JPH10121090A - Detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a detergent composition having a good detergency, excellent foaming performance, being not irritating to e.g. the skin and refreshing after use by combining a surfactant having a specified structure with another surfactant. SOLUTION: This composition comprises a combination of an amidocarboxylic acid represented by formula I or a salt thereof or a dicarboxylic acid imide represented by formula II with a surfactant commonly used as a detergent or a sequestering agent and a cationized polymer. In formulas I and II, R<1> is an 8-22C, desirably 8-18C alkyl, alkenyl or hydroxyalkyl, A is H, a 1-6C alkyl or hydroxyalkyl; or a 4-7C sugar residue or a sugar alcohol residue; X is -CH(OH)CH2 -, -CH2 CH(OH)- or the like; and M is H, an ion of a metal such as sodium or potassium or an ammonium ion.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a detergent composition and, more particularly, to a skin and hair which have low irritation, good foaming, and good use feeling such as a very refreshing feel upon rinsing or after washing. Cleaning composition.

[0002]

2. Description of the Related Art Generally, higher fatty acid salts, alkyl sulfates, and alkyl sulfonates are used as detergent compositions for skin and hair. Higher fatty acid salts have the drawback of causing squeaks and tension during rinsing.Alkyl sulfates and alkyl sulfonates are excellent in detergency and foaming, but when used on the skin they are slick and irritating. There was also a problem in the point.

[0003] Therefore, amphoteric surfactants and the like, and amino acid-type surfactants and sugar-based surfactants and the like as low-stimulant activators have been used. There were problems such as inferior foaming power, and a lack of smoothness of the skin even when used in combination. Also, citric acid amide type surfactants have been reported as surfactants having good foaming and good rinsing properties (JP-A-57-8).
However, when used alone, there was a problem that the foam quality was slightly inferior.

Further, a carboxylic acid, a neutralized salt and a maleic amide having reduced skin irritation (Japanese Patent Application Laid-Open No. 48-90)
No. 982), but they have a drawback that they give a "slimy", "squeaky" or "tough" feeling when rinsing, and citric amide foams and has good rinsing properties. Although it is known as a mild surfactant (JP-A-57-83599), the foam quality is not always at a satisfactory level.

[0005] Further, as surfactants used for body and hair cleansing agents, ether carboxylic acid surfactants, polyoxyethylene alkyl ether sulfate and the like are also used. Although these surfactants show good lathering, these surfactants leave a "slimy" when rinsed and are not always of satisfactory performance.

[0006] N-acylated amino acid type surfactants are also surfactants which are excellent in foaming and have low irritation. However, this surfactant is also "slimy" when rinsed
There is a disadvantage of leaving. Further, surfactants other than anions, for example, detergents containing an amphoteric surfactant as a main component, and detergents in which the amount of an anionic surfactant is reduced have been developed. It was not satisfactory in terms of gender.

Therefore, the present inventors have found that the skin irritation is low, the foaming properties are excellent, the foaming properties are excellent, and the sensation upon rinsing is excellent. As a composition suitable for a detergent, a detergent composition containing a hydroxyamidocarboxylic acid or a salt thereof having a specific structure represented by the following general formula (3) has been previously proposed (Japanese Patent Application No. 7-300). No. 117962).

Embedded image (Wherein, R ′, M ′: the same as the definition of R in the general formula (1), A ′: a hydrogen atom, a linear or branched alkyl group or hydroxyalkyl group having 1 to 6 carbon atoms) However, when this hydroxyamide carboxylic acid or a salt thereof is used alone, the foaming power is not sufficient, and the foam peculiarity, foam quality and feel in use are not sufficiently satisfactory. There was a problem that scum was generated.

[0008]

SUMMARY OF THE INVENTION It is an object of the present invention to provide foaming, excellent foaming and detergency, low irritation, no slimyness, no squeaky feeling and no crispness at the time of rinsing and after washing, and a refreshing feeling of use. It is an object of the present invention to provide a detergent composition which has no scum and has no scum.

[0009]

As a result of intensive studies, the present inventors have found that an amide carboxylic acid type surfactant and / or a dicarboxylic acid imide type surfactant having a specific structure can be combined with another surfactant. By combining, it has good detergency, excellent foaming, no irritation to the skin, etc.,
It is possible to obtain a detergent composition having no slimy feeling or squeaky feeling in the feeling of use after washing, and also to have a refreshing feeling of use, and also by combining it with a polyvalent carboxylic acid or a salt thereof. It is possible to obtain a detergent composition having low skin irritation, excellent foaming, foam quality, and excellent refreshing feeling at the time of rinsing, and further, extremely low scum generation. By being blended, it is possible to obtain a detergent composition having low skin irritation, excellent foaming properties, long lasting foam, a refreshing feeling after rinsing or after washing, and a feeling excellent in use during washing, such as a feeling of use during washing. And completed the present invention.

That is, according to the present invention, there is provided a detergent composition comprising the following components (A) and (B). (A) at least one selected from the group consisting of an amide carboxylic acid represented by the following general formula (1) or a salt thereof, and a dicarboxylic imide represented by the following general formula (2): (B) a surfactant

Embedded image (Wherein, R ^{1 is} a straight-chain or branched-chain alkyl group, alkenyl group or hydroxyalkyl group having 8 to 22 carbon atoms A: a hydrogen atom, a straight-chain or branched alkyl group or hydroxyalkyl group having 1 to 6 carbon atoms) Or 4 carbon atoms
To 7 sugar residues or sugar alcohol residues M: hydrogen atom, alkali metal ion, monovalent alkali earth metal ion, ammonium ion or organic ammonium ion

Embedded image (Wherein R ¹ and X are the same as described above) Further, according to the present invention, there is provided a detergent composition comprising the following components (A) and (C). (A) at least one member selected from the group consisting of an amide carboxylic acid represented by the following general formula (1) or a salt thereof, and a dicarboxylic acid imide represented by the following general formula (2); seed

Embedded image (Wherein R ¹ , A, X and M are the same as above)

Embedded image (Wherein R ¹ and X are the same as described above) Further, according to the present invention, there is provided a cleaning composition comprising the following components (A) and (D). (A) at least one selected from the group consisting of an amide carboxylic acid represented by the following general formula (1) or a salt thereof, and a dicarboxylic imide represented by the following general formula (2): (D) at least one type of a cationized polymer

Embedded image (Wherein R ¹ , A, X and M are the same as above)

Embedded image (Wherein, R ¹ and X are the same as described above)

[0011]

BEST MODE FOR CARRYING OUT THE INVENTION The cleaning composition of the present invention comprises (A)
As the component, an amide carboxylic acid represented by the general formula (1) or a salt thereof, or a dicarboxylic imide represented by the general formula (2) is used, and the component (B) is commonly used in a detergent. It contains a combination of a surfactant or a combination of a sequestering agent as the component (C), and further contains a combination of a cationized polymer as the component (D). The cleaning composition of the present invention can appropriately contain components commonly used in cleaning agents, and can be used as various cleaning agents. In the present invention, the component (A) includes:
It goes without saying that two or more of the component (B), the component (C), and the component (D) can be combined.

Hereinafter, each component of the cleaning composition of the present invention will be described in more detail. First, the amide carboxylic acid represented by the above general formula (1) or a salt thereof of the component (A), which is an important component of the cleaning composition of the present invention, and the dicarboxylic acid represented by the above general formula (2) As for the imide, in the general formulas (1) and (2), R ¹
Is a linear or branched alkyl, alkenyl, or hydroxyalkyl group having 8 to 22 carbon atoms, preferably 8 to 18 carbon atoms, and specifically, for example, an octyl group, a decyl group, a lauryl group, Examples include a myristyl group, a hexadecyl group, an octadecyl group, a behenyl group, an oleyl group, and the like, and a decyl group, a lauryl group, and a myristyl group are particularly preferable. If the carbon number of R ¹ is less than 8, it is inferior to the surfactant, and if it has more than 22, the dispersibility of the solution is poor.

The general formulas (1) and (2)
In the above, A is a hydrogen atom, a linear or branched alkyl or hydroxyalkyl group having 1 to 6 carbon atoms, or a sugar residue or sugar alcohol residue having 4 to 7 carbon atoms. Specific examples of the above alkyl group and hydroxyalkyl group include a methyl group, an ethyl group, a hydroxyoethyl group, and a hydroxypropyl group. 6 carbon atoms
If it exceeds, dispersibility in a solution is not good. Specific examples of the sugar residue or sugar alcohol residue include a 1-deoxysorbicyl group, a 1-deoxyerythrityl group, a 1-deoxyxylytyl group, and a 1-deoxy-4-glycoside.
Examples thereof include a sorbitol group, a 1-deoxymannityl group, a 1-deoxyarabityl group, and a 1-deoxygalactyl group.

Further, the general formulas (1) and (2)
In, X _{is, -CH (OH) CH 2 -} , - CH 2 CH
(OH) -, - CH ( OH) CH (OH) -, - CH 2
—CH ₂ —.

Further, in the general formula (1), M is a hydrogen atom, an alkali metal ion such as sodium or potassium, an alkaline earth metal ion equivalent to monovalent, an ammonium ion or an organic ammonium ion.

Specific examples of the amide carboxylic acid represented by the above general formula (1) and the salt thereof of the component (A) of the present invention, and the dicarboxylic imide represented by the above general formula (2) include mono-carboxylic acid. N-lauryl malic acid potassium salt, mono-N-lauryl malic acid amide, mono-N-decyl malic acid potassium salt, mono-N-myristyl malic acid potassium salt, mono-N-decyl malic acid amide, mono-N -Ammonium decyl tartaramide, mono-N-decyl tartaramide, potassium mono-N-laurylsuccinate, mono-N-lauryl malamide, mono-N-myristyl malamide, mono-N
-Decyl malic imide, mono-N-decyl tartarimide, mono-N-decyl tartarimide and the like.
The optical isomers may be used alone or in a racemic form.

The amide carboxylate and the dicarboxylic imide of the component (B) used in the present invention are represented by, for example, an amine represented by RANH and HOOC-X-COOH as shown in the following reaction formula. The dicarboxylic acid can be obtained from an inexpensive raw material by reacting it with a dicarboxylic acid without a solvent or using an appropriate solvent without a catalyst or in the presence of a basic catalyst. Further, by neutralization thereafter, an amide carboxylate can be obtained in a usual manner.

[0018]

[Table 1]

Specific examples of the raw material amine include octylamine, decylamine, dodecylamine, tetradecylamine, hexadecylamine, octadecylamine,
Primary amines such as behenylamine, or octylmethylamine, decylmethylamine, dodecylmethylamine, dodecylethylamine, dodecylhydroxyethylamine, tetradecylmethylamine, hexadecylmethylamine, octadecylmethylamine, tetradecylhydroxypropylamine, N -Dodecyl-N-1-deoxysorbytylamine, N-dodecyl-N-1-deoxyerythritylamine, N-dodecyl-N-1-deoxyxylytylamine, N-tetradecyl-N-1-deoxy-4- Glucoside-sorbicylamine, N-dodecyl-N-1-deoxymannitylamine, N-dodecyl-N-1-deoxyarabicylamine, N-dodecyl-
Secondary amines such as N-1-deoxygalactylamine are exemplified.

Specific examples of the starting dicarboxylic acid are tartaric acid, malic acid and succinic acid.

Next, as the component (B) of the detergent composition of the present invention, an anionic surfactant, a nonionic surfactant,
What is usually used for a detergent, such as an amphoteric surfactant, can be used. Examples of the anionic surfactant (B) include a sulfonic acid type or sulfate ester type anionic surfactant, a carboxylic acid type anionic surfactant, and a phosphate ester type anionic surfactant. As the sulfonic acid type or sulfate ester type anionic surfactant, olefin sulfonic acid type, alkane sulfonic acid type, α-sulfofatty acid ester type, sulfosuccinic acid type, isethionate type, taurate type, amide ether sulfonic acid type,
Surfactants such as alkyl or alkenyl sulfates and alkyl ether sulfates are exemplified. Preferred examples include sulfosuccinic acids, isethionates, and taurates. Examples of the carboxylic acid type anionic surfactant include higher fatty acid salts, N acyl amino acid salts, N acyl N alkyl amino acid salts, alkyl ether carboxylate salts, amide ether carboxylate salts, monoalkylamide polyvalent carboxylate salts, and the like. . Preferred examples include N acyl N-alkyl amino acid salts, N acyl amino acid salts, and higher fatty acid salts. Preferred carboxylic acid-type anionic surfactants are preferred because of their lower impact on the environment.

The nonionic surfactant of the component (B) is represented by the following general formula:

Embedded image (Where R^TwoIs saturated or unsaturated having 1 to 22 carbon atoms
Represents a straight-chain or branched-chain hydrocarbon;
And m represents a number from 0 to 30. However, l + m ≧ 1)
Monoacylglycerin, a nonionic surfactant represented by
Surfactants, alkyl polyglycosides, alkyl glycols
Coside fatty acid ester, alkyl glucamide, sugar esthetic
And sugar-based surfactants such as

As the amphoteric surfactant (B), carboxybetaine surfactant, amidobetaine surfactant, sulfobetaine surfactant, hydroxysulfobetaine surfactant, amidosulfobetaine surfactant And a surfactant such as an amidohydroxysulfobetaine-based surfactant and a phosphobatan-based surfactant.

As other surfactants of the component (B), amine oxide type and fatty acid amide derivative type surfactants are used. The amine oxide has the following general formula:

Embedded image (Where R^ThreeIs saturated or unsaturated having 1 to 22 carbon atoms
A straight or branched chain hydrocarbon;^FourAnd R^FiveIs
Each represents an alkyl group having 1 to 3 carbon atoms. )
Things. Also as the fatty acid amide derivative
Is the following general formula

Embedded image 中 where R⁶Represents an alkyl group having 1 to 22 carbon atoms;⁷
And R⁸Are the same or different and each represent a hydrogen atom,
3 alkyl groups, hydroxyalkyl groups having 1 to 3 carbon atoms
Or,-(CH_TwoCH_TwoO)_mH and m represent a number of 2 to 4
You. And those represented by｝.

In the cleaning composition of the present invention, the mixing ratio of the components (A) and (B) is such that A / B = 1/10 by weight.
To 100/1, particularly preferably 1/80 to 50/1. The total amount of the components (A) and (B) differs depending on the dosage form of the cleaning composition. Generally speaking, 1 to 50% by weight in a liquid composition and 10 to 10% in a powdery composition.
70% by weight, 1 to 60% by weight in the gel composition,
In a solid composition, 40 to 95% by weight is appropriate.

Next, as the sequestering agent which is the component (C) of the detergent composition of the present invention, for example, a polyvalent carboxylic acid or a salt thereof, specifically, succinic acid, maleic acid,
Examples thereof include low molecular weight polyvalent carboxylic acids such as fumaric acid, malic acid, tartaric acid, citric acid, and diglycolic acid, and alkali metal, ammonium, or organic ammonium salts thereof.

When the above component (C) is used, the amount of the activator comprising the amide carboxylic acid or its salt or its imide derivative as the component (A) varies depending on the form of the composition. Generally speaking, 1 to 70 for liquid compositions
The appropriate range is 1 to 40% by weight for a powdery composition, 1 to 60% by weight for a gel composition, and 1 to 95% by weight for a solid composition.

The amount of component (C) is from 0.01 to 20.
% Is suitable, preferably 0.1 to 10% by weight.

Next, as the cationized polymer which is the component (D) of the detergent composition of the present invention, for example, dimethyldiallylammonium chloride / allylamide copolymer, cationized cellulose, cationized guar gum, dimethylaminohydroxy adipate Propyldiethyltriariamine copolymer, polyethyleneimine, polyethylene glycol, epichlorohydrin, tallow alkylamine,
And dipropylene triamine condensate. Of these, dimethyldiallylammonium chloride / acrylamide copolymer and cationized cellulose are preferred.

When the above component (D) is used, the compounding amount of the activator composed of the amide carboxylic acid or a salt thereof or the imide derivative thereof as the component (A) is 0.5 to 0.5% in the detergent composition.
It is preferably 40% by weight, particularly 1 to 30% by weight.
Is preferred. If it is less than 0.5% by weight, foaming is poor, and
If the amount is more than about 10% by weight, a favorable feeling of use for washing cannot be obtained.

The amount of the component (D) is suitably 0.01 to 5.0% by weight, preferably 0.05 to 3.0% by weight in the detergent composition. If it is less than 0.01%, the persistence of the foam is poor, and if it exceeds 5.0% by weight, the rinsing property is poor.

In the cleaning composition of the present invention, the component (A) may contain two or more of the components (B), (C) and (D) in combination. The compounding ratio and amount of each component at this time are the same as described above, that is, the weight ratio of the component (A) to the component (B) is A / B
= 1/10 to 100/1, the total amount of components (A) and (B) generally ranges from 1 to 50 in a liquid composition.
%, Preferably 10 to 70% by weight in a powder composition, 1 to 60% by weight in a gel composition, and 40 to 95% by weight in a solid composition. Also,
The compounding amount of the component (C) is preferably 0.01 to 20% by weight, and the compounding amount of the component (D) is preferably 0.01 to 5.0% by weight.

In the present invention, in addition to the component (A), the component (B), the component (C), and the component (D), a known detergent component usually used for a detergent can be blended. Such known detergent components include, for example, builders such as zeolite, sodium (potassium) carbonate, sodium silicate, and polyacrylate, humectants such as (poly) glycerin and sorbitol, methylcellulose, and polyoxyethylene glycol Viscosity modifiers such as stearate, ethanol, (poly) ethylene glycol and (poly) propylene glycol; preservatives such as methylparaben and butylparaben; anti-inflammatory agents such as dipotassium glycyrrhizinate and tocopherol acetate; other antioxidants; Absorbent, fungicide, water-soluble polymer compound, water-soluble inorganic salt, pH
Organic and inorganic compounds used in the preparation, esters,
Examples include amide-based pearlescent agents, pigments, and fragrances. These detergent components can be blended in any ratio as long as the effects of the present invention are not impaired.

The cleaning composition of the present invention can be produced by a conventional method and can be in the form of a paste, gel, liquid, or solid, and is suitable as a body cleaning agent.

[0035]

DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be specifically described below based on embodiments.

Examples 1 to 30, Comparative Examples 1 to 17 <Combined Use of Components (A) and (B)> The cleaning performance of each cleaning composition shown in Tables 2, 3 and 4 is as follows. The evaluation was made according to test methods and evaluation criteria. Tables 2 and 3 show the results.
It is shown in Table 4. [Foaming power] Prepare a 50-fold diluted aqueous solution of each detergent composition with 3 times hard water, put 20 ml of the solution in a 100 ml Epton tube, keep at 40 ° C, and determine the foam height (ml) after shaking. The foaming power was evaluated. ◎: 85 ml or more 〜 to ；: 75 ml to less than 85 ml ○: 65 ml to less than 75 ml △: 50 ml to less than 65 ml ×: less than 50 ml

[Bubble performance] and [Refreshing feeling upon rinsing] A 5-fold diluted aqueous solution of each cleaning composition was prepared, and 5 ml of the solution was prepared.
Was taken, the foam performance by hand washing and the refreshing feeling upon rinsing were evaluated according to the following criteria, and the presence or absence of a feeling of tightness was further evaluated. Evaluation criteria Foam performance during washing ◎; fairly good ○; slightly good △; good ×; not good Refreshing feeling at the time of rinsing ◎; fairly refreshing ○; refreshing △;

[0038]

[Table 2]

[0039]

[Table 3]

[0040]

[Table 4]

Examples 31 to 40, Comparative Example 8 <Combined use of components (A) and (C)>
The above-mentioned performance tests were performed on the cleaning compositions of Examples 31 to 40 and the cleaning composition of Comparative Example 8. Table 5 shows the results. The performance tests in each of the examples and comparative examples were performed according to the following test methods, and the evaluation was made according to the following criteria. [Amount of scum] The detergent composition was prepared by adding a surfactant concentration of 0.5.
% And diluted with hard water three times, and the turbidity of the aqueous solution was observed and evaluated.

[0042]

[Table 5]

Examples 41 to 50 and Comparative Examples 19 to 22 <Combined Use of Components (A) and (D)>
Detergent compositions of Examples 41 to 50 and Comparative examples 19 to 2
The above-described performance test was performed on the detergent composition of No. 2.
Table 6 shows the results.

Various performances were evaluated according to the following test methods. [Feeling of use] Ten panelists washed the body of each cleaning composition, and the sensory evaluation was performed. For the evaluation, the average value was calculated according to the following criteria. The average value was 4.5 or more, ◎, 3.5 to 4.4, 、, 2.5 to 3.5, 2.4.
The following cases were evaluated as x. -Refreshing feeling 5: Refreshing feeling 4: Somewhat refreshing feeling 3: Normal 2: Not refreshing feeling 1: No refreshing feeling-Skin sliding feeling 5: Good sliding of skin 4: Good sliding of skin 3: Normal 2: Slippage of the skin is slightly bad 1: Slippage of the skin is bad

[Skin irritation] For each detergent composition, a panel of 5 men and women, a total of 10 panelists, was used to convert one of the left and right forearms into a 1% by weight sample concentration aqueous solution at 40 ° C.
The operation of immersing the other forearm in water at the same temperature once a day,
The test was performed for two consecutive days, and the difference between the rough skin conditions of the left and right forearms was visually determined. The evaluation criteria at this time are as follows. ：: Skin roughness remarkably weak 0 to 1 person out of 10 had rough skin on the sample side. ：: Slightly rough skin property 2 to 4 persons out of 10 had rough skin on the sample side. Δ: Severe skin roughness 5 to 7 out of 10 subjects showed rough skin on the sample side. ×: Extremely rough skin 8 to 10 persons out of 10 had rough skin on the sample side.

[Measurement of Foaming Amount and Persistence of Foam] For each of the detergent compositions, 20 ml (25 ° C.) of a 5% solution was added to 100
ml cylinder, shake 20 times for 10 seconds, 3
The foam volume (ml) after 0 seconds was measured. Further, the volume (ml) of the foam after standing for 1 minute was measured to determine the persistence of the foam. Evaluation criteria ◎: Foam volume of 80 ml or more ：: Foam volume of 65 ml or more and less than 80 ml Δ: Foam volume of 40 ml or more and less than 65 ml ×: Foam volume of less than 40 ml

[Creamy property of foam] Ten panelists washed hands of each cleaning composition, and the sensory evaluation was performed. In the evaluation, the average value was calculated according to the following criteria, and the average value was 4.5 or more: ◎, 3.5 to 4.4: ○, 2.5 to
3.5 was evaluated as Δ, and the case of 2.4 or less was evaluated as ×. -Evaluation criteria 5: Creamy 4: Slightly creamy 3: Normal 2: Not slightly creamy 1: Not creamy

[0048]

[Table 6]

Example 51 [Body shampoo]% by weight (1) lauryl malate amide triethanolamine 10.0 (2) myristyl malate amide triethanolamine 10.0 (3) kayacryl resin 0.1 (4) Propylene glycol 10.0 (5) Sorbitol 3.0 (6) Ethylenediaminetetraacetate 0.15 (7) Fragrance 0.2 (8) Purified water balance According to the above composition, the above (1) to (6) are added to heated water. After dissolving the components and cooling, the above-mentioned component (7) was added to prepare a body shampoo composition. When the body was washed with the obtained body shampoo composition, it was found that the foam was excellent in creaminess and foam retention, and that the skin was smooth and refreshed from rinsing to drying, and was excellent in usability.

Example 52 [Gel-like facial cleanser]% by weight (1) Sodium lauryl malate 10.0 (2) Sodium myristyl malate 10.0 (3) Sodium palmityl malate 6.0 (4) ) Leogard MLP 0.4 (5) Propylene glycol 10.0 (6) Ethylenediaminetetraacetate 0.15 (7) Fragrance 0.2 (8) Purified water balance According to the above composition, heated water (1) to (6) )) After dissolving the components and cooling, the above-mentioned component (7) was added to prepare a gel-like face wash. When the face was washed with the obtained facial cleansing composition, it was found that the foam was excellent in creaminess and retention of foam, and that the skin was refreshed smoothly from rinsing to drying, and that it was excellent in usability.

Example 53 [Creamy facial cleanser]% by weight (1) Sodium lauryl malate 2.0 (2) Sodium myristyl malate 10.0 (3) Sodium palmityl malate 5.0 (4) ) Sodium stearyl malamide 3.0 (5) Leogard MLP 0.1 (6) 1,3-butylene glycol 12.0 (7) Sorbitol 5.0 (8) Benzoate 1.0 (9) Fragrance 0 2.2 (10) Purified water balance According to the above composition, the components (1) to (8) were dissolved in heated water, and after cooling, the component (9) was added to prepare a creamy face wash. When the face was washed with the obtained facial cleansing composition, the creamy properties of the foam and the foam were excellent, and the skin slipped well from rinsing to drying,
Excellent usability.

Example 54 [Liquid facial cleanser]% by weight (1) lauryl malate amide diethanolamine 8.0 (2) myristyl malate amide diethanolamine 3.0 (3) laurate diethanolamine 3.0 (4) kayacryl resin 0.1 (5) Propylene glycol 10.0 (6) Hydroxyethane diphosphonic acid 0.2 (7) Fragrance 0.5 (8) Purified water balance According to the above composition, heat water (1) to (6) After dissolving the components and cooling, the above component (7) was added to prepare a liquid face wash. When the face was washed with the obtained facial cleansing composition, it was found that the foam was excellent in creaminess and retention of foam, and that the skin was refreshed smoothly from rinsing to drying, and that it was excellent in usability.

Example 55 [Shampoo]% by weight (1) Lauryl malate amide triethanolamine 10.0 (2) Lauroyl-N-glutamic acid triethanolamine 7.0 (3) Lauryl dimethylamine oxide 3.0 (4) ) Hydroxypropyl methylcellulose 0.3 (5) Leogard MLP 1.0 (6) Propylene glycol 10.0 (7) Ethylenediaminetetraacetate 0.2 (8) Fragrance 0.9 (9) Purified water balance According to the above composition, The components (1) to (7) were dissolved in heated water, and after cooling, the component (8) was added to prepare a shampoo composition. When the hair was washed with the obtained shampoo composition, the foam was excellent in creaminess and foam retention,
From the time of rinsing to the time of drying, the hair was refreshing and slippery, and was excellent in usability.

Similarly, specific examples of various dosage forms are shown. Example 56 [Body shampoo]% by weight Potassium mono-N-lauryl malate amide 10.0 Fatty acid potassium 5.0 Coconut oil fatty acid diethanolamide 5.0 Dodecyldimethylamine oxide 3.0 Propylene glycol 5.0 Fragrance Trace ion exchange Water balance

Example 57 [Shampoo]% by weight mono-N-lauryl malic acid amide triethanolamine salt 12.0 coconut oil fatty acid amide propyl betaine 4.0 coconut oil fatty acid diethanolamide 4.0 cationized cellulose 0.5 ethanol 2.5 Fragrance 0.5 Deionized water balance

Example 58 [Cleaning agent for kitchen]% by weight of potassium salt of mono-N-lauryl malic acid amide 13.0 LES-Na (3EO) 5.0 Dodecyl dimethylamine oxide 3.0 Diethanolamide laurate 2.5 Ethanol 4.0 Fragrance Trace ion exchange water Balance

Example 59 [Soap]% by weight Mono-N-lauryl malic acid amide sodium salt 15.0 Mono-N-myristyl malic acid amide sodium salt 10.0 Mono-N-palmityl malic acid amide sodium salt 5 Mono-N-oleyl malic acid sodium salt 30.0 Titanium dioxide 0.2 EDTA 0.1 Fragrance 1.0 Ion exchange water Balance

Example 60 [Shampoo]% by weight mono-N-lauryl malic imide 12.0 Coconut oil fatty acid amide propyl betaine 4.0 Coconut oil fatty acid diethanolamide 4.0 Cationized cellulose 0.5 Ethanol 2.5 Water Potassium oxide 2.4 Fragrance 0.5 Deionized water Balance

Example 61 [Kitchen detergent]% by weight mono-N-lauryl malate imide 13.0 LES-Na (3EO) 5.0 dodecyldimethylamine oxide 3.0 lauric acid diethanolamide 2.5 ethanol 4 2.0 Potassium hydroxide 2.6 Fragrance Trace amount Deionized water Balance

Example 62 [Soap]% by weight Mono-N-laurylmalimide 13.0 Mono-N-myristylmalimide 8.5 Mono-N-palmitylmalimide 30.0 Mono-N-oleyl Malic imide 27.0 Titanium dioxide 0.2 Sodium hydroxide 9.4 EDTA 0.1 Fragrance 1.0 Ion exchange water Balance The above body shampoo, shampoo, detergent for kitchen,
All the soaps had good foaming and were excellent in refreshing feeling at the time of rinsing and after rinsing.

[0061]

The cleaning composition according to the first aspect is excellent in detergency, foaming power and foaming performance, and is excellent in rinsing feeling (for example, excellent in refreshing feeling and no flat feeling). It is mild and mild. The detergent composition according to the second aspect is excellent in foaming and foam quality, has high detergency, is excellent in a refreshing feeling upon rinsing, is mild on the skin, and does not generate scum. The cleaning composition of claim 3 is not only less irritating to skin and hair, but also
It is excellent in foam quality and foam persistence, and has good skin and hair feel after washing, and is suitable as a skin and hair cleansing agent. In addition, these cleaning compositions are appropriately blended with other components that are usually blended in a cleaning agent,
Various types of detergents such as body shampoos, shampoos, kitchen detergents, soaps, etc. These detergents also have a detergency, a foaming power, a foaming performance, a feeling of use during rinsing and after washing, etc. Excellent and mild.

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[Procedure amendment]

[Submission date] August 29, 1997

[Procedure amendment 1]

[Document name to be amended] Statement

[Correction target item name] Claim 2

[Correction method] Change

[Correction contents]

Embedded image (Wherein, R ¹ , A, X, and M are the same as described above)

Embedded image (Wherein R ¹ and X are the same as described above)

[Procedure amendment 2]

[Document name to be amended] Statement

[Correction target item name] Claim 3

[Correction method] Change

[Correction contents]

Embedded image (Wherein, R ¹ , A, X, and M are the same as described above)

Embedded image (Wherein R ¹ and X are the same as described above)

[Procedure amendment 3]

[Document name to be amended] Statement

[Correction target item name] 0013

[Correction method] Change

[Correction contents]

The general formulas (1) and (2)
In the above, A is a hydrogen atom, a linear or branched alkyl or hydroxyalkyl group having 1 to 6 carbon atoms, or a sugar residue or sugar alcohol residue having 4 to 7 carbon atoms. Specific examples of the alkyl group and the hydroxyalkyl group include a methyl group, an ethyl group, a hydroxyethyl group ,
And a hydroxypropyl group. If the number of carbon atoms exceeds 6, dispersibility in a solution is not good. Specific examples of the above sