JPH10265716A - Composition for treating sealing material - Google Patents
Composition for treating sealing materialInfo
- Publication number
- JPH10265716A JPH10265716A JP8882797A JP8882797A JPH10265716A JP H10265716 A JPH10265716 A JP H10265716A JP 8882797 A JP8882797 A JP 8882797A JP 8882797 A JP8882797 A JP 8882797A JP H10265716 A JPH10265716 A JP H10265716A
- Authority
- JP
- Japan
- Prior art keywords
- sealing material
- composition
- treating
- solvent
- aliphatic hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003566 sealing material Substances 0.000 title claims abstract description 59
- 239000000203 mixture Substances 0.000 title claims abstract description 53
- 239000002904 solvent Substances 0.000 claims abstract description 55
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 28
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 23
- 229920000642 polymer Polymers 0.000 claims abstract description 15
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 13
- 239000011737 fluorine Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 238000007789 sealing Methods 0.000 claims abstract description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims abstract description 4
- 238000009835 boiling Methods 0.000 claims abstract description 3
- 229920002313 fluoropolymer Polymers 0.000 claims description 11
- 239000004811 fluoropolymer Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 230000003373 anti-fouling effect Effects 0.000 claims description 6
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 6
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical group CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical group C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 6
- 238000006116 polymerization reaction Methods 0.000 abstract description 6
- 230000003405 preventing effect Effects 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract 1
- 239000002689 soil Substances 0.000 abstract 1
- -1 alicyclic hydrocarbon Chemical class 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- 239000011347 resin Substances 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 229930195733 hydrocarbon Natural products 0.000 description 10
- 150000002430 hydrocarbons Chemical class 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 9
- 239000000178 monomer Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000428 dust Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 229920001296 polysiloxane Polymers 0.000 description 7
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000000565 sealant Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
- 241000272194 Ciconiiformes Species 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 125000001153 fluoro group Chemical group F* 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 239000005077 polysulfide Substances 0.000 description 4
- 229920001021 polysulfide Polymers 0.000 description 4
- 150000008117 polysulfides Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 3
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- 230000000873 masking effect Effects 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 241000178435 Eliokarmos dubius Species 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000002519 antifouling agent Substances 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000004069 aziridinyl group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical class C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- 229940038384 octadecane Drugs 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、シーリング材処理
用組成物に関する。[0001] The present invention relates to a composition for treating a sealing material.
【0002】[0002]
【従来の技術】建築物の内外装の目地部等に適用される
シーリング材は、水密や気密を付与する目的で各種建築
部材間等の接合部や隙間に充填することにより使用され
る材料である。2. Description of the Related Art Sealing materials applied to joints of the interior and exterior of buildings are materials used by filling joints and gaps between various building members for the purpose of imparting watertightness and airtightness. is there.
【0003】従来よりシーリング材としては、シリコー
ン系、変成シリコーン系、ポリスルフィド系、変成ポリ
スルフィド系、またはポリウレタン系等の樹脂からなる
ものがあり、これらのうち、耐久性および耐候性等の点
で優れた性能をバランスよく有することから、特に変成
シリコーン系、変成ポリスルフィド系またはポリウレタ
ン系の樹脂が広く使われている。[0003] Conventionally, as a sealing material, there have been resins made of silicone, modified silicone, polysulfide, modified polysulfide, polyurethane or the like, and among these, they are excellent in durability and weather resistance. In particular, a modified silicone resin, a modified polysulfide resin or a polyurethane resin is widely used because they have a good balance of performance.
【0004】しかし、これらの樹脂からなるシーリング
材は、硬化後も表面にべたつき(タック)が残るため、
目地部に大気中の塵埃が付着し美観を損なう問題があ
る。特に関東地方においては、関東ローム層の影響で、
シーリング材の表面が顕著に汚れる問題もあり、美観上
の理由から、シーリング材表面に防汚性を付与する技術
が提案されている。[0004] However, since the sealing material made of these resins remains sticky (tacky) on the surface even after curing,
There is a problem that dust in the atmosphere adheres to the joints and impairs the appearance. Especially in the Kanto region, due to the Kanto loam,
There is also a problem that the surface of the sealing material is significantly stained, and for aesthetic reasons, a technique for imparting antifouling properties to the surface of the sealing material has been proposed.
【0005】例えば、シーリング材を硬化した後に、そ
の表面に着塵防止剤を塗布してバリア層を設ける方法が
提案されているが、シーリング材が硬化するまでの間の
塵埃の付着を防止できない問題がある。また着塵防止剤
としては、アクリル系、ウレタン系、シリコーン系など
の樹脂を主成分としたものであり、被膜の硬度が硬くな
るために目地の動きに追従できず、または、光の作用で
劣化し、クラックを生じ、そこに塵埃が付着する問題も
あった。For example, a method has been proposed in which a barrier layer is provided by applying a dust-preventing agent to the surface of a sealing material after the sealing material has been cured. However, it is not possible to prevent adhesion of dust until the sealing material is cured. There's a problem. In addition, as a dust-prevention agent, an acrylic, urethane-based, or silicone-based resin is the main component, and the hardness of the coating film is hard, so that it cannot follow the movement of joints, or it is affected by the action of light. There is also a problem of deterioration, cracks, and adhesion of dust there.
【0006】また、シーリング材が硬化するまでの間に
塵埃が付着することを防止するために、フッ素樹脂を主
成分とする溶剤型の防汚加工剤を、シーリング材の未硬
化時に塗布する方法が提案されている(特開平2−18
2767、特開平7−118572)。Further, in order to prevent dust from adhering before the sealing material is cured, a method of applying a solvent type antifouling agent containing a fluororesin as a main component when the sealing material is not cured. (Japanese Patent Laid-Open No. 2-18 / 1990)
2767, JP-A-7-118572).
【0007】[0007]
【発明が解決しようとする課題】フッ素樹脂を主成分と
する溶剤型の防汚加工材には、溶剤として塩素化フッ素
化炭化水素や塩素化炭化水素が用いられてきたが、近年
環境上の配慮から該溶剤以外の他の溶剤を選択する必要
がでてきた。The chlorinated fluorinated hydrocarbons and chlorinated hydrocarbons have been used as solvents for solvent-type antifouling materials containing a fluorine resin as a main component. Due to consideration, it has become necessary to select a solvent other than the solvent.
