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JPH11198967A - Inner bag of bag-in-box for dairy products - Google Patents

Inner bag of bag-in-box for dairy products

Info

Publication number
JPH11198967A
JPH11198967A JP757398A JP757398A JPH11198967A JP H11198967 A JPH11198967 A JP H11198967A JP 757398 A JP757398 A JP 757398A JP 757398 A JP757398 A JP 757398A JP H11198967 A JPH11198967 A JP H11198967A
Authority
JP
Japan
Prior art keywords
film
bag
inner bag
box
density polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP757398A
Other languages
Japanese (ja)
Inventor
Naoki Kotani
直己 小谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP757398A priority Critical patent/JPH11198967A/en
Publication of JPH11198967A publication Critical patent/JPH11198967A/en
Pending legal-status Critical Current

Links

Landscapes

  • Bag Frames (AREA)
  • Packages (AREA)
  • Laminated Bodies (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an inner bag for a bag-in-box of large capacity having high impact resistance and resistance to pin hole. SOLUTION: In the inner bag of bag-in-box for dairy products wherein an inside film 11 is laminated onto an outside film 12 and the outer peripheries of both the films are heat sealed, as the inside film 11 to be in contact with the contents of the bag, an additive-free linear low density polyethylene film is used and in the outside film 12, a biaxially oriented nylon film is used as an intermediate layer 12a and the layer 12a is sandwiched between linear low density polyethylene films 12b, 12c to form a laminated composite film.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、液体または粘体の
乳製品を充填する大型のバッグインボックスの内袋に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an inner bag of a large bag-in-box filled with a liquid or viscous dairy product.

【0002】[0002]

【従来の技術】従来、生クリームや牛乳などの乳製品を
収納するバッグインボックスの内袋は、内容物に対する
衛生性の観点から、材料としては無添加ポリエチレンを
使用することが義務づけられている。そして、内袋の強
度維持のため、主に破裂強度を維持するために、特開平
7−2255号公報、特開平7−187233号公報、
特開平7−187234号公報等に開示されているよう
な低密度ポリエチレン(LDPE)と高密度ポリエチレ
ン(HDPE)との共押出しフィルムを用いた内袋とし
ている。
2. Description of the Related Art Conventionally, from the viewpoint of hygiene of contents, it is obligatory to use additive-free polyethylene as an inner bag of a bag-in-box for storing milk products such as fresh cream and milk. . And, in order to maintain the strength of the inner bag, mainly in order to maintain the burst strength, JP-A-7-2255, JP-A-7-187233,
The inner bag uses a co-extruded film of low-density polyethylene (LDPE) and high-density polyethylene (HDPE) as disclosed in JP-A-7-187234.

【0003】しかし、本来、無添加ポリエチレンは引っ
張り強度や耐ピンホール強度などのフィルム強度が弱い
ため、容量が10〜20リットル程度のバッグインボッ
クスの大型液体容器に適するとはいえない。また、破裂
強度を持たせるために使用する高密度ポリエチレンにつ
いても、剛性を有するために引っ張り強度や耐突き刺し
性などには強いが、柔軟性がないため耐屈曲ピンホール
性が悪く、流通時の振動でピンホールが発生し易いとい
う問題点がある。さらに高密度ポリエチレンの場合、フ
ィルムが硬いため落下時の衝撃でシールエッジ部分に破
袋が起こりやすい。
However, since additive-free polyethylene originally has low film strength such as tensile strength and pinhole resistance, it cannot be said that polyethylene is suitable for a large liquid container of a bag-in-box having a capacity of about 10 to 20 liters. In addition, high-density polyethylene used to have burst strength also has high rigidity, so it has strong tensile strength and puncture resistance, but lacks flexibility and has poor bending pinhole resistance. There is a problem that a pinhole is easily generated by vibration. Further, in the case of high-density polyethylene, since the film is hard, bag breakage is likely to occur at the seal edge portion due to the impact when dropped.

