JPH10298441A - Resin composition for sliding material and resin-made gear - Google Patents
Resin composition for sliding material and resin-made gearInfo
- Publication number
- JPH10298441A JPH10298441A JP5592998A JP5592998A JPH10298441A JP H10298441 A JPH10298441 A JP H10298441A JP 5592998 A JP5592998 A JP 5592998A JP 5592998 A JP5592998 A JP 5592998A JP H10298441 A JPH10298441 A JP H10298441A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- whisker
- mohs hardness
- resin composition
- whiskers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 52
- 239000011342 resin composition Substances 0.000 title claims description 35
- 239000011347 resin Substances 0.000 claims abstract description 90
- 229920005989 resin Polymers 0.000 claims abstract description 90
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 17
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 17
- 239000000314 lubricant Substances 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims abstract description 14
- 239000009719 polyimide resin Substances 0.000 claims abstract description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 10
- 229920006259 thermoplastic polyimide Polymers 0.000 claims abstract description 10
- 229920001643 poly(ether ketone) Polymers 0.000 claims abstract description 9
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010456 wollastonite Substances 0.000 claims abstract description 7
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 7
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 6
- 239000002557 mineral fiber Substances 0.000 claims abstract description 6
- 229920000412 polyarylene Polymers 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 9
- 239000000835 fiber Substances 0.000 abstract description 11
- 238000005299 abrasion Methods 0.000 abstract description 9
- 238000013329 compounding Methods 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 2
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 abstract description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 2
- 235000019589 hardness Nutrition 0.000 description 55
- 239000004734 Polyphenylene sulfide Substances 0.000 description 13
- 229920000069 polyphenylene sulfide Polymers 0.000 description 13
- 239000000126 substance Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- 239000004760 aramid Substances 0.000 description 11
- 229920003235 aromatic polyamide Polymers 0.000 description 11
- 238000000465 moulding Methods 0.000 description 10
- 239000004519 grease Substances 0.000 description 8
- 230000003014 reinforcing effect Effects 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 230000013011 mating Effects 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- 239000004696 Poly ether ether ketone Substances 0.000 description 3
- 229930182556 Polyacetal Natural products 0.000 description 3
- 230000002159 abnormal effect Effects 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920002530 polyetherether ketone Polymers 0.000 description 3
- 229920001721 polyimide Polymers 0.000 description 3
- 229920006324 polyoxymethylene Polymers 0.000 description 3
- 239000007779 soft material Substances 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 229920013632 Ryton Polymers 0.000 description 2
- 239000004736 Ryton® Substances 0.000 description 2
- 229920004695 VICTREX™ PEEK Polymers 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 125000005462 imide group Chemical group 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 125000001174 sulfone group Chemical group 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 125000004149 thio group Chemical group *S* 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- VQVIHDPBMFABCQ-UHFFFAOYSA-N 5-(1,3-dioxo-2-benzofuran-5-carbonyl)-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(C(C=2C=C3C(=O)OC(=O)C3=CC=2)=O)=C1 VQVIHDPBMFABCQ-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 102100030716 Ankyrin repeat and SOCS box protein 8 Human genes 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 101000703115 Homo sapiens Ankyrin repeat and SOCS box protein 8 Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000016571 aggressive behavior Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012765 fibrous filler Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920005575 poly(amic acid) Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical class [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- SRRKNRDXURUMPP-UHFFFAOYSA-N sodium disulfide Chemical compound [Na+].[Na+].[S-][S-] SRRKNRDXURUMPP-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
- F05C2225/00—Synthetic polymers, e.g. plastics; Rubber
- F05C2225/04—PTFE [PolyTetraFluorEthylene]
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Gears, Cams (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、摺動材用樹脂組成
物に関し、とくに滑り軸受や歯車等のような耐摩耗性の
必要な部材に適用できる摺動材用樹脂組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a resin composition for a sliding material, and more particularly to a resin composition for a sliding material which can be applied to members requiring abrasion resistance such as sliding bearings and gears.
【0002】[0002]
【従来の技術】近年、音響機器、複写機などの事務機
器、自動車部品その他の機械部品類に、摺動材用樹脂組
成物を成形することにより得られる、樹脂製滑り軸受や
樹脂製歯車が多用されている。金属製の滑り軸受や歯車
に比較して、極端な高荷重下や高温下では使用できない
制約はあるものの、軽量化、低コスト化、グリースレス
化、複合部品の一体化などが可能であり、樹脂製滑り軸
受や樹脂製歯車は、その使用量が増加している。2. Description of the Related Art In recent years, resin sliding bearings and resin gears obtained by molding a resin composition for a sliding material into office equipment such as audio equipment and copying machines, automobile parts and other mechanical parts have been developed. It is heavily used. Compared to metal plain bearings and gears, although they cannot be used under extremely high loads or high temperatures, they can be reduced in weight, cost, greaseless, and integrated with composite parts. The usage of resin sliding bearings and resin gears is increasing.
【0003】樹脂製滑り軸受や樹脂製歯車として必要な
特性に、自らの耐摩耗性や相手材への低攻撃性がある。
すなわち、相手材との摺動による自らの摩耗量と、相手
材の摩耗量を共に少なくすることが必要であるが、この
二つの特性は相反する面を有している。たとえば、ポリ
フェニレンスルフィド樹脂を主とする摺動材用樹脂組成
物では繊維状充填材を加えないと自らの摩耗量が著しく
多くなるため、通常ガラス繊維を配合することが多い。
しかし、この場合、相手材が軟質材、たとえばアルミニ
ウムや合成樹脂材などの場合は、ガラス繊維が比較的硬
いため、攻撃性が高くなり、相手材の摩耗量が多くなる
傾向がある。一方、炭素繊維などの比較的柔らかい充填
材を配合すると、相手材への攻撃性は少なくなるが、樹
脂製歯車としての強度が弱くなるとともに自らの摩耗量
が増加する。[0003] The characteristics required for a resin sliding bearing or a resin gear include its own abrasion resistance and low aggression to a mating material.
That is, it is necessary to reduce both the wear amount of the partner material due to sliding with the partner material and the wear amount of the partner material, but these two characteristics have contradictory surfaces. For example, in a resin composition for a sliding material mainly composed of polyphenylene sulfide resin, if a fibrous filler is not added, the wear amount of the resin itself becomes extremely large.
However, in this case, when the mating material is a soft material, for example, aluminum or a synthetic resin material, the glass fiber is relatively hard, so that the aggressiveness increases and the mating material tends to wear more. On the other hand, when a relatively soft filler such as carbon fiber is blended, the aggressiveness to the mating material is reduced, but the strength of the resin gear is reduced and the wear amount of the resin gear is increased.
【0004】このような相反する問題に対処する摺動材
用樹脂組成物として、特開平 5-306371 号公報や特開平
6-279689 号公報が知られている。たとえば、特開平 5
-306371 号公報は、ポリフェニレンスルフィド樹脂とポ
リテトラフルオロエチレン樹脂と芳香族ポリアミドパル
プと酸化亜鉛ウィスカとを構成要素とするものであり、
特開平 6-279689 号公報は、合成樹脂とウィスカと芳香
族ポリアミド繊維と固体潤滑剤とを構成要素とするもの
である。As a resin composition for a sliding material which addresses such conflicting problems, Japanese Patent Application Laid-Open Nos.
No. 6-279689 is known. For example,
No. 306371 discloses a composition comprising a polyphenylene sulfide resin, a polytetrafluoroethylene resin, an aromatic polyamide pulp, and zinc oxide whiskers,
Japanese Patent Application Laid-Open No. 6-279689 discloses a composition comprising synthetic resin, whiskers, aromatic polyamide fiber and solid lubricant.
【0005】[0005]
【発明が解決しようとする課題】しかしながら、近年事
務機器などにおいて、機器の小型軽量化や、機器作動時
の騒音を極力少なくする静音化対策が重要となるにつ
れ、従来の摺動材用樹脂組成物では、機器の小型軽量化
や静音化に十分対応できる樹脂製滑り軸受や樹脂製歯車
が得られないという問題がある。たとえば、芳香族ポリ
アミドパルプや芳香族ポリアミド繊維は、見掛け比重が
小さく嵩だかな充填材であるため、樹脂組成物の造粒工
程や射出成形工程で工程条件が制限され、小型軽量化を
目的とした複雑な製品形状によっては成形ができないも
のも生じるという問題があった。However, in recent years, in office equipment and the like, it has become important to reduce the size and weight of the equipment and to reduce noise during operation of the equipment as much as possible. However, there is a problem that a resin sliding bearing or a resin gear that can sufficiently cope with the reduction in size and weight of the device and the noise reduction cannot be obtained. For example, aromatic polyamide pulp and aromatic polyamide fiber are bulky fillers having a small apparent specific gravity, so that the process conditions are limited in the granulation process and the injection molding process of the resin composition, and the purpose is to reduce the size and weight. There is a problem that molding cannot be performed depending on the complicated product shape.
【0006】また、芳香族ポリアミドパルプや芳香族ポ
リアミド繊維は、射出成形でガスが発生するため、金型
を汚染しやすい。このため、所定回数毎に金型の洗浄を
しなければならず、連続成形が困難であるという問題が
ある。In addition, aromatic polyamide pulp and aromatic polyamide fiber tend to contaminate a mold because gas is generated during injection molding. For this reason, the mold must be cleaned every predetermined number of times, and there is a problem that continuous molding is difficult.
【0007】さらに、芳香族ポリアミドパルプや芳香族
ポリアミド繊維は吸湿性の高い材料であり、射出成形前
にペレットの乾燥工程を確実に行わないと、成形品に発
泡等の不具合が発生する場合がある。このため、材料本
来の高コストとともに、工程数が増えることによる生産
コスト上昇となり、樹脂製滑り軸受や樹脂製歯車として
の工業的有用性が制限されるという問題があった。Further, aromatic polyamide pulp and aromatic polyamide fiber are highly hygroscopic materials, and if the drying step of pellets is not performed properly before injection molding, problems such as foaming may occur in molded products. is there. For this reason, there is a problem that the production cost is increased due to an increase in the number of steps together with the inherent high cost of the material, and the industrial utility as a resin sliding bearing or a resin gear is limited.
【0008】一方、静音化対策が要求される事務機器に
おいては、高荷重や高温に曝される部位で使用される鉄
系焼結歯車にグリース類を塗布し、歯車の噛み含わせ音
を防ぐ場合が多い。この場合、このグリース類が樹脂製
歯車に伝搬付着すると樹脂製歯車の摩耗により発生した
樹脂摩耗粉や脱落した繊維状補強材がグリース類によっ
て捕獲され摺動界面で研磨剤のように働き、自らも相手
材も非常に大きな摩耗をおこすという問題があった。こ
れは、とくにガラス繊維などを補強材とした場合に顕著
に見られる問題であった。On the other hand, in office equipment which requires noise reduction measures, greases are applied to iron-based sintered gears used in parts exposed to high loads and high temperatures to prevent the gears from being bitten. Often. In this case, when the grease propagates and adheres to the resin gear, the resin abrasion powder generated by the wear of the resin gear and the dropped fibrous reinforcing material are captured by the grease and act like an abrasive at the sliding interface. However, there is also a problem that the other member causes very large wear. This is a problem that is particularly noticeable when glass fiber or the like is used as a reinforcing material.
【0009】本発明は、このような課題に対処するため
になされたもので、機械的強度が高く、グリースの有無
に関わらず耐摩耗性に優れ、鉄系の非軟質材はもとより
軟質材に対しても攻撃性が低く、成形が容易であり、さ
らに工業的有用性の高い樹脂成形体が得られる摺動材用
樹脂組成物および樹脂製歯車を提供することを目的とす
る。The present invention has been made to address such problems, and has high mechanical strength, excellent abrasion resistance regardless of the presence or absence of grease, and can be used not only for iron-based non-soft materials but also for soft materials. An object of the present invention is to provide a resin composition for a sliding material and a resin gear, which have a low aggressiveness, are easy to mold, and provide a resin molded article having high industrial utility.
【0010】[0010]
【課題を解決するための手段】本発明の摺動材用樹脂組
成物は、樹脂に少なくとも固体潤滑剤およびウィスカ材
とを配合してなる摺動材用樹脂組成物であって、該ウィ
スカ材はモース硬度 5未満のウィスカとモース硬度 5以
上のウィスカとを含むことを特徴とする。また、該ウィ
スカ材は、モース硬度 5未満のウィスカ配合量がモース
硬度 5以上のウィスカより配合量が多いことを特徴とす
る。SUMMARY OF THE INVENTION The resin composition for a sliding material of the present invention is a resin composition for a sliding material comprising a resin and at least a solid lubricant and a whisker material. Is characterized by including whiskers having a Mohs hardness of less than 5 and whiskers having a Mohs hardness of 5 or more. Further, the whisker material is characterized in that the compounding amount of the whisker having a Mohs hardness of less than 5 is larger than that of the whisker having a Mohs hardness of 5 or more.
【0011】モース硬度 5未満のウィスカがウオラスト
ナイトウィスカおよび炭酸カルシウムウィスカから選ば
れた少なくとも一つのウィスカであり、モース硬度 5以
上のウィスカがホウ酸アルミニウムウィスカおよび鉱物
繊維から選ばれた少なくとも一つのウィスカであること
を特徴とする。The whiskers having a Mohs hardness of less than 5 are at least one whisker selected from wollastonite whiskers and calcium carbonate whiskers, and the whiskers having a Mohs hardness of 5 or more are at least one whisker selected from aluminum borate whiskers and mineral fibers. It is a whisker.
【0012】摺動材用樹脂組成物を構成する樹脂がポリ
アリーレンスルフィド系樹脂、ポリエーテルケトン系樹
脂および熱可塑性ポリイミド系樹脂の中から選ばれた少
なくとも一つの樹脂であることを特徴とする。[0012] The resin constituting the resin composition for a sliding material is characterized in that it is at least one resin selected from a polyarylene sulfide resin, a polyether ketone resin and a thermoplastic polyimide resin.
【0013】また、摺動材用樹脂組成物を構成する固体
潤滑剤がポリテトラフルオロエチレンであることを特徴
とする。[0013] The solid lubricant constituting the resin composition for a sliding material is polytetrafluoroethylene.
【0014】本発明の樹脂製歯車は、上述の摺動材用樹
脂組成物の成形体からなる樹脂製歯車であることを特徴
とする。The resin gear of the present invention is characterized in that it is a resin gear made of a molded product of the above resin composition for a sliding material.
