JPH10283921A - Method of manufacturing cathode for discharge lamp - Google Patents

Abstract

(57) [Problem] To provide a method of manufacturing a cathode for a discharge lamp capable of stabilizing arc discharge for a long time. SOLUTION: Except for the arc discharge part at the tip, other parts are cut to a substantially final form, and then the whole outer surface of the cathode is carbonized,
The arc discharge portion at the tip is cut to a final shape.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a method for manufacturing a cathode for a discharge lamp. In particular, the present invention relates to a carbonization method capable of improving the electron emission of an arc emitting portion.

[0002]

2. Description of the Related Art In order to obtain stable radiation from a discharge lamp for a long time, it is necessary to stabilize an arc discharge generated between electrodes for a long time. For this reason, a tungsten rod containing thorium oxide as an electron-emitting substance (emitter) has been used for the cathode.

In order to stabilize the arc discharge for a longer time, a technique of carbonizing a tungsten rod containing thorium oxide has been established. The principle is that a tungsten carbide (W2C) layer (hereinafter, referred to as "W2C") formed on the cathode surface
The "carbonized layer" traps oxygen of thorium oxide (ThO2) diffused during the arc discharge operation and efficiently supplies thorium (Th) atoms to the arc discharge portion at the tip of the cathode. On the other hand, when the carbonized layer is formed up to the arc emitting portion at the cathode tip, the arc emitting portion becomes extremely hot during the arc discharge operation.
For example, since the temperature becomes about 2900 ° C., the carbonized layer is melted, and as a result, the arc discharge becomes unstable and a short life occurs.

[0004] In order to solve this problem, the following carbonization treatment has conventionally been performed. . Mix the carbon (carbon) and the volatile organic solvent to knead the paste-like coating agent. . This paste-like coating agent is applied to the surface of the cathode (tungsten rod), but not to the arc discharge portion at the tip. . By performing high-temperature heat treatment in this state, a desired carbonized layer film was formed on the surface of the tungsten rod except for the tip arc emission portion. However, in this method, the organic solvent in the paste-like coating agent applied to the tungsten rod evaporates, causing cracks, resulting in an uneven application state as a whole. That is, even in the region where the carbonized layer should be formed, the portion where the carbonized layer is formed and the portion where the carbonized layer is not formed are undesirably generated, and as a result, the arc discharge cannot be stabilized for a long time. .

[0005] As a prior art document that solves the above-mentioned problem, there is Japanese Patent Publication No. 5-86026, for example, which discloses a method of uniformly covering a portion of a cathode (tungsten rod) except a tip thereof with a carbonized layer. Specifically, carbon is deposited by a gas containing carbon (for example, CH4), and at this time, a portion where the carbonized layer at the tip must not be covered is inserted into a recess of a batch support (Chargentraeger) and covered. That is. That is, after the cathode is cut to almost the final form, the carbonized layer is coated by a vapor phase growth method, and the coating is prevented by inserting the tip of the cathode into a recess provided in a member supporting the cathode. Things. However, even with this method, it is difficult to completely prevent carbonization of the tip arc emitting portion, that is, a carbonized layer is formed in the tip arc emitting portion although it is delicate. It is considered that this is because it is difficult to completely shield simply by inserting the tip into the depression of the support.

[0006]

SUMMARY OF THE INVENTION An object of the present invention is to provide a method of manufacturing a cathode for a discharge lamp capable of stabilizing an arc discharge operation for a long time. An object of the present invention is to provide a method for producing a cathode for a discharge lamp, which enables a good supply of thorium atoms by carbonization treatment and does not cause a problem such as defective arc discharge operation due to melting of carbide.

[0007]

SUMMARY OF THE INVENTION The present invention is a method of manufacturing a cathode for a high pressure discharge lamp containing an electron emitting material,
Except for the arc-emitting portion at the tip, the other portions are cut to a substantially final form, and then the entire outer surface of the cathode is carbonized. It is characterized by cutting to the final form.

[0008]

According to the method for manufacturing a cathode for a discharge lamp of the present invention, when manufacturing a rod-shaped cathode having a sharp tip as a final form, first, a sharp tip (that is, an arc emitting portion) is cut into the shape. Instead, the other parts are cut to almost the final form. next,
In this state, the whole is carbonized, and thereafter, a cutting process is performed to finish the tip portion (arc portion) of the sharp electrode. Therefore, the shape of the cathode is not finished before the carbonization treatment is performed as in the conventional manufacturing method, but only the portion to be carbonized is finished. The shape is cut and finished.

[0009]

FIG. 1 shows an overall view of a high-pressure discharge lamp. An anode 2 and a cathode 3 are arranged in an arc tube 1 made of quartz. The anode 2 is made of tungsten, and the cathode 3 is made of tungsten containing thorium oxide as an emitter (so-called tritan). Reference numeral 4 denotes an external current supply lead rod, which is electrically connected to the anode 2 and the cathode 3 via a metal foil or the like. The structure itself of such a discharge lamp is not particularly unusual, and details thereof are omitted. Mercury and argon are sealed in the arc tube 1. This discharge lamp is rated 2 for example.
An arc discharge is performed with KW to emit ultraviolet light having a wavelength of 365 nm or the like.

FIG. 2 shows a method for manufacturing a cathode for a discharge lamp according to the present invention. FIG. 3A shows the shape of a tungsten rod (cathode) when performing carbonization. Arc discharge part 3 at the tip
1 is not cut as a final form, and is therefore as shown in the figure. Other parts are processed almost to the final form. This cutting process is not a special method, but a normal method using a lathe or the like can be applied.