【0004】そのため、例えば、図3に示したような最
内層(内容物が接する側)に無添加LDPE(10
1)、中間層に無添加LDPE(102)、そして最外
層には無添加HDPE(103)の両側を無添加LDP
E(104、105)でラミネートした複合フィルムか
らなる三重袋を使用したりしているが、それでも完全と
はいえない。
For this reason, for example, as shown in FIG. 3, the innermost layer (the side where the contents come in contact) has no LDPE (10%).
1), a non-doped LDPE (102) in the middle layer, and a non-doped LDP on both sides of non-doped HDPE (103) in the outermost layer
Although a triple bag made of a composite film laminated with E (104, 105) is used, it is still not perfect.

【0005】[0005]

【発明が解決しようとする課題】本発明は、無添加ポリ
エチレンを用いた大型のバッグインボックスの内袋に関
する以上のような問題点に着目してなされたもので、耐
衝撃性や耐ピンホール性に優れた大容量の乳製品用のバ
ッグインボックスの内袋を提供することを目的とする。
SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems relating to the inner bag of a large bag-in-box using non-added polyethylene, and has been made in view of impact resistance and pinhole resistance. An object of the present invention is to provide an inner bag of a large-capacity dairy product bag-in-box excellent in performance.

【0006】[0006]

【課題を解決するための手段】本発明は、内側フィルム
と外側フィルムを2枚重ねた二重フィルム同士を重ねて
周囲をヒートシールしてなる乳製品用バッグインボック
スの内袋において、内容物と接する内側フィルムには無
添加線状低密度ポリエチレンフィルムを用い、外側フィ
ルムには二軸延伸ナイロンフィルムを中間層とし、この
両側に線状低密度ポリエチレンフィルムをラミネートし
た複合フィルムを用いてなる乳製品用バッグインボック
スの内袋である。
SUMMARY OF THE INVENTION The present invention relates to an inner bag of a dairy bag-in-box, which is formed by stacking two double films, each having an inner film and an outer film, and heat sealing the periphery. A non-added linear low-density polyethylene film is used for the inner film in contact with the outer film, and a biaxially stretched nylon film is used as an intermediate layer for the outer film, and a composite film obtained by laminating a linear low-density polyethylene film on both sides is used. This is the inner bag of the product bag-in-box.

【0007】上記のように本発明によれば、内容物と接
する内側フィルムには無添加線状低密度ポリエチレンフ
ィルムを用い、外側フィルムには二軸延伸ナイロンフィ
ルムを中間層とし、その両面に線状低密度ポリエチレン
フィルムをラミネートした複合フィルムを用いたので、
耐衝撃性や耐ピンホール性に優れた内袋が得られる。ま
た、内容物と接する内側フィルムには無添加樹脂を使用
しているので、衛生的にも問題がない。
[0007] As described above, according to the present invention, an additive-free linear low-density polyethylene film is used for the inner film in contact with the contents, and a biaxially stretched nylon film is used as the intermediate layer for the outer film. Since a composite film laminated with a low-density polyethylene film was used,
An inner bag with excellent impact resistance and pinhole resistance can be obtained. Further, since the additive-free resin is used for the inner film in contact with the contents, there is no problem in hygiene.

【0008】[0008]

【発明の実施の形態】以下実施例により本発明を詳細に
説明する。図1は、本発明の内袋用フィルムの層構成の
一例を示す断面構成説明図であり、図2は、この内袋を
用いて作製した乳製品用バッグインボックスの内袋の平
面説明図である。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described in detail below with reference to embodiments. FIG. 1 is an explanatory sectional view showing an example of the layer constitution of the film for an inner bag of the present invention, and FIG. 2 is an explanatory plan view of an inner bag of a dairy bag-in-box produced using the inner bag. It is.

【0009】本発明の内袋は、図1に示すように、内容
物と接する側に設けられる内側フィルム(11)とその
外側に位置する外側フィルム(12)を2枚重ねた二重
フィルム(10)から構成される。
As shown in FIG. 1, the inner bag of the present invention comprises a double film (2) in which an inner film (11) provided on the side in contact with the contents and an outer film (12) located outside the inner film (12) are laminated. 10).