【0015】本発明の摺動材用樹脂組成物は、モース硬
度の異なるウィスカを配合することにより、樹脂組成物
の流動性を向上させ、また、樹脂製滑り軸受や樹脂製歯
車としたときに、グリースの有無に関わらず摺動時に相
手材を攻撃することが少なく、自身の耐摩耗性にも優れ
ている。The resin composition for a sliding material according to the present invention improves the fluidity of the resin composition by mixing whiskers having different Mohs hardnesses. In addition, regardless of the presence or absence of grease, it is less likely to attack the mating material during sliding, and is excellent in its own wear resistance.
【0016】[0016]
【発明の実施の形態】本発明に係る樹脂は、摺動部材に
必要とされる耐熱温度、雰囲気その他の条件によって任
意に選択することができる。たとえば、ポリアセタール
樹脂、ポリアミド樹脂、ポリエチレン樹脂、ポリイミド
樹脂、ポリアミドイミド樹脂、熱可塑性ポリイミド樹
脂、ポリエーテルエーテルケトン樹脂、ポリエーテルケ
トン樹脂、ポリエーテルニトリル樹脂、芳香族ポリエス
テル樹脂、フェノール樹脂、エポキシ樹脂、ポリフェニ
レンスルフィド樹脂等を例示することができる。これら
は、単独でも 2種以上の樹脂からなるポリマーアロイや
ポリマーブレンドであっても使用することができる。DESCRIPTION OF THE PREFERRED EMBODIMENTS The resin according to the present invention can be arbitrarily selected according to the heat-resistant temperature, atmosphere and other conditions required for a sliding member. For example, polyacetal resin, polyamide resin, polyethylene resin, polyimide resin, polyamideimide resin, thermoplastic polyimide resin, polyetheretherketone resin, polyetherketone resin, polyethernitrile resin, aromatic polyester resin, phenolic resin, epoxy resin, Examples include polyphenylene sulfide resin. These can be used singly or as a polymer alloy or polymer blend composed of two or more resins.
【0017】これらの中でも、ポリフェニレンスルフィ
ド樹脂等のポリアリーレンスルフィド系樹脂、ポリエー
テルエーテルケトン樹脂等のポリエーテルケトン系樹
脂、熱可塑性ポリイミド系樹脂が摺動部材としての耐熱
性、機械的強度、成形性に優れているため好ましい。さ
らにポリフェニレンスルフィド樹脂がより成形性に優れ
るとともに低価格で工業的有用性に優れているため最も
好ましい。Among these, polyarylene sulfide resin such as polyphenylene sulfide resin, polyether ketone resin such as polyether ether ketone resin, and thermoplastic polyimide resin are used for heat resistance, mechanical strength and molding as a sliding member. It is preferable because it has excellent properties. Further, polyphenylene sulfide resin is most preferable because it is more excellent in moldability, and is inexpensive and excellent in industrial utility.
【0018】ポリアリーレンスルフィド系樹脂として、
たとえばポリフェニレンスルフィド樹脂は、芳香族基が
チオエーテル結合で連結された構造を有する樹脂をい
い、その繰り返し単位を化1に示す。As the polyarylene sulfide resin,
For example, a polyphenylene sulfide resin is a resin having a structure in which aromatic groups are linked by a thioether bond, and its repeating unit is shown in Chemical formula 1.
【0019】[0019]
【化1】 Embedded image
【0020】これらのうち、とくに典型的なものは化2
で示されるものであり、米国フィリップス・ペトローリ
アム社から「ライトン」の商標で市販され、その製造方
法は米国特許第 3,354,129号(対応日本特許「特公昭 4
5-3368」)等に開示されている。Of these, the most typical one is
Which is commercially available from Philips Petroleum Corporation under the trademark "Ryton" and is manufactured according to U.S. Pat. No. 3,354,129 (corresponding Japanese Patent
5-3368 ”).
【0021】[0021]
【化2】 Embedded image
【0022】それによると、「ライトン」は N- メチル
-2- ピロリドン溶媒中、 160〜250℃、加圧条件下に p-
ジクロルベンゼンと二硫化ソーダとを反応させること
によって製造される。この場合、樹脂中に架橋構造が全
くないものから部分的架橋構造を有するものに至るまで
各種重合度のものを後熱処埋工程にかけて自由に製造す
ることができるので、目的の溶融ブレンドに適正な溶融
粘度特性を有するものを任意に選択使用することが可能
である。また、上記した以外に架橋構造をとらない直鎖
状のポリフェニレンスルフィド樹脂を採用してもよい。According to that, "Ryton" is N-methyl
-2- p-pyrrolidone in a solvent at 160-250 ° C under pressure
It is produced by reacting dichlorobenzene with sodium disulfide. In this case, resins with various degrees of polymerization, from those without any cross-linking structure to those with partial cross-linking structure in the resin, can be freely manufactured by post-heat treatment, making it suitable for the target melt blend. It is possible to arbitrarily select and use those having excellent melt viscosity characteristics. Further, other than the above, a linear polyphenylene sulfide resin having no crosslinked structure may be employed.
【0023】ポリフェニレンスルフィド樹脂の溶融粘度
は、 300℃で 10 〜10,000Pa・s 、好ましくは 30 〜3,
000 Pa・s 、より好ましくは 30 〜1,000 Pa・s 、最も
好ましくは 50 〜800 Pa・s である。また、ポリフェニ
レンスルフィド樹脂の末端にSH基を導入した樹脂であ
ってもよい。そのようなポリフェニレンスルフィド樹脂
の市販品としては、T4AG(トープレン社、商品
名)、B160(東ソー社、商品名)、KPS W21
4(呉羽化学工業社、商品名)等が挙げられる。The melt viscosity of the polyphenylene sulfide resin at 300 ° C. is 10 to 10,000 Pa · s, preferably 30 to 3,
000 Pa · s, more preferably 30 to 1,000 Pa · s, and most preferably 50 to 800 Pa · s. Further, a resin in which an SH group is introduced into a terminal of a polyphenylene sulfide resin may be used. Commercially available products of such polyphenylene sulfide resin include T4AG (Topren Co., trade name), B160 (Tosoh Co., trade name), KPS W21
4 (Kureha Chemical Industry Co., Ltd., trade name) and the like.
【0024】ポリエーテルケトン系樹脂は、下記化3で
示される繰り返し単位を有する樹脂、またはこのような
繰り返し単位とともに下記化4で示される繰り返し単位
をポリエーテルケトン系樹脂本来の特性が失われない程
度に共存させている樹脂をいう。The polyetherketone-based resin is a resin having a repeating unit represented by the following formula (3) or a repeating unit represented by the following formula (4) together with such a repeating unit does not lose the original characteristics of the polyetherketone-based resin. It refers to a resin that coexists to a certain extent.
【0025】[0025]
【化3】 Embedded image
【0026】[0026]
【化4】 Embedded image
【0027】このようなポリエーテルケトン系樹脂の市
販品としては、下記化5で表されるPEEK150P
(ビクトレックス (VICTREX)社、商品名)、下記化6で
表されるPEK220G(ICI社、商品名)、下記化
7で表されるUltrapekA2000(BASF
社、商品名)が挙げられる。これらの製法は、たとえば
特開昭 54-90265 号公報等に記載されている。A commercially available product of such a polyetherketone resin is PEEK150P represented by the following formula (5).
