JPH1059828A - Manicuring material - Google Patents
Manicuring materialInfo
- Publication number
- JPH1059828A JPH1059828A JP23150396A JP23150396A JPH1059828A JP H1059828 A JPH1059828 A JP H1059828A JP 23150396 A JP23150396 A JP 23150396A JP 23150396 A JP23150396 A JP 23150396A JP H1059828 A JPH1059828 A JP H1059828A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- silylating agent
- integer
- treated
- nail
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、皮膜形成剤及び有
機溶剤を含有する美爪料において、ポリオキシエチレン
鎖及び／又はポリオキシプロピレン鎖を有するシリル化
剤で処理した増粘付与性粉体を配合することを特徴とす
る美爪料に関する。すなわち、本発明は無機顔料やパー
ル剤の沈降がなく、経時安定性に優れ、しかも良好な化
粧持ち等の塗膜物性、使用性を有する美爪料の提供を目
的としたものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a nail polish containing a film-forming agent and an organic solvent, which is treated with a silylating agent having a polyoxyethylene chain and / or a polyoxypropylene chain. The present invention relates to a beauty nail preparation characterized by containing That is, an object of the present invention is to provide a beauty nail preparation which has no sedimentation of an inorganic pigment or a pearl agent, has excellent stability over time, and has good coating properties such as long-lasting makeup and usability.
【０００２】[0002]
【従来の技術】一般的に、美爪料には皮膜形成剤、樹
脂、可塑剤、溶剤等と共に、メーキャップ効果を付与す
るためにチタン、マイカ、雲母チタン等の無機顔料やパ
ール剤を配合する。ところがこれら無機顔料やパール剤
は比重が大きく、経時的に沈降し、その結果美爪料の外
観、美粧効果、使用性に悪影響を及ぼし、品質低下の原
因となる場合があった。従来、美爪料において比重の大
きい物質の沈降を防止し、分散安定性を保持するために
有機粘土鉱物を配合すること等、様々な検討が行われて
きた。例えば、有機粘土鉱物と無機酸又は有機酸とを混
合分散し、次いでパール剤を分散させる方法（特開昭４
７−４０３７５号公報）や有機粘土鉱物と疎水性シリカ
とを配合して経時での沈降・分離を防ぐ方法などがあっ
た。2. Description of the Related Art In general, nail polish is blended with a film-forming agent, a resin, a plasticizer, a solvent, etc., together with an inorganic pigment such as titanium, mica, mica titanium or a pearl agent to impart a makeup effect. . However, these inorganic pigments and pearling agents have a large specific gravity and settle with time, and as a result, they have an adverse effect on the appearance, cosmetic effect, and usability of the nail enamel, and may cause a deterioration in quality. Conventionally, various investigations have been made on, for example, blending an organoclay mineral to prevent sedimentation of a substance having a large specific gravity and maintain dispersion stability in a beautiful nail material. For example, a method of mixing and dispersing an organoclay mineral and an inorganic acid or an organic acid and then dispersing a pearling agent (Japanese Patent Laid-Open No.
No. 7-40375) and a method of blending an organoclay mineral with hydrophobic silica to prevent sedimentation / separation over time.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、無機酸
又は有機酸を添加する方法では、たとえパール剤の沈降
を防止できたとしても、有機顔料の変褪色を促進した
り、塗膜物性の低下といった問題が生じ必ずしも満足の
できるものではなかった。又、疎水性シリカを添加する
方法は、経時安定性は確保できるものの、その配合量に
よっては経時での増粘が起こる等、使用性面では必ずし
も満足できるものではなかった。本発明者らは、この様
な状況に鑑み、経時安定性に優れ、しかも塗膜物性、使
用性に優れた美爪料を開発すべく鋭意研究した結果、皮
膜形成剤及び有機溶剤を含有する美爪料において、ポリ
オキシエチレン鎖及び／又はポリオキシプロピレン鎖を
有するシリル化剤で処理した増粘付与性粉体を配合する
ことにより、経時安定性に非常に優れ、しかも塗膜物
性、使用性に優れた美爪料を見いだし本発明を完成させ
るに至った。However, in the method of adding an inorganic acid or an organic acid, even if the sedimentation of the pearling agent can be prevented, the discoloration of the organic pigment is accelerated and the physical properties of the coating film are deteriorated. Problems arose and were not always satisfactory. Further, the method of adding hydrophobic silica is not always satisfactory in terms of usability, for example, although the stability with time can be ensured, but the viscosity increases with time depending on the compounding amount. In view of such a situation, the inventors of the present invention have conducted intensive studies to develop a nail polish having excellent stability over time and excellent physical properties of a coating film and excellent usability. As a result, the present invention contains a film forming agent and an organic solvent. By adding a thickening-imparting powder treated with a silylating agent having a polyoxyethylene chain and / or a polyoxypropylene chain to a nail polish, the stability with time is extremely excellent, and the physical properties of the coating film and use The present inventors have found a beautiful nail material having excellent properties and completed the present invention.
【０００４】[0004]
【課題を解決するための手段】すなわち本発明は、皮膜
形成剤及び有機溶剤を含有する美爪料において、ポリオ
キシエチレン鎖及び／又はポリオキシプロピレン鎖を有
するシリル化剤で処理した増粘付与性粉体を配合するこ
とを特徴とした美爪料を提供するものである。以下に本
発明の構成について述べる。That is, the present invention is to provide a thickening agent containing a film-forming agent and an organic solvent, which is provided with a thickening agent treated with a silylating agent having a polyoxyethylene chain and / or a polyoxypropylene chain. An object of the present invention is to provide a beautiful nail material characterized by blending a functional powder. Hereinafter, the configuration of the present invention will be described.
【０００５】本発明に用いられる増粘付与性粉体は、塗
料、マニキュア、乳液、ファンデーションなどにおい
て、増粘剤として又はその他のゲル化剤の助剤として用
いられるものであり、一般に増粘作用を有するものであ
れば何でも良く、例えば、炭酸カルシウム、シリカ、ケ
イ酸カルシウム、マグネシウムオキシサルフェート等が
挙げられ、必要に応じてこれらの粉体を複合化したもの
を用いることができる。市販品としてはアエロジル（日
本アエロジル社製のアエロジル２００、３００、３８
０、Ｒ９７２等）やサイリシア（富士シリシア社製のサ
イリシア２５０、３１０等）、ゾノトライト（宇部化学
工業社製）、モスハイジ（宇部化学工業社製）、ＭＳＫ
（丸尾カルシウム社製のＭＳＫ−Ａ、ＭＳＫ−Ｃ等）等
が挙げられる。更に、経時安定性の確保をしつつ良好な
使用性を得るためには、粒径が小さい方が適しており、
好ましくは１０μｍ以下であり、また上記粉体のなかで
も、透明性のより優れたものが得られる点ではシリカを
用いるのが特に好ましい。The thickening powder used in the present invention is used as a thickener in paints, nail varnishes, emulsions, foundations and the like, or as an auxiliary agent for other gelling agents. Any of those having the following can be used. Examples thereof include calcium carbonate, silica, calcium silicate, and magnesium oxysulfate. If necessary, a composite of these powders can be used. Aerosil (Aerosil 200, 300, 38 manufactured by Nippon Aerosil Co., Ltd.)
0, R972, etc.), Thylithia (Thylithia 250, 310, etc., manufactured by Fuji Silysia), Zonotorite (Ube Chemical Industries, Ltd.), Moss Heidi (Ube Chemical Industries, Ltd.), MSK
(MSK-A, MSK-C, etc., manufactured by Maruo Calcium Co., Ltd.). Furthermore, in order to obtain good usability while securing the stability over time, a smaller particle size is more suitable,
It is preferably 10 μm or less, and among the above powders, it is particularly preferable to use silica from the viewpoint of obtaining more excellent transparency.
【０００６】本発明に使用されるポリオキシエチレン鎖
及び／又はポリオキシプロピレン鎖を有するシリル化剤
（以下単に「シリル化剤」という）は、ポリオキシエチ
レン鎖及び／又はポリオキシプロピレン鎖を有するもの
であればシリル化剤の種類は特に限定されないが、下記
一般式（１）で表されるシリル化剤が好ましい。 （Ｒ1Ｏ）aＲ2 bＳｉ（Ｒ3Ｏ）p（Ｃ2Ｈ4Ｏ）q（Ｃ3Ｈ6Ｏ）rＲ4 …（１） （式中、Ｒ1は炭素数１〜１０のアルキル基、Ｒ2は炭素
数１〜１０のアルキル基又はフェニル基、Ｒ3は炭素数
２〜５の２価の炭化水素基、Ｒ4は水素又は炭素数１〜
１０のアルキル基、又は−Ｒ3ＳｉＲ2 b（ＯＲ1）a基で
ある。また、ａは１〜３の整数、ｂは０〜２の整数であ
り、ａ＋ｂは３である。ｐは０か１の整数、ｑは０〜２
００の整数、ｒは０〜２００の整数であり、ｑ＋ｒは３
〜２００の整数である。）The silylating agent having a polyoxyethylene chain and / or a polyoxypropylene chain (hereinafter simply referred to as "silylating agent") used in the present invention has a polyoxyethylene chain and / or a polyoxypropylene chain. The type of silylating agent is not particularly limited as long as it is a compound, but a silylating agent represented by the following general formula (1) is preferred. (R 1 O) a R 2 b Si (R 3 O) p (C 2 H 4 O) q (C 3 H 6 O) r R 4 (1) (wherein, R 1 has 1 to 10 carbon atoms) R 2 is an alkyl group having 1 to 10 carbon atoms or a phenyl group, R 3 is a divalent hydrocarbon group having 2 to 5 carbon atoms, R 4 is hydrogen or 1 to carbon atoms.