【0010】内側フィルム(11)は、内容物である乳
製品が接するため、酸化防止剤等の添加物を添加するこ
とは許されず、無添加ポリエチレン樹脂からなることが
条件である。本発明では、無添加の直鎖状低密度ポリエ
チレン樹脂(LLDPE)をインフレーション法または
Tダイ法で成形したフィルムが用いられる。50〜10
0μm程度のの厚さのものが好適に使用できる。
The inner film (11) is not allowed to contain additives such as antioxidants and the like, because the dairy product as the contents is in contact with the inner film (11). In the present invention, a film obtained by molding an additive-free linear low density polyethylene resin (LLDPE) by an inflation method or a T-die method is used. 50-10
Those having a thickness of about 0 μm can be suitably used.

【0011】外側フィルム(12)は、内側フィルムを
保護する目的で設けられるもので、引っ張り強度等の物
理的物性のほかに耐ピンホール性、耐落下衝撃性等が要
求されると共に、内側フィルムとの熱融着性も要求され
る。このため、中間層(12a)として厚さ10〜20
μm程度の二軸延伸ナイロンフィルム(ONy)を用
い、この両側(12b、12c)に厚さ30〜60μm
程度のLDPEを押出しラミネート法、ドライラミネー
ト法等によりラミネートして外側フィルム(12)とし
た。なお、外側フィルム(12)は、内容物と接触しな
いため、酸化防止剤等の添加物を添加しても構わない。
The outer film (12) is provided for the purpose of protecting the inner film. The outer film (12) is required to have not only physical properties such as tensile strength but also pinhole resistance, drop impact resistance and the like. Is also required. Therefore, the thickness of the intermediate layer (12a) is 10 to 20
A biaxially stretched nylon film (ONy) having a thickness of about 30 μm is used on both sides (12b, 12c).
About LDPE was laminated by an extrusion laminating method, a dry laminating method or the like to obtain an outer film (12). Since the outer film (12) does not come into contact with the contents, additives such as an antioxidant may be added.

【0012】内側フィルム(11)と外側フィルム(1
2)を2枚重ねた二重フィルム(10)の内側フィルム
面同士を相対させて二重フィルムの一方のフィルムに注
出口(22)を穿設すると共に、四方形にヒートシール
(21)し製袋する。注出口(22)にはキャップが打
栓嵌合され、内袋が作製される。これらの注出口および
キャップは、無添加の低密度ポリエチレン(LDPE)
を素材として射出成形法により成形される。
The inner film (11) and the outer film (1)
2) A spout (22) is formed in one of the double films by making the inner film surfaces of the double film (10) in which two sheets are stacked face each other, and heat sealing (21) is performed in a square shape. Make a bag. A cap is stopper-fitted to the spout (22) to form an inner bag. These spouts and caps are made of low density polyethylene (LDPE) with no additives
Is molded by an injection molding method.

【0013】[0013]

【実施例】以下に本発明の実施例をさらに具体的に説明
する。 〈実施例1〉内側フィルム(11)として75μm厚さ
の無添加グレードのLLDPEを準備した。
EXAMPLES Examples of the present invention will be described below more specifically. <Example 1> As an inner film (11), a non-addition grade LLDPE having a thickness of 75 µm was prepared.

【0014】中間層(12a)として厚さ15μmのO
Nyを準備し、このONyの内側フィルムと接する方の
側(12b)に55μm厚さのLLDPEを、内側フィ
ルムと接しない方の側(12c)に35μm厚さのLL
DPEを押出しラミネート法によりラミネートし、外側
フィルム(12)とした。外側フィルムの素材には酸化
防止剤等の添加剤が添加されている。
As an intermediate layer (12a), a 15 μm thick O
Ny is prepared, and LLDPE having a thickness of 55 μm is provided on the side (12b) of the ONy which is in contact with the inner film, and LL having a thickness of 35 μm is provided on the side (12c) which is not in contact with the inner film.
DPE was laminated by extrusion lamination to form an outer film (12). Additives such as antioxidants are added to the material of the outer film.

