JPH10195305A - Plastic molding and its production - Google Patents
Plastic molding and its productionInfo
- Publication number
- JPH10195305A JPH10195305A JP9013171A JP1317197A JPH10195305A JP H10195305 A JPH10195305 A JP H10195305A JP 9013171 A JP9013171 A JP 9013171A JP 1317197 A JP1317197 A JP 1317197A JP H10195305 A JPH10195305 A JP H10195305A
- Authority
- JP
- Japan
- Prior art keywords
- molded product
- molding
- plastic
- plastic molded
- paper powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 24
- 238000010137 moulding (plastic) Methods 0.000 title abstract 2
- 229920003023 plastic Polymers 0.000 claims abstract description 115
- 239000004033 plastic Substances 0.000 claims abstract description 115
- 239000000843 powder Substances 0.000 claims abstract description 48
- 238000000465 moulding Methods 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims abstract description 31
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 15
- 238000001746 injection moulding Methods 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 14
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 16
- 238000005034 decoration Methods 0.000 claims description 11
- 238000010422 painting Methods 0.000 claims description 8
- 238000012546 transfer Methods 0.000 claims description 4
- 239000005001 laminate film Substances 0.000 claims description 3
- 239000008188 pellet Substances 0.000 abstract description 14
- 238000007639 printing Methods 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 4
- 230000008859 change Effects 0.000 abstract description 3
- 238000005453 pelletization Methods 0.000 abstract description 2
- 238000010023 transfer printing Methods 0.000 abstract description 2
- 239000004566 building material Substances 0.000 abstract 1
- 238000010017 direct printing Methods 0.000 abstract 1
- 239000011369 resultant mixture Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 31
- 239000011347 resin Substances 0.000 description 31
- 238000004898 kneading Methods 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 14
- 239000004698 Polyethylene Substances 0.000 description 11
- 239000004743 Polypropylene Substances 0.000 description 10
- 238000005452 bending Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 238000013461 design Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 239000000428 dust Substances 0.000 description 5
- -1 polypropylene Polymers 0.000 description 5
- 235000013339 cereals Nutrition 0.000 description 4
- 239000002991 molded plastic Substances 0.000 description 4
- 238000010298 pulverizing process Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000002987 primer (paints) Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
- Moulding By Coating Moulds (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、プラスチック成形
物及びその製造方法に関し、更に詳しくは、家電製品、
家具、車両部材、建築用部材などの分野に広く利用でき
るよう、その加工適性、寸法安定性、接着性を改善した
プラスチック成形物と、その製造方法に関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a plastic molded product and a method for producing the same, and more particularly, to a home appliance,
The present invention relates to a plastic molded product having improved processability, dimensional stability, and adhesiveness so as to be widely used in fields such as furniture, vehicle members, and architectural members, and a method for producing the same.
【0002】[0002]
【従来の技術】従来、建築用部材、家電製品、車両部材
などにプラスチック成形物を用いた場合、耐水性があ
り、カビが発生し難いなどの長所がある反面、例えば、
施工現場などで鋸引きが困難であるとか、釘打ちができ
ないなど、その加工適性に問題があり、また、材質によ
っては、温度変化による線膨張係数が大きく、寸法安定
性に欠け、特に、扉などの建具に用いた場合、気温の変
化により開閉が困難になるとか、隙間を生じ易いなどの
問題があった。また、加工適性や寸法安定性に関して
は、家電製品や車両部材などに用いた場合も、同様に、
反りなどの変形や、隙間、或いは、表面に加飾を施す際
の接着性などの問題を生じ、その利用範囲に制約があっ
た。2. Description of the Related Art Conventionally, when plastic molded articles are used for architectural members, home electric appliances, vehicle members, and the like, they have the advantages of being water-resistant and hardly generating mold.
There are problems with workability such as difficulty in sawing or nailing at construction sites, etc.Depending on the material, the coefficient of linear expansion due to temperature changes is large, and dimensional stability is lacking. When it is used for fittings such as, for example, there are problems that opening and closing becomes difficult due to a change in temperature and that a gap is easily formed. In addition, regarding processing suitability and dimensional stability, similarly, when used for home appliances and vehicle components,
Problems such as deformation such as warpage, gaps, and adhesiveness when decorating the surface occur, and the range of use is limited.
【0003】また、プラスチックは、材質面で種類が多
く、多種類のものがそれぞれの特徴を生かして使用され
ているが、近年、廃棄物処理の問題からリサイクルが求
められ、この点から軽量且つ安価でリサイクルし易いポ
リオレフィン系樹脂が注目されている。しかし、ポリオ
レフィン系樹脂は、前記加工適性のほか、寸法安定性も
悪く、また、成形物表面に加飾を施す際の接着性にも問
題があり、実際には、市場に充分には受け入れられてい
ない。There are many types of plastics in terms of material, and various types are used taking advantage of their respective characteristics. However, in recent years, recycling has been demanded due to the problem of waste disposal. Inexpensive and easily recyclable polyolefin-based resins have attracted attention. However, polyolefin-based resins have poor dimensional stability, in addition to the above-mentioned processability, and also have a problem in adhesiveness when decorating the surface of a molded product, and in fact, they are well accepted in the market. Not.
【0004】このような問題を解決するために、一部に
は、木粉をブレンドしたプラスチックを利用することも
試みられた。しかし、木粉をプラスチックにブレンドし
た場合、前記鋸引きや釘打ちなどの加工適性は改善され
るが、成形物の表面が黒味を帯び、濁った色となるた
め、成形物の外観が損なわれ、表面に加飾を施した場合
にも、その影響を受け、意匠性が低下するという問題が
あった。[0004] In order to solve such a problem, some attempts have been made to utilize plastics blended with wood flour. However, when wood powder is blended with plastic, the suitability for processing such as sawing and nailing is improved, but the surface of the molded product becomes blackish and becomes cloudy, which impairs the appearance of the molded product. However, even when the surface is decorated, there is a problem that the design is deteriorated due to the influence.
【0005】[0005]
【発明が解決しようとする課題】本発明は、以上のよう
な背景に鑑みてなされたものであり、プラスチックの共
通の欠点である鋸引きや釘打ちなどの加工適性を改善
し、また、ポリオレフィン系樹脂など、その線熱膨張係
数が1×10-4/℃以上のように大きい場合には、これ
を小さくして温度による寸法安定性を向上させると共
に、成形物の表面の接着性を向上させて、加飾のための
インキ、塗料、或いは加飾用シートなどを表面に積層し
た時、充分な強度で接着し、更に、廃棄の際にも、容易
に粉砕、焼却、或いはリサイクルできるという、性能、
加工適性、廃棄性に優れ、家電製品を始め、家具、車両
部材、建築用部材など、広い分野に利用できるプラスチ
ック成形物及びその製造方法を提供することを目的とす
る。SUMMARY OF THE INVENTION The present invention has been made in view of the above background, and has been made to improve the common drawbacks of plastics, such as sawing and nailing, and to provide a polyolefin. When the coefficient of linear thermal expansion of a base resin or the like is as large as 1 × 10 −4 / ° C. or more, it is reduced to improve the dimensional stability with temperature and to improve the adhesiveness of the surface of the molded product. Then, when ink, paint, or decorative sheet for decoration is laminated on the surface, it adheres with sufficient strength, and it can be easily crushed, incinerated or recycled even at the time of disposal. , Performance,
It is an object of the present invention to provide a plastic molded article which is excellent in processability and disposability and can be used in a wide range of fields, such as home appliances, furniture, vehicle members, architectural members, and a method for producing the same.
【0006】[0006]
【課題を解決するための手段】上記の課題を解決するた
め鋭意研究した結果、以下の本発明により目的を達成し
たものである。即ち、請求項1に記載した発明は、線熱
膨張係数が1×10-4/℃以上のプラスチックに紙粉が
混練された組成物で形成されていることを特徴とするプ
ラスチック成形物からなる。尚、本発明において、線熱
膨張係数は、JIS K6911適用箇条5.25に準
拠して測定した値である。As a result of intensive studies to solve the above-mentioned problems, the following objects have been achieved by the present invention. That is, the invention described in claim 1 comprises a plastic molded product characterized by being formed of a composition obtained by kneading paper powder with a plastic having a linear thermal expansion coefficient of 1 × 10 −4 / ° C. or more. . In the present invention, the coefficient of linear thermal expansion is a value measured in accordance with JIS K6911, applicable clause 5.25.
【0007】このような構成を採ることにより、線熱膨
張係数が1×10-4/℃以上のように大きいプラスチッ
クでも、その値を小さくすることができるので、温度変
化によるプラスチック成形物の寸法安定性が向上し、適
用できる用途範囲を広げることができる。また、プラス
チックに紙粉を含有させることにより、成形物を鋸引き
した際、摩擦熱により樹脂が鋸刃に粘着することがなく
なり、スムーズに切れるようになる。また、成形物に釘
を打っても成形物の歪みが吸収されるため割れることが
なくなり、成形物の加工適性が向上する。更に、プラス
チック成形物の表面がポーラスになり粗面化されると同
時に、表面に紙粉の一部が露出するので印刷インキや塗
料、或いは加飾用シートとの接着性が向上する。更に、
紙粉が含有されることによりコストが低減し、焼却など
による廃棄性も向上する。By adopting such a configuration, even a plastic having a large linear thermal expansion coefficient of 1 × 10 −4 / ° C. or more can be reduced in value, so that the size of the plastic molded product due to a temperature change can be reduced. The stability is improved, and the applicable range of applications can be expanded. In addition, by incorporating paper powder into the plastic, when the molded product is sawed, the resin does not stick to the saw blade due to frictional heat, and can be cut smoothly. Further, even when the molded article is nailed, the molded article is not broken because the distortion of the molded article is absorbed, and the workability of the molded article is improved. Further, the surface of the plastic molded product becomes porous and roughened, and at the same time, a part of the paper powder is exposed on the surface, so that the adhesiveness with a printing ink, a paint, or a decorative sheet is improved. Furthermore,
The cost is reduced by containing paper powder, and the disposability by incineration is also improved.
【0008】請求項2に記載した発明は、前記紙粉が、
長径6mm以下の大きさで、且つ、含有されるパルプの
繊維長が1mm以下であることを特徴とする請求項1に
記載のプラスチック成形物からなる。このような紙粉を
用いることにより、プラスチックとの混練が容易にな
り、均一な分散が可能になるため、前記プラスチックの
改善効果が確実に得られるようになる。[0008] In the invention described in claim 2, the paper dust is:
The plastic molded article according to claim 1, wherein the length of the major axis is 6 mm or less, and the fiber length of the pulp contained is 1 mm or less. By using such paper powder, kneading with plastic becomes easy and uniform dispersion becomes possible, so that the effect of improving the plastic can be reliably obtained.
【0009】そして、請求項3に記載した発明は、前記
組成物が、プラスチック100重量部に対して、紙粉5
〜40重量部の配合割合で形成されていることを特徴と
する請求項1または2に記載のプラスチック成形物であ
る。プラスチック成形物を、このような配合割合の組成
物で形成することにより、曲げ強度、その他の機械的強
度を実用可能なレベルに維持しながら、前記寸法安定
性、加工適性、接着適性の向上、および、コスト低減、
廃棄性の向上を達成できる。According to a third aspect of the present invention, the composition is characterized in that the paper powder 5
The plastic molded product according to claim 1, wherein the plastic molded product is formed in a mixing ratio of 40 parts by weight. By forming a plastic molded article with a composition having such a compounding ratio, while maintaining bending strength and other mechanical strength at a practical level, the dimensional stability, workability, and adhesion suitability are improved. And cost reduction,
Improved disposability can be achieved.
【0010】請求項4に記載した発明は、前記プラスチ
ックが、ポリオレフィン系樹脂であることを特徴とする
請求項1乃至3のいずれかに記載のプラスチック成形物
である。このような構成を採ることにより、ポリオレフ
ィン系樹脂の欠点である前記温度による寸法安定性、加
工適性、接着適性が改善され、更に、その長所である軽
量性、成形の容易性、耐薬品性、耐溶剤性、そして、廃
棄性(粉砕による減容化が容易で、また、焼却しても有
害ガスを発生せず、燃えかすなども残らない)、リサイ
クル性、経済性(安価)が生かされるため、幅広い用途
に使用できるようになる。According to a fourth aspect of the present invention, there is provided the plastic molded product according to any one of the first to third aspects, wherein the plastic is a polyolefin resin. By adopting such a configuration, the dimensional stability due to the temperature, which is a drawback of the polyolefin resin, the suitability for processing, the suitability for adhesion are improved, and further, its advantages such as light weight, ease of molding, chemical resistance, Solvent resistance and disposability (easy volume reduction by pulverization, no harmful gas generated even when incinerated, no burning remains), recyclability, economy (low cost) Therefore, it can be used for a wide range of applications.
【0011】請求項5に記載した発明は、前記プラスチ
ック成形物の表面に加飾が施されていることを特徴とす
る請求項1乃至4のいずれかに記載のプラスチック成形
物である。このように、プラスチック成形物の表面に加
飾を施すことにより、前記請求項1乃至4の発明に記載
したそれぞれの作用効果に加えて、外観、意匠性が向上
するため、多方面の用途に好ましく使用できるようにな
る。The invention described in claim 5 is the plastic molded product according to any one of claims 1 to 4, wherein the surface of the plastic molded product is decorated. As described above, by decorating the surface of the plastic molded product, in addition to the respective functions and effects described in the first to fourth aspects of the present invention, the appearance and the design are improved. It can be used preferably.
【0012】請求項6に記載した発明は、前記加飾が、
射出成形同時絵付け法により加飾されていることを特徴
とする請求項5に記載のプラスチック成形物である。こ
のような構成を採ることにより、成形と同時に表面の加
飾が行われるため、生産工程が簡略化され生産性が向上
すると同時に、加飾のために必要な熱と圧が、成形条件
により自動的に充分に加えられるので、プラスチック成
形物の表面に施された加飾の接着性が向上する。In the invention described in claim 6, the decoration is:
The plastic molded product according to claim 5, wherein the plastic molded product is decorated by a simultaneous painting method of injection molding. By adopting such a configuration, surface decoration is performed at the same time as molding, so that the production process is simplified and productivity is improved, and at the same time, heat and pressure required for decoration are automatically adjusted according to molding conditions. Is sufficiently added, the adhesiveness of the decoration applied to the surface of the plastic molded product is improved.
【0013】そして、請求項7に記載した発明は、線熱
膨張係数が1×10-4/℃以上のプラスチック100重
量部に対して、長径が6mm以下の大きさで、且つ、含
有されるパルプの繊維長が1mm以下の紙粉を5〜40
重量部の配合割合で混練した組成物を作製し、該組成物
を成形することを特徴とするプラスチック成形物の製造
方法からなる。このような製造方法を採ることにより、
プラスチックに必要量の紙粉が均一に分散された組成物
を容易に作製することができ、更に、その組成物を公知
の成形方法で成形することにより、鋸引きや釘打ちなど
の加工性、温度に対する寸法安定性、表面の接着性など
に優れると共に、粉砕や焼却などによる廃棄性にも優れ
たプラスチック成形物を安価に生産性よく製造すること
ができる。[0013] The invention described in claim 7 has a long diameter of 6 mm or less and is contained in 100 parts by weight of plastic having a linear thermal expansion coefficient of 1 × 10 -4 / ° C. or more. Pulp fiber length of 1mm or less 5 ~ 40
It comprises a method for producing a plastic molded product, which comprises preparing a composition kneaded in a mixing ratio of parts by weight, and molding the composition. By adopting such a manufacturing method,
A composition in which a required amount of paper powder is uniformly dispersed in plastic can be easily produced, and further, by molding the composition by a known molding method, processability such as sawing and nailing, A plastic molded product having excellent dimensional stability against temperature, surface adhesiveness, and the like, and excellent in disposability by pulverization or incineration can be produced at low cost and high productivity.
【0014】請求項8に記載した発明は、前記プラスチ
ックにポリオレフィン系樹脂を用いることを特徴とする
請求項7記載のプラスチック成形物の製造方法からな
る。このような製造方法を採ることにより、従来、ポリ
オレフィン系樹脂成形物の欠点であった温度に対する寸
法安定性、鋸引きや釘打ちなどの加工性、表面の接着性
を改善でき、更に、長所である軽量性、成形の容易性、
耐薬品性、耐溶剤性などの優れた耐性、そして、廃棄性
(粉砕による減容化が容易で、また、焼却しても有害ガ
スを発生せず、燃えかすなども残らない)、リサイクル
性、経済性(安価)が生かされ、幅広い用途に使用でき
るプラスチック成形物を製造することができる。An eighth aspect of the present invention is a method for producing a plastic molded product according to the seventh aspect, wherein a polyolefin resin is used as the plastic. By adopting such a manufacturing method, it has been possible to improve dimensional stability against temperature, workability such as sawing and nailing, and surface adhesiveness, which were disadvantages of the conventional polyolefin resin molded product. Some lightness, ease of molding,
Excellent resistance, such as chemical resistance and solvent resistance, and recyclability (easy volume reduction by pulverization, no harmful gas generated by incineration, no burning) It is possible to produce a plastic molded product that can be used for a wide range of applications by making use of economy (low cost).
【0015】また、請求項9に記載した発明は、前記成
形に、絵柄層を設けた転写フィルムまたはラミネートフ
ィルムを金型内に配置して行う射出成形同時絵付け法を
用いて、成形と同時に加飾を施すことを特徴とする請求
項7または8に記載のプラスチック成形物の製造方法か
らなる。このような製造方法を採ることにより、前記請
求項7または8に記載した発明の作用効果に加えて、簡
略化された製造工程でプラスチック成形物の成形と、そ
の表面への自由なデザインによる加飾を接着性よく施す
ことができるので、意匠性に優れたプラスチック成形物
を生産性よく製造することができる。Further, the invention according to claim 9 is characterized in that the molding is performed simultaneously with the molding by using an injection molding simultaneous painting method in which a transfer film or a laminate film provided with a picture layer is placed in a mold. The method for manufacturing a plastic molded product according to claim 7 or 8, wherein the method is a decoration. By adopting such a manufacturing method, in addition to the functions and effects of the invention described in claim 7 or 8, the molding of the plastic molded product can be performed by a simplified manufacturing process and the surface can be freely designed. Since the decoration can be applied with good adhesiveness, it is possible to produce a plastic molded product having excellent design properties with good productivity.
【0016】[0016]
【発明の実施の形態】以下に、本発明のプラスチック成
形物に用いる材料、および、製造方法など、発明の実施
の形態について説明する。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, embodiments of the present invention, such as a material used for a plastic molded product of the present invention and a manufacturing method, will be described.
【0017】(1)材料について 本発明において、使用するプラスチックは、線熱膨張係
数が1×10-4/℃以上のプラスチックであり、例え
ば、ポリプロピレン、ポリエチレン、ポリブテンなどの
ポリオレフィン系樹脂のほか、ナイロン11、ナイロン
12などのポリアミド樹脂などが挙げられる。これらの
樹脂はそれぞれ単独で用いてもよいが、他の樹脂を一種
以上ブレンドした混合樹脂でもよく、また、共重合体で
あってもよい。これらのプラスチックに紙粉を混練する
ことにより、前記したように鋸引き、釘打ちなどの加工
適性、接着適性と共に、温度による寸法安定性を向上さ
せることができる。尚、上記以外のプラスチック、即
ち、線熱膨張係数が1×10-4/℃よりも小さく、温度
による寸法安定性が比較的良好なプラスチックであって
も、紙粉を混練することにより、鋸引きや釘打ちなどの
加工適性、表面の接着適性などは改善することができる
ので、このような目的の場合は、前記以外のプラスチッ
クも自由に使用することができる。(1) Material In the present invention, the plastic used is a plastic having a linear thermal expansion coefficient of 1 × 10 −4 / ° C. or more. For example, in addition to polyolefin resins such as polypropylene, polyethylene and polybutene, Examples thereof include polyamide resins such as nylon 11 and nylon 12. Each of these resins may be used alone, but may be a mixed resin in which one or more other resins are blended, or may be a copolymer. By kneading paper dust with these plastics, as described above, the suitability for processing such as sawing and nailing, the suitability for adhesion, and the dimensional stability due to temperature can be improved. It should be noted that even if a plastic other than the above, that is, a plastic having a coefficient of linear thermal expansion of less than 1 × 10 −4 / ° C. and having relatively good dimensional stability with temperature, sawing is performed by kneading paper powder. Since the suitability for processing such as pulling and nailing, the suitability for surface adhesion, and the like can be improved, plastics other than those described above can be used freely for such purposes.
【0018】そして、プラスチックに混練する紙粉は、
断裁などで発生する白紙の裁ち屑を粉砕して用いてもよ
いが、製本などのミーリング加工(回転刃による面出
し)の際、大量に発生する紙粉を用いることができる。
紙粉自体、形は不定形であるが、長径が6mm以下で、
含まれるパルプの繊維長が1mm以下のものが好まし
い。紙粉の長径が6mm以上で、繊維長が1mm以上に
なるとプラスチックとの混練性が低下し、混練に時間を
要し、紙粉が更に細分化されにくくなるため、不均一に
なり易く好ましくない。紙粉の長径が6mm以下で、繊
維長が1mm以下であればプラスチックとの混練は可能
であり、小さいほど混練が容易である。このような紙粉
を用いることは、廃棄物の有効利用であり、パルプ資源
の有効活用となる点でも好ましく、安価で原料入手も容
易である。The paper powder kneaded with the plastic is
White paper cutting waste generated by cutting or the like may be crushed and used, but a large amount of paper powder generated during milling processing (surface facing with a rotary blade) such as bookbinding can be used.
Paper powder itself is indefinite in shape, but its major axis is 6 mm or less,
The pulp preferably has a fiber length of 1 mm or less. When the major diameter of the paper powder is 6 mm or more, and the fiber length is 1 mm or more, the kneading property with the plastic decreases, the kneading requires time, and the paper powder is less likely to be further subdivided, so that it tends to be non-uniform, which is not preferable. . If the major diameter of the paper powder is 6 mm or less and the fiber length is 1 mm or less, kneading with plastic is possible, and the kneading is easier as the length is smaller. Use of such paper powder is advantageous in terms of effective use of waste and effective use of pulp resources, and it is inexpensive and easy to obtain raw materials.
【0019】(2)製造方法について 前記のようなプラスチック(樹脂)と紙粉とを混練する
ことにより、成形に用いるペレットを作製する。混練お
よびペレット化の装置としては、せん断力の強いインテ
ンシブミキサー(バンバリーミキサー)にペレタイザー
を組み込んだ装置を使用するのが能率的である。この装
置で樹脂を加熱し、軟化させた状態で紙粉を混練するこ
とにより、紙粉は更に破砕され均一に分散される。紙粉
を混練した樹脂はペレタイザーを通して冷却、ペレット
化する。(2) Manufacturing Method The above-mentioned plastic (resin) and paper powder are kneaded to produce pellets used for molding. As a device for kneading and pelletizing, it is efficient to use a device in which a pelletizer is incorporated in an intensive mixer (Banbury mixer) having a strong shearing force. By heating the resin with this device and kneading the paper powder in a softened state, the paper powder is further crushed and uniformly dispersed. The resin obtained by kneading the paper powder is cooled and pelletized through a pelletizer.
【0020】混練に際して、樹脂に添加する紙粉の量
は、樹脂100重量部に対して、紙粉5〜40重量部の
範囲が、成形物の鋸引き、釘打ちなどの加工適性、表面
の接着適性の向上、および線熱膨張係数の低下による寸
法安定性の向上、更には廃棄性の向上、コスト低減効果
などを総合的に得られる点で好ましい。添加量が5重量
部未満の場合は、前記の効果がいずれも不充分であり、
また、40重量部を超える場合は、加工適性、寸法安定
性の向上およびコスト低減効果は得られるが、成形によ
る成形物表面の平滑性の低下が著しくなり、また、機械
的強度も低下するため好ましくない。In kneading, the amount of paper powder to be added to the resin is in the range of 5 to 40 parts by weight of paper powder with respect to 100 parts by weight of resin. It is preferable in terms of improving the suitability for adhesion, improving the dimensional stability by lowering the coefficient of linear thermal expansion, and further improving the disposability and reducing the cost. When the added amount is less than 5 parts by weight, all of the above effects are insufficient,
If the amount exceeds 40 parts by weight, the workability, dimensional stability and cost reduction are obtained, but the smoothness of the molded product surface is significantly reduced by molding, and the mechanical strength is also reduced. Not preferred.
【0021】以上のように作製したペレットを成形機で
成形してプラスチック成形物を作製することができる。
成形方法自体は、特に限定されず、例えば、公知の射出
成形、押出し成形、圧縮成形、トランスファー成形など
いずれの方法も利用でき、成形物の形状に応じて適する
方法を適宜選択して使用することができる。The pellets produced as described above can be molded by a molding machine to produce a plastic molded product.
The molding method itself is not particularly limited. For example, any of known methods such as injection molding, extrusion molding, compression molding, and transfer molding can be used, and a method suitable for a shape of a molded product is appropriately selected and used. Can be.
【0022】また、プラスチック成形物の表面に加飾を
施す場合、通常は成形後、別工程で加飾を施すが、成形
方法が射出成形の場合は、公知の射出成形同時絵付け法
により、成形と同時に加飾を施すことができる。成形物
の成形後、その表面に加飾する場合、公知のシルクスク
リーン印刷、グラビアオフセット印刷、タンポ印刷など
により直接印刷する方法、転写印刷による方法、或い
は、特公昭61−5895号公報、特公平1−3333
2号公報、特公平3−2666号公報等に開示される所
謂ラッピング加工と呼ばれるフィルムラミネート方式な
ど、いずれの方法を用いてもよく、また、エンボス加工
を施すこともできる。In the case of decorating the surface of a plastic molded product, usually, the surface is decorated in a separate step after molding, but when the molding method is injection molding, a known injection molding simultaneous painting method is used. Decoration can be performed simultaneously with molding. In the case of decorating the surface after molding of the molded article, a method of directly printing by known silk screen printing, gravure offset printing, tampo printing, etc., a method of transfer printing, or Japanese Patent Publication No. Sho 61-5895, Japanese Patent Publication No. 1-3333
No. 2, JP-B-3-2666, etc., any method such as a so-called wrapping film lamination method may be used, and embossing may be performed.
【0023】特に、ラッピング加工は、予め印刷などに
より加飾したロール状のフィルムを成形物表面にラミネ
ートするもので、成形物表面への接着方法は、例えばロ
ール状フィルムの印刷絵柄の上に予め感熱性接着剤を塗
布しておいて、この面を成形物表面に合わせて加熱ロー
ルなどにより熱圧着してもよく、また、ドライラミネー
ト用接着剤を貼り合わせ直前にフィルム側に塗布し、溶
剤を熱風乾燥などにより除いた後、そのまま成形物表面
に熱圧着して接着させてもよい。尚、以上のように成形
物の成形後、その表面に加飾を施す場合は、成形物の表
面に予めコロナ放電処理、オゾン処理、フレーム(火
炎)処理など公知の表面処理やプライマーコートなどの
前処理を施すことにより、加飾の接着性を一層向上また
は安定化させることもできる。In particular, the lapping process involves laminating a roll-shaped film, which has been decorated in advance by printing or the like, on the surface of a molded product. A heat-sensitive adhesive may be applied, and this surface may be thermocompressed with a heating roll or the like according to the surface of the molded product. May be removed by hot-air drying or the like, and then directly bonded to the surface of the molded product by thermocompression bonding. When the surface of the molded article is decorated after molding as described above, the surface of the molded article is subjected to a known surface treatment such as corona discharge treatment, ozone treatment, flame (flame) treatment, primer coating, or the like. By performing the pretreatment, the adhesiveness of the decoration can be further improved or stabilized.
【0024】また、射出成形同時絵付け法を用いる場合
は、成形用金型内に、予め印刷などにより絵柄層を設け
た加飾用フィルムを配置して、樹脂を射出し、成形と同
時に一体化して加飾する方法、或いは、絵柄層を設けた
転写フィルムを金型内に配置して、成形と同時に絵柄層
のみを成形物表面に接着させて加飾する方法があり、い
ずれの方法も用いることができる。このような方法を採
ることにより、製造工程が簡略化され、生産性を高める
ことができる。When using the simultaneous painting method of injection molding, a decorative film provided with a picture layer in advance by printing or the like is placed in a molding die, resin is injected, and molded simultaneously with molding. There is a method of decorating by decorating, or a method in which a transfer film provided with a picture layer is placed in a mold, and at the same time of molding, only the picture layer is adhered to the surface of the molded article and decorated. Can be used. By adopting such a method, the manufacturing process can be simplified and the productivity can be increased.
【0025】[0025]
【実施例】以下に、実施例、比較例を挙げて本発明を詳
細に説明する。但し、本発明は、これらの実施例に限定
されるものではない。The present invention will be described in detail below with reference to examples and comparative examples. However, the present invention is not limited to these examples.
【0026】(実施例1)ポリプロピレン(以下PP)
樹脂〔ポリプロピレンJ−700G 出光石油化学
(株)製〕100重量部に対して、長径が6mm以下で
含まれるパルプの繊維長が1mm以下の紙粉を20重量
部の配合割合で混合し、バンバリーミキサーで加熱、混
練した後、ペレタイザーを通して、紙粉が分散されたP
Pのペレットを作製した。上記ペレットを用いて射出成
形法により、上部に幅400mm、長さ600mmの略
長方形の平面部を有する肉厚5mmの蓋状の成形物を作
製した。次に、上記成形物の平面部に、ポリウレタン系
のインキを用いてシルクスクリーン印刷法で木目柄の絵
柄を印刷し、実施例1の木目柄入りプラスチック成形物
を作製した。Example 1 Polypropylene (hereinafter PP)
100 parts by weight of resin [Polypropylene J-700G manufactured by Idemitsu Petrochemical Co., Ltd.] is mixed with 20 parts by weight of a paper powder having a major axis of 6 mm or less and a fiber length of 1 mm or less in a blending ratio of 20 parts by weight. After heating and kneading with a mixer, the powder containing the paper powder is dispersed through a pelletizer.
P pellets were prepared. Using the above-mentioned pellets, a lid-shaped molded product having a thickness of 5 mm and a substantially rectangular flat portion having a width of 400 mm and a length of 600 mm formed on the upper portion by an injection molding method. Next, a wood-grain pattern was printed on the flat part of the above-mentioned molded product by a silk-screen printing method using a polyurethane-based ink to produce a plastic molded product having a wood-grain pattern in Example 1.
【0027】(実施例2)実施例1のプラスチック成形
物の構成において、紙粉の混合量のみを増加することと
し、前記PP樹脂100重量部に対して、前記紙粉を3
0重量部の比率で混合してペレットを作製した他は、総
て実施例1と同様に加工して実施例2の木目柄入りプラ
スチック成形物を作製した。(Example 2) In the structure of the plastic molded product of Example 1, only the mixing amount of the paper powder was increased, and the amount of the paper powder was reduced by 3 with respect to 100 parts by weight of the PP resin.
Except that the pellets were prepared by mixing at a ratio of 0 parts by weight, all were processed in the same manner as in Example 1 to prepare a wood-molded plastic molded product of Example 2.
【0028】(実施例3)実施例1のプラスチック成形
物の構成において、紙粉を混練したPP樹脂をポリエチ
レン(以下PE)樹脂〔ポリエチレン110J 出光石
油化学(株)製〕に換えてペレットを作製した他は、総
て実施例1と同様に加工して実施例3の木目柄入りプラ
スチック成形物を作製した。(PE樹脂と紙粉の混合比
率は100:20)(Example 3) In the structure of the plastic molded product of Example 1, pellets were produced by replacing the PP resin kneaded with paper powder with a polyethylene (hereinafter PE) resin (polyethylene 110J manufactured by Idemitsu Petrochemical Co., Ltd.). Except for the above, all were processed in the same manner as in Example 1 to produce a wood-molded plastic molded article of Example 3. (The mixing ratio of PE resin and paper powder is 100: 20)
【0029】(実施例4)実施例3のプラスチック成形
物の構成において、紙粉の混合量のみを増加することと
し、前記PE樹脂100重量部に対して、前記紙粉を3
0重量部の比率で混合してペレットを作製した他は、総
て実施例3と同様に加工して実施例4の木目柄入りプラ
スチック成形物を作製した。(Example 4) In the structure of the plastic molded product of Example 3, only the mixing amount of the paper dust was increased, and the amount of the paper dust was reduced to 100 parts by weight of the PE resin.
Except that the pellets were prepared by mixing at a ratio of 0 parts by weight, all were processed in the same manner as in Example 3 to prepare a wood-molded plastic molded article of Example 4.
【0030】(比較例1)実施例1のプラスチック成形
物の構成において、PP樹脂に対する紙粉の混練を止
め、前記PP樹脂単独のペレットを用いた他は、総て実
施例1と同様に加工して比較例1の木目柄入りプラスチ
ック成形物を作製した。(Comparative Example 1) In the structure of the plastic molded product of Example 1, all processes were the same as in Example 1 except that kneading of the paper powder with the PP resin was stopped and pellets of the PP resin alone were used. Thus, a plastic molded article having a wood grain pattern in Comparative Example 1 was produced.
【0031】(比較例2)実施例3のプラスチック成形
物の構成において、PE樹脂に対する紙粉の混練を止
め、前記PE樹脂単独のペレットを用いた他は、総て実
施例3と同様に加工して比較例2の木目柄入りプラスチ
ック成形物を作製した。(Comparative Example 2) In the construction of the plastic molded product of Example 3, all processes were the same as in Example 3 except that the kneading of the paper powder with the PE resin was stopped and the pellets of the PE resin alone were used. Thus, a plastic molded article having a wood grain pattern in Comparative Example 2 was produced.
【0032】(比較例3)成形用のペレットとして、線
熱膨張係数が1×10-4/℃より小さいABS樹脂〔J
SR ABS57 日本合成ゴム(株)製〕単独のペレ
ットを用い、以下、成形、および印刷は、実施例1と同
様に行って比較例3の木目柄入りプラスチック成形物を
作製した。以上、実施例1〜4、比較例1〜3の各プラ
スチック成形物の射出成形において、それぞれの成形性
は特に問題なく良好に成形できた。(Comparative Example 3) As a molding pellet, an ABS resin having a coefficient of linear thermal expansion of less than 1 × 10 −4 / ° C. [J
SR ABS57 Nippon Synthetic Rubber Co., Ltd.] Using a single pellet, molding and printing were carried out in the same manner as in Example 1 to produce a plastic molded article with a grain pattern in Comparative Example 3. As described above, in the injection molding of each of the plastic molded products of Examples 1 to 4 and Comparative Examples 1 to 3, the respective moldability was favorably molded without any problem.