An alkyl group of 10 or a —R 3 SiR 2 b (OR 1 ) a group. A is an integer of 1 to 3, b is an integer of 0 to 2, and a + b is 3. p is an integer of 0 or 1, q is 0-2
An integer of 00, r is an integer of 0 to 200, and q + r is 3
It is an integer of ~ 200. )
【０００７】具体的に例示すれば、例えば、（ＣＨ
3Ｏ）3ＳｉＣ4Ｈ8Ｏ（Ｃ2Ｈ4Ｏ）10Ｈ、（ＣＨ3Ｏ）3Ｓ
ｉＣ3Ｈ6Ｏ（Ｃ2Ｈ4Ｏ）10ＣＨ3、（Ｃ2Ｈ5Ｏ）3ＳｉＣ
3Ｈ6Ｏ（Ｃ2Ｈ4Ｏ）20（Ｃ3Ｈ6Ｏ）10ＣＨ3、（ＣＨ
3Ｏ）3ＳｉＣ3Ｈ6Ｏ（Ｃ2Ｈ4Ｏ）30Ｃ2Ｈ5、（ＣＨ
3Ｏ）2（ＣＨ3）ＳｉＣ3Ｈ6Ｏ（Ｃ2Ｈ4Ｏ）5Ｃ3Ｈ7、
（ＣＨ3Ｏ）3ＳｉＣ4Ｈ8Ｏ（Ｃ2Ｈ4Ｏ）10Ｃ4Ｈ9、（Ｃ
2Ｈ5Ｏ）（ＣＨ3）2ＳｉＣ5Ｈ10Ｏ（Ｃ2Ｈ4Ｏ）20Ｃ
Ｈ3、（ＣＨ3Ｏ）3Ｓｉ（Ｃ3Ｈ6Ｏ）10ＣＨ3、（ＣＨ3
Ｏ）3ＳｉＣ2Ｈ4Ｏ（Ｃ3Ｈ6Ｏ）10ＣＨ3、（ＣＨ3Ｏ）3
ＳｉＣ3Ｈ6Ｏ（Ｃ2Ｈ4Ｏ）10Ｃ3Ｈ6Ｓｉ（ＯＣＨ3）3、
等が挙げられる。これらのシリル化剤は必要に応じて１
種又は２種以上を用いることができる。Specifically, for example, (CH
3 O) 3 SiC 4 H 8 O (C 2 H 4 O) 10 H, (CH 3 O) 3 S
iC 3 H 6 O (C 2 H 4 O) 10 CH 3 , (C 2 H 5 O) 3 SiC
3 H 6 O (C 2 H 4 O) 20 (C 3 H 6 O) 10 CH 3, (CH
3 O) 3 SiC 3 H 6 O (C 2 H 4 O) 30 C 2 H 5 , (CH
3 O) 2 (CH 3) SiC 3 H 6 O (C 2 H 4 O) 5 C 3 H 7,
(CH 3 O) 3 SiC 4 H 8 O (C 2 H 4 O) 10 C 4 H 9 , (C
2 H 5 O) (CH 3 ) 2 SiC 5 H 10 O (C 2 H 4 O) 20 C
H 3 , (CH 3 O) 3 Si (C 3 H 6 O) 10 CH 3 , (CH 3
O) 3 SiC 2 H 4 O (C 3 H 6 O) 10 CH 3 , (CH 3 O) 3
SiC 3 H 6 O (C 2 H 4 O) 10 C 3 H 6 Si (OCH 3 ) 3 ,
And the like. These silylating agents may be used as needed.
Species or two or more can be used.
【０００８】本発明のシリル化剤で増粘付与性粉体を処
理する方法としては、特に限定されるのもではないが、
粉体を水、アルコール、又はこれらの混合液に分散し、
この分散液に同じく水、アルコール又はこれらの混合液
に溶解したシリル化剤を添加し、撹拌処理あるいはボー
ルミル処理した後、水分を除去し、乾燥、熱処理、粉砕
する湿式法や、粉体にシリル化剤をスプレーし、乾燥、
熱処理する乾式法等があげられる。The method for treating the thickening-imparting powder with the silylating agent of the present invention is not particularly limited.