【0008】フッ素樹脂を溶解しうる他の溶剤として
は、酢酸エチル、酢酸ブチル等のエステル系溶剤、メチ
ルエチルケトン、メチルイソブチルケトン等のケトン系
溶剤、キシレン、トルエン等の芳香族炭化水素系溶剤が
ある。しかし、これらの溶剤は有機系材料に対する溶解
性が高いため、シーリング材周辺の有機系材料が変色す
る、縮みがでる、光沢が変化する等の問題があり、上記
他の溶剤を含む防汚加工剤は、シーリング材周辺の材料
が無機系材料であるものへの適用に限定される問題があ
った。また、溶剤への溶解性を考慮すると、フッ素樹脂
中のフッ素含量が低くなる問題があり、フッ素に由来す
る性能を期待するためには塗工量が多くなる問題もあっ
た。また、塗工量を多くすると、外観が変化したりクラ
ックの発生の原因になる問題があった。Other solvents capable of dissolving the fluororesin include ester solvents such as ethyl acetate and butyl acetate, ketone solvents such as methyl ethyl ketone and methyl isobutyl ketone, and aromatic hydrocarbon solvents such as xylene and toluene. . However, since these solvents have high solubility in organic materials, there are problems such as discoloration, shrinkage, and change in gloss of the organic materials around the sealing material. The agent has a problem that it is limited to application to a material in which the material around the sealing material is an inorganic material. Further, considering the solubility in a solvent, there is a problem that the fluorine content in the fluororesin is low, and there is also a problem that the coating amount is large in order to expect performance derived from fluorine. In addition, when the coating amount is increased, there is a problem that the appearance is changed or a crack is generated.
【0009】[0009]
【課題を解決するための手段】本発明は、上記の問題を
解決しようとするもので、シーリング材表面を処理する
ための組成物であって、脂肪族炭化水素系溶剤および該
溶剤に可溶性の含フッ素重合体を含有することを特徴と
するシーリング材処理用組成物を提供する。SUMMARY OF THE INVENTION The present invention is intended to solve the above-mentioned problems, and is directed to a composition for treating the surface of a sealing material, comprising an aliphatic hydrocarbon solvent and a solvent soluble in the solvent. Provided is a composition for treating a sealing material, comprising a fluoropolymer.
【0010】[0010]
【発明の実施の形態】本発明における脂肪族炭化水素系
溶剤としては、脂肪族炭化水素を主成分とする公知の溶
剤が採用できる。本明細書における脂肪族炭化水素と
は、炭素原子と水素原子のみからなる狭義の脂肪族炭化
水素である。DESCRIPTION OF THE PREFERRED EMBODIMENTS As the aliphatic hydrocarbon-based solvent in the present invention, a known solvent containing an aliphatic hydrocarbon as a main component can be used. The aliphatic hydrocarbon in the present specification is a narrowly defined aliphatic hydrocarbon composed of only carbon atoms and hydrogen atoms.
【0011】本発明における脂肪族炭化水素系溶剤とし
ては、脂肪族炭化水素を80重量%以上含む溶剤が好ま
しい。脂肪族炭化水素系溶剤中には、脂肪族炭化水素系
溶剤以外の溶剤を実質的に含まないのが好ましく、特に
芳香族炭化水素や酢酸エステル、ケトン類等の含酸素溶
媒等を含まないことが好ましいが、有機塗装への影響が
無視できる範囲であれば、少量を含んでいてもよい。As the aliphatic hydrocarbon solvent in the present invention, a solvent containing at least 80% by weight of an aliphatic hydrocarbon is preferable. It is preferable that the aliphatic hydrocarbon-based solvent does not substantially contain a solvent other than the aliphatic hydrocarbon-based solvent, and particularly does not contain an oxygen-containing solvent such as an aromatic hydrocarbon, an acetate, and a ketone. However, a small amount may be contained as long as the effect on the organic coating can be ignored.
【0012】脂肪族炭化水素系溶剤としては、工業ガソ
リンJIS規格4号、5号に分類される溶剤が好まし
く、パラフィン系炭化水素、またはイソパラフィン系炭
化水素を主成分とするパラフィン系溶剤が好ましい。該
パラフィン系溶剤炭化水素は、通常は炭素数の異なるパ
ラフィン系炭化水素またはイソパラフィン系炭化水素が
2種以上含まれる混合物であり、炭素数6以上の複数の
パラフィン系炭化水素またはイソパラフィン系炭化水素
化合物が含まれるのが好ましく、特に炭素数7〜12の
パラフィン系炭化水素、または炭素数7〜12のイソパ
ラフィン系炭化水素が80重量%以上含まれるものが好
ましい。例えば、パラフィン系溶剤としては、イソペン
タン、n−ペンタン、n−ヘキサン、n−ヘプタン、n
−オクタン等を含むものが好ましい。さらに、脂肪族炭
化水素系溶剤の沸点は80〜300℃であるのが好まし
い。As the aliphatic hydrocarbon-based solvent, a solvent classified according to industrial gasoline JIS Nos. 4 and 5 is preferable, and a paraffin-based hydrocarbon or a paraffin-based solvent containing isoparaffin-based hydrocarbon as a main component is preferable. The paraffinic solvent hydrocarbon is usually a mixture containing two or more kinds of paraffinic hydrocarbons or isoparaffinic hydrocarbons having different carbon numbers, and a plurality of paraffinic hydrocarbons or isoparaffinic hydrocarbon compounds having 6 or more carbon atoms. It is particularly preferable that the content of paraffin-based hydrocarbon having 7 to 12 carbon atoms or isoparaffin-based hydrocarbon having 7 to 12 carbon atoms be 80% by weight or more. For example, as a paraffin-based solvent, isopentane, n-pentane, n-hexane, n-heptane, n
Those containing octane or the like are preferred. Further, the boiling point of the aliphatic hydrocarbon-based solvent is preferably from 80 to 300 ° C.
【0013】上記の脂肪族炭化水素系溶剤は、市販され
ており、本発明においては該市販品をそのまま使用でき
る。市販品としては以下のものが挙げられる。Aソルベ
ント、Kソルベント、ミネラルスピリット、ドライソル
ベント、ニューソルDX、LAソルベント(以上、日本
石油社製商品名)、ベガゾールAN45、ベガゾール3
040(以上、モービル社製商品名)、エッソナフサN
o.6、エッソナフサNo.5(以上、エッソ化学社製
商品名)、LAWS、シェルエイト、ブライトソル、シ
ェルソル140(以上、シェル化学社製商品名)、昭石
ソルベント、昭石SSドライゾール、昭石ナフゾール1
号(以上、昭和石油社製商品名)、共石特ソルベント、
共石ホワイトゾール、LAソルベント(以上、共同石油
社製商品名)、ミネラルターペン、ダイヤソルベント
(以上、三菱石油社製商品名)、ソルベントケロシンL
A、ソルベントケロシン(以上、ゼネラル石油社製商品
名)、ダイナソルベント(大協石油社製商品名)、出光
ソルベント(出光興産社製商品名)等。The above-mentioned aliphatic hydrocarbon-based solvent is commercially available, and the commercially available product can be used as it is in the present invention. Commercially available products include the following. A Solvent, K Solvent, Mineral Spirit, Dry Solvent, New Solve DX, LA Solvent (trade names of Nippon Oil Co., Ltd.), Vegazol AN45, Vegazol 3
040 (above, product names manufactured by Mobile), Essonafusa N
o. 6, Essonafusa No. 5 (above, trade name of Esso Chemical Co., Ltd.), LAWS, Shell Eight, Bright Sol, Shell Sol 140 (above, trade name of Shell Chemical Co., Ltd.), Shoseki Solvent, Shoseki SS Dry Sol, Shoseki Naphsol 1
No. (the trade name of Showa Sekiyu KK), Kyoishi Special Solvent,
Kyoishi White Sol, LA Solvent (above, trade name of Kyodo Sekiyu), Mineral Tarpen, Diamond Solvent (above, trade name of Mitsubishi Petroleum), Solvent Kerosene L
A, Solvent Kerosene (above, trade names made by General Petroleum Co., Ltd.), Dyna Solvent (trade name made by Daikyo Oil Co., Ltd.), Idemitsu Solvent (trade name made by Idemitsu Kosan Co., Ltd.), etc.