(VICTREX, trade name), PEK220G (ICI, trade name) represented by the following chemical formula 6, UltrapekA2000 (BASF) represented by the following chemical formula 7
Company, product name). These production methods are described, for example, in JP-A-54-90265.
【0028】[0028]
【化5】 Embedded image
【0029】[0029]
【化6】 Embedded image
【0030】[0030]
【化7】 Embedded image
【0031】熱可塑性ポリイミド樹脂は、分子構造の繰
り返し単位中に、熱的特性、機械的強度等に優れたイミ
ド基が芳香族基を取り囲みながらも、熱などのエネルギ
ーが加えられることにより適度な溶融特性を示すエーテ
ル結合部分を複数個有する構造のイミド系樹脂がよく、
機械的特性、剛性、耐熱性、射出成形性を満足させるた
め、エーテル結合部を繰り返し単位中に 2個有する熱可
塑性ポリイミド樹脂が好ましい。たとえば、芳香族エー
テルジアミン類や芳香族エーテルジイソシアネート類等
と、ピロメリット酸無水物、ベンゾフェノンテトラカル
ボン酸無水物、ビフェニルテトラカルボン酸無水物等の
1種以上の酸無水物またはその誘導体との反応により得
られる樹脂を挙げることができる。The thermoplastic polyimide resin has a moderate property due to the application of energy such as heat while the imide group having excellent thermal characteristics and mechanical strength surrounds the aromatic group in the repeating unit of the molecular structure. An imide-based resin having a structure having a plurality of ether bond portions exhibiting melting characteristics is good,
In order to satisfy mechanical properties, rigidity, heat resistance, and injection moldability, a thermoplastic polyimide resin having two ether bond portions in a repeating unit is preferable. For example, aromatic ether diamines and aromatic ether diisocyanates and the like, pyromellitic anhydride, benzophenone tetracarboxylic anhydride, biphenyl tetracarboxylic anhydride and the like
Resins obtained by reaction with one or more acid anhydrides or derivatives thereof can be mentioned.
【0032】具体的に、イミド基と芳香族基とを有する
重合体の一例を化8に示す。Specifically, an example of a polymer having an imide group and an aromatic group is shown in Chemical formula 8.
【0033】[0033]
【化8】 Embedded image
【0034】(式中、Xは直結または炭素数 1〜 10 の
炭化水素基、六フッ素化されたイソプロピリデン基、カ
ルボニル基、チオ基およびスルホン基からなる群より選
ばれた基を表わし、R1 〜R4 は水素、低級アルキル基
(好ましくは炭素数 1〜5 )、低級アルコキシ基(好ま
しくは炭素数 1〜5 )、塩素または臭素を表わし、互い
に同じであっても異なっていてもよい。Yは炭素数 2以
上の脂肪族基、環式脂肪族基、単環式芳香族基、縮合多
環式芳香族基、芳香族基が直接または架橋基により相互
に連結された非縮合多環式芳香族基からなる群から選ば
れた 4価の基を表わす。)(Wherein X represents a group selected from the group consisting of a directly bonded or C 1-10 hydrocarbon group, a hexafluorinated isopropylidene group, a carbonyl group, a thio group and a sulfone group; 1 to R 4 represent hydrogen, a lower alkyl group (preferably having 1 to 5 carbon atoms), a lower alkoxy group (preferably having 1 to 5 carbon atoms), chlorine or bromine, and may be the same or different from each other; Y is an aliphatic group having 2 or more carbon atoms, a cycloaliphatic group, a monocyclic aromatic group, a condensed polycyclic aromatic group, or a non-condensed polycyclic group in which aromatic groups are connected directly or by a cross-linking group. Represents a tetravalent group selected from the group consisting of cyclic aromatic groups.)
【0035】化8で示される熱可塑性ポリイミド樹脂
は、たとえば、下記化9で示される芳香族エーテルジア
ミンと 1種以上の芳香族テトラカルボン酸二無水物の反
応によって得られるポリアミド酸を脱水環化して得られ
る。The thermoplastic polyimide resin represented by the chemical formula 8 can be obtained, for example, by dehydrating and cyclizing a polyamic acid obtained by reacting an aromatic ether diamine represented by the following chemical formula 9 with one or more aromatic tetracarboxylic dianhydrides. Obtained.
【0036】[0036]
【化9】 Embedded image
【0037】(式中、Xは直結または炭素数 1〜 10 の
炭化水素基、六フッ素化されたイソプロピリデン基、カ
ルボニル基、チオ基およびスルホン基からなる群より選
ばれた基を表わし、R1 〜R4 は水素、低級アルキル基
(好ましくは炭素数 1〜5 )、低級アルコキシ基(好ま
しくは炭素数 1〜5 )、塩素または臭素を表わし、互い
に同じであっても異なっていてもよい。) このような熱可塑性ポリイミド樹脂のうち、市販品とし
ては化8におけるR1〜R4 が全て水素である三井化学
社製の商品名オーラム(AURUM)などを挙げること
ができる。(Wherein X represents a group selected from the group consisting of a directly bonded or C 1-10 hydrocarbon group, a hexafluorinated isopropylidene group, a carbonyl group, a thio group and a sulfone group; 1 to R 4 represent hydrogen, a lower alkyl group (preferably having 1 to 5 carbon atoms), a lower alkoxy group (preferably having 1 to 5 carbon atoms), chlorine or bromine, and may be the same or different from each other; Among such thermoplastic polyimide resins, commercially available products include AURUM (trade name, manufactured by Mitsui Chemicals, Inc.) in which all of R 1 to R 4 in Chemical Formula 8 are hydrogen.
【0038】固体潤滑剤としてはポリテトラフルオロエ
チレン(以下、PTFEと略称する)等のフッ素樹脂や
グラファイト、二硫化モリブデン等を挙げることがで
き、これらを単独で、または混合して用いることができ
る。とくにPTFEは最も潤滑性に優れており好適に使
用できる。PTFEは懸濁重合法によるモールディング
パウダ、乳化重合法によるファインパウダのいずれも使
用することができる(以下、モールディングパウダおよ
びファインパウダをバージンPTFEと略称する)。ま
た、このバージンPTFEを加圧・加熱した後粉砕した
ものや、加圧・加熱した後粉砕しさらにγ線照射したも
の(以下、これらを再生PTFEと略称する)を使用す
ることができる。Examples of the solid lubricant include fluororesins such as polytetrafluoroethylene (hereinafter abbreviated as PTFE), graphite, molybdenum disulfide and the like, and these can be used alone or in combination. . In particular, PTFE is most excellent in lubricity and can be suitably used. As the PTFE, any of a molding powder by a suspension polymerization method and a fine powder by an emulsion polymerization method can be used (hereinafter, the molding powder and the fine powder are abbreviated as virgin PTFE). Further, virgin PTFE which has been crushed after being pressurized and heated, or virgin PTFE which has been crushed after being pressurized and heated and then irradiated with γ-rays (hereinafter, these are abbreviated as regenerated PTFE) can be used.
【0039】バージンPTFEは、樹脂組成物を造粒す
る際、繊維化するため造粒化に悪影響を及ぼすが、少量
であれば補強効果を有するため再生PTFEや他の固体
潤滑剤と併用して使用することが好ましい。これらの固
体潤滑剤の摺動材用樹脂組成物における配合割合は、樹
脂 100重量部に対して、 5〜100 重量部であり、好まし
くは 5〜 80 重量部である。この範囲であると他の特性
を維持して潤滑性を向上させることができる。Virgin PTFE, when granulating a resin composition, has a bad effect on granulation because it is fiberized, but if it is used in a small amount, it has a reinforcing effect, so it can be used in combination with recycled PTFE and other solid lubricants. It is preferred to use. The mixing ratio of these solid lubricants in the resin composition for a sliding material is 5 to 100 parts by weight, preferably 5 to 80 parts by weight, per 100 parts by weight of the resin. Within this range, other properties can be maintained and lubricity can be improved.
【0040】本発明に係るウィスカ材は、平均アスペク
ト比 10 以上で繊維長 100μm 以下の短繊維材をあらわ
し、本発明にあっては、モース硬度 5未満のウィスカと
モース硬度 5以上のウィスカとを 2種以上混合して用い
る。モース硬度 5未満のウィスカは、たとえば樹脂製歯
車への補強効果は小さいが、グリースを介在してもその
柔らかさゆえに異常摩耗を起こしにくい。一方、モース
硬度5以上のウィスカは、補強効果は大きいが、異常摩
耗を起こしやすくする。本発明の摺動材用樹脂組成物
は、モース硬度 5未満のウィスカとモース硬度 5以上の
ウィスカとを混合して用いることにより、樹脂製滑り軸
受や歯車等への補強効果と耐摩耗性とのバランスをとる
ものである。なお、本願で説明するモース硬度は、モー
ス硬度 5を基準としているので、新モース硬度、旧モー
ス硬度のいずれの評価基準を採用してもよいが、本願で
説明するモース硬度については旧モース硬度を基準にし
て評価する。The whisker material according to the present invention represents a short fiber material having an average aspect ratio of 10 or more and a fiber length of 100 μm or less. In the present invention, a whisker having a Mohs hardness of less than 5 and a whisker having a Mohs hardness of 5 or more are used. Use a mixture of two or more. Whiskers with a Mohs hardness of less than 5 have a small reinforcing effect on, for example, resin gears, but are not likely to cause abnormal wear due to their softness even with grease. On the other hand, whiskers having a Mohs' hardness of 5 or more have a large reinforcing effect, but tend to cause abnormal wear. The resin composition for a sliding material of the present invention is a mixture of a whisker having a Mohs hardness of less than 5 and a whisker having a Mohs hardness of 5 or more. Balance. Since the Mohs hardness described in the present application is based on Mohs hardness 5, any of the evaluation criteria of the new Mohs hardness and the old Mohs hardness may be adopted. Is evaluated based on
【0041】モース硬度 5未満のウィスカとしては、ウ
ォラストナイトウィスカ(モース硬度 4.5)、硫酸カル
シウムウィスカ(モース硬度 3)、炭酸カルシウムウィ
スカ(モース硬度 3.5〜4 )、チタン酸カリウムウィス
カ(モース硬度 3.5)などを挙げることができる。これ
らのなかで、補強効果が高く比較的安価なため、ウォラ
ストナイトウィスカおよび/または炭酸カルシウムウィ
スカが好ましい。The whiskers having a Mohs hardness of less than 5 include wollastonite whiskers (Mohs hardness 4.5), calcium sulfate whiskers (Mohs hardness 3), calcium carbonate whiskers (Mohs hardness 3.5 to 4), and potassium titanate whiskers (Mohs hardness 3.5). ). Among these, wollastonite whiskers and / or calcium carbonate whiskers are preferred because of their high reinforcing effect and relatively low cost.
【0042】モース硬度 5以上のウィスカとしては、ホ
ウ酸アルミニウムウィスカ(モース硬度 7〜 7.5)、ホ
ウ酸マグネシウムウィスカ(モース硬度 5.5)、酸化チ
タンウィスカ(モース硬度 7〜7.5 )、窒化ケイ素ウィ
スカ(モース硬度 9)、炭化ケイ素ウィスカ(モース硬
度 9)、アルミナウィスカ(モース硬度 9)、火成岩を
溶融し加工精製した鉱物繊維(モース硬度 6)などを挙
げることができる。これらのなかで、比較的長形であり
補強効果が高いため、ホウ酸アルミニウムウィスカおよ
び鉱物繊維が好ましい。As whiskers having a Mohs hardness of 5 or more, aluminum borate whiskers (Mohs hardness 7 to 7.5), magnesium borate whiskers (Mohs hardness 5.5), titanium oxide whiskers (Mohs hardness 7 to 7.5), silicon nitride whiskers (Mohs Hardness 9), silicon carbide whiskers (Mohs hardness 9), alumina whiskers (Mohs hardness 9), mineral fibers obtained by melting and processing and refining igneous rock (Mohs hardness 6). Among these, aluminum borate whiskers and mineral fibers are preferred because of their relatively long shape and high reinforcing effect.
【0043】これらのモース硬度の異なる 2種以上のウ
ィスカは、モース硬度 5未満のウィスカをモース硬度 5
以上のウィスカより多量に配合すると、補強効果が大き
いままで、グリースを使用した場合においても異常摩耗
が起こり難くなる。モース硬度の異なる 2種以上のウィ
スカの好ましい配合割合は、モース硬度 5以上のウィス
カの総量を 100重量部とした場合に、モース硬度 5未満
のウィスカの総量が 100〜1000重量部である。より好ま
しくは、モース硬度 5以上のウィスカの総量を 100重量
部とした場合に、モース硬度 5未満のウィスカの総量は
150〜500 重量部である。The two or more whiskers having different Mohs hardnesses are obtained by converting whiskers having a Mohs hardness of less than 5 to a Mohs hardness of 5 or less.
If the whisker is blended in a larger amount, abnormal wear is less likely to occur even when grease is used while the reinforcing effect is still large. A preferable mixing ratio of two or more whiskers having different Mohs hardnesses is 100 to 1000 parts by weight of whiskers having a Mohs hardness of 5 or more, where the total amount of whiskers having a Mohs hardness of 5 or more is 100 parts by weight. More preferably, when the total amount of whiskers having a Mohs hardness of 5 or more is 100 parts by weight, the total amount of whiskers having a Mohs hardness of less than 5 is
150 to 500 parts by weight.
【0044】これらのウィスカの摺動材用樹脂組成物に
おける配合割合は、樹脂 100重量部に対して、 5〜250
重量部であり、好ましくは 10 〜150 重量部、さらに好
ましくは 20 〜100 重量部である。 5〜250 重量部の範
囲にあると補強効果や成形体自身の耐摩耗性が向上す
る。また、本発明の摺動材用樹脂組成物は、ウィスカ材
と芳香族ポリアミド繊維材とを併用した樹脂組成物に比
較して成形性が向上する。The mixing ratio of these whiskers in the resin composition for a sliding material is 5 to 250 parts by weight per 100 parts by weight of the resin.
Parts by weight, preferably from 10 to 150 parts by weight, more preferably from 20 to 100 parts by weight. When it is in the range of 5 to 250 parts by weight, the reinforcing effect and the wear resistance of the molded article itself are improved. Further, the resin composition for a sliding material of the present invention has improved moldability as compared with a resin composition using a whisker material and an aromatic polyamide fiber material in combination.