The carbonization is performed in this state, and the carbonization is performed by, for example, a gas phase carbonization method. FIG. 2B shows this gas phase carbonization method. The tungsten rod 3 (cathode) is arranged in a glass container 20 and the tungsten rod 3 is heated by a high-frequency heating coil 21 arranged outside the container. When a mixture of benzene (C6 H6) vapor and hydrogen gas is allowed to flow through the container, the benzene (C6 H6) vapor is decomposed on the surface of the tungsten rod in a high-temperature heating state, and carbon atoms are decomposed. Are loosely fixed. In this case, a desired carbonized layer is formed by controlling the concentration of benzene (C6 H6) vapor and the temperature at which tungsten is heated. For example, high-frequency heating is performed at a heating temperature of 1500 ° C. for 20 minutes. In addition, it is not limited to benzene, and vapor of a carbon-based derivative can be used. Then, by flowing only hydrogen gas and heating the tungsten rod 3 for several minutes, the surface of the tungsten rod 3 changes from 2WC to W2 C + C, and the free carbon (C) generated there is converted to the cathode (tungsten rod) 3. The heat is diffused from the outermost surface to the inside and reacts with the tungsten atoms inside (C + 2W → W2C), that is, the same W2C layer as the surface is formed. Next, the tip portion of the cathode is processed into a final shape. As shown in FIG. 3C, a portion indicated by a dotted line 31a is cut to finish it into a desired sharp shape. That is, the surface of the processed portion is also carbonized, but in the manufacturing method of the present invention, since the portion is shaved off after the carbonizing process, a portion that has not been carbonized can be satisfactorily formed.

FIG. 3 shows another embodiment of the manufacturing method of the present invention. Tungsten rod 3 in long glass container 30
2 are arranged. In this tungsten rod 32, reduced portions 33 are formed in some places. Then, a power supply member 34 and a power supply 36 are attached to both ends of the tungsten rod 32, respectively, and when electricity is supplied, the tungsten rod 32 itself generates heat as a conductor and reaches a temperature required for carbonization. A gas obtained by mixing benzene (C6H6) vapor and hydrogen gas flows into the glass container 30 from a gas inlet 35 provided in the glass container 30. After carbonizing the outer surface of the tungsten rod 32 in this manner, the reduced portion 33
By cutting a predetermined position in and other parts, a plurality of cathodes can be made satisfactorily. In addition, in the case of this manufacturing method, since the electrical resistance increases in the reduced portion 33 of the tungsten rod, there is an advantageous effect in that the heating effect is enhanced.

Next, the characteristics of the discharge lamp using the cathode of the present invention will be compared with those of a conventional discharge lamp. FIG. 4 shows the attenuation characteristics of the emitted ultraviolet light, the horizontal axis represents the operation time, and the vertical axis represents the relative light output. The relative light output was 10 at the start of the arc discharge.
The optical output at each time when it is set to 0 is shown. In the figure, a is a discharge lamp using a cathode according to the manufacturing method of the present invention, b is a discharge lamp using a cathode carbonized by a conventional manufacturing method, c is a discharge using a cathode not carbonized. The ultraviolet attenuating characteristics of the lamp are shown. As a result, it can be seen that the discharge lamp using the cathode according to the manufacturing method of the present invention maintains the light output of 90% or more of the time when the arc discharge started even after about 1000 hours.
On the other hand, it can be seen that the light output of the discharge lamp using the cathode subjected to the carbonization treatment reaction by the conventional manufacturing method is attenuated to about 80% when the arc discharge is started. In addition, it can be seen that the discharge lamp which has not been subjected to the carbonization treatment has attenuated to about 60% when the arc discharge has been performed for about 500 hours. That is, it is clearly understood how the discharge lamp using the cathode according to the manufacturing method of the present invention enables stable arc discharge for a long time.

Next, the arc stability of the discharge lamp using the cathode of the present invention will be compared with that of a conventional discharge lamp. FIG. 5 shows the stability of the arc. The degree of stability is obtained by evaluating the degree of fluctuation with respect to 100 when ultraviolet light is input at a constant standard power. In the figure, a is a discharge lamp using a cathode according to the manufacturing method of the present invention, b is a discharge lamp using a cathode carbonized by a conventional manufacturing method, c is a discharge using a cathode not carbonized. Indicates the degree of swing of the arc of the lamp. As a result, it can be seen that in the discharge lamp using the cathode according to the manufacturing method of the present invention, arc shaking hardly occurred during about 1000 hours of arc discharge. On the other hand, it can be seen that the discharge lamp using the cathode which has been carbonized by the conventional manufacturing method and the discharge lamp which has not been subjected to the carbonization show arc swaying.

[0015]

The discharge lamp using the cathode according to the manufacturing method of the present invention can obtain a stable arc discharge for a long time. More specifically, thorium atoms are satisfactorily supplied by satisfactorily carbonizing the cathode bar, thereby improving electron emission, and there is no problem such as poor lighting due to melting of carbide.

[Brief description of the drawings]

FIG. 1 shows the general outline of a high-pressure discharge lamp.

FIG. 2 shows a manufacturing method of the present invention.

FIG. 3 shows a method for producing a cathode of the present invention.

FIG. 4 shows the effect of the present invention.

FIG. 5 shows the effect of the present invention.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 Arc tube 2 Anode 3 Cathode 4 Lead bar 20 Glass container 21 High frequency heating coil 30 Glass container 31 Arc emission part 32 Cathode 33 Reduction part 34 Power supply member 35 Inlet 36 Power supply

Claims (1)

[Claims] 1. A method of manufacturing a cathode for a discharge lamp containing an emitter material, wherein a portion other than an arc-emitting portion at a tip is cut to a substantially final form, and A method for producing a cathode for a discharge lamp, wherein a carbonizing treatment is performed on an outer surface, and thereafter, the arc emitting portion is cut to a final shape.