【0015】内側フィルムと外側フィルムを2枚重ねた
二重フィルム(10)の内側フィルム面同士を相対させ
て二重フィルムの一方のフィルムに無添加のLDPEか
らなる注出口(22)を穿設すると共に、58cm×5
9cmの略四方形に周囲をヒートシール(21)し製袋
した。注出口には無添加LDPE製のキャップが打栓嵌
合され、18リットル入りの58cm×59cmの内袋
が作製された。
A double film (10) in which two inner films and an outer film are superposed on each other, and a spout (22) made of LDPE containing no additive is formed in one of the two films with the inner film surfaces facing each other. At the same time, 58cm × 5
The periphery was heat-sealed (21) into a 9 cm substantially square shape to make a bag. An LDPE-free cap was plug-fitted into the spout to produce a 58 cm × 59 cm inner bag containing 18 liters.

【0016】〈比較例1〉内層(内容物が接する側)フ
ィルムとして無添加グレードのHDPEの両側を無添加
グレードのLDPEでラミネートした複合フィルム(総
厚60μm)を、中間層フィルムとして内層と同様の無
添加グレードのHDPEの両側を無添加グレードのLD
PEでラミネートした複合フィルム(総厚60μm)
を、外層フィルムとして無添加グレードのLDPEと無
添加グレードのHDPEをラミネートした複合フィルム
(総厚130μm)を、それぞれ準備した。
<Comparative Example 1> A composite film (total thickness: 60 μm) obtained by laminating both sides of a non-additive grade HDPE with a non-additive grade LDPE as an inner layer (side in contact with the contents) was used as an intermediate layer film. Additive grade LDPE on both sides of additive free grade HDPE
Composite film laminated with PE (total thickness 60μm)
And a composite film (total thickness: 130 μm) obtained by laminating an additive-free grade LDPE and an additive-free grade HDPE as an outer layer film.

【0017】これらの内層フィルム、中間層フィルム、
外層フィルムをそれぞれ重ねた三重フィルムの内層フィ
ルム面同士を相対させて三重フィルムの一方のフィルム
に注出口を穿設させると共に、58cm×59cmの四
方形に周囲をヒートシールし、製袋した。注出口には無
添加LDPE製のキャップを打栓嵌合し、18リットル
入りの寸法が58cm×59cmの内袋を作製した。
These inner layer film, intermediate layer film,
The inner film surfaces of the three-layer film in which the outer layer films were stacked were opposed to each other, a spout was formed in one of the three-layer films, and the periphery was heat-sealed into a 58 cm × 59 cm square to form a bag. An LDPE-free cap was plugged and fitted to the spout to produce an inner bag with dimensions of 58 cm × 59 cm containing 18 liters.

【0018】このようにして作製した2種類のバッグイ
ンボックス内袋に、5°Cの冷水を18リットル充填
し、落下試験と振動試験を下記方法、条件に従って実施
した。その結果を表1に示す。 落下試験、底シール方向の落下‥内袋の底シール(図
2において、下側にあたるシール)が最初にコンクリー
ト床に当たるようにして1mの高さから繰り返し5回落
下させる(実施例1)。内袋の底シールが最初にコンク
リート床に当たるようにして、0.5mの高さから1回
落下させる(比較例1)。 サイドシール方向の落下‥内袋のサイドシール(図2
において、左側または右側にあたるシール)が最初にコ
ンクリート床に当たるようにして0.5mの高さから繰
り返し5回落下させる(実施例1)。内袋のサイドシー
ルが最初にコンクリート床に当たるようにして、0.5
mの高さから1回落下させる(比較例1)。 床面に水平方向の落下‥内袋の底面(図2において、
注出口が取り付けてない方の面)が最初にコンクリート
床に当たるようにして、0.5mの高さから繰り返し5
回落下させる(実施例1)。内袋の底面が最初にコンク
リート床に当たるようにして、0.5mの高さから1回
落下させる(比較例1)。 なお、各条件での試料数(n)は2であった。
The two kinds of bag-in-boxes thus produced were filled with 18 liters of cold water at 5 ° C., and a drop test and a vibration test were performed according to the following methods and conditions. Table 1 shows the results. Drop test, drop in the direction of the bottom seal ‥ Drop five times repeatedly from a height of 1 m so that the bottom seal of the inner bag (the lower seal in FIG. 2) first hits the concrete floor (Example 1). The inner bag is dropped once from a height of 0.5 m so that the bottom seal of the inner bag first contacts the concrete floor (Comparative Example 1). Drop in side seal direction ‥ Side seal of inner bag (Fig. 2
In Example 1, the material is repeatedly dropped five times from a height of 0.5 m so that the left or right side of the seal) first hits the concrete floor (Example 1). With the side seal of the inner bag hitting the concrete floor first,
It is dropped once from a height of m (Comparative Example 1). Horizontal drop on the floor 方向 Bottom of inner bag (in FIG. 2,
5) Repeat from the height of 0.5m so that the side with no spout attached first hits the concrete floor.
Drop it once (Example 1). The inner bag is dropped once from a height of 0.5 m such that the bottom surface of the inner bag first contacts the concrete floor (Comparative Example 1). The number of samples (n) under each condition was 2.

【0019】振動試験‥各内袋をそれぞれ内法が273
mm×273mm×274mmの段ボールケースに収納
し、振動試験機で振幅:2.2mm、振動数:15H
z、振動方向:垂直、の条件で60分間振動を加えた。
各条件での試料数(n)は4であった。
Vibration test: Each inner bag was 273 in inner method.
mm × 273 mm × 274 mm in a cardboard case, amplitude: 2.2 mm, vibration frequency: 15 H with a vibration tester
Vibration was applied for 60 minutes under the conditions of z, vibration direction: vertical.
The number of samples (n) under each condition was 4.

【0020】[0020]

【表1】 [Table 1]

【0021】表1から考察すると、内(接液)側フィル
ムに無添加LLDPEを用いた内袋は(実施例1)は、
内側フィルムに無添加LDPE/HDPEを用いた内袋
(比較例1)に比較して、落下試験、振動試験とも、格
段に優れていることが分かった。
Considering from Table 1, the inner bag using the non-added LLDPE for the inner (wetted) side film (Example 1) is as follows.
It was found that both the drop test and the vibration test were remarkably superior to the inner bag (Comparative Example 1) using LDPE / HDPE without additives for the inner film.

【0022】[0022]

【発明の効果】上記のように本発明によれば、内側フィ
ルムを無添加低密度ポリエチレンから無添加直鎖状低密
度ポリエチレンにすることによって、シール強度や耐ピ
ンホール強度が向上した。外側フィルムを二軸延伸ナイ
ロンフィルムの両側に直鎖状低密度ポリエチレンをラミ
ネートした複合フィルムを用いることにより、落下衝撃
強度や耐ピンホール強度が向上した。内側フィルムは無
添加直鎖状低密度ポリエチレンであるため、内容物の衛
生性にも問題がない。
As described above, according to the present invention, the seal strength and the pinhole resistance are improved by changing the inner film from an additive-free low-density polyethylene to an additive-free linear low-density polyethylene. The use of a composite film in which a linear low-density polyethylene was laminated on both sides of a biaxially stretched nylon film as the outer film improved drop impact strength and pinhole resistance. Since the inner film is an additive-free linear low-density polyethylene, there is no problem in the hygiene of the contents.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の内袋用フィルムの層構成の一例を示す
断面構成説明図である。
FIG. 1 is a cross-sectional configuration explanatory view showing an example of a layer configuration of an inner bag film of the present invention.

【図2】本発明の内袋を用いて作製したバッグンボック
スの内袋の平面説明図である。
FIG. 2 is an explanatory plan view of an inner bag of a bagon box manufactured using the inner bag of the present invention.

【図3】従来の乳製品用バッグンボックスの内袋のフィ
ルムの層構成を示す断面構成説明図である。
FIG. 3 is an explanatory sectional view showing a layer structure of a film of an inner bag of a conventional dairy bag box.

【符号の説明】[Explanation of symbols]

10‥‥二重フィルム 11‥‥内側フィルム 12‥‥外側フィルム 12a‥‥中間層、ONy 12b、12c‥‥LLDPE 20‥‥バッグンボックスの内袋 21‥‥シール部 22‥‥注出口 101、102、104、105‥‥LDPE 103‥‥HDPE 10 Double film 11 Inner film 12 Outer film 12a Intermediate layer, ONy 12b, 12c LLDPE 20 Inner bag of bagon box 21 Seal part 22 Outlet 101, 102 , 104, 105 ‥‥ LDPE 103 ‥‥ HDPE

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】内側フィルムと外側フィルムを2枚重ねた
二重フィルム同士を重ねて周囲をヒートシールしてなる
乳製品用バッグインボックスの内袋において、 内容物と接する内側フィルムには無添加線状低密度ポリ
エチレンフィルムを用い、外側フィルムには二軸延伸ナ
イロンフィルムを中間層とし、この両側に線状低密度ポ
リエチレンフィルムをラミネートした複合フィルムを用
いてなることを特徴とする乳製品用バッグインボックス
の内袋。
1. An inner bag of a dairy product bag-in-box in which a double film in which two inner films and an outer film are stacked and the periphery thereof is heat-sealed is not added to the inner film in contact with the contents. A dairy product bag comprising a composite film in which a linear low-density polyethylene film is used, a biaxially stretched nylon film is used as an intermediate layer for the outer film, and a linear low-density polyethylene film is laminated on both sides of the intermediate film. Inner bag of inbox.
JP757398A 1998-01-19 1998-01-19 Inner bag of bag-in-box for dairy products Pending JPH11198967A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP757398A JPH11198967A (en) 1998-01-19 1998-01-19 Inner bag of bag-in-box for dairy products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP757398A JPH11198967A (en) 1998-01-19 1998-01-19 Inner bag of bag-in-box for dairy products

Publications (1)

Publication Number Publication Date
JPH11198967A true JPH11198967A (en) 1999-07-27

Family

ID=11669562

Family Applications (1)

Application Number Title Priority Date Filing Date
JP757398A Pending JPH11198967A (en) 1998-01-19 1998-01-19 Inner bag of bag-in-box for dairy products

Country Status (1)

Country Link
JP (1) JPH11198967A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002193326A (en) * 2000-12-27 2002-07-10 Toppan Printing Co Ltd Inner bag for liquid
JP2003011274A (en) * 2001-06-29 2003-01-15 Toppan Printing Co Ltd Packaging vessel and manufacturing method thereof
JP2006017209A (en) * 2004-07-01 2006-01-19 Matsushita Electric Ind Co Ltd Vacuum heat insulating material
JP2007238129A (en) * 2006-03-08 2007-09-20 Toppan Printing Co Ltd Inner bag for bag-in box
JP2008150095A (en) * 2006-12-20 2008-07-03 Dainippon Printing Co Ltd Packaging bag for bag-in box
JP2018111264A (en) * 2017-01-12 2018-07-19 凸版印刷株式会社 Laminated body, packaging bag, package, and method for producing laminated body

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002193326A (en) * 2000-12-27 2002-07-10 Toppan Printing Co Ltd Inner bag for liquid
JP2003011274A (en) * 2001-06-29 2003-01-15 Toppan Printing Co Ltd Packaging vessel and manufacturing method thereof
JP2006017209A (en) * 2004-07-01 2006-01-19 Matsushita Electric Ind Co Ltd Vacuum heat insulating material
JP2007238129A (en) * 2006-03-08 2007-09-20 Toppan Printing Co Ltd Inner bag for bag-in box
JP2008150095A (en) * 2006-12-20 2008-07-03 Dainippon Printing Co Ltd Packaging bag for bag-in box
JP2018111264A (en) * 2017-01-12 2018-07-19 凸版印刷株式会社 Laminated body, packaging bag, package, and method for producing laminated body

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