【0045】このような組成物は、滑り軸受や歯車、具
体的には、歯車の内径部分が回転摺動するアイドラギア
用の組成物として好適である。そして、そのような機構
部品の用途部位としては、たとえば、トナー像転写式の
湿式静電複写機や乾式静電複写機(PPC)、レーザー
ビームプリンタ(LBP)、液晶シャッタ(LCD)プ
リンタ、ファクシミリ(FAX)用プリンタ、発光ダイ
オード(LED)、銀塩写真方式によるプリンタ(CR
T)等、プリンタ、印刷機などといった画像形成装置全
般を適用可能なものとして挙げることができる。また、
本発明の樹脂組成物からなる滑り軸受、歯車、滑り軸受
を有する歯車(たとえばアイドラギア)等の機構部品
は、感光部、現像部、定着部など、画像形成装置内のい
かなる配置部位にも用いることができる。しかし、たと
えばポリアリーレンスルフィド系樹脂、ポリエーテルケ
トン系樹脂、熱可塑性ポリイミド系樹脂等の優れた耐熱
性を考慮すれば、感光部や現像部よりも高温で使用され
る定着部周辺部位に用いられる機構部品として好適であ
る。Such a composition is suitable as a composition for a slide bearing or a gear, more specifically, an idler gear in which the inner diameter portion of the gear rotates and slides. The application parts of such mechanical components include, for example, a toner image transfer type wet electrostatic copying machine, a dry electrostatic copying machine (PPC), a laser beam printer (LBP), a liquid crystal shutter (LCD) printer, a facsimile machine. (FAX) printer, light emitting diode (LED), silver halide photographic printer (CR
T), etc., and can be applied to all image forming apparatuses such as printers and printing machines. Also,
Mechanical parts such as a sliding bearing, a gear, and a gear having a sliding bearing (for example, an idler gear) made of the resin composition of the present invention can be used in any location in an image forming apparatus such as a photosensitive section, a developing section, and a fixing section. Can be. However, considering the excellent heat resistance of, for example, polyarylene sulfide resin, polyether ketone resin, thermoplastic polyimide resin, etc., it is used in the vicinity of the fixing part used at a higher temperature than the photosensitive part and the developing part. It is suitable as a mechanical component.
【0046】樹脂製歯車の一例を図1に示す。図1は画
像形成装置における定着部周辺の部分拡大斜視図であ
る。図1において、1は駆動ギアを、2は定着ローラギ
アを、3はアイドラギアを、4は排紙ローラギアを、5
はヒータを、6は排紙ローラを、7は定着ローラをそれ
ぞれ示す。本発明の樹脂製歯車をこのような定着部周辺
に用いると現像部周辺等よりも高温で使用されても優れ
た機械的強度や耐摩耗性、摺動時に相手材を攻撃し難い
性質を維持することができる。FIG. 1 shows an example of a resin gear. FIG. 1 is a partially enlarged perspective view of the vicinity of a fixing unit in the image forming apparatus. In FIG. 1, 1 is a drive gear, 2 is a fixing roller gear, 3 is an idler gear, 4 is a discharge roller gear, 5
Denotes a heater, 6 denotes a paper discharge roller, and 7 denotes a fixing roller. When the resin gear of the present invention is used in the vicinity of such a fixing section, excellent mechanical strength and abrasion resistance even when used at a higher temperature than in the vicinity of the developing section, and the property of hardly attacking a partner material during sliding are maintained. can do.
【0047】[0047]
【実施例】実施例および比較例に使用した原材料を一括
して以下に示す。なお、[]内に表1での略号または化
学記号を示し、配合割合は全て重量部である。 (1)樹脂1:ポリフェニレンスルフィド樹脂[PP
S]:#B160(東ソー社製商品名) (2)樹脂2:ポリイミド樹脂[PI]:オーラム45
0(三井化学社製商品名) (3)樹脂3:ポリエーテルエーテルケトン樹脂[PE
EK]:PEEK150P(ビクトレックス社製商品
名) (4)ウィスカ1:ウォラストナイトウィスカ[CaS
iO3 ];モース硬度 4.5:ケモリットASB8(丸和
バイオケミカル社製商品名) (5)ウィスカ2:炭酸カルシウムウィスカ[CaCO
3 ];モース硬度 4:ウィスカルAS3(丸尾カルシウ
ム社製商品名) (6)ウィスカ3:硫酸カルシウムウィスカ[CaSO
4 ];モース硬度 3:フランクリンファイバーA30
(大日精化社製商品名) (7)ウィスカ4:ホウ酸アルミニウムウィスカ[9A
l2 O3 ・2B2 O3 ];モース硬度 7:アルボレック
スY(四国化成工業社製商品名) (8)ウィスカ5:鉱物繊維[SiO、Al2 O3 ];
モース硬度 6:ラピナスロックフィルRF5104(ラ
ピナスファイバーズ社製商品名) (9)固体潤滑剤1:再生PTFE[PTFE−1]:
KT400H(喜多村社製商品名) (10)固体潤滑剤2:バージンPTFE[PTFE−
2]:TEFLON−7J(デュポン社製商品名) (11)芳香族ポリアミド繊維:[ARPA]:コーネ
ックスカットファイバー1mm(帝人社製商品名) (12)炭素繊維:[CF]:クレカチョップM104
T(呉羽化学工業社製商品名)EXAMPLES The raw materials used in the examples and comparative examples are collectively shown below. In addition, the symbol or chemical symbol in Table 1 is shown in [], and all the mixing ratios are parts by weight. (1) Resin 1: Polyphenylene sulfide resin [PP
S]: # B160 (trade name, manufactured by Tosoh Corporation) (2) Resin 2: Polyimide resin [PI]: Aurum 45
0 (trade name, manufactured by Mitsui Chemicals, Inc.) (3) Resin 3: Polyetheretherketone resin [PE
EK]: PEEK150P (trade name, manufactured by Victrex) (4) Whisker 1: wollastonite whisker [CaS
iO 3 ]; Mohs hardness 4.5: Chemolit ASB8 (trade name, manufactured by Maruwa Biochemical Co., Ltd.) (5) Whisker 2: Calcium carbonate whisker [CaCO
3 ]; Mohs hardness 4: Whiscal AS3 (trade name, manufactured by Maruo Calcium Co., Ltd.) (6) Whisker 3: Calcium sulfate whisker [CaSO
4 ]; Mohs hardness 3: Franklin fiber A30
(7) Whisker 4: Aluminum borate whisker [9A
l 2 O 3 · 2B 2 O 3]; Mohs hardness of 7: Alborex Y (Shikoku Chemicals Corporation, trade name) (8) Whisker 5: mineral fibers [SiO, Al 2 O 3] ;
Mohs hardness 6: Rapinas Rockfill RF5104 (trade name, manufactured by Rapinas Fibers) (9) Solid lubricant 1: Recycled PTFE [PTFE-1]:
KT400H (trade name of Kitamura Co., Ltd.) (10) Solid lubricant 2: Virgin PTFE [PTFE-
2]: TEFLON-7J (trade name, manufactured by DuPont) (11) Aromatic polyamide fiber: [ARPA]: Conex cut fiber 1 mm (trade name, manufactured by Teijin Limited) (12) Carbon fiber: [CF]: Crecachop M104
T (product name made by Kureha Chemical Industry Co., Ltd.)