【0014】また、本発明における脂肪族炭化水素系溶
剤としては、脂肪族炭化水素を単独で用いてもよい。該
脂肪族炭化水素としては、炭素数10〜18のノルマル
パラフィン類が好ましく、具体的には、デカン、ウンデ
カン、ドデカン、テトラデカン、ヘキサデカン、オクタ
デカン等が挙げられる。また、脂肪族炭化水素系溶剤
は、メチルシクロヘキサンのような脂環式炭化水素であ
ってもよい。Further, as the aliphatic hydrocarbon solvent in the present invention, an aliphatic hydrocarbon may be used alone. As the aliphatic hydrocarbon, normal paraffins having 10 to 18 carbon atoms are preferable, and specific examples include decane, undecane, dodecane, tetradecane, hexadecane, and octadecane. Further, the aliphatic hydrocarbon-based solvent may be an alicyclic hydrocarbon such as methylcyclohexane.
【0015】本発明における含フッ素重合体としては、
ポリフルオロアルキル基を含む重合体が好ましい。な
お、以下において、アクリレートとメタクリレートとを
総称して「(メタ)アクリレート」と記載する。他の化
合物においても同様である。また、以下においてポリフ
ルオロアルキル基をRf 基と記載する。The fluorinated polymer in the present invention includes:
Polymers containing polyfluoroalkyl groups are preferred. In the following, acrylate and methacrylate are collectively referred to as “(meth) acrylate”. The same applies to other compounds. Hereinafter, a polyfluoroalkyl group is referred to as an Rf group.
【0016】Rf 基は、アルキル基の水素原子の2個以
上がフッ素原子に置換された基を意味する。また、本発
明におけるRf 基は、炭素−炭素結合間にエーテル性の
酸素原子を含んでいてもよい。Rf 基の炭素数は1〜2
0が好ましく、4〜16がさらに好ましく、6〜12が
特に好ましい。また、Rf 基は、直鎖または分岐の構造
が好ましく、直鎖の構造がより好ましい。分岐の構造で
ある場合には、分岐部分がRf 基の末端部分に存在し、
かつ、炭素数が1〜3程度の短鎖である場合が好まし
い。The R f group means a group in which two or more hydrogen atoms of an alkyl group have been replaced by fluorine atoms. Further, the R f group in the present invention may contain an etheric oxygen atom between carbon-carbon bonds. The carbon number of the R f group is 1-2.
0 is preferable, 4 to 16 is more preferable, and 6 to 12 is particularly preferable. The R f group preferably has a linear or branched structure, and more preferably has a linear structure. In the case of a branched structure, the branched portion exists at the terminal portion of the R f group,
And it is preferable that it is a short chain having about 1 to 3 carbon atoms.
【0017】Rf 基中のフッ素原子数は、[(Rf 基中
のフッ素原子数)/(Rf 基に対応する同一炭素数のア
ルキル基中の水素原子数)]×100%で示した場合
に、60%以上が好ましく、特に80%以上が好まし
く、実質的に100%であるのが好ましい。The number of fluorine atoms in the R f group is represented by [(the number of fluorine atoms in the R f group) / (the number of hydrogen atoms in the alkyl group having the same carbon number corresponding to the R f group)] × 100%. In this case, it is preferably 60% or more, particularly preferably 80% or more, and preferably substantially 100%.
【0018】Rf 基は、通常は末端部がペルフルオロア
ルキル基であるものが好ましいが、末端部に水素原子も
しくは塩素原子を含むもの、または、該基の炭素−炭素
結合間にエーテル性の酸素原子が挿入された基であって
もよく、例えば、オキシポリフルオロアルキレン基含有
基などであってもよい。Usually, the R f group is preferably a group having a hydrogen atom or a chlorine atom at the terminal, or an etheric oxygen between the carbon-carbon bonds of the group. It may be a group having an inserted atom, for example, an oxypolyfluoroalkylene group-containing group.
【0019】Rf 基は、アルキル基の水素原子の全てが
フッ素原子に置換されたペルフルオロアルキル基が好ま
しい。ペルフルオロアルキル基の炭素原子数は4〜20
が好ましく、4〜16がさらに好ましく、6〜12が特
に好ましい。ペルフルオロアルキル基の構造は直鎖また
は分岐の構造が好ましく、特に直鎖の構造が好ましい。
直鎖の構造のペルフルオロアルキル基は、Cn F
2n+1(ただし、nは4〜16の整数を示す)で表される
基が好ましく、特にnが6〜12のものが好ましい。The R f group is preferably a perfluoroalkyl group in which all hydrogen atoms of the alkyl group have been replaced by fluorine atoms. The perfluoroalkyl group has 4 to 20 carbon atoms.
Is preferable, 4-16 are more preferable, and 6-12 are especially preferable. The structure of the perfluoroalkyl group is preferably a linear or branched structure, and particularly preferably a linear structure.
A perfluoroalkyl group having a linear structure is represented by C n F
A group represented by 2n + 1 (where n represents an integer of 4 to 16) is preferable, and a group having n of 6 to 12 is particularly preferable.
