JPH10305509A - Bright prints - Google Patents

Abstract

(57) [Summary] [Problem] To provide a brilliant printed matter having a complicated brilliant feeling and capable of a novel design expression rich in changes with depth and a three-dimensional effect. A plurality of glittering printing layers containing glittering pigments having different particle sizes are provided, and at least one of the glittering printing layers is formed in a discontinuous pattern. Preferably, a glitter print layer containing a glitter pigment having a larger particle size has a pattern in which the area of each image area is smaller, and is provided on the surface side. Or
A brilliant print layer containing a plurality of brilliant pigments having different particle sizes, and preferably having a brilliantly distributed brilliant pigment having a large particle size is provided.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a glitter print using a glitter pigment. More specifically, the present invention relates to a glitter printed matter which realizes a novel design effect by using a combination of a plurality of glitter pigments having different particle diameters.

[0002]

2. Description of the Related Art Conventionally, metal powders such as flaky aluminum powders and pearlescent pigments such as titanium dioxide-coated mica have been used for the purpose of obtaining a special design effect of reflecting illumination light and exhibiting glitter. Brilliant pigments are mixed into a suitable binder resin using a brilliant ink, and a brilliant printed matter obtained by printing a brilliant pattern or the like on a substrate is used for various purposes. Widely used.

[0003] For example, in the surface decoration of building materials, furniture, housings of home electric appliances and the like, the luster, depth, and texture of wood peculiar to natural wood are reproduced by a printing technique in order to reproduce the luster of wood grain. Those with additional layers are widely used.
In addition to wood grain, for example, silky tone, pearl tone, metallic tone, etc., various glittering prints expressing various concrete or abstract design feelings with glitter are used in a wide range of fields. .

By the way, as the glitter pigment, various pigments having a particle size ranging from about several μm to 100 μm or more are commercially available. Various types of films having different glossiness are used. However, in a glitter print using a printing technique, the glitter pigment generally has an average particle size of about 30 μm or less because of the limitations on printability of the ink into which the glitter pigment is kneaded. I have.

[0005] Among them, those having a maximum particle size of approximately 15 µm or less (average particle size of 10 µm or less) can print a pattern with gradation and can express deeply in design. However, since the particle size is small, the sense of brightness is weak, and the expression is limited to a silky expression with strong whiteness. On the other hand, the particle size 15
If a brilliant pigment containing particles exceeding μm is used, the brightness is improved, but it is difficult to print a pattern with gradation, so the pattern becomes monotonous and rich in changes with depth and three-dimensional effect. Design expression is impossible.

[0006]

SUMMARY OF THE INVENTION The present invention has been made for the purpose of solving the above-mentioned problems of the prior art, and has a complicated luminous feeling and is rich in a variety of depth and three-dimensional effects. It is an object of the present invention to provide a brilliant printed material capable of a novel design expression.

[0007]

The glitter print of the present invention is a glitter print comprising a glitter print layer containing a glitter pigment on a substrate, wherein the glitter print layer comprises:
It is composed of a plurality of brilliant printing layers containing brilliant pigments having different particle diameters, and at least one of the plurality of brilliant printing layers is formed in a discontinuous pattern. It is a feature.

[0008] In particular, the present invention is characterized in that, among the plurality of glittering printing layers, the glittering printing layer having a larger particle size of the glittering pigment contained therein is formed on the surface side.

[0009] In particular, among the plurality of glittering printing layers,
The glittering printing layer having a greater glittering pigment particle size is formed in a discontinuous pattern in which the area of each image portion is smaller.

The glitter print of the present invention is a glitter print comprising a glitter print layer containing a glitter pigment on a substrate, wherein the glitter print layer has a plurality of types of particles having different particle diameters. It is characterized by containing a glitter pigment, and at least one of the plurality of glitter pigments is sparsely distributed in the glitter print layer.

In particular, among the plurality of types of glittering pigments, glittering pigments that are sparsely distributed in the glittering printing layer are characterized in that they have a larger particle size than other glittering pigments. .