【0048】実施例1〜6および比較例1〜4 以上の原料を表1に示す割合で配合し、ヘンシェルミキ
サーで充分混合した後、二軸溶融押出機に供給しペレッ
トを造粒した。得られたペレットを射出成形機に供給
し、所定の金型を用い各試験片を成形し下記の評価を行
った。Examples 1 to 6 and Comparative Examples 1 to 4 The above-mentioned raw materials were blended in the proportions shown in Table 1 and thoroughly mixed with a Henschel mixer, and then supplied to a twin-screw extruder to pelletize pellets. The obtained pellets were supplied to an injection molding machine, and each test piece was molded using a predetermined mold, and the following evaluation was performed.
【0049】a.摩擦摩耗試験 摩擦摩耗試験機を用い、外径φ 21 mm、内径φ 17 mm、
高さ 10 mmの試験片により、摩擦係数と摩耗係数を測定
した。試験条件は、滑り速度 6m/min.、面圧 5kgf/c
m2 、雰囲気温度 120℃、試験時間 100hとし、相手材
として圧延鋼(SS41)を用い、無潤滑にて行った。A. Friction and wear test Using a friction and wear tester, outer diameter φ 21 mm, inner diameter φ 17 mm,
Coefficients of friction and wear were measured on 10 mm high test specimens. The test conditions were a sliding speed of 6 m / min. And a surface pressure of 5 kgf / c.
m 2 , an ambient temperature of 120 ° C., and a test time of 100 hours, using a rolled steel (SS41) as a mating material, and performing no lubrication.
【0050】b.歯車耐久試験 自社製の動力吸収型の歯車耐久試験機を用いて、内径部
分が回転摺動するアイドラギヤ(モジュール= 1、歯数
= 35 、歯幅= 8)に実施例および比較例の摺動材用樹
脂組成物からなる歯車を採用し、駆動ギヤ(モジュール
= 1、歯数= 35 、歯幅= 8)にガラス繊維強化PPS
からなる歯車を、負荷ギヤ(モジュール= 1、歯数= 3
5 、歯幅= 8)にポリアセタール樹脂からなる歯車を採
用した。試験条件は、複写機用の定着部位での仕様に準
ずるように、駆動軸回転数 125rpm 、負荷トルク 2.5kg
f-cm、雰囲気温度 150℃で 500時問連続運転した。な
お、試験開始時にグリースを駆動ギヤ表面に塗布しグリ
ース潤滑とした。試験後のアイドラギヤ、駆動ギヤおよ
び負荷ギヤの摩耗量(mg)を測定した。B. Gear endurance test Using an in-house power absorption type gear endurance tester, slide the examples and comparative examples on idler gears (module = 1, number of teeth = 35, tooth width = 8) whose inner diameter part rotates and slides. A gear made of a resin composition for materials is used, and glass fiber reinforced PPS is used for the drive gear (module = 1, number of teeth = 35, tooth width = 8).
Gear consisting of a load gear (module = 1, number of teeth = 3
5. Gears made of polyacetal resin were adopted for tooth width = 8). The test conditions were as follows: the drive shaft rotation speed was 125 rpm and the load torque was 2.5 kg so as to conform to the specifications at the fixing part for copying machines.
It was operated continuously for 500 hours at f-cm and an ambient temperature of 150 ° C. Grease was applied to the surface of the drive gear at the start of the test to provide grease lubrication. The wear amount (mg) of the idler gear, drive gear and load gear after the test was measured.
【0051】c.成形性 表1に示す配合による摺動材用樹脂組成物の前述の試験
片を射出成形する際に観察し、試験片の成形が容易か否
かを評価した。 1000 ショットの連続成形を行い、連続
成形可能であれば○で、連続成形が不可能であれば×で
評価した。C. Moldability The injection molding of the above-mentioned test piece of the resin composition for a sliding material having the composition shown in Table 1 was observed to evaluate whether or not the test piece was easily formed. 1000 shots of continuous molding were performed, and the evaluation was evaluated as "O" if continuous molding was possible, and "X" if continuous molding was impossible.
【0052】[0052]
【表1】 [Table 1]
【0053】表1の試験結果から明らかなように、モー
ス硬度 5以上とモース硬度 5未満のウィスカを適量配合
した実施例1、2は、摩耗が少なくかつ相手攻撃性も良
好であった。さらに成形性に優れている。モース硬度 5
以上とモース硬度 5未満のウィスカを適量配合している
ものの、芳香族ポリアミド繊維を添加した比較例1は、
成形性が悪く、また製造コストが実施例1に比較して約
30 %高価となった。モース硬度 5未満のウィスカだけ
を配合した比較例2は、補強効果が小さいため、歯車の
歯の一部が破壊されていた。モース硬度 5以上のウィス
カだけを配合した比較例3は、ポリアセタール樹脂から
なる相手歯車の攻撃性が高かった。ウィスカーの代わり
に炭素繊維を配合した比較例4は、自身および相手の耐
摩耗性が極端に低下した。As is evident from the test results in Table 1, Examples 1 and 2 in which whiskers having a Mohs 'hardness of 5 or more and a Mohs' hardness of less than 5 were blended in an appropriate amount exhibited low abrasion and good aggressiveness to the other party. Furthermore, it has excellent moldability. Mohs hardness 5
Comparative Example 1 in which the above and an appropriate amount of whiskers having a Mohs hardness of less than 5 were blended, but an aromatic polyamide fiber was added,
The moldability is poor and the manufacturing cost is about
30% more expensive. In Comparative Example 2, in which only whiskers having a Mohs hardness of less than 5 were blended, a part of the gear teeth was broken because the reinforcing effect was small. In Comparative Example 3, in which only whiskers having a Mohs hardness of 5 or more were blended, the aggressiveness of the mating gear made of polyacetal resin was high. In Comparative Example 4 in which carbon fibers were blended instead of the whiskers, the wear resistance of itself and the partner was extremely reduced.
【0054】[0054]
【発明の効果】本発明の摺動材用樹脂組成物は、固体潤
滑剤およびモース硬度 5未満のウィスカとモース硬度 5
以上のウィスカとを含むので、機械的強度や耐摩耗性に
優れ、摺動時に相手材を攻撃し難い性質を有する摺動部
材が得られる。The resin composition for a sliding material of the present invention comprises a solid lubricant and a whisker having a Mohs hardness of less than 5 and a Mohs hardness of 5 or less.
By including the above whiskers, a sliding member having excellent mechanical strength and abrasion resistance and having a property of hardly attacking a partner material during sliding can be obtained.
【0055】また、モース硬度 5未満のウィスカ配合量
がモース硬度 5以上のウィスカより配合量が多い場合、
モース硬度 5未満のウィスカがウオラストナイトウィス
カ、モース硬度 5以上のウィスカがホウ酸アルミニウム
ウィスカである場合、樹脂がポリフェニレンスルフィド
樹脂である場合においては、あるいはこれらの組み合わ
せの場合においては、上述の特性がより向上する。その
結果、本発明の摺動材用樹脂組成物を成形することによ
って、優れた機械的強度や耐摩耗性、摺動時に相手材を
攻撃し難い性質を有する樹脂製滑り軸受や樹脂製歯車が
得られる。When the amount of the whisker having a Mohs hardness of less than 5 is larger than that of the whisker having a Mohs hardness of 5 or more,
If the whisker with a Mohs hardness of less than 5 is wollastonite whisker and the whisker with a Mohs hardness of 5 or more is aluminum borate whisker, the resin is a polyphenylene sulfide resin, or a combination of these, Is more improved. As a result, by molding the resin composition for a sliding material of the present invention, a resin sliding bearing or a resin gear having excellent mechanical strength and abrasion resistance, properties of hardly attacking a partner material during sliding can be obtained. can get.
【図1】画像形成装置における定着部周辺の部分拡大斜
視図である。FIG. 1 is a partially enlarged perspective view of the vicinity of a fixing unit in an image forming apparatus.
1 駆動ギア 2 定着ローラギア 3 アイドラギア 4 ローラギア 5 ヒータ 6 排紙ローラ 7 定着ローラ DESCRIPTION OF SYMBOLS 1 Drive gear 2 Fixing roller gear 3 Idler gear 4 Roller gear 5 Heater 6 Discharge roller 7 Fixing roller
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI F16H 55/06 F16H 55/06 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification code FI F16H 55/06 F16H 55/06
Claims (7)
スカ材とを配合してなる摺動材用樹脂組成物であって、
前記ウィスカ材はモース硬度 5未満のウィスカとモース
硬度 5以上のウィスカとを含むことを特徴とする摺動材
用樹脂組成物。A sliding material resin composition comprising a resin and at least a solid lubricant and a whisker material,
The resin composition for a sliding material, wherein the whisker material includes a whisker having a Mohs hardness of less than 5 and a whisker having a Mohs hardness of 5 or more.
ウィスカ配合量がモース硬度 5以上のウィスカ配合量よ
り多いことを特徴とする請求項1記載の摺動材用樹脂組
成物。2. The resin composition for a sliding material according to claim 1, wherein the amount of the whisker having a Mohs hardness of less than 5 is larger than the amount of the whisker having a Mohs hardness of 5 or more.
ラストナイトウィスカおよび炭酸カルシウムウィスカか
ら選ばれた少なくとも一つのウィスカであることを特徴
とする請求項1または請求項2記載の摺動材用樹脂組成
物。3. The resin for a sliding material according to claim 1, wherein the whisker having a Mohs hardness of less than 5 is at least one whisker selected from wollastonite whiskers and calcium carbonate whiskers. Composition.
酸アルミニウムウィスカおよび鉱物繊維から選ばれた少
なくとも一つのウィスカであることを特徴とする請求項
1ないし請求項3のいずれか1項記載の摺動材用樹脂組
成物。4. The slide according to claim 1, wherein the whisker having a Mohs hardness of 5 or more is at least one whisker selected from aluminum borate whiskers and mineral fibers. A resin composition for a moving material.
樹脂、ポリエーテルケトン系樹脂および熱可塑性ポリイ
ミド系樹脂の中から選ばれた少なくとも一つの樹脂であ
ることを特徴とする請求項1ないし請求項4のいずれか
1項記載の摺動材用樹脂組成物。5. The resin according to claim 1, wherein said resin is at least one resin selected from a polyarylene sulfide resin, a polyether ketone resin and a thermoplastic polyimide resin. The resin composition for a sliding material according to claim 1.
チレンであることを特徴とする請求項1ないし請求項5
のいずれか1項記載の摺動材用樹脂組成物。6. The solid lubricant according to claim 1, wherein said solid lubricant is polytetrafluoroethylene.
The resin composition for a sliding material according to any one of the above.
であって、前記樹脂組成物が請求項1ないし請求項6の
いずれか1項記載の摺動材用樹脂組成物であることを特
徴とする樹脂製歯車。7. A resin gear formed from a molded product of a resin composition, wherein the resin composition is the resin composition for a sliding material according to any one of claims 1 to 6. Characteristic resin gear.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP05592998A JP3961103B2 (en) | 1997-02-25 | 1998-02-20 | Resin composition for sliding material and resin gear |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9-40211 | 1997-02-25 | ||
JP4021197 | 1997-02-25 | ||
JP05592998A JP3961103B2 (en) | 1997-02-25 | 1998-02-20 | Resin composition for sliding material and resin gear |
Related Child Applications (2)
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JP2006294736A Division JP2007107721A (en) | 1997-02-25 | 2006-10-30 | Resin gear |
JP2006294766A Division JP2007046064A (en) | 1997-02-25 | 2006-10-30 | Resin composition for sliding member and resin gear |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH10298441A true JPH10298441A (en) | 1998-11-10 |
JP3961103B2 JP3961103B2 (en) | 2007-08-22 |
Family
ID=26379652
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WO2006098303A1 (en) * | 2005-03-16 | 2006-09-21 | Daikin Industries, Ltd. | Composition for slide member, slide member and fluid machinery |
KR100636939B1 (en) * | 2001-10-15 | 2006-10-19 | 스미토모 베이클리트 컴퍼니 리미티드 | Polyether aromatic ketone resin composition and its film and sheet |
JP2006283706A (en) * | 2005-04-01 | 2006-10-19 | Daikin Ind Ltd | Composition for sliding member, sliding member and fluid machine |
JP2010535922A (en) * | 2007-08-13 | 2010-11-25 | ライプニッツ−インスティチュート フュア ポリマーフォルシュング ドレスデン エーファウ | Polyphenylene sulfide (per) fluoropolymer materials and methods for their production and use |
CN111995774A (en) * | 2020-08-20 | 2020-11-27 | 株洲时代新材料科技股份有限公司 | Preparation method of wear-resistant polyamide-imide molding powder |
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JP2007046064A (en) * | 1997-02-25 | 2007-02-22 | Ntn Corp | Resin composition for sliding member and resin gear |
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1998
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100636939B1 (en) * | 2001-10-15 | 2006-10-19 | 스미토모 베이클리트 컴퍼니 리미티드 | Polyether aromatic ketone resin composition and its film and sheet |
WO2006098303A1 (en) * | 2005-03-16 | 2006-09-21 | Daikin Industries, Ltd. | Composition for slide member, slide member and fluid machinery |
JP2006283706A (en) * | 2005-04-01 | 2006-10-19 | Daikin Ind Ltd | Composition for sliding member, sliding member and fluid machine |
WO2006109511A1 (en) * | 2005-04-01 | 2006-10-19 | Daikin Industries, Ltd. | Composition for sliding member, sliding member, and fluid machine |
AU2006234097B2 (en) * | 2005-04-01 | 2010-04-15 | Daikin Industries, Ltd. | Sliding member forming composition, sliding member, and fluid machinery |
EP1849818A4 (en) * | 2005-04-01 | 2012-04-25 | Daikin Ind Ltd | COMPOSITION FOR SLIDING ELEMENT, SLIDING MEMBER AND HYDRAULIC MACHINE |
JP2010535922A (en) * | 2007-08-13 | 2010-11-25 | ライプニッツ−インスティチュート フュア ポリマーフォルシュング ドレスデン エーファウ | Polyphenylene sulfide (per) fluoropolymer materials and methods for their production and use |
CN111995774A (en) * | 2020-08-20 | 2020-11-27 | 株洲时代新材料科技股份有限公司 | Preparation method of wear-resistant polyamide-imide molding powder |
CN111995774B (en) * | 2020-08-20 | 2023-02-07 | 株洲时代新材料科技股份有限公司 | Preparation method of wear-resistant polyamide-imide molding powder |
CN113024993A (en) * | 2021-03-24 | 2021-06-25 | 广州机械科学研究院有限公司 | Polyether-ether-ketone composite material and preparation method and application thereof |
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