずれかに記
載の車両シート用ラミネート材。4. The conductive adhesive layer has a thickness of 5 to 100 g / m.
Vehicle seat laminate material according to any one of claims 1 to 3, characterized in that it is 2.
表皮及び又は前記シートパッドに滲み込んだ部分も含
む)が5〜1000μmであることを特徴とする請求項
1〜4のいずれかに記載の車両シート用ラミネート材。5. The conductive adhesive layer according to claim 1, wherein the conductive adhesive layer has a thickness (including a portion penetrating into the sheet skin and / or the seat pad) of 5 to 1000 μm. A laminate material for a vehicle seat according to claim 1.
むことを特徴とする請求項1〜5のいずれかに記載の車
両シート用ラミネート材。6. The laminate material for a vehicle seat according to claim 1, wherein the conductive adhesive layer contains a phosphorus-based flame retardant.
0重量部に対し、前記リン系難燃剤を1〜200重量部
含むことを特徴とする請求項6記載の車両用ラミネート
材。7. The conductive adhesive layer has an adhesive solid content of 10.
The laminating material for a vehicle according to claim 6, wherein the phosphorous-based flame retardant is contained in an amount of 1 to 200 parts by weight based on 0 parts by weight.
ることを特徴とする請求項6又は7記載の車両シート用
ラミネート材。8. The laminate material for a vehicle seat according to claim 6, wherein the phosphorus-based flame retardant is non-halogen-containing.
クッション性を有するシートパッドとを導電性フィラー
を含む導電性接着剤で接着することを特徴とする車両シ
ート用ラミネート材の製法。9. A method for producing a laminate material for a vehicle seat, wherein a seat skin formed using conductive fibers and a seat pad having a cushioning property are bonded with a conductive adhesive containing a conductive filler.
導電性フィラーを含む導電性接着剤を塗布し、その塗布
面に導電繊維を用いて形成したシート表皮を載せて接着
することを特徴とする車両シート用ラミネート材の製
法。10. A vehicle seat wherein a conductive adhesive containing a conductive filler is applied to a seat pad having a cushioning property, and a seat skin formed using conductive fibers is placed on the applied surface and bonded. Manufacturing method for laminated materials
ることを特徴とする請求項9又は10記載の車両シート
用ラミネート材の製法。11. The method according to claim 9, wherein the conductive filler is carbon.
00重量部に対し、前記導電性フィラーを0.1〜20
0重量部含むことを特徴とする請求項9〜11のいずれ
かに記載の車両シート用ラミネート材の製法。12. The conductive adhesive according to claim 1, wherein the adhesive has a solid content of 1.
0.1 to 20 parts by weight of the conductive filler with respect to 00 parts by weight.
The method for producing a vehicle seat laminate according to any one of claims 9 to 11, wherein the laminate contains 0 parts by weight.
換算で5〜100g/m2 であることを特徴とする請求
項9〜12のいずれかに記載の車両シート用ラミネート
材の製法。13. The method according to claim 9, wherein the conductive adhesive is used in an amount of 5 to 100 g / m 2 in terms of solid content. .
含むことを特徴とする請求項9〜13のいずれかに記載
の車両シート用ラミネート材の製法。14. The method according to claim 9, wherein the conductive adhesive contains a phosphorus-based flame retardant.
00重量部に対し、前記リン系難燃剤を1〜200重量
部含むことを特徴とする請求項14記載の車両用ラミネ
ート材の製法。15. The conductive adhesive according to claim 1, wherein the adhesive solid content is 1.
The method according to claim 14, wherein the phosphorus-based flame retardant is contained in an amount of 1 to 200 parts by weight based on 00 parts by weight.
あることを特徴とする請求項14又は15記載の車両シ
ート用ラミネート材の製法。16. The method according to claim 14, wherein the phosphorus-based flame retardant is halogen-free.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10182682A JPH1199866A (en) | 1997-08-01 | 1998-06-29 | Laminate material for vehicle seat, and its manufacture |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20804697 | 1997-08-01 | ||
JP9-208046 | 1997-08-01 | ||
JP10182682A JPH1199866A (en) | 1997-08-01 | 1998-06-29 | Laminate material for vehicle seat, and its manufacture |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH1199866A true JPH1199866A (en) | 1999-04-13 |
Family
ID=26501398
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10182682A Pending JPH1199866A (en) | 1997-08-01 | 1998-06-29 | Laminate material for vehicle seat, and its manufacture |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH1199866A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20020000748A (en) * | 2001-11-19 | 2002-01-05 | 남제희 | vehicle seat-cover for static electrictity prevent |
JP2007297757A (en) * | 2006-05-02 | 2007-11-15 | Daiwa Kagaku Kogyo Kk | Method for processing fiber and paper |
WO2015002320A1 (en) * | 2013-07-05 | 2015-01-08 | 株式会社フジクラ | Membrane and seat device |
-
1998
- 1998-06-29 JP JP10182682A patent/JPH1199866A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20020000748A (en) * | 2001-11-19 | 2002-01-05 | 남제희 | vehicle seat-cover for static electrictity prevent |
JP2007297757A (en) * | 2006-05-02 | 2007-11-15 | Daiwa Kagaku Kogyo Kk | Method for processing fiber and paper |
WO2015002320A1 (en) * | 2013-07-05 | 2015-01-08 | 株式会社フジクラ | Membrane and seat device |
US20160172127A1 (en) * | 2013-07-05 | 2016-06-16 | Fujikura Ltd. | Membrane and seat device |
EP3018680A4 (en) * | 2013-07-05 | 2016-07-06 | Fujikura Ltd | Membrane and seat device |
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