JPH10149911A - Magnetic sensor element, its manufacture, and burglarproof system provided with it - Google Patents

Abstract

PROBLEM TO BE SOLVED: To enable a magnetic sensor element to generate a signal having a detectable intensity even when the element has an extremely short length by containing an amorphous magnetic alloy containing Co, Fe, B, and Si at a specific atomic composition ratio in the element. SOLUTION: A magnetic sensor element 18 is composed of an amorphous magnetic alloy having an atomic composition ratio of (Cox Fe1-x )1-n (By Si1-y )n (where, X=0-1, y=0.2, and n=0.1-0.3) and contains such a group III or IV metallic element as Cr, Ni, Mn, etc., up to 5 atomic %. The heat treatment of the amorphous magnetic alloy is performed for one minutes or larger at 200-460 deg.C in the air or another atmosphere while the external magnetic filed is brought nearer to zero (0). In addition, the sensor 18 shows four peaks per cycle which are twice as many as the number of peaks of the radiated waveform.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for heat-treating a soft magnetic substance so that a unique electric signal can be generated in an alternating magnetic field, and an algorithm for an anti-theft system using such a substance. More specifically, the present invention performs a magnetic field-free heat treatment on a cobalt-based amorphous magnetic alloy ribbon or wire having a zero magnetostriction composition so that two main peaks and two sub-peaks are formed while the external AC magnetic field changes by one period. It is an object of the present invention to provide a sensor showing a peak, and to provide an electronic circuit concept capable of detecting such a unique electric signal to determine whether or not the sensor exists in a predetermined space.

A magnetic sensor according to the present invention can be used for manufacturing a target (sticker) for an anti-theft system. Anti-theft systems include libraries, bookstores, department stores,
It is provided to prevent articles such as books, clothes, and compact discs from being stolen from a restricted protected area such as a supermarket. Most anti-theft systems serve their purpose by attaching a target capable of providing a unique signal to each item so that the target can be monitored at the exit of the protected area. FIG. 1 schematically illustrates a magnetic type anti-theft system in which a magnetic sensor according to the present invention may be used.
0), a receiver antenna (16) for detecting a high-frequency pulse signal generated when a target (14) attached to an article (12) is exposed to an AC magnetic field, and a high-frequency electric signal processing device.

[0003]

2. Description of the Related Art FIG.
FIG. 3 illustrates the shape attached to 2), and FIG.
FIG. 3 is an enlarged cross-sectional view showing a target portion. As shown in FIGS. 2 and 3, the target (14) comprises a magnetic sensor element (18) and a tape substrate (20) having double-sided adhesiveness. Magnetic sensor element (18)
Should be made of a soft magnetic material having a high magnetic permeability so that the magnetic field is easily saturated even if the external magnetic field is small, and the shape of the demagnetizing field should be small. In order to make the magnitude of the demagnetizing field smaller than a certain size, the shape should be longer than a certain ratio. For example, when the saturation magnetization value is 65
When the width of the amorphous ribbon is 1 emu / cm ³ and the thickness is 0.025 mm, the magnitude of the demagnetizing field is 0.5 Oe.
To be smaller, the length of the ribbon must be greater than about 4 cm. Therefore, if the conventional soft magnetic sensor element has a large permeability and a short shape, it is difficult to be saturated by the external magnetic field, and the change in the magnetic velocity density due to the change in the external magnetic field is slow and small, so that the sensor is difficult to sense. The signal of the required magnitude could not be generated.

[0004]

SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a sensor which is necessary for sensing even in a form having a length significantly shorter than that of a conventional sensor element due to a sudden change in the magnetization value depending on the magnitude of the critical magnetic field. An object of the present invention is to provide a magnetic sensor element capable of generating a signal having a magnitude. On the other hand, if the magnitude of the demagnetizing field is smaller than a critical value (for example, 0.5 Oe), sensitivity above a certain value can be maintained irrespective of the shape of the sensor. , A wire or the like.

[0005]

[Means for Solving the Problems] [Co _x Fe _1-x ] _1-n
Preparing an amorphous magnetic alloy having an atomic composition ratio of [B _y Si _1-y ] _n ;
A method for manufacturing a magnetic sensor and a magnetic sensor element, comprising a step of performing a heat treatment in air at a temperature in a range of from ℃ to 460 ° C for at least one minute.