【0020】Rf 基の具体例としては、以下のものが挙
げられる。なお、以下の具体例中には、それぞれの構造
異性の基に相当する基も含まれる。 C4 F9 −[例えば、CF3 (CF2 )3 −、(CF
3 )2 CFCF2 −、(CF3 )3 C−、CF3 CF2
CF(CF3 )−等の構造異性体。]、C5 F11−[例
えば、CF3 (CF2 )4 −、(CF3 )2 CF(CF
2 )2 −、(CF3 )3 CCF2 −、CF3 (CF2 )
2 CF(CF3 )−等の構造異性体。]、C6 F13−
[CF3 (CF2 )2 C(CF3 )2 −等の構造異性
体。]、C8 F17−、C10F21−、C12F25−、C14F
29−、C16F31−、C18F37−、(CF3 )2 CFCs
F2s−(ここで、sは1〜15の整数である。)、HC
t F2t−(ここで、tは1〜18の整数である。)、テ
トラフルオロフェニル基、3−トリフルオロメチルフェ
ニル基、1,3−ビストリフルオロメチルフェニル基
等。Specific examples of the R f group include the following. In addition, in the following specific examples, groups corresponding to respective structurally isomer groups are also included. C 4 F 9 - [e.g., CF 3 (CF 2) 3 -, (CF
3 ) 2 CFCF 2- , (CF 3 ) 3 C-, CF 3 CF 2
CF (CF 3) - and the like structural isomers. ], C 5 F 11 - [e.g., CF 3 (CF 2) 4 -, (CF 3) 2 CF (CF
2) 2 -, (CF 3 ) 3 CCF 2 -, CF 3 (CF 2)
2 CF (CF 3) - and the like structural isomers. ], C 6 F 13 −
[CF 3 (CF 2) 2 C (CF 3) 2 - and the like structural isomers. ], C 8 F 17 -, C 10 F 21 -, C 12 F 25 -, C 14 F
29 -, C 16 F 31 - , C 18 F 37 -, (CF 3) 2 CFC s
F2s- (where s is an integer of 1 to 15), HC
t F 2t - (., where, t is 1 to 18 integer), tetrafluorophenyl group, 3-trifluoromethylphenyl group, 1,3-bis-trifluoromethylphenyl group and the like.
【0021】また、Rf 基がエーテル性の酸素原子を含
む基である場合の具体例としては、以下のものが挙げら
れる。ただし、uは1〜10の整数、vは1〜11の整
数、wは1〜11の整数を示す。mは1〜10の整数を
示し、1〜6の整数が好ましい。 CF3 (CF2 )4 OCF(CF3 )−、F[CF(C
F3 )CF2 O]u CF(CF3 )−、F(CF2 CF
2 CF2 O)v CF2 CF2 −、F(CF2 CF2 O)
w CF2 CF2 −、F[CF(CF3 )CF2 O]m C
F(CF3 )−。Specific examples of the case where the R f group is a group containing an etheric oxygen atom include the following. Here, u represents an integer of 1 to 10, v represents an integer of 1 to 11, and w represents an integer of 1 to 11. m represents an integer of 1 to 10, and preferably an integer of 1 to 6. CF 3 (CF 2) 4 OCF (CF 3) -, F [CF (C
F 3 ) CF 2 O] u CF (CF 3 ) —, F (CF 2 CF)
2 CF 2 O) v CF 2 CF 2- , F (CF 2 CF 2 O)
w CF 2 CF 2 -, F [CF (CF 3) CF 2 O] m C
F (CF 3) -.
【0022】本発明におけるRf 基を含有するフッ素樹
脂としては、Rf 基を含有する(メタ)アクリレートの
重合単位を含む重合体が好ましい。Rf 基を含有する
(メタ)アクリレートとしては、以下の化合物が好まし
い。なお、下式におけるRf は炭素数1〜20のペルフ
ルオロアルキル基を示し、R4 は水素原子またはメチル
基を示す。As the fluorine resin containing an R f group in the present invention, a polymer containing polymerized units of a (meth) acrylate containing an R f group is preferable. The following compounds are preferred as the (meth) acrylate containing an R f group. In the following formula, R f represents a C 1-20 perfluoroalkyl group, and R 4 represents a hydrogen atom or a methyl group.
【0023】CH2=C(R4)COOCH2CH2Rf CH2=C(R4)COOCH2CH2N(C3H7)CORf CH2=C(R4)COOCH(CH3)CH2Rf CH2=C(R4)COOCH2CH2N(CH3)SO2Rf CH2=C(R4)COOCH2CH2N(CH3)CORf CH2=C(R4)COOCH2CH2N(C2H5)SO2Rf CH2=C(R4)COOCH2CH2N(C2H5)CORf CH2=C(R4)COOCH2CH2N(C3H7)SO2Rf CH2=C(R4)COOCH(CH2Cl)CH2OCH2CH2N(CH3)SO2Rf CH 2 = C (R 4 ) COOCH 2 CH 2 R f CH 2 = C (R 4 ) COOCH 2 CH 2 N (C 3 H 7 ) COR f CH 2 = C (R 4 ) COOCH (CH 3 ) CH 2 R f CH 2 = C (R 4 ) COOCH 2 CH 2 N (CH 3 ) SO 2 R f CH 2 = C (R 4 ) COOCH 2 CH 2 N (CH 3 ) COR f CH 2 = C ( R 4 ) COOCH 2 CH 2 N (C 2 H 5 ) SO 2 R f CH 2 = C (R 4 ) COOCH 2 CH 2 N (C 2 H 5 ) COR f CH 2 = C (R 4 ) COOCH 2 CH 2 N (C 3 H 7 ) SO 2 R f CH 2 = C (R 4 ) COOCH (CH 2 Cl) CH 2 OCH 2 CH 2 N (CH 3 ) SO 2 R f
【0024】Rf 基を含有する(メタ)アクリレートの
重合単位を含む重合体中には、Rf基を含有する(メ
タ)アクリレートの重合単位が、1種または2種以上含
まれていてもよい。2種以上を含む場合には、Rf 基部
分の炭素数が異なる2種以上のRf 基を含有する(メ
タ)アクリレートを併用するのが好ましい。[0024] The polymer containing polymerized units of containing the R f group (meth) acrylate, containing the R f group (meth) acrylate polymerization units, also contain one or more Good. If it contains 2 or more is preferably used together R f number of carbon atoms contained in the group moiety contains two or more different the R f group (meth) acrylate.
【0025】Rf 基を含有する(メタ)アクリレートの
重合単位を含む重合体は、Rf 基を含有する(メタ)ア
クリレートの重合単位以外のラジカル重合性の不飽和結
合を有する単量体の重合単位を含んでいてもよい。な
お、以下において該ラジカル重合性の不飽和結合を有す
る単量体を「他の単量体」と記す。[0025] R f containing a group (meth) polymer comprising polymerized units of acrylate, of a monomer having a radical polymerizable unsaturated bond other than polymerized units of which contain the R f group (meth) acrylate It may contain a polymerized unit. In the following, the monomer having the radical polymerizable unsaturated bond is referred to as “other monomer”.
【0026】他の単量体としては、上記の脂肪族炭化水
素系溶剤への溶解性の点から、下記のものが挙げられ
る。これらのうち、他の単量体としては、シクロヘキシ
ル(メタ)アクリレートを必須とするのが好ましく、特
にシクロヘキシルメタクリレートを必須とするのが好ま
しい。Other monomers include the following from the viewpoint of solubility in the above-mentioned aliphatic hydrocarbon solvents. Among these, it is preferable that cyclohexyl (meth) acrylate is essential as the other monomer, and it is particularly preferable that cyclohexyl methacrylate is essential.