Disperse the powder in water, alcohol, or a mixture thereof,
To this dispersion, a silylating agent similarly dissolved in water, alcohol or a mixture thereof is added, followed by stirring or ball milling, followed by removal of water, drying, heat treatment, and pulverization. Spraying agent, drying,
A dry method of heat treatment and the like can be given.
【０００９】また、シリル化剤の処理量は、増粘付与性
粉体の形状や種類、処理剤の種類や処理方法によって異
なり、特に限定されないが、塗膜性能、粘度の経時安定
性において、増粘付与性粉体に対し０．０１〜３０．０
重量％（以下単に［％］で示す）が好ましく、更に好ま
しくは０．１〜１５．０％である。The amount of the silylating agent to be treated depends on the shape and type of the thickening powder, the type of the treating agent and the treatment method, and is not particularly limited. 0.01 to 30.0 with respect to the thickening imparting powder
% By weight (hereinafter simply referred to as [%]), and more preferably 0.1 to 15.0%.
【００１０】上記シリル化剤で処理した増粘付与性粉体
（以下単に「処理粉体」という）の配合量は特に限定さ
れるものではないが、塗布時の使用性において、好まし
くは０．０１〜２０％、更に好ましくは０．０１〜１０
％である。これらの処理粉体は必要に応じて１種又は２
種以上を用いることができる。The amount of the thickening-imparting powder treated with the above silylating agent (hereinafter simply referred to as "treated powder") is not particularly limited, but is preferably 0.1% in terms of usability during coating. 01-20%, more preferably 0.01-10
%. One or two of these treated powders may be used as needed.
More than one species can be used.
【００１１】本発明に使用される皮膜形成剤としては、
通常美爪料に使用されるものであれば特に制限されるこ
とはなく、例えばニトロセルロース、アルキッド樹脂、
アクリル系樹脂、トルエンスルホンアミド樹脂、シリコ
ン樹脂などが挙げられ、それらの１種又は２種以上を用
いることができる。The film forming agent used in the present invention includes:
It is not particularly limited as long as it is usually used for a nail preparation, for example, nitrocellulose, alkyd resin,
An acrylic resin, a toluenesulfonamide resin, a silicone resin and the like can be mentioned, and one or more of them can be used.
【００１２】本発明に使用される有機溶剤は、通常美爪
料に使用されるものであれば特に制限されることはな
く、例えば芳香族炭化水素、酢酸エステル、アルコー
ル、セロソルブ等が挙げられ、それらの１種又は２種以
上を用いることができるが、非芳香族系炭化水素で構成
されるいわゆるトルエンフリータイプの美爪料におい
て、特に顕著な効果を得ることができる。[0012] The organic solvent used in the present invention is not particularly limited as long as it is usually used for a nail preparation, and examples thereof include aromatic hydrocarbons, acetates, alcohols and cellosolves. One or two or more of them can be used, but a particularly remarkable effect can be obtained in a so-called toluene-free nail polish comprising a non-aromatic hydrocarbon.
【００１３】本発明の美爪料には上記必須成分以外に可
塑剤、粘土鉱物、顔料、界面活性剤、酸化防止剤、香
料、紫外線吸収剤、美容成分あるいはその他の化粧品用
原料を配合することができる。[0013] In addition to the above essential components, the nail polish of the present invention contains a plasticizer, a clay mineral, a pigment, a surfactant, an antioxidant, a fragrance, an ultraviolet absorber, a cosmetic ingredient, and other cosmetic ingredients. Can be.
【００１４】[0014]
【発明の実施の形態】本発明の美爪料には、ネイルエナ
メル、エナメルトップコート、エナメルベースコート等
を挙げることができる。BEST MODE FOR CARRYING OUT THE INVENTION Nail enamels, enamel top coats, enamel base coats and the like can be given as examples of the nail polish of the present invention.
【００１５】[0015]
【実施例】以下、実施例を挙げて更に詳細に説明する
が、本発明はこれらに限定されるものではない。 製造例１．処理粉体Ａ シリカ（アエロジル３００、平均粒径０．００７μｍ）
１００ｇをメタノール１０００ｇに分散し、均一なスラ
リーとした。このスラリーに下記式に示すシリル化剤の
１０％水溶液３０ｇを添加し、ボールミルで５分間処理
を行った。処理後のスラリーを減圧乾燥した後、１００
℃で１時間熱処理を行った。これをエタノールで洗浄
し、乾燥後粉砕して、処理粉体を得た。 （ＣＨ3Ｏ）3ＳｉＣ3Ｈ6Ｏ（Ｃ2Ｈ4Ｏ）nＣＨ3 （式中、n＝３０〜３４である。）EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto. Production Example 1. Processed powder A silica (Aerosil 300, average particle size 0.007 μm)
100 g was dispersed in 1000 g of methanol to obtain a uniform slurry. To this slurry, 30 g of a 10% aqueous solution of a silylating agent represented by the following formula was added, and the mixture was treated with a ball mill for 5 minutes. After the slurry after the treatment is dried under reduced pressure,
Heat treatment was performed at 1 ° C. for 1 hour. This was washed with ethanol, dried and pulverized to obtain a treated powder. (CH 3 O) 3 SiC 3 H 6 O (C 2 H 4 O) n CH 3 ( wherein, a n = 30 to 34.)
【００１６】製造例２．処理粉体Ｂ ケイ酸カルシウム（ゾノトライト、平均粒径０．２５μ
ｍ）１００ｇをメタノール１０００ｇに分散し、均一な
スラリーとした。製造例１で使用したシリル化剤の２５
％水溶液４０ｇを添加し、ボールミルで５分間処理を行
った。処理後のスラリーを減圧乾燥した後、１００℃で
１時間熱処理した。これをエタノールで洗浄し、乾燥後
粉砕して、処理粉体を得た。Production Example 2 Processed powder B Calcium silicate (Zonotorite, average particle size 0.25μ
m) 100 g was dispersed in 1000 g of methanol to form a uniform slurry. 25 of the silylating agent used in Production Example 1
A 40% aqueous solution was added, and the mixture was treated with a ball mill for 5 minutes. The slurry after the treatment was dried under reduced pressure, and then heat-treated at 100 ° C. for 1 hour. This was washed with ethanol, dried and pulverized to obtain a treated powder.
【００１７】製造例３．処理粉体Ｃ シリカ（アエロジル２００、平均粒径０．０１２μｍ）
１００ｇをメタノール１０００ｇに分散し、均一なスラ
リーとした。このスラリーに下記式に示すシリル化剤の
２５％水溶液１００ｇを添加し、ボールミルで５分間処
理を行った。処理後のスラリーを減圧乾燥した後、１０
０℃で１時間熱処理した。これをエタノールで洗浄し、
乾燥後粉砕して、処理粉体を得た。 （ＣＨ3Ｏ）3Ｓｉ（Ｃ3Ｈ6Ｏ）nＣＨ3 （式中、n=１０〜１４である）Production Example 3 Processed powder C silica (Aerosil 200, average particle size 0.012 μm)
100 g was dispersed in 1000 g of methanol to obtain a uniform slurry. 100 g of a 25% aqueous solution of a silylating agent represented by the following formula was added to the slurry, and the slurry was treated for 5 minutes by a ball mill. After drying the slurry after the treatment under reduced pressure, 10
Heat treatment was performed at 0 ° C. for 1 hour. This is washed with ethanol,
After drying and pulverization, a treated powder was obtained. (CH 3 O) 3 Si (C 3 H 6 O) n CH 3 (where n = 10 to 14)
【００１８】製造例４．処理粉体Ｄ シリカ（アエロジル２００）１００ｇをメタノール１０
００ｇに分散し、均一なスラリーとした。このスラリー
に製造例３で使用したシリル化剤の１０％水溶液１０ｇ
を添加し、ペイントコンディショナーで１０分間処理を
行った。処理後のスラリーを減圧乾燥した後、１００℃
で１時間熱処理した。これをエタノールで洗浄し、乾燥
後粉砕して、処理粉体を得た。Production Example 4 Processed powder D 100 g of silica (Aerosil 200) in methanol 10
00g to make a uniform slurry. 10 g of a 10% aqueous solution of the silylating agent used in Production Example 3 was added to this slurry.
Was added, and the mixture was treated with a paint conditioner for 10 minutes. After the slurry after the treatment is dried under reduced pressure,
For 1 hour. This was washed with ethanol, dried and pulverized to obtain a treated powder.
【００１９】実施例１〜６及び比較例１〜４ 美爪料 表１に示す組成の美爪料を調製し、化粧持ち（剥がれ難
さ、かけ難さ）、経時での使用性（伸びの良さ）、経時
安定性について下記の方法により各評価を行った。その
結果も併せて表１に示す。Examples 1 to 6 and Comparative Examples 1 to 4 Nail preparations Nail preparations having the composition shown in Table 1 were prepared, and were used for long-lasting makeup (difficulty of peeling and applying) and aging (elongation). Good) and stability over time were evaluated by the following methods. Table 1 also shows the results.
【００２０】[0020]
【表１】 [Table 1]
【００２１】（製法） 実施例１〜６及び比較例１〜４ Ａ．成分１〜４及び５の一部、６〜８を混合溶解する。
Ｂ．成分５の残部と成分９を混合分散する。これをＡに
均一に分散させた後、成分１０〜２１を添加分散し、容
器に充填して製品とする。(Manufacturing method) Examples 1 to 6 and Comparative Examples 1 to 4 A part of components 1 to 4 and 5 and 6 to 8 are mixed and dissolved.
B. The remainder of component 5 and component 9 are mixed and dispersed. After this is uniformly dispersed in A, components 10 to 21 are added and dispersed, and filled in a container to obtain a product.
【００２２】（評価方法及び判定基準） １．官能評価 各試料について、専門パネル２０名による使用テストを
行い、化粧持ち（剥がれ難さ、かけ難さ）、経時（製造
２日後及び２カ月後）での使用性（のびの良さ）につい
て、（１）絶対評価基準を用いて５段階に評価し、各試
料ごとの評点の平均値を（２）４段階評価基準を用いて
評価した。 （１）絶対評価基準 ５点：非常に良好 ４点：良好 ３点：普通 ２点：やや不良 １点：不良 （２）４段階評価基準 ◎：４．０〜５．０点 ○：３．０〜４．０点未満 △：２．０〜３．０点未満 ×：１．０〜２．０点未満(Evaluation Method and Judgment Criteria) Sensory evaluation For each sample, a use test was conducted by 20 specialized panels, and the results were as follows: (1) Make-up (difficulty in peeling and spreading), and (2 days after production and 2 months after production) 1) Evaluation was made in five steps using an absolute evaluation standard, and the average value of the scores for each sample was evaluated using (2) a four-step evaluation standard. (1) Absolute evaluation criteria 5 points: Very good 4 points: Good 3 points: Normal 2 points: Somewhat poor 1 point: Poor (2) Four-step evaluation criteria A: 4.0 to 5.0 points O: 3. 0 to less than 4.0 points Δ: 2.0 to less than 3.0 points ×: 1.0 to less than 2.0 points
【００２３】２．経時安定性評価 各試料につき、ガラス性の透明容器に充填し、４０℃の
恒温槽に１カ月セットして外観の沈降物、分離の有無、
経時での粘度上昇の確認を行った。評価は下記の判定基
準に従って行った。 判定基準 （沈降、分離） ◎：変化なし。 ○：わずかに沈降もしくは分離が観察される。 △：沈降、分離が観察される。 ×：激しい沈降、分離が観察される。2. Stability evaluation over time Each sample was filled in a glass transparent container, set in a 40 ° C constant temperature bath for one month, and the sediment of appearance, the presence or absence of separation,
The increase in viscosity over time was confirmed. The evaluation was performed according to the following criteria. Judgment criteria (sedimentation, separation) A: No change. ：: Slight sedimentation or separation is observed. Δ: Settling and separation were observed. X: Vigorous sedimentation and separation are observed.
【００２４】上記結果から明らかなように、本発明品に
係わる実施例１〜６の美爪料は、比較例１〜４の美爪料
に比較して、沈降、分離色むらの発生が観察されず極め
て良好な経時安定性を有し、また、化粧持ち、経時での
使用性の全ての点ではるかに優れた特性を有しているこ
とがわかる。これに対し、比較例の美爪料は、経時安定
性、化粧持ち、経時での使用性のすべての項目を満足す
るものではなかった。As is apparent from the above results, the nail polish of Examples 1 to 6 according to the present invention was observed to have settling and uneven color separation as compared with the nail polish of Comparative Examples 1 to 4. However, it has very good stability over time, and has much better properties in all aspects of long-lasting makeup and usability over time. On the other hand, the nail polish of the comparative example did not satisfy all items of stability over time, long-lasting makeup, and usability over time.
【００２５】実施例７ ベースコート （成分） （％） １．ニトロセルロース １２．０ ２．トルエンスルホンアミド樹脂 ３．０ ３．アルキッド樹脂 ３．０ ４．クエン酸アセチルトリブチル ３．０ ５．酢酸ブチル ２６．５ ６．酢酸エチル ２９．０ ７．イソプロピルアルコール ５．０ ８．ｎ−ブタノール １．５ ９．処理粉体Ｄ １５．０ １０．ナイロン繊維 ２．０ （製法） Ａ．成分９を成分５の一部に混合分散する。 Ｂ．１〜８を混合溶解し、そこにＡを添加分散する。 Ｃ．Ｂに成分１０を添加分散し、容器に充填して製品と
する。Example 7 Base coat (component) (%) Nitrocellulose 12.0 2. 2. Toluenesulfonamide resin 3.0 Alkyd resin 3.0 4. Acetyltributyl citrate 3.0 5. Butyl acetate 26.5 6. Ethyl acetate 29.0 7. Isopropyl alcohol 5.0 8. n-butanol 1.5 9. Processed powder D 15.0 10. Nylon fiber 2.0 (Production method) A. Component 9 is mixed and dispersed in a part of component 5. B. 1 to 8 are mixed and dissolved, and A is added and dispersed therein. C. Component 10 is added and dispersed in B, and filled into a container to obtain a product.
【００２６】本発明品は、経時での使用性に優れ、経時
での粉体の凝集、沈降が観察されず、ベースコートとし
ての機能である付着性に優れたものであった。The product of the present invention was excellent in usability over time, did not show any agglomeration and sedimentation of the powder over time, and was excellent in adhesion as a function as a base coat.
【００２７】実施例８ トップコート （成分） （％） １．ニトロセルロース １５．０ ２．トルエンスルホンアミド樹脂 ５．０ ３．アクリルスチレン樹脂 ５．０ ４．クエン酸アセチルトリブチル ５．０ ５．酢酸ブチル ３３．４８ ６．酢酸エチル ３０．０ ７．イソプロピルアルコール ５．０ ８．ｎ−ブタノール １．５ ９．処理粉体Ｄ ０．０２ （製法） Ａ．成分９を成分５の一部に混合分散する。 Ｂ．１〜８を混合溶解し、そこにＡを添加分散し、容器
に充填して製品とする。Example 8 Topcoat (component) (%) 1. Nitrocellulose 15.0 2. Toluenesulfonamide resin 5.0 Acrylic styrene resin 5.0 4. Acetyltributyl citrate 5.0 5.0 Butyl acetate 33.48 6. Ethyl acetate 30.0 7. Isopropyl alcohol 5.0 8. n-butanol 1.5 9. Processed powder D 0.02 (Production method) A. Component 9 is mixed and dispersed in a part of component 5. B. 1 to 8 are mixed and dissolved, A is added and dispersed therein, and filled in a container to obtain a product.
【００２８】本発明品は、経時での使用性に優れ、経時
での粉体の凝集、沈降が観察されず、トップコートとし
ての機能である化粧持ちに優れたものであった。The product of the present invention was excellent in usability over time, no agglomeration and sedimentation of the powder over time was observed, and was excellent in long-lasting function as a top coat.
【００２９】[0029]
【発明の効果】本発明の美爪料は、化粧持ち、光沢とい
った塗膜性能に優れ、顔料の凝集が原因となった沈降、
色むらの発生が観察されず、特に、従来では実現し得な
かった経時での使用性においても良好であった。The nail polish of the present invention has excellent coating properties such as long lasting and gloss, sedimentation caused by aggregation of pigments,
No color unevenness was observed, and in particular, the usability over time, which could not be realized conventionally, was good.
Claims (7)
において、ポリオキシエチレン鎖及び／又はポリオキシ
プロピレン鎖を有するシリル化剤で処理した増粘付与性
粉体を配合することを特徴とする美爪料。A nail polish containing a film-forming agent and an organic solvent, wherein a thickening-imparting powder treated with a silylating agent having a polyoxyethylene chain and / or a polyoxypropylene chain is blended. And beauty nail charge.
シプロピレン鎖を有するシリル化剤が下記一般式（１）
で表されるシリル化剤である請求項１記載の美爪料。 （Ｒ1Ｏ）aＲ2 bＳｉ（Ｒ3Ｏ）p（Ｃ2Ｈ4Ｏ）q（Ｃ3Ｈ6Ｏ）rＲ4 …（１） （式中、Ｒ1は炭素数１〜１０のアルキル基、Ｒ2は炭素
数１〜１０のアルキル基又はフェニル基、Ｒ3は炭素数
２〜５の２価の炭化水素基、Ｒ4は水素又は炭素数１〜
１０のアルキル基、又は−Ｒ3ＳｉＲ2 b（ＯＲ1）a基で
ある。また、ａは１〜３の整数、ｂは０〜２の整数であ
り、ａ＋ｂは３である。ｐは０か１の整数、ｑは０〜２
００の整数、ｒは０〜２００の整数であり、ｑ＋ｒは３
〜２００の整数である。）2. A silylating agent having a polyoxyethylene chain and / or a polyoxypropylene chain is represented by the following general formula (1):
The nail polish according to claim 1, which is a silylating agent represented by the formula: (R 1 O) a R 2 b Si (R 3 O) p (C 2 H 4 O) q (C 3 H 6 O) r R 4 (1) (wherein, R 1 has 1 to 10 carbon atoms) R 2 is an alkyl group having 1 to 10 carbon atoms or a phenyl group, R 3 is a divalent hydrocarbon group having 2 to 5 carbon atoms, R 4 is hydrogen or 1 to carbon atoms.
An alkyl group of 10 or a —R 3 SiR 2 b (OR 1 ) a group. A is an integer of 1 to 3, b is an integer of 0 to 2, and a + b is 3. p is an integer of 0 or 1, q is 0-2
An integer of 00, r is an integer of 0 to 200, and q + r is 3
It is an integer of ~ 200. )
シプロピレン鎖を有するシリル化剤の処理量が処理され
る粉体に対し、０．０１〜３０重量％である請求項１又
は請求項２記載の美爪料。3. The process according to claim 1, wherein the amount of the silylating agent having a polyoxyethylene chain and / or a polyoxypropylene chain is 0.01 to 30% by weight based on the powder to be treated. Beauty nails.
シプロピレン鎖を有するシリル化剤で処理した粉体の配
合量が０．０１〜２０重量％である請求項１、２、又は
請求項３記載の美爪料。4. The compound according to claim 1, wherein the amount of the powder treated with the silylating agent having a polyoxyethylene chain and / or a polyoxypropylene chain is 0.01 to 20% by weight. Beauty nails.
である請求項１、２、３又は請求項４記載の美爪料。5. The nail polish according to claim 1, wherein the thickening powder has an average particle size of 10 μm or less.
とする請求項１、２、３、４又は請求項５記載の美爪
料。6. The nail enamel according to claim 1, wherein the thickening powder is silica.
を特徴とする請求項１、２、３、４、５又は請求項６記
載の美爪料。7. The nail polish according to claim 1, wherein the organic solvent is a non-aromatic hydrocarbon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23150396A JP3513867B2 (en) | 1996-08-13 | 1996-08-13 | Nail polish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23150396A JP3513867B2 (en) | 1996-08-13 | 1996-08-13 | Nail polish |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH1059828A true JPH1059828A (en) | 1998-03-03 |
| JP3513867B2 JP3513867B2 (en) | 2004-03-31 |
Family
ID=16924522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23150396A Expired - Fee Related JP3513867B2 (en) | 1996-08-13 | 1996-08-13 | Nail polish |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3513867B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002234821A (en) * | 2001-02-08 | 2002-08-23 | Kose Corp | Solvent based manicure preparation |
| JP4492911B2 (en) * | 2001-08-09 | 2010-06-30 | 株式会社資生堂 | Transparent nail polish |
| US20140127140A1 (en) * | 2012-11-02 | 2014-05-08 | Dow Corning Corporation | Cosmetic Composition Comprising Hydrophilic Organosilanes |
| US20140302318A1 (en) * | 2011-11-04 | 2014-10-09 | Dow Corning Corporation | Hydrophilic Organosilanes |
| US10011687B2 (en) * | 2013-05-08 | 2018-07-03 | Dow Silicones Corporation | Hydrophilic organosilanes |
-
1996
- 1996-08-13 JP JP23150396A patent/JP3513867B2/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002234821A (en) * | 2001-02-08 | 2002-08-23 | Kose Corp | Solvent based manicure preparation |
| JP4492911B2 (en) * | 2001-08-09 | 2010-06-30 | 株式会社資生堂 | Transparent nail polish |
| US20140302318A1 (en) * | 2011-11-04 | 2014-10-09 | Dow Corning Corporation | Hydrophilic Organosilanes |
| JP2015502343A (en) * | 2011-11-04 | 2015-01-22 | ダウ コーニング コーポレーションＤｏｗ Ｃｏｒｎｉｎｇ Ｃｏｒｐｏｒａｔｉｏｎ | Hydrophilic organosilane |
| US20140127140A1 (en) * | 2012-11-02 | 2014-05-08 | Dow Corning Corporation | Cosmetic Composition Comprising Hydrophilic Organosilanes |
| CN104736138A (en) * | 2012-11-02 | 2015-06-24 | 道康宁公司 | Cosmetic composition comprising hydrophilic organosilanes |
| US10219992B2 (en) | 2012-11-02 | 2019-03-05 | Dow Corning Corporation | Cosmetic composition comprising hydrophilic organosilanes |
| US10011687B2 (en) * | 2013-05-08 | 2018-07-03 | Dow Silicones Corporation | Hydrophilic organosilanes |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3513867B2 (en) | 2004-03-31 |
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