The anti-theft system according to the present invention comprises a frequency oscillating means, a means for generating a sine wave of a specific frequency, a means for amplifying the sine wave to generate a magnetic field, and a magnetic field surrounding the magnetic field. A magnetic sensor element provided with a field, a receiver means adjacent to said magnetic sensor element for receiving a signal sensed by said magnetic sensor element, a sensor signal connected to said receiver means and emerging from said receiver means Means for generating a rectangular wave based on the waveform of the control signal, control signal generating means for generating a control signal by a signal output from the frequency oscillating means coupled to the frequency oscillating means,
A comparison unit coupled between the control signal generation unit and the square wave generation unit, for comparing the frequency of the control signal with the frequency of the signal output from the square wave generation unit and the number of pulses;
And an alarming means coupled to the comparing means and issuing an alarm in response to a sensor presence / absence determination signal output from the comparing means.

[0007]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail with reference to the accompanying drawings.

The magnetic sensor element (18) according to the present invention shown in FIGS. 2 and 3 processes a magnetic substance having a small coercive force (for example, 0.1 Oe) in an alternating magnetic field of about 1 kHz or outside by a special method. It has unique characteristics. The magnetic sensor element adopted in the present invention includes [Co _x Fe _1-x ] _1-n [B _y Si _1-y ] _n where x = 0 to 1, y = 0.2 to 1, and n = 0. .
An amorphous magnetic alloy having an atomic composition ratio of 1 to 0.3, and may contain up to 5 atomic% of a third or fourth metal element such as Cr, Ni, and Mn.

However, the most suitable composition for utilizing the present invention is a composition having a saturation magnetostriction of zero, for example, C
o _70.5 Fe _4.5 B ₂₅ is that. This is because an amorphous magnetic alloy having a composition with zero saturation magnetostriction not only has a small coercive force in an alternating magnetic field, but also inevitably receives external stress during the process of making a target or when attaching it to an article. This is because deterioration of the original characteristics due to this is the least.

The oxide film layer (22) in FIG. 3 is not necessary for obtaining the characteristics according to the present invention, but forms a quasi-ferromagnetic material with the inner layer (24) of the sensor element. This can be done in the process of stabilizing the characteristics.

FIG. 4 shows a magnetic hysteresis curve of a conventional magnetic sensor element such as a permalloy strip, an amorphous magnetic alloy ribbon or a wire used in an anti-theft system. The X axis in FIG. 4 indicates the magnitude (unit: Oe) and direction (positive or negative) of the external magnetic field applied in the length direction of the magnetic sensor element, and the Y axis indicates the inside of the sensor element that changes according to the strength of the external magnetic field. Shows the magnetization value (unit: Gauss). When the external magnetic field H is strongly applied in the negative direction (A
Point), the magnetization value M also becomes saturated in the negative direction. Even if the sensor element becomes magnetically saturated at the point A and the external magnetic field H is increased in the negative direction, the magnetization value does not increase any more. On the other hand, point A
Even if the external magnetic field is increased in the positive direction from, the magnetization value saturated in the negative direction will not change for the time being, but the magnetization will only occur after the external magnetic field has passed the point B given in the positive direction. The point where the value is saturated in the same positive direction as the direction of the external magnetic field is point C. Even if an external magnetic field is applied more strongly in the positive direction than point C, there is no further change in the magnetization value. When an external magnetic field is applied in a negative direction from point C, the positively saturated magnetization value does not change up to point D located in the negative external magnetic field. When an external magnetic field is applied to the, the magnetization value is decreased in the negative direction, and eventually becomes saturated in the negative direction (point A).

That is, when the external magnetic field sequentially changes in a positive direction and a negative direction with a sufficiently large strength, that is, when a sufficiently strong AC magnetic field is applied, the sensor elements A, B,
Reacts magnetically along the path of C, D, A...

As shown in FIG. 4, a large change in the magnetization value M is a very limited range of the change width of the external magnetic field.
That is, it exists only between point B and point C. Due to the change in this section, the sensor element generates disturbance of the external magnetic field,
The effect is so great as to be perceived. Strictly speaking, when the external magnetic field changes, the magnetization value changes rapidly and the slope dM / dH in the magnetic hysteresis curve is larger, so that a higher value high-frequency component can be obtained and it can be more easily sensed. .

FIG. 5 shows the value of the slope dM / dH in the magnetic hysteresis curve shown in FIG. 4 with time on the X-axis. As shown in FIG. 5, two pulses are obtained while the external magnetic field changes by about one cycle (from point A to the next point A). The degree to which the external magnetic field is disturbed depends on whether the high-frequency component of this pulse is as follows, and the magnitude of the high-frequency component depends on how narrow and high the pulse is.

FIG. 6 shows a magnetic hysteresis curve of the magnetic sensor element according to the present invention. The X-axis in FIG. 6 shows the magnitude (unit: Oe) and direction (positive or negative) of the external magnetic field given in the length direction of the magnetic sensor element, and the Y-axis shows the inside of the sensor element that changes according to the strength of the external magnetic field. Shows the magnetization value (unit: Gauss). When the external magnetic field H is strongly applied in the negative direction [point (a)], the magnetization value M is also saturated in the negative direction, and even if the external magnetic field H is increased in the negative direction, the magnetization value does not increase any more. On the other hand, even if the external magnetic field is increased in the positive direction from the point (a), the magnetization value saturated in the negative direction does not change for the time being, but the external magnetic field is further applied in the positive direction. After the point (b), the magnetization value starts to increase in the positive direction. When the external magnetic field is further increased in the positive direction and the magnetization value reaches near "0" (point (d)), the magnetization value does not change even if the external magnetic field is increased in the positive direction. When the external magnetic field is further increased in the positive direction and reaches the point (e), the magnetization value changes abruptly (process (f)) and the magnetization value reaches the point (h) where the magnetization value is almost saturated in the positive direction. That is, even if the external magnetic field H is increased in the positive direction, the magnetization value does not further increase.

Here, when an external magnetic field is applied in the negative direction, the magnetization value positively saturated until point (i) located in the external magnetic field in the negative direction hardly changes.
When an external magnetic field is applied in a direction more negative than the point (i), the magnetization value decreases in the negative direction, and when the magnetization value approaches "0" [point (k)], the external force becomes stronger in the negative direction. Even if a magnetic field is applied, there is no further change in the magnetization value. When the external magnetic field is further increased in the negative direction and the point (l) is reached, the magnetization value changes abruptly (process (m)), and the point (a) is reached which is almost saturated in the negative direction. When the external magnetic field is increased in the negative direction, the magnetization value does not decrease any more.

That is, when the external magnetic field sequentially changes in a positive direction and a negative direction with a sufficiently large strength, that is, when a sufficiently strong AC magnetic field is applied, the sensor element (a)
(B), (d), (e), (f), (h), (i),
(K), (l), (m), (a)... Magnetically react along the route.

FIG. 7 shows the value of the slope dM / dH in the magnetic hysteresis curve shown in FIG. 6 with the X-axis as time. As shown in FIG. 7, the external magnetic field is applied for about one cycle [(a)
From the point to the next point (a)], four pulses are obtained. By the way, the conventional magnetic sensor element shows two pulses while the external magnetic field changes for about one cycle, whereas the magnetic sensor element according to the present invention shows four pulses while the external magnetic field changes for about one cycle. Therefore, the magnetic sensor element according to the present invention can easily and without malfunction by counting the number of pulses per cycle. On the other hand, as described above, the degree of disturbance of the external magnetic field depends on how large the high frequency component of this pulse is, and the magnitude of the high frequency component depends on how narrow and high this pulse is,
The magnitudes of the high frequency components of the main peaks (g) and (n) in FIG. 7 are very large. Therefore, the magnetic sensor element according to the present invention can be well applied to existing anti-theft systems that determine the presence or absence of a sensor based on the magnitude of a high frequency component.

The magnetic sensor element according to the present invention having the unique magnetic hysteresis curve shown in FIG. 6 and the unique pulse shown in FIG. 7 is an amorphous magnetic alloy having an atomic composition ratio in the above-mentioned range, especially Co.
The _70.5 Fe _4.5 amorphous magnetic alloy having a composition saturation magnetostriction as B ₂₅ is 0 (zero) is that prepared by heat-treating in a special way. The special heat treatment here is 200 ° C
Heat treatment is performed in a temperature range of ４460 ° C., in the air or other atmosphere for one minute or more, and the external magnetic field during the heat treatment approaches zero (0).

FIG. 8 is a block diagram of one embodiment of an anti-theft system designed to take advantage of the unique characteristics of a magnetic sensor element according to the present invention. A sine wave (FIG. 9a) of a specific frequency is generated by a frequency oscillator (81) and a magnetic field generating circuit (82), and the sine wave is amplified by a current amplifying circuit (84), and a transmitter (90) and a transmitter antenna (10) are generated. ) To generate a magnetic field. This magnetic field is received by a receiver (85) and sent to an amplification and signal processing circuit (86). Sensor element (1
8) When sensed, amplification and signal processing circuit (86)
FIG. 9c. Is formed, Eref-h and Er
FIG. 9d with reference to the voltage of ef-1. The rectangular wave shown in FIG. The comparison circuit (87) compares the frequency of the control signal (FIG. 9b) with the frequency of the signal generated by the amplification and signal processing circuit (86) and the number of pulses, and compares the sensor element (1).
After the presence or absence of 8) is determined, it is sent to an alarm device (88) to issue an alarm, thereby fulfilling the purpose of preventing theft. FIG.
When FIG. 9 is compared with FIG. In FIG. 5, there are four peaks (n), (c), (i) and (g) in one cycle of the sine wave of FIG. That is, the feature of the magnetic sensor element according to the present invention is that the number of peaks of the oscillated waveform is twice, that is, four peaks per cycle.

While the above has been described with reference to illustrative embodiments of the present invention, such description should not be construed in a limiting sense. Those skilled in the art to which the present invention pertains may make various modifications or combinations of the exemplary embodiments with reference to the detailed description of the present invention. it is obvious. It is, therefore, to be understood that the appended claims are intended to cover all such modifications and embodiments.

[Brief description of the drawings]

FIG. 1 is a schematic diagram showing an article to which a target composed of a magnetic sensor element according to the present invention is attached, and an anti-theft system for sensing the target.

FIG. 2 is a schematic view showing an article to which a target comprising the magnetic sensor element according to the present invention of FIG. 1 is attached.

FIG. 3 is an enlarged sectional view showing an article to which the target of FIG. 2 is attached.

FIG. 4 is a magnetic hysteresis curve of a conventional magnetic sensor element.

FIG. 5 When a sufficiently large magnetic field changes in an alternating manner,
A pulse signal generated when an AC magnetic field is disturbed by a conventional magnetic sensor element.

FIG. 6 is a magnetic hysteresis curve of a magnetic sensor having unique characteristics according to the present invention used for the targets of FIGS. 1 to 3;

FIG. 7: When a sufficiently large magnetic field changes in an alternating manner,
A pulse signal generated by a magnetic sensor element having unique characteristics according to the present invention used in the target shown in FIGS.

8 is a block diagram of an anti-theft system using the unique characteristics of a magnetic sensor element having the magnetic characteristics shown in FIG. 6 and the electric characteristics shown in FIG.

FIG. 9 is a dimming chart for explaining the operation principle of the anti-theft system as shown in FIG. 8;

[Explanation of symbols]

 10: Transmitter antenna 12: Article 14: Target 16: Receiver antenna 22: Oxide layer 24: Inner layer 18: Magnetic sensor element 81: Oscillator 82: Magnetic field generation circuit 83: Control signal generation circuit 84: Amplification circuit 85: Receiver 86: Amplification and signal processing circuit 87: Comparison circuit 88: Alarm device 90: Transmitter

Claims (8)

[Claims] [Claim 1] [Co _x Fe _1-x ] _1-n [B _y Si
_1-y ] _n (where x = 0 to 1, y = 0.2 to 1, and n = 0.1 to 0.3). Magnetic sensor element. 2. The amorphous magnetic alloy according to claim 1, wherein said amorphous magnetic alloy has a C content of up to 5 atomic%.
2. The magnetic sensor element according to claim 1, further comprising a third or fourth metal element such as r, Ni, Mn. 3. The magnetic sensor element according to claim 1, wherein the magnetic sensor element exhibits two main peaks and two sub-peaks while the external alternating magnetic field changes by one cycle. 4. [Co _x Fe _1-x ] _1-n [B _y Si
_1-y ] _n (where x = 0 to 1, y = 0.2 to 1 and n = 0.1 to 0.3). Preparing an amorphous magnetic alloy having an atomic composition ratio; Heat-treating the amorphous magnetic alloy having the above composition in the air at a temperature in the range of 200 to 460 ° C. for 1 minute or more. 5. The method according to claim 4, wherein the heat treatment step causes an external magnetic field to approach a zero value. 6. The amorphous magnetic alloy according to claim 1, wherein said amorphous magnetic alloy has a C content of up to 5 atomic%.
The magnetic sensor manufacturing method according to claim 4, further comprising a third or fourth metal element such as r, Ni, and Mn. 7. A frequency oscillating means (81), a means (82) for generating a sine wave of a specific frequency, and a means (8) for current-amplifying the sine wave to generate a magnetic field.
4) a magnetic sensor element (18) having a characteristic according to claim 4 surrounding the magnetic field and being provided with the magnetic field, a signal adjacent to the magnetic sensor element and sensing the magnetic sensor element Receiver means (85) connected to the receiver means for generating a rectangular wave based on the waveform of the sensor signal output from the receiver means (86); coupled to the frequency oscillating means; Control signal generating means (83) for generating a control signal according to a signal output from the frequency oscillating means, coupled between the control signal generating means and the rectangular wave generating means, and the frequency of the control signal and the rectangular wave generating means Comparing means (87) for comparing the frequency of the signal output from the control unit with the number of pulses, and receiving the determination signal of the presence or absence of the sensor output from the comparing means. Anti-theft system, characterized in that it comprises an alarm means (88), which emits broadcast. 8. The method according to claim 6, wherein the determination of the presence or absence of the sensor is performed by detecting signals indicating two main peaks and two sub-peaks while the external AC magnetic field changes by one cycle. Anti-theft system.