【0027】エチレン、酢酸ビニル、フッ化ビニル、ハ
ロゲン化ビニルスチレン、α−メチルスチレン、p−メ
チルスチレン、(メタ)アクリル酸とそのアルキルエス
テル、ポリ(オキシアルキレン)(メタ)アクリレー
ト、(メタ)アクリルアミド、ジアセトン(メタ)アク
リルアミド、メチロール化(メタ)アクリルアミド、N
−メチロール(メタ)アクリルアミド、ビニルアルキル
エーテル、ビニルアルキルケトン、ブタジエン、イソプ
レン、クロロプレン、グリシジル(メタ)アクリレー
ト、アジリジニル(メタ)アクリレート、ベンジル(メ
タ)アクリレート、イソシアナートエチル(メタ)アク
リレート、シクロヘキシル(メタ)アクリレート、2−
エチルヘキシル(メタ)アクリレート、無水マレイン
酸、トリアリールイソシアヌレート、ポリシロキサンを
有する(メタ)アクリレート、N−ビニルカルバゾール
等。Ethylene, vinyl acetate, vinyl fluoride, halogenated vinyl styrene, α-methyl styrene, p-methyl styrene, (meth) acrylic acid and its alkyl ester, poly (oxyalkylene) (meth) acrylate, (meth) Acrylamide, diacetone (meth) acrylamide, methylolated (meth) acrylamide, N
-Methylol (meth) acrylamide, vinyl alkyl ether, vinyl alkyl ketone, butadiene, isoprene, chloroprene, glycidyl (meth) acrylate, aziridinyl (meth) acrylate, benzyl (meth) acrylate, isocyanatoethyl (meth) acrylate, cyclohexyl (meth) ) Acrylate, 2-
Ethylhexyl (meth) acrylate, maleic anhydride, triaryl isocyanurate, (meth) acrylate having polysiloxane, N-vinylcarbazole, and the like.
【0028】本発明における重合体中のフッ素量は20
〜30重量%が好ましい。フッ素量が少なすぎると、効
果を得るための加工剤使用量が多くなり、外観への影響
やクラックの発生の恐れが高くなる。一方フッ素量が多
すぎると樹脂の溶剤への溶解性が低下し、不溶解部が発
生する恐れがある。In the present invention, the amount of fluorine in the polymer is 20.
~ 30% by weight is preferred. If the amount of fluorine is too small, the amount of the processing agent used for obtaining the effect increases, and the influence on the appearance and the risk of cracks increase. On the other hand, when the amount of fluorine is too large, the solubility of the resin in the solvent is reduced, and an insoluble portion may be generated.
【0029】重合体の分子量は、重量平均分子量で1
0, 000〜200,000が好ましく、特に30,0
00〜100,000が好ましい。分子量が小さすぎる
と塵埃に対する防汚性が充分でなく、一方大きすぎると
溶剤への溶解性が低下したり、粘度が上昇するため好ま
しくない。The molecular weight of the polymer is 1 in terms of weight average molecular weight.
000-200,000 is preferable, and especially 30,0
00 to 100,000 is preferred. If the molecular weight is too small, the antifouling property against dust is not sufficient. On the other hand, if the molecular weight is too large, the solubility in a solvent is reduced and the viscosity is undesirably increased.
【0030】Rf 基を含有する(メタ)アクリレートの
重合単位を含む重合体を得る方法としては、脂肪族炭化
水素系溶剤にRf 基を含有する(メタ)アクリレートお
よび必要に応じて他の単量体を溶解させ、加熱撹拌下に
重合させる方法が好ましい。重合は、重合開始源を作用
させて実施するのが好ましく、重合開始源としては、有
機酸過酸化物、アゾ化合物、過硫酸塩等の重合開始剤、
γ−線等の電離性放射線などが採用され得る。[0030] As a method for obtaining a polymer containing polymerized units of containing the R f group (meth) acrylate contains the R f group in an aliphatic hydrocarbon solvent (meth) acrylate and other optionally A method in which a monomer is dissolved and polymerized under heating and stirring is preferable. The polymerization is preferably carried out by allowing a polymerization initiation source to act.As the polymerization initiation source, a polymerization initiator such as an organic acid peroxide, an azo compound, or a persulfate,
Ionizing radiation such as γ-rays may be employed.
【0031】本発明のシーリング剤処理用組成物は、上
記の脂肪族炭化水素系溶剤と含フッ素重合体を含む。シ
ーリング剤処理用組成物中の含フッ素重合体量は特に限
定されないが、濃度が低すぎると効果の程度が低くなる
恐れや、多量に塗布する必要から液垂れが起こる恐れが
あり、濃度が高すぎると不経済であるため、組成物の1
00重量部に対して含フッ素重合体を0.1〜15重量
部含ませるのが好ましく、特に0.3〜8重量部含ませ
るのが好ましい。さらに脂肪族炭化水素系溶剤は、該組
成物の100重量部に対して85〜99.9重量部含ま
せるのが好ましく、特に92〜99.7重量%含ませる
のが好ましい。The composition for treating a sealant of the present invention contains the above-mentioned aliphatic hydrocarbon-based solvent and a fluoropolymer. The amount of the fluoropolymer in the composition for treating a sealing agent is not particularly limited, but if the concentration is too low, the degree of the effect may be reduced, or dripping may occur due to the necessity of applying a large amount, and the concentration may be high. If too much is uneconomical, one of the compositions
The fluoropolymer is preferably contained in an amount of 0.1 to 15 parts by weight, more preferably 0.3 to 8 parts by weight, per 100 parts by weight. Further, the aliphatic hydrocarbon solvent is preferably contained in an amount of 85 to 99.9 parts by weight, more preferably 92 to 99.7% by weight, based on 100 parts by weight of the composition.
【0032】本発明のシーリング剤処理用組成物は、上
記の脂肪族炭化水素系溶剤と含フッ素重合体のみからな
るものでもよいが、必要に応じて他の添加物を含んでい
てもよい。他の添加物としては、香料、消泡剤、防カビ
剤等が挙げられる。また、他の添加物を含む場合には、
該組成物の100重量部に対して0.01〜1重量部含
ませるのが好ましく、特に0.05〜0.5重量%含ま
せるのが好ましい。The composition for treating a sealant of the present invention may be composed of only the above-mentioned aliphatic hydrocarbon-based solvent and fluoropolymer, but may further contain other additives as necessary. Other additives include fragrances, defoamers, fungicides and the like. When other additives are included,
It is preferably contained in an amount of 0.01 to 1 part by weight, particularly preferably 0.05 to 0.5% by weight, based on 100 parts by weight of the composition.
【0033】本発明のシーリング剤処理用組成物は、シ
ーリング材表面に適用し、該シーリング材表面に被膜を
形成させることにより、汚れの付着を防止できる。シー
リング材としては変成シリコーン系、変成ポリスルフィ
ド系またはポリウレタン系の樹脂からなるシーリング材
が好ましく、特に変成シリコーン系の樹脂が好ましい。The composition for treating a sealing agent of the present invention can be applied to the surface of a sealing material to form a film on the surface of the sealing material, thereby preventing adhesion of dirt. As the sealing material, a sealing material made of a modified silicone-based, modified polysulfide-based or polyurethane-based resin is preferable, and a modified silicone-based resin is particularly preferable.
【0034】該シーリング材としては、POSシール、
POSシールタイプII、POSシールLM等(以上、セ
メダイン社製商品名)、ペンギンシール2500DR
Y、ペンギンシール2570等(以上、サンスター技研
社製商品名)の変成シリコーン系の樹脂からなるシーリ
ング材、S−750(以上、セメダイン社製商品名)、
ペンギンシール980、ペンギンシール999(以上、
サンスター技研社製商品名)、ハマタイトUH−30、
ハマタイトシールエース(以上、横浜ゴム社製商品名)
等のポリウレタン系の樹脂からなるシーリング材が挙げ
られる。As the sealing material, a POS seal,
POS seal type II, POS seal LM, etc. (these are brand names manufactured by Cemedine), penguin seal 2500DR
Y, a sealing material made of denatured silicone resin such as penguin seal 2570 (above, trade name of Sunstar Giken), S-750 (above, trade name of Cemedine Co.),
Penguin seal 980, penguin seal 999 (or more,
Sunstar Giken Co., Ltd.), Hamatite UH-30,
Hamatite Seal Ace (trade name of Yokohama Rubber Co., Ltd.)
And a sealing material made of a polyurethane-based resin.
【0035】シーリング材表面に適用する方法として
は、特に限定されず、シーリング材をパテ等で付けた
後、防汚加工剤を刷毛、ロール、スプレー等によって該
シーリング材表面に塗布する方法が挙げられる。また、
塗布の時期については特に限定されず、シーリング材の
硬化後または、硬化前のいずれであってもよい。また、
目地部周辺にあらかじめマスキングテープを貼って、シ
ーリング剤処理用組成物の壁材への付着を防止してもよ
い。The method for applying to the surface of the sealing material is not particularly limited, and includes a method of applying a sealing material with a putty or the like, and then applying an antifouling agent to the surface of the sealing material by a brush, a roll, a spray, or the like. Can be Also,
The timing of the application is not particularly limited, and may be after or after the sealing material is cured. Also,
A masking tape may be applied in advance around the joint to prevent the sealing composition from adhering to the wall material.
【0036】本発明においては、組成物を塗布後に乾燥
させて、シーリング材表面に含フッ素重合体の皮膜を形
成させる。乾燥は、自然乾燥でも加熱乾燥でもよい。特
に塵埃が多い工場等で使用する場合には、加熱すること
で乾燥時間を縮め、溶剤蒸発前に塵埃が付着するのを防
ぐことが好ましい。In the present invention, the composition is applied and then dried to form a fluoropolymer film on the surface of the sealing material. Drying may be natural drying or heat drying. In particular, when used in a factory with a lot of dust, it is preferable to shorten the drying time by heating and to prevent dust from adhering before the solvent is evaporated.
【0037】含フッ素重合体の皮膜は、シーリング材の
表面に0.1〜5μmの膜厚で形成されるのが好まし
い。薄すぎると充分な効果が得られず、厚すぎるとひび
割れの原因となり、また不経済でもある。The fluoropolymer film is preferably formed on the surface of the sealing material to a thickness of 0.1 to 5 μm. If it is too thin, sufficient effects cannot be obtained, and if it is too thick, it causes cracks and is uneconomical.
【0038】本発明の組成物で処理されるシーリング材
の適用箇所は、特に限定されない。例えば、各種建築部
材間の接合部や隙間に存在するシーリング材、輸送機器
に使用されるシーリング材、電気機器に使用されるシー
リング材、家具や台所用品に使用されるシーリング材等
が挙げられる。これらのうち、本発明の組成物は、各種
建築部材間の接合部や隙間に存在するシーリング材に適
用するのが好ましい。The application site of the sealing material treated with the composition of the present invention is not particularly limited. For example, there are a sealing material present at a joint or a gap between various building members, a sealing material used for transportation equipment, a sealing material used for electric equipment, a sealing material used for furniture and kitchenware, and the like. Among them, the composition of the present invention is preferably applied to a sealing material present at a joint or a gap between various building members.
【0039】[0039]
【実施例】 [例1]シーリング材処理用組成物の調製例 撹拌機のついた1リットルのオートクレーブにミネラル
スピリット(日本石油社製商品名)200重量部、ペル
フルオロアルキルエチルアクリレート(該化合物のペル
フルオロアルキル基は炭素数6、8、10、12、14
の混合物であり、平均は9である。以下、FAと記
す。)45重量部、シクロヘキシルメタクリレート51
重量部、トリアリルイソシアヌレート4重量部、アゾビ
スイソブチロニトリル1重量部を加えた。内部の空気を
窒素ガスにより置換して300rpmで撹拌しつつ、6
0℃に昇温して20時間保持し、淡黄色の液を得た。ガ
スクロマトグラフによるモノマーの転化率は99%以上
であった。生成した淡黄色の液をニューソル(日本石油
社製商品名)によって固形分濃度が2重量%になるよう
希釈し、組成物1とした。EXAMPLES Example 1 Preparation Example of Composition for Treating Sealant In a 1 liter autoclave equipped with a stirrer, 200 parts by weight of mineral spirit (trade name, manufactured by Nippon Oil Co., Ltd.), perfluoroalkylethyl acrylate (perfluoro The alkyl group has 6, 8, 10, 12, 14 carbon atoms.
And the average is 9. Hereinafter, it is described as FA. ) 45 parts by weight, cyclohexyl methacrylate 51
Parts by weight, 4 parts by weight of triallyl isocyanurate and 1 part by weight of azobisisobutyronitrile were added. While replacing the air inside with nitrogen gas and stirring at 300 rpm, 6
The temperature was raised to 0 ° C. and maintained for 20 hours to obtain a pale yellow liquid. The conversion of the monomer by gas chromatography was 99% or more. The resulting pale yellow liquid was diluted with Newsol (trade name, manufactured by Nippon Oil Co., Ltd.) so that the solid content concentration became 2% by weight, to obtain Composition 1.