[0012]

DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the glitter printed matter of the present invention will be described below in detail with reference to the drawings. Figure 1
3 is a side sectional view showing an embodiment of the glitter printed matter of the present invention.

The glitter print of the present invention comprises a glitter print layer 2 containing a glitter pigment on a substrate 1 as shown in FIG. 1, for example. And the glitter print layer 2
Is composed of two layers, a glitter print layer 21 formed on the entire surface and a glitter print layer 22 formed in a discontinuous pattern, and the latter glitter print layer 22 includes the former. The glittering pigment contains a glittering pigment having a particle size larger than that of the glittering pigment contained in the glittering printing layer 21.

The material of the substrate 1 is not particularly limited, and any material which has been conventionally used as a substrate for glittering printed matter can be used. Specifically, for example, paper, woven fabric, nonwoven fabric, resin film or sheet, resin plate, metal foil or metal plate, inorganic base material such as glass, or a laminate or composite thereof can be used. it can. When the base material 1 is composed of a laminate of a plurality of materials, the glitter print layer 2 may be provided on some of the constituent material layers, and then the whole may be laminated. Further, the shape of the substrate 1 is not necessarily limited to a planar shape, and may be formed or processed into an appropriate shape.

The glitter print layer 2 is obtained by dispersing a scaly glitter pigment having light reflectivity in an appropriate binder resin, and optionally, a solvent, a dispersant, an extender, a tackifier, Additives such as desiccants, flow-cutting agents, and leveling agents and kneaded glittering inks, for example, gravure printing, offset printing, letterpress printing, screen printing, flexographic printing, electrostatic printing, etc. It can be provided by an appropriate printing method.

In the case where the glittering print layer 21 is provided on the entire surface, as in the example shown in FIG. 1, in addition to the various printing methods described above, for example, a roll coating method, a rod coating method,
Various coating methods such as gravure coating, microgravure coating, knife coating, air knife coating, comma coating, die coating, lip coating, spray coating, dip coating, and flow coating are also applicable. is there.

Examples of the binder resin for the glitter print layer 2 include rosin, polymerized rosin, rosin-modified phenol resin,
Polyvinyl chloride resin, polyvinyl acetate resin, vinyl chloride-vinyl acetate copolymer resin, polyvinyl butyral resin, styrene resin, acrylic resin, polyolefin resin, polyester resin, urethane resin, epoxy resin, melamine resin Resins, alkyd-based resins, polyamide-based resins, petroleum-based resins, ketone-based resins, natural resins such as shellac, cellulose derivatives such as nitrified cotton or cellulose acetate propionate, and the like can be used. Two or more kinds may be used in combination.

The glitter pigment to be added to the glitter print layer 2 includes, for example, ground materials such as pearls, shells, fish scales, and pearls such as basic lead carbonate, lead hydrogen arsenate, bismuth oxychloride, and titanium dioxide-coated mica. Gloss pigment, aluminum, brass, gold,
Metal powders such as silver and copper, pulverized metal vapor-deposited films such as aluminum-deposited polyester films and the like can be used, and if necessary, two or more of these may be used in combination.

However, when a metal pigment such as a metal powder is used, although a sense of brightness is produced, the color tends to be grayish and dark tones as a whole, and the effect of concealing the base is strong. When used for the glitter print layer 22, the glitter of the underlying glitter print layer 21 is hidden. Therefore, in the present invention, it is preferable to use a pearlescent pigment as the glittering pigment.

In the present invention, glitter pigments having different particle diameters are added to the glitter print layers 21 and 22 constituting the glitter print layer 2. In the case of the example shown in FIG. 1, the glitter print layer 22 formed in a discontinuous pattern shape includes
It contains a glitter pigment having a larger particle size than the glitter pigment contained in the glitter print layer 21 formed on the entire surface. Therefore, a pattern having a strong brightness feeling with a large particle size glittering pigment was formed on a base having a fine and soft brightness feeling with a glittering pigment having a small particle size. Thus, a brilliant printed matter having the following design properties can be obtained.

Of course, the relationship between the particle sizes of the glittering pigments contained in the glittering printing layers 21 and 22 is, conversely, that the glittering printing layer 21 formed on the entire surface has a discontinuous pattern. A glitter pigment having a larger particle diameter than the glitter pigment contained in the glitter print layer 22 formed in a shape may be included. With this configuration, on the contrary, a pattern having a fine and soft luster due to a glittering pigment having a small particle size is provided on a base having a strong granularity due to a glittering pigment having a large particle diameter. The formed brilliant print having a brilliant change is obtained.

However, in this configuration, the glittering pigment having a large particle diameter contained in the glittering printing layer 21 formed on the entire surface has a strong sense of brightness, and as a result, the glittering printing formed in a discontinuous pattern shape. The effect of the brilliant pigment having a small particle size contained in the layer 22 due to the soft brightness is not so noticeable, and the brilliancy change is often poor. Therefore,
As described at the beginning, it is preferable to add a glitter pigment having a large particle size to the glitter print layer 22 formed in a discontinuous pattern.

Needless to say, the magnitude of the particle size mentioned above is not a comparison of the particle sizes of the individual brilliant pigment particles, but the countless luminosity contained in each of the brilliant print layers 21 and 22. This means the distribution range of the particle size of the pigment particles, or the size of the average particle size in comparison. That is, for example, even if each of the glittering printing layers 21 and 22 has the same particle size, for example, 20 μm, the central particle size in the particle size distribution range,
Or the average particle size is, for example, 1
0 μm and 30 μm in the glitter print layer 22,
Both of them exhibit different glittering feelings depending on the difference in particle size.

The larger the difference in the particle size of the glitter pigments contained in each of the glitter print layers 21 and 22 and the smaller the overlap between the particle size distribution ranges, the lower the brightness and glitter of the two. The difference becomes large, so that a glittering print excellent in design feeling can be obtained. Specifically, it is preferable that the difference in the average particle diameter is at least 10 μm or more, more preferably 30 μm or more, and the overlap of the particle size distribution ranges is 10% or less, more preferably 5% or less.

However, the above average particle size means a weight average particle size, and the overlapping of the above particle size distribution ranges means the weight percentage of particles having a size smaller than or equal to the boundary particle size of the bright pigment having a large particle size, When the value of the boundary particle size is defined so that the weight percentage of particles having a size larger than the boundary particle size of the glitter pigment having a small diameter becomes equal, the value of each weight percentage is meant.

In particular, glitter pigments having a small particle size include
Average particle size 15 containing almost no particles having a particle size of 30 μm or more
μm or less, and as the brilliant pigment having a large particle diameter, the average particle diameter containing particles having a particle diameter of 100 μm or more is 5
It is most preferable to use those having a particle size of 0 μm or more, since a glittering printed matter having a very large change in glittering and rich in design can be obtained.

When a glitter pigment having a maximum particle diameter of about 15 μm or less is used as a glitter pigment having a small particle size, not only solid printing but also gradation printing can be expressed. By combining with the above, a design expression having a more complicated change in glitter can be realized. For example, in the example shown in FIG. 1, by printing the glitter print layer 21 formed on the entire surface in a gradation manner, a silk-like soft glitter having a gradation and a stronger glitter can be obtained. A bright printed matter with a deep, three-dimensional design feeling can be obtained in combination with the pattern having the printed pattern.

It should be noted that the type of the particle size of the glitter pigment is not limited to two types, and as shown in FIG. Bright print layers 21, 22, 23 may be provided. As a result, it is possible to obtain a glitter printed matter having a more varied design in which the glitter is changed in multiple stages.

It is not always necessary to form one of the glitter print layers 2 over the entire surface. For example, as shown in FIG. 3, a glitter print layer formed in a plurality of discontinuous patterns is formed. It is also possible to configure by a combination of 22 and 23. The patterns of the glitter print layers 22 and 23 may be mutually intersecting patterns or may be provided independently.

However, a plurality of glittering printing layers 21, 22, 2
When 3 is formed in an overlapping manner, the strong brilliancy of the brilliant printing layer containing the brilliant pigment having a large particle size is changed to the brilliancy having a low brilliancy containing the brilliant pigment having another small particle size. It is preferable to form the glittering pigment on the surface side as the glittering pigment layer has a larger particle diameter so that the glittering pigment is not obscured by the printing layer.

If the area ratio of the glitter print layer exhibiting a strong glitter is too large as compared with the glitter print layer having a weak glitter, the glitter strength of the overall glitter is increased. The presence of the weak portion is reduced, and it is difficult for the change in glitter to be realized as a sense of design. Therefore, as the glittering printing layer in which the particle size of the glittering pigment contained is larger, the area of the individual image portions is smaller in a discontinuous pattern so that the presence of the glittering pigment is emphasized in a portion having a stronger glittering feeling. Preferably, it is formed.

In particular, the pattern is designed so that a glitter print layer containing a glitter pigment having a small particle size always exists under a glitter print layer having a strong glitter containing a glitter pigment having a large particle size. Then, a glitter print layer using a glitter pigment having a large particle size fills the gaps that are often included in the image area, and a glitter with a continuous feeling can be obtained. It is also possible to make the end of the line unclear.

Instead of forming a plurality of glitter print layers as described above, a plurality of glitter pigments having different particle diameters may be used.
By forming a single glittering print layer 2 using inks that are combined in significantly different contents, it is possible to obtain a glittering print having a glittering change.

FIG. 4 shows an example of such a case.
The glitter print layer 2 provided above contains two glitter pigments 3, a glitter pigment 31 having a small particle size and a glitter pigment 32 having a large particle size. Among them, the glitter pigment 31 having a small particle size is contained in a sufficiently large amount, so that the glitter pigment 31 is so dense that it appears in the glitter print layer 2 that the individual particles appear to be closely and continuously present. On the other hand, since the glitter pigments 32 having a large particle size have a small content, they are sparsely distributed to such an extent that the individual particles can be visually recognized as being present independently. Accordingly, a design in which a large number of bright spots having a high brightness due to the glitter pigment 32 having a large particle size are scattered in a surface exhibiting a smooth and soft glitter by the glitter pigment 31 having a small particle diameter.

In the above example, when the content of the glitter pigment 32 having a large particle size is increased to such an extent that the glitter pigment 32 does not fill up the printing surface, the particle size increases in contrast to the above. Because the bright pigment 32 having a large particle diameter does not exist on the surface of the glitter pigment 32 which exhibits a strong granular glitter,
A glitter print having a design in which a number of points exhibiting a smooth and soft glitter by the glitter pigment 31 having a small particle size are dispersed is obtained.

When the content of the brilliant pigment 32 having a large particle size is about the middle of these ranges, a portion exhibiting a strong brilliant shine by the brilliant pigment 32 having a large particle size and a brilliant pigment having a small particle size are provided. A bright printed matter having a complicated intricate design with the portion exhibiting a smooth and soft glitter due to 31 is obtained.

As is clear from the above description, the phrase "the glitter pigment is sparsely distributed in the glitter print layer" in the present invention means that the glitter pigment does not completely fill the printed image area. Means that the portions where the glittering pigment is not present are visible and distributed at a certain concentration. In addition, the relationship between the particle diameters of a plurality of types of glittering pigments in the case of such a configuration can be said to be the same as in the case of providing a plurality of glittering printing layers described above, but the distribution is particularly sparse. Generally, as the glitter pigment, the larger the particle size, the more effective it is. Specifically, it is preferable to use a glitter pigment having an average particle size of 50 μm or more containing particles having a particle size of 100 μm or more.

As described above, the method of providing a glitter print layer containing a plurality of types of glitter pigments having different particle sizes includes a method of providing a plurality of glitter print layers containing glitter pigments having different particle sizes. In comparison, there are drawbacks in that the types of designs that can be expressed are limited, but the structure is simple and the printing process of the glitter print layer only needs to be performed once, which is superior in terms of manufacturing cost and quality control. is there.

In the example shown in FIG. 4, the glitter print layer 2 containing a plurality of glitter pigments having different particle diameters is formed in a solid pattern over the entire surface. Needless to say, they may be provided in a simple pattern. In addition, the two types of means described above, that is, a method of providing a glitter print layer 2 containing a plurality of glitter pigments having different particle sizes, and a plurality of glitter prints containing glitter pigments having different particle sizes from each other By applying the method in combination with the method of providing the layer 2, it is possible to obtain a brilliant print having a unique novel design.

In addition to the above, the glitter print of the present invention can be carried out with various modifications in detail depending on the intended use without departing from the gist thereof.

For example, as shown in FIG.
In addition, by providing a solid or pattern-shaped normal printing layer 40 made of a normal printing ink or a coating agent or the like having no glitter, a high degree of combination of the glitter design and the color design. The design can be realized. The position where the normal printing layer 40 is formed may be on the back side or the front side of the glittering printing layer 2, in the middle of the glittering printing layer 2, or on the plurality of glittering printing layers 2. There may be some places, each of which can have a unique design expression. In particular, when the pattern-shaped opaque normal print layer 40 is formed on the surface side of at least one glitter print layer 2, a change in glitter is taken into account, and a glitter print with a rich design feeling can be obtained.

When a plurality of glittering printing layers 21 and 22 are provided, for example, as shown in FIG. 6, a transparent or translucent resin or the like is provided between the glittering printing layers 21 and 22. A transparent intermediate layer 41 can be provided. With such a configuration, the positional relationship in the height direction of the plurality of glitter print layers 21 and 22 changes, and their positional relationship changes depending on the viewing angle, thereby obtaining a glitter print having excellent depth and three-dimensional appearance. be able to.

For the purpose of imparting physical properties such as abrasion resistance, stain resistance, solvent resistance, and light resistance to the surface, for example, as shown in FIG. A surface protection layer 42 made of a transparent or translucent resin or the like may be provided on the surface. As a method for forming the surface protective layer 42, for example, a transparent or translucent synthetic resin film such as a polyolefin resin or a polyvinyl chloride resin is applied through an adhesive.
Or a method of directly applying by a heat fusion method or the like, a method of extruding and laminating a transparent or translucent resin, an acrylic resin, a urethane-based resin, an aminoalkyd-based resin, a topcoating agent such as a cellulose derivative, etc. A conventionally known arbitrary method such as a method of coating and a method of forming by transfer using a transfer sheet can be appropriately applied.

Further, as shown in FIG.
3 or a concave portion of the emboss 43 may be filled with a coloring agent 44 by a wiping method or the like, or a top coat layer 45 made of a transparent or translucent resin may be further formed on the surface thereof. The top coat layer 45 can be adjusted to a desired gloss state by adding a gloss adjusting agent as needed. Further, a gloss adjusting layer may be provided on the entire surface or in a pattern, separately from the top coat layer 45.

In addition, as mentioned in the section of the prior art,
In the use of decorative materials used for surface decoration of housings of building materials, furniture, home appliances, etc., the base material 1 using a transparent or translucent resin film such as polyvinyl chloride resin or polyester resin is used for surface protection. Is often used on the front side, and various printings are performed on the back side. The glitter print of the present invention can also be used in such a form.

More specifically, as shown in FIG. 9, for example, the glitter print layer 2 and the normal print layer 40 are provided on the back surface of the base material 1 made of a transparent or translucent resin film. The printing is performed in the reverse order of printing on the surface of No. 1. By doing so, the surface side of the substrate 1
That is, when viewed from the non-printed side, it is possible to obtain an excellent design feeling that is rich in a desired change in glitter. That is, it can be said that this is a glittering printed material of the base material see-through type.

Of course, even in such a configuration, if necessary, the embossing 43 and the coloring agent 44 can be filled in the embossed concave portions.
The top coat layer 45 and the like can be appropriately applied to the surface side of the substrate 1. Further, if necessary, a concealed solid printing layer and / or an opaque resin layer for hiding the base and stabilizing the color tone may be further laminated on the back side of the glittering printing layer 2 or the normal printing layer 40. .

In addition, instead of directly forming the glitter printed matter of the present invention on the surface of the target substrate 1 by printing, the glitter printed layer 2 or the like is formed on an appropriate substrate sheet in advance. It is also possible to prepare a sheet and use it to manufacture it by a transfer method. Of course, such a transfer sheet is also included in the present invention. However, in the present invention, the “front side” in the transfer layer of the transfer sheet means a side that becomes a surface after transfer, that is, a side close to the base sheet.

FIG. 10 shows an example of this, in which the glitter print layer 2 and the normal print layer 40 are provided on the surface of a base sheet 50 such as a synthetic resin film in the same manner as in the case of the above-described base-substrate type. In the reverse order to the normal case, except that the base sheet 50
Is provided so as to be peelable. If necessary, release layer 51 and / or release layer 52 for facilitating release of glitter print layer 2 and the like from base material sheet 50, and adhesion of glitter print layer 2 and the like to a substrate to be transferred. It is also possible to provide an adhesive layer 53 for obtaining the property.

The application of the glitter print of the present invention is not limited to the use of the decorative material used for the building material, the furniture, the housing of the home electric appliance and the like mentioned above, for example, books, newspapers, magazines, etc. It can be applied to all kinds of printed materials such as commercial printed materials such as printed materials, posters, calendars, catalogs, etc., cards, securities such as gift certificates and lotteries, art printed materials, industrial packaging materials, etc. It is rich.

[0051]

【Example】

<Example 1> On a surface of an opaque semi-rigid polyvinyl chloride resin film having a thickness of 100 µm, an abstract pattern was first printed by a gravure printing method using a normal ink, and then the following three types having different particle sizes were used. Each of the three commercially available glittering inks containing the glittering pigment (titanium dioxide-coated mica powder) was prepared by the gravure printing method using FIG.
As shown in Fig. 1, first, the whole surface is printed with a gradation plate using a "small particle size" glitter ink, and then a large discontinuous pattern is formed with a "medium particle size" glitter ink. Was printed, and finally a fine spot-like pattern was printed with a “large particle size” glittering ink.

Thereafter, a transparent polyethylene terephthalate resin film having a thickness of 50 μm is laminated on the front surface with a transparent adhesive, and further hot-pressed with a hot-dip galvanized steel sheet having a thickness of 0.25 mm via a primer layer on the back surface. Thus, a PET decorative steel sheet for home electric appliances such as a refrigerator was produced.

Particle size of brilliant pigment “Small particle size”: weight average particle size 7 μm, particle size distribution 3 to 15 μm
m “Medium particle size”: weight average particle size 20 μm, particle size distribution 10 to 6
0 μm “large particle size”: weight average particle size 70 μm, particle size distribution 20 to 2
00 μm

FIG. 12 is a graph showing the particle size distribution of the three types of glitter pigments. In the figure, the horizontal axis indicates the particle size (unit: μm), and the vertical axis indicates the integrated weight percentage (unit:%). As is clear from this graph, the difference between the "small particle size" glitter pigment and the "medium particle size" glitter pigment and the "medium particle" glitter pigment and the "large particle size" glitter pigment. The overlap of the particle size distribution range with the glitter pigment is 5% or less in all cases.

The obtained PET decorative steel sheet is provided with a pattern pattern having a rather strong glitter on a soft silky glitter having a gentle change in the glitter.
It has a complex, deep and three-dimensional luminosity combined with a spot-like pattern with very strong luminosity, and is combined with the color effect of the abstract pattern of the lowermost ordinary ink. And a very novel and excellent design feeling.

<Example 2> The glittering ink having the "small particle size" and the "greater particle size" used in Example 1 were applied to a printing paper which had been previously subjected to solid black printing in a weight ratio of 9: When the ink mixed in 1 was printed by a gravure printing method using a 60-line solid stencil, a bright printed matter having a characteristic glittering design feeling in which strong bright spots were scattered in a soft silk tone was obtained. I got it.

[0057]

The glitter print of the present invention comprises a plurality of glitter print layers containing glitter pigments having different particle diameters, and at least one of the plurality of glitter print layers comprises: A configuration in which a glitter print layer formed in a discontinuous pattern is provided on a base material, or contains a plurality of glitter pigments having different particle sizes, and the plurality of glitters At least one of the luminescent pigments is provided with a brilliant printing layer, which is sparsely distributed in the brilliant printing layer, on a base material. It has an extremely remarkable effect that is not seen in the conventional technology, and has a rich and complex brilliant feeling that combines various feelings, and a novel design expression with a deep feeling and a three-dimensional feeling can be obtained. is there.

[Brief description of the drawings]

FIG. 1 is a side sectional view showing an embodiment of a glitter print of the present invention.

FIG. 2 is a side sectional view showing an embodiment of a glitter print of the present invention.

FIG. 3 is a side sectional view showing an embodiment of a glitter print of the present invention.

FIG. 4 is a side sectional view showing an embodiment of a glitter print of the present invention.

FIG. 5 is a side sectional view showing an embodiment of a glitter print of the present invention.

FIG. 6 is a side sectional view showing an embodiment of a glitter print of the present invention.

FIG. 7 is a side sectional view showing an embodiment of a glitter print of the present invention.

FIG. 8 is a side sectional view showing an embodiment of a glitter print of the present invention.

FIG. 9 is a side sectional view showing an embodiment of a glitter print of the present invention.

FIG. 10 is a side sectional view showing an embodiment of a glitter print of the present invention.

FIG. 11 is a plan view showing a part of a print pattern of a glitter print layer in Example 1 of the present invention.

FIG. 12 is a graph showing the particle size distribution of glitter pigments used in Examples 1 and 2 of the present invention.

[Explanation of symbols]

1 base material 2 glitter print layer 21 glitter print layer formed on the whole surface 22, 23 glitter print layer formed in a discontinuous pattern 3 glitter pigment 31 {Glitter pigment with small particle size 32} Glitter pigment with large particle size 40} Normal printing layer 41} Transparent intermediate layer 42} Surface protection layer 43} Emboss 44} Colorant 45} Top Coating layer 50 ‥‥ Base sheet 51 ‥‥ Release layer 52 ‥‥ Release layer 53 ‥‥ Adhesive layer 60 ‥‥ Printed area of “small particle size” glittering ink 61 ‥‥ Glossiness of “medium particle size” Ink printing section 62 ‥‥ Printing area of “large particle size” glittering ink 70 ‥‥ Integrated particle size distribution curve of “small particle size” glittering pigment 71 ‥‥ Cumulative particle size distribution curve 72 ° Cumulative particle size distribution curve of glitter pigment with “large particle size”

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁶ Identification code FI B44F 1/02 B44F 1/02

Claims (5)

[Claims] 1. A glitter print comprising a glitter print layer containing a glitter pigment on a substrate, wherein the glitter print layer comprises a plurality of glitters containing glitter pigments having different particle sizes from each other. A glittering printed material, comprising: a glittering printing layer; and at least one of the glittering printing layers is formed in a discontinuous pattern. 2. The glitter according to claim 1, wherein, among the plurality of glitter print layers, the glitter print layer having a larger particle size of the glitter pigment is formed on the surface side. Printed matter. 3. A glittering printing layer, in which the glittering pigment contained therein has a larger particle size among the plurality of glittering printing layers, is formed in a discontinuous pattern in which the area of each image portion is smaller. The glittering printed matter according to claim 1 or 2, wherein: 4. A glitter print comprising a glitter print layer containing a glitter pigment on a base material, wherein the glitter print layer contains a plurality of glitter pigments having different particle diameters,
In addition, at least one of the plurality of types of glitter pigments is sparsely distributed in the glitter print layer. 5. A glitter pigment which is sparsely distributed in the glitter print layer among the plurality of glitter pigments has a larger particle size than other glitter pigments. The glittering printed matter described in 1.