【0033】(試験および結果)以上のように作製した
実施例1〜4、および比較例1〜3の木目柄入りプラス
チック成形物、および、別途それぞれの配合のペレット
を射出成形して作製した所定寸法の試験用成形物につい
て、下記項目の測定および試験を行い、その結果を表1
にまとめて示した。(Tests and Results) The plastic molded products having the woodgrain pattern prepared in Examples 1 to 4 and Comparative Examples 1 to 3 prepared as described above, and the pellets separately prepared by injection molding the pellets of the respective blends. Measurements and tests of the following items were performed on the molded articles for testing dimensions, and the results are shown in Table 1.
Are shown together.
【0034】(1)線熱膨張係数の測定 各成形物について、線熱膨張係数をJIS K6911
適用箇条5.25に準拠して測定した。(1) Measurement of coefficient of linear thermal expansion For each molded product, the coefficient of linear thermal expansion was determined according to JIS K6911.
Measured in accordance with applicable clause 5.25.
【0035】(2)成形物の加工適性 各プラスチック成形物について、鋸引き及び釘打ちのテ
ストを行い、その加工適性を下記の基準で評価した。 ○:鋸引きの際、樹脂が刃に粘着せずスムーズに切れ、
また、釘打ちにより割れの発生または保持性不良のない
もの。 ×:鋸引きの際、樹脂が刃に粘着し切りにくくなるか、
或いは、釘打ちにより割れの発生または保持性不良のあ
るもの。(2) Processability of Molded Product Each plastic molded product was subjected to a sawing and nailing test, and the processability was evaluated according to the following criteria. ○: During sawing, the resin cuts smoothly without sticking to the blade,
No cracking or poor retention due to nailing. ×: When sawing, is the resin sticking to the blade and difficult to cut?
Or, those with cracking or poor retention due to nailing.
【0036】(3)成形物表面の接着適性 (各プラスチック成形物の表面にポリウレタン系インキ
で印刷された木目柄のインキ層の接着性で評価)実施例
1〜4、および比較例1〜3で作製したそれぞれの木目
柄入りプラスチック成形物を常温で3日間放置した後、
各試料の印刷加工面に、カッターで1mm間隔の切り込
みを縦横各11本碁盤目状に入れ、その面にセロハン粘
着テープ〔セロテープLD−18 ニチバン(株)製〕
を貼着した後、180°方向の剥離テストを行い、その
結果を下記の基準により記号で表1に示した。 ○:印刷絵柄の剥離がないもの ×:印刷絵柄の剥離があるもの(3) Adhesive aptitude of molded product surface (Evaluated by adhesiveness of wood-grain pattern ink layer printed with polyurethane-based ink on the surface of each plastic molded product) Examples 1-4 and Comparative Examples 1-3 After leaving each of the wood-molded plastic molded products prepared in step 3 at room temperature for 3 days,
Cuts are made at intervals of 1 mm on the printed surface of each sample with a cutter in a grid pattern of eleven in length and width, and cellophane adhesive tape [Cellotape LD-18 made by Nichiban Co., Ltd.]
, And a 180 ° peel test was performed. The results are shown in Table 1 by symbols according to the following criteria. ○: No peeling of printed pattern ×: Peeling of printed pattern
【0037】(4)曲げ強度の測定 各成形物について、曲げ強度をJIS K7203に準
拠して測定した。数値は〔kgf/cm2 〕の単位で表
示した。(4) Measurement of bending strength The bending strength of each molded product was measured according to JIS K7203. Numerical values are shown in units of [kgf / cm 2 ].
【0038】[0038]
【表1】 (注)表1において( )内は樹脂と紙粉の配合割合を示す。[Table 1] (Note) In Table 1, parentheses indicate the mixing ratio of resin and paper powder.
【0039】表1に示した試験結果から明らかなよう
に、PP樹脂に紙粉を混練して、成形し、その表面にポ
リウレタン系のインキを用いて木目柄を印刷した実施例
1、2のプラスチック成形物は、紙粉が混練されていな
い比較例1のプラスチック成形物との対比で分かるよう
に、線熱膨張係数が、約1/2から1/3に迄小さくな
り、温度による寸法安定性が向上すると共に、成形物の
加工適性、および成形物表面の接着適性も向上した。
只、曲げ強度は低下しているが、特に著しいものではな
く、実用上問題のない程度である。As is evident from the test results shown in Table 1, paper powder was kneaded with PP resin, molded, and the grain pattern was printed on the surface thereof using a polyurethane ink. As can be seen from the comparison with the plastic molded product of Comparative Example 1 in which the paper dust was not kneaded, the linear thermal expansion coefficient of the plastic molded product was reduced from about 1/2 to 1/3, and the dimensional stability due to temperature was reduced. In addition to the improved properties, the workability of the molded product and the adhesiveness of the surface of the molded product were also improved.
Although the bending strength has been reduced, it is not particularly remarkable, and is of a level that does not cause any practical problems.
【0040】また、PE樹脂に紙粉を混練して同様に作
製した実施例3、4のプラスチック成形物も、PE樹脂
単独による比較例2のプラスチック成形物と対比して分
かるように、線熱膨張係数が、約1/2から1/4に迄
小さくなり、温度による寸法安定性が向上し、成形物の
加工適性、および成形物表面の接着適性も向上した。こ
の場合も曲げ強度は低下しているが、実用上問題はな
い。そして、比較例1、2のPP樹脂またはPE樹脂単
独によるプラスチック成形物は、両者とも、線熱膨張係
数が大きく、また、成形物の加工適性、成形物表面の接
着適性のいずれもが劣っており好ましくない。また、比
較例3のABS樹脂単独によるプラスチック成形物は、
線熱膨張係数が小さく、成形物表面の接着適性も良好で
あるが、成形物の加工適性が劣っており、実施例のプラ
スチック成形物と比較すると、総合面で劣っている。Further, the plastic molded products of Examples 3 and 4, which were similarly prepared by kneading paper powder with the PE resin, also showed linear heat as compared with the plastic molded product of Comparative Example 2 using only the PE resin. The expansion coefficient was reduced from about 1/2 to 1/4, the dimensional stability with temperature was improved, and the workability of the molded product and the adhesiveness of the molded product surface were also improved. Also in this case, the bending strength is reduced, but there is no practical problem. The plastic molded products of Comparative Examples 1 and 2 made of the PP resin or PE resin alone have large linear thermal expansion coefficients, and are inferior in both the workability of the molded products and the adhesiveness of the molded product surface. Not preferred. In addition, the plastic molded product of the ABS resin alone of Comparative Example 3 was:
Although the coefficient of linear thermal expansion is small and the adhesive suitability of the surface of the molded product is good, the workability of the molded product is inferior, and the overall plastic surface is inferior to the plastic molded products of the examples.
【0041】[0041]
【発明の効果】以上詳しく説明したように、請求項1に
記載した発明は、線熱膨張係数が1×10-4/℃以上の
プラスチックに紙粉が混練された組成物で形成されてい
ることを特徴とするプラスチック成形物であり、このよ
うな構成を採ることにより、以下のような効果を奏す
る。As described in detail above, the invention described in claim 1 is formed of a composition in which paper powder is kneaded with a plastic having a coefficient of linear thermal expansion of 1 × 10 −4 / ° C. or more. This is a plastic molded product characterized by the following features. By adopting such a configuration, the following effects can be obtained.
【0042】線熱膨張係数が1×10-4/℃以上のよ
うに大きいプラスチックに紙粉を混練することにより、
プラスチック成形物の線熱膨張係数が小さくなり、温度
による寸法安定性が向上する。従って、プラスチック成
形物を一層広範囲の用途に使用できるようになる。 プラスチック成形物を鋸引きしても、樹脂が摩擦熱で
粘着することなく容易に切断することができ、釘打ちし
ても歪みが吸収されるため割れることがなくなり、プラ
スチック成形物の加工適性が向上する。 紙粉の混練により、プラスチック成形物の表面がポー
ラスになり粗面化されると同時に、紙粉の一部が表面に
露出するため、表面の接着適性が向上し、加飾など表面
加工が容易になる。 紙粉を混練することにより、コストが低減し、焼却な
どによる廃棄性も向上できる。By kneading paper powder with a plastic having a large linear thermal expansion coefficient of 1 × 10 −4 / ° C. or more,
The linear thermal expansion coefficient of the plastic molded product is reduced, and the dimensional stability with temperature is improved. Therefore, the plastic molded article can be used for a wider range of applications. Even when sawing a plastic molded product, the resin can be easily cut without sticking due to frictional heat. improves. By kneading the paper powder, the surface of the plastic molded product becomes porous and roughened, and at the same time, a part of the paper powder is exposed on the surface, improving the adhesiveness of the surface and facilitating surface processing such as decoration. become. By kneading the paper powder, the cost can be reduced and the disposability by incineration can be improved.
【0043】請求項2に記載した発明は、前記プラスチ
ックに混練する紙粉に、長径が6mm以下の大きさで、
且つ、含有されるパルプの繊維長が1mm以下のものを
用いたものであり、このような紙粉を用いることによ
り、樹脂との混練が容易になり、均一な分散が可能とな
るため、前記プラスチック成形物の各性能の改善効果が
一層確実に得られるようになる。According to a second aspect of the present invention, paper powder kneaded with the plastic has a major axis of 6 mm or less,
In addition, the fiber length of the pulp contained is 1 mm or less, and the use of such a paper powder facilitates kneading with a resin and enables uniform dispersion. The effect of improving each performance of the plastic molded product can be more reliably obtained.
【0044】請求項3に記載した発明は、前記プラスチ
ック100重量部に対して、前記紙粉を5〜40重量部
の配合割合で混練した組成物でプラスチック成形物を形
成したものであり、このような構成を採ることにより、
曲げ強度などの機械的強度を実用可能なレベルに維持し
ながら、前記寸法安定性、加工適性、接着適性の向上、
および、コスト低減、廃棄性の向上を達成することがで
きる。According to a third aspect of the present invention, a plastic molded product is formed from a composition obtained by kneading the paper powder in a mixing ratio of 5 to 40 parts by weight with respect to 100 parts by weight of the plastic. By adopting such a configuration,
While maintaining mechanical strength such as bending strength at a practicable level, the dimensional stability, workability, improvement of adhesive suitability,
In addition, cost reduction and improvement in disposability can be achieved.
【0045】請求項4に記載した発明は、前記プラスチ
ックにポリオレフィン系樹脂を用いてプラスチック成形
物を形成したものであり、このような構成を採ることに
より、ポリオレフィン系樹脂の欠点である温度による寸
法安定性、成形物の加工適性、接着適性が改善され、更
に、その長所である成形の容易性、耐薬品性、耐溶剤
性、軽量性、そして、廃棄性、リサイクル性、経済性な
どが生かされるため、プラスチック成形物を幅広い用途
に使用できるようになる。According to a fourth aspect of the present invention, a plastic molded product is formed by using a polyolefin-based resin for the plastic. By adopting such a structure, the size of the polyolefin-based resin, which is a drawback of temperature, is a disadvantage. Stability, processability of molded products, and adhesive suitability have been improved. In addition, the advantages of ease of molding, chemical resistance, solvent resistance, light weight, and disposal, recyclability, economic efficiency, etc. are utilized. Therefore, the plastic molded product can be used for a wide range of applications.
【0046】請求項5に記載した発明は、前記プラスチ
ック成形物の表面に加飾が施されたものであり、これに
よりプラスチック成形物の外観、意匠性が向上し、一層
広い用途に好ましく使用できるようになる。According to the invention described in claim 5, the surface of the plastic molded product is decorated, whereby the appearance and design of the plastic molded product are improved, and the plastic molded product can be preferably used for a wider range of applications. Become like
【0047】請求項6に記載した発明は、前記加飾が射
出成形同時絵付け法により施されたプラスチック成形物
であり、このような加飾方法を採ることにより、成形と
同時に表面の加飾が行われるため、生産性が向上すると
同時に、加飾に必要な熱と圧が充分に成形条件により自
動的に加えられるため、プラスチック成形物表面に接着
性良好な加飾が得られる。According to a sixth aspect of the present invention, the decorating is a plastic molded article applied by a simultaneous painting method of injection molding, and by adopting such a decorating method, the surface is decorated simultaneously with the molding. Is performed, the productivity is improved, and at the same time, the heat and pressure required for decorating are sufficiently applied automatically according to the molding conditions, so that decorating with good adhesiveness can be obtained on the surface of the plastic molded product.
【0048】そして、請求項7に記載した発明は、線熱
膨張係数が1×10-4/℃以上のプラスチック100重
量部に対して、長径が6mm以下の大きさで、且つ、含
有されるパルプの繊維長が1mm以下の紙粉を5〜40
重量部の配合割合で混練した組成物を作製し、該組成物
を成形することを特徴とするプラスチック成形物の製造
方法である。このような製造方法を採ることにより、曲
げ強度などの機械的強度が実用可能なレベルに維持さ
れ、且つ、温度による寸法安定性がよく、前記加工適
性、接着適性に優れると共に、安価で焼却など廃棄性に
優れたプラスチック成形物を製造することができる。According to the seventh aspect of the present invention, the long diameter is not more than 6 mm and is contained in 100 parts by weight of the plastic having a linear thermal expansion coefficient of 1 × 10 −4 / ° C. or more. Pulp fiber length of 1mm or less 5 ~ 40
A method for producing a plastic molded product, comprising preparing a composition kneaded in a blending ratio of parts by weight, and molding the composition. By adopting such a manufacturing method, mechanical strength such as bending strength is maintained at a practicable level, and dimensional stability by temperature is good, and the workability and adhesion suitability are excellent, and inexpensive incineration etc. It is possible to produce a plastic molded product having excellent disposability.
【0049】請求項8に記載した発明は、前記プラスチ
ックにポリオレフィン系樹脂を用いることを特徴とする
請求項7記載のプラスチック成形物の製造方法であり、
このような製造方法を採ることにより、ポリオレフィン
系樹脂の欠点である前記温度による寸法安定性、加工適
性、接着適性が改善されると同時に、その長所である成
形の容易性、耐薬品性、耐溶剤性、軽量性、そして、廃
棄性(粉砕による減容化が容易で、また、焼却しても有
害ガスを発生せず、燃えかすなども残らない)、リサイ
クル性、経済性(安価)が生かされるため、幅広い用途
に使用できるポリオレフィン系樹脂成形物を製造でき
る。The invention according to claim 8 is the method for producing a plastic molded product according to claim 7, wherein a polyolefin resin is used for the plastic.
By adopting such a production method, the dimensional stability due to the temperature, processability, and adhesion suitability, which are disadvantages of the polyolefin resin, are improved, and at the same time, its advantages such as ease of molding, chemical resistance, and Solvent properties, light weight, and disposal (easy volume reduction by pulverization, no harmful gas generated even when incinerated, no burning remains), recyclability, economy (low cost) Since it is utilized, it is possible to produce a polyolefin-based resin molded product that can be used for a wide range of applications.
【0050】また、請求項9に記載した発明は、前記成
形に、絵柄層を設けた転写フィルムまたはラミネートフ
ィルムを金型内に配置して行う射出成形同時絵付け法を
用いて、成形と同時に加飾を施すことを特徴とする請求
項7または8に記載のプラスチック成形物の製造方法で
ある。このような製造方法を採ることにより、簡略化さ
れた製造工程でプラスチック成形物の成形と、その表面
への自由なデザインによる加飾を接着性よく施すことが
できるので、前記請求項7または8に記載した発明の効
果に加えて、意匠性にも優れたプラスチック成形物を生
産性よく製造することができる。The invention according to claim 9 is characterized in that the molding is performed simultaneously with molding by using a simultaneous injection molding painting method in which a transfer film or a laminate film provided with a picture layer is placed in a mold. The method for manufacturing a plastic molded product according to claim 7, wherein the plastic molded product is decorated. By adopting such a manufacturing method, it is possible to form a plastic molded product and decorate the surface thereof with a free design with good adhesiveness in a simplified manufacturing process. In addition to the effects of the invention described in (1), a plastic molded product excellent in design can be produced with high productivity.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 FI C08L 23/00 B29C 67/16 // B29K 23:00 105:16 511:12 B29L 9:00 ────────────────────────────────────────────────── ─── Continued on the front page (51) Int.Cl. 6 Identification code FI C08L 23/00 B29C 67/16 // B29K 23:00 105: 16 511: 12 B29L 9:00
Claims (9)
スチックに紙粉が混練された組成物で形成されているこ
とを特徴とするプラスチック成形物。1. A plastic molded product comprising a composition in which paper powder is kneaded with a plastic having a coefficient of linear thermal expansion of 1 × 10 −4 / ° C. or higher.
且つ、含有されるパルプの繊維長が1mm以下であるこ
とを特徴とする請求項1記載のプラスチック成形物。2. The paper powder according to claim 1, wherein said paper powder has a major axis of 6 mm or less.
The plastic molded product according to claim 1, wherein the fiber length of the pulp contained is 1 mm or less.
に対して、紙粉5〜40重量部の配合割合で形成されて
いることを特徴とする請求項1または2に記載のプラス
チック成形物。3. The plastic molded article according to claim 1, wherein the composition is formed in a mixing ratio of 5 to 40 parts by weight of paper powder with respect to 100 parts by weight of the plastic.
脂であることを特徴とする請求項1乃至3のいずれかに
記載のプラスチック成形物。4. The plastic molded article according to claim 1, wherein said plastic is a polyolefin resin.
されていることを特徴とする請求項1乃至4のいずれか
に記載のプラスチック成形物。5. The plastic molded product according to claim 1, wherein a decoration is applied to a surface of the plastic molded product.
施されていることを特徴とする請求項5に記載のプラス
チック成形物。6. The plastic molded product according to claim 5, wherein the decorating is performed by an injection molding simultaneous painting method.
スチック100重量部に対して、長径が6mm以下の大
きさで、且つ、含有されるパルプの繊維長が1mm以下
の紙粉を5〜40重量部の配合割合で混練した組成物を
作製し、該組成物を成形することを特徴とするプラスチ
ック成形物の製造方法。7. A paper having a major axis of 6 mm or less and a pulp fiber length of 1 mm or less with respect to 100 parts by weight of a plastic having a linear thermal expansion coefficient of 1 × 10 −4 / ° C. or more. A method for producing a plastic molded product, comprising preparing a composition in which powder is kneaded at a mixing ratio of 5 to 40 parts by weight, and molding the composition.
を用いることを特徴とする請求項7記載のプラスチック
成形物の製造方法。8. The method according to claim 7, wherein a polyolefin resin is used as the plastic.
またはラミネートフィルムを金型内に配置して行う射出
成形同時絵付け法を用いて、成形と同時に加飾を施すこ
とを特徴とする請求項7または8に記載のプラスチック
成形物の製造方法。9. The molding is performed simultaneously with molding using a simultaneous injection molding painting method in which a transfer film or a laminate film provided with a picture layer is placed in a mold. A method for producing a plastic molded product according to claim 7.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9013171A JPH10195305A (en) | 1997-01-10 | 1997-01-10 | Plastic molding and its production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9013171A JPH10195305A (en) | 1997-01-10 | 1997-01-10 | Plastic molding and its production |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH10195305A true JPH10195305A (en) | 1998-07-28 |
Family
ID=11825744
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9013171A Withdrawn JPH10195305A (en) | 1997-01-10 | 1997-01-10 | Plastic molding and its production |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH10195305A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100451055B1 (en) * | 2000-09-27 | 2004-10-02 | 강현 | Method for preparing injection molding material having low expansion and superior heat-resistance properties |
WO2005079110A1 (en) * | 2004-02-18 | 2005-08-25 | Matsushita Electric Industrial Co., Ltd. | Speaker, speaker-use diaphragm, dust cap, production methods and production devices for them |
JP2005252775A (en) * | 2004-03-05 | 2005-09-15 | Matsushita Electric Ind Co Ltd | DUST CAP FOR SPEAKER, SPEAKER USING THE SAME, AND ELECTRONIC DEVICE AND DEVICE USING THE SPEAKER |
JP2006001275A (en) * | 2004-05-17 | 2006-01-05 | Teijin Dupont Films Japan Ltd | Biaxially oriented laminated film and magnetic recording medium |
JP2010180313A (en) * | 2009-02-05 | 2010-08-19 | Mitsubishi Electric Corp | Polypropylene colored molded article and method for producing the same |
-
1997
- 1997-01-10 JP JP9013171A patent/JPH10195305A/en not_active Withdrawn
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100451055B1 (en) * | 2000-09-27 | 2004-10-02 | 강현 | Method for preparing injection molding material having low expansion and superior heat-resistance properties |
WO2005079110A1 (en) * | 2004-02-18 | 2005-08-25 | Matsushita Electric Industrial Co., Ltd. | Speaker, speaker-use diaphragm, dust cap, production methods and production devices for them |
JP2005252775A (en) * | 2004-03-05 | 2005-09-15 | Matsushita Electric Ind Co Ltd | DUST CAP FOR SPEAKER, SPEAKER USING THE SAME, AND ELECTRONIC DEVICE AND DEVICE USING THE SPEAKER |
JP2006001275A (en) * | 2004-05-17 | 2006-01-05 | Teijin Dupont Films Japan Ltd | Biaxially oriented laminated film and magnetic recording medium |
JP2010180313A (en) * | 2009-02-05 | 2010-08-19 | Mitsubishi Electric Corp | Polypropylene colored molded article and method for producing the same |
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