【0040】[例2]シーリング材処理用組成物の調製
例 撹拌機のついた1リットルオートクレーブにニューソル
(日本石油社製商品名)200重量部、FA45重量
部、シクロヘキシルメタクリレート51重量部、トリア
リルイソシアヌレート4重量部、アゾビスイソブチロニ
トリル1重量部を加えた。内部の空気を窒素ガスにより
置換し300rpmで撹拌しつつ、60℃に昇温し、2
0時間保持した。反応粗液をガスクロマトグラフにより
分析した結果、モノマ−の転化率は99%以上であっ
た。反応粗液をミネラルスピリット(日本石油社製商品
名)により固形分濃度が3重量%となるように希釈し、
組成物2とした。Example 2 Preparation Example of Sealing Material Treatment Composition In a 1-liter autoclave equipped with a stirrer, 200 parts by weight of Neusol (trade name, manufactured by Nippon Oil Co., Ltd.), 45 parts by weight of FA, 51 parts by weight of cyclohexyl methacrylate, triallyl 4 parts by weight of isocyanurate and 1 part by weight of azobisisobutyronitrile were added. The internal air was replaced with nitrogen gas, and the temperature was raised to 60 ° C. while stirring at 300 rpm.
Hold for 0 hours. As a result of analyzing the reaction crude liquid by gas chromatography, the conversion of the monomer was 99% or more. The reaction crude liquid was diluted with mineral spirit (trade name of Nippon Oil Co., Ltd.) so that the solid concentration became 3% by weight,
Composition 2 was obtained.
【0041】[例3]シーリング材処理用組成物の調製
例 例1における組成物1をさらに希釈し、固形分濃度が
0.5重量%としたものを組成物3とした。Example 3 Preparation Example of Composition for Processing Sealant The composition 1 in Example 1 was further diluted to have a solids concentration of 0.5% by weight.
【0042】[例4]シーリング材処理用組成物の調製
例 例1における組成物1と固形分濃度5重量%である点の
みが異なる組成物を調製し、組成物4とした。Example 4 Preparation Example of Composition for Processing Sealant A composition 4 was prepared which was different from composition 1 in Example 1 only in that the solid content concentration was 5% by weight.
【0043】[例5]シーリング材処理用組成物の比較
調製例 例1における淡黄色の液から溶媒を留去し、これに、酢
酸エチルを加えて固形分濃度が2重量%である組成物を
調製し、組成物5とした。[Example 5] Comparative preparation example of a composition for treating a sealing material The solvent was distilled off from the pale yellow liquid in Example 1, and ethyl acetate was added to the composition to give a solid concentration of 2% by weight. Was prepared to obtain composition 5.
【0044】[例6]シーリング材処理用組成物の比較
調製例 撹拌機のついた1リットルオートクレーブにメチルイソ
ブチルケトン200重量部、FA10重量部、メチルメ
タクリレート51重量部、シクロヘキシルメタクリレー
ト35重量部、トリアリルイソシアヌレート4重量部、
アゾビスイソブチロニトリル1重量部を加えた。内部の
空気を窒素ガスにより置換し300rpmで撹拌しつ
つ、60℃に昇温し、20時間保持した。反応粗液をガ
スクロマトグラフにより分析した結果、モノマーの転化
率は99%以上であった。反応粗液をメチルイソブチル
ケトンにより固形分濃度が3重量%となるように希釈
し、組成物6とした。Example 6 Comparative Preparation Example of Composition for Treating Sealant In a 1-liter autoclave equipped with a stirrer, 200 parts by weight of methyl isobutyl ketone, 10 parts by weight of FA, 51 parts by weight of methyl methacrylate, 35 parts by weight of cyclohexyl methacrylate, 4 parts by weight of allyl isocyanurate,
1 part by weight of azobisisobutyronitrile was added. The internal air was replaced with nitrogen gas, and the temperature was raised to 60 ° C. while being stirred at 300 rpm, and maintained for 20 hours. As a result of analyzing the reaction crude liquid by gas chromatography, the conversion of the monomer was 99% or more. The reaction crude liquid was diluted with methyl isobutyl ketone so that the solid content concentration became 3% by weight, to obtain composition 6.
【0045】[評価例1〜5]上記で調製した組成物1
〜4を、それぞれ、以下の評価方法で評価した。結果を
表1に示す。[Evaluation Examples 1 to 5] Composition 1 prepared above
To 4 were evaluated by the following evaluation methods. Table 1 shows the results.
【0046】[比較評価例6〜9]上記で調製した組成
物5、6を、同様に、以下の評価方法で評価した。ま
た、組成物を処理しないもの(評価例6、7)を同様の
以下の評価方法で評価した。結果を表1に示す。[Comparative Evaluation Examples 6 to 9] The compositions 5 and 6 prepared above were similarly evaluated by the following evaluation methods. In addition, those which did not treat the composition (Evaluation Examples 6 and 7) were evaluated by the same evaluation method described below. Table 1 shows the results.
【0047】[表面状態の評価方法]厚さ6mmのスレ
ートで10mm幅の目地をつくり、目地に添ってマスキ
ングテープを貼った。目地の間に1成分系シリコーン系
シーリング材(セメダイン社製商品名:POSシー
ル)、または、ポリウレタン樹脂系シーリング材(横浜
ゴム社製商品名:ハマタイトUH−30)を充填し、シ
ーリング材表面をへらで押えて平面にした。その直後
に、シーリング材処理用組成物を噴霧器で噴霧し、組成
物から形成される被膜が0.1〜5μmの範囲の膜厚と
なるようにスプレー塗布した。すぐにマスキングテープ
を剥したものを試験目地とし、南面45度の角度の屋外
暴露台に採りつけて放置した。[Evaluation Method of Surface Condition] A joint having a width of 10 mm was formed with a slate having a thickness of 6 mm, and a masking tape was applied along the joint. A one-component silicone-based sealing material (trade name: POS seal manufactured by Cemedine) or a polyurethane resin-based sealing material (trade name: Hamatite UH-30 manufactured by Yokohama Rubber Co.) is filled between the joints, and the surface of the sealing material is filled. It was flattened with a spatula. Immediately thereafter, the composition for treating a sealing material was sprayed with a sprayer, and spray-coated so that a film formed from the composition had a thickness in the range of 0.1 to 5 μm. Immediately, the masking tape was peeled off, and this was used as a test joint.
【0048】7日後、30日後、180日後の試験目地
の表面の汚れの状態を目視で観察し、下記A〜Dの基準
で評価した。また、180日後の試験目地について、ひ
び割れの有無を観察した。 A:汚れの付着が認められない、 B:若干の汚れの付着が認められる、 C:表面が少し黒を帯びている、 D:表面が真っ黒である、 +:ひび割れあり、 ±:ひび割れ若干あり、 −:ひび割れなし。After 7 days, 30 days and 180 days, the surface of the test joints was visually inspected for stains and evaluated according to the following criteria A to D. Further, the test joints 180 days later were examined for the presence or absence of cracks. A: No adhesion of dirt is observed. B: Some adhesion of dirt is observed. C: The surface is slightly blackened. D: The surface is completely black. +: Cracked. ±: Slightly cracked. ,-: No crack.
【0049】[有機塗膜への影響の評価方法]縦横各3
00mm、厚さ6mmポリメチルメタクリレート樹脂板
に、アクリル塗料(赤)を20〜30μmの範囲の膜厚
となるように塗布し、100℃で5分間乾燥し、室温で
放冷した塗装板を準備した。塗装板に組成物を噴霧器で
噴霧し、組成物から形成される被膜が2cmの幅で2μ
mの膜厚となるようにスプレー塗布した。室温で30分
放置し、塗装板表面の外観を目視で評価した。 〇:外観の変化が認められない、 ×:塗膜の変色、むら等が認められる。[Evaluation method for influence on organic coating film]
Acrylic paint (red) is applied to a 00 mm, 6 mm thick polymethyl methacrylate resin plate so as to have a thickness in the range of 20 to 30 μm, dried at 100 ° C. for 5 minutes, and cooled to room temperature to prepare a coated plate. did. The composition is sprayed on the coated plate with a sprayer, and a film formed from the composition is 2 μm in width of 2 cm.
m was spray-coated. It was left at room temperature for 30 minutes, and the appearance of the coated plate surface was visually evaluated. 〇: No change in appearance is observed. ×: Discoloration, unevenness, etc. of the coating film are observed.
【0050】[タック性の評価方法]防汚性の評価で用
いた試験目地と同じものを準備し、1時間室温乾燥後の
目地表面のべたつき感(タック性)の有無を、手でさわ
って評価した。[Evaluation Method of Tack Property] The same test joint as used in the evaluation of antifouling property was prepared, and the joint surface after drying for 1 hour at room temperature was touched by hand to determine whether or not there was a sticky feeling (tack property). evaluated.
【0051】[0051]
【表1】 [Table 1]
【0052】[0052]
【発明の効果】本発明のシーリング材処理用組成物は、
シーリング材表面に耐久性に優れた防汚性を付与でき
る。また、シーリング材を近傍に有機塗装による塗膜が
存在したとしても、該塗膜に悪影響を及ぼす心配なく使
用できる。また、本発明のシーリング材処理用組成物に
より形成される被膜は、ひび割れを防止でき、外観の変
化が少ない利点もある。The composition for treating a sealing material of the present invention comprises:
A highly durable antifouling property can be imparted to the surface of the sealing material. Further, even if a coating film made of an organic coating is present in the vicinity of the sealing material, the sealing material can be used without fear of adversely affecting the coating film. Further, the coating formed by the composition for treating a sealing material of the present invention has the advantages that cracks can be prevented and the appearance does not change much.
フロントページの続き (72)発明者 池本 陽子 東京都中央区八丁堀2丁目23番1号 旭硝 子コートアンドレジン株式会社内Continued on the front page (72) Inventor Yoko Ikemoto 2-23-1, Hatchobori, Chuo-ku, Tokyo Asahi Glass Coat and Resin Co., Ltd.
Claims (9)
であって、脂肪族炭化水素系溶剤および該溶剤に可溶性
の含フッ素重合体を含有することを特徴とするシーリン
グ材処理用組成物。1. A composition for treating a surface of a sealing material, which comprises an aliphatic hydrocarbon solvent and a fluoropolymer soluble in the solvent.
80重量%以上含有する請求項1記載のシーリング材処
理用組成物。2. The composition for treating a sealing material according to claim 1, wherein the aliphatic hydrocarbon solvent contains at least 80% by weight of the aliphatic hydrocarbon.
0℃である請求項1または2記載のシーリング材処理用
組成物。3. The aliphatic hydrocarbon-based solvent has a boiling point of 80 to 30.
The composition for treating a sealing material according to claim 1, wherein the composition has a temperature of 0 ° C. 4.
基を含むアクリレートの重合単位またはポリフルオロア
ルキル基を含有するメタクリレートの重合単位を含む重
合体である請求項1、2または3記載のシーリング材処
理用組成物。4. The sealing material according to claim 1, wherein the fluorine-containing polymer is a polymer containing polymerized units of an acrylate containing a polyfluoroalkyl group or polymerized units of a methacrylate containing a polyfluoroalkyl group. Processing composition.
基を含むメタクリレートの重合単位を含む重合体である
請求項1、2または3記載のシーリング材処理用組成
物。5. The composition for treating a sealing material according to claim 1, wherein the fluorinated polymer is a polymer containing methacrylate polymer units containing a perfluoroalkyl group.
レートの重合単位またはシクロヘキシルメタクリレート
の重合単位を含む共重合体である請求項4または5記載
のシーリング材用防汚加工用組成物。6. The antifouling composition for a sealing material according to claim 4, wherein the fluoropolymer is a copolymer containing polymerized units of cyclohexyl acrylate or polymerized units of cyclohexyl methacrylate.
35重量%である請求項1、2、3、4、5または6記
載のシーリング材処理用組成物。7. A fluorine-containing polymer having a fluorine content of 20 to 20.
The composition for treating a sealing material according to claim 1, 2, 3, 4, 5, or 6, which is 35% by weight.
載のシーリング材処理用組成物により、シーリング剤表
面を処理することを特徴とする処理方法。8. A treatment method comprising treating a surface of a sealing agent with the composition for treating a sealing material according to claim 1, 2, 3, 4, 5, 6, or 7.
載のシーリング材処理用組成物により処理されたシーリ
ング材が用いられた建築部材。9. A building member using a sealing material treated with the sealing material-treating composition according to claim 1, 2, 3, 4, 5, 6, or 7.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP08882797A JP3830226B2 (en) | 1997-03-24 | 1997-03-24 | Sealant treatment composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP08882797A JP3830226B2 (en) | 1997-03-24 | 1997-03-24 | Sealant treatment composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH10265716A true JPH10265716A (en) | 1998-10-06 |
JP3830226B2 JP3830226B2 (en) | 2006-10-04 |
Family
ID=13953778
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP08882797A Expired - Fee Related JP3830226B2 (en) | 1997-03-24 | 1997-03-24 | Sealant treatment composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3830226B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017128725A (en) * | 2016-01-18 | 2017-07-27 | ダイキン工業株式会社 | Sealant composition |
-
1997
- 1997-03-24 JP JP08882797A patent/JP3830226B2/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017128725A (en) * | 2016-01-18 | 2017-07-27 | ダイキン工業株式会社 | Sealant composition |
JP2021102780A (en) * | 2016-01-18 | 2021-07-15 | ダイキン工業株式会社 | Sealant composition |
Also Published As
Publication number | Publication date |
---|---|
JP3830226B2 (en) | 2006-10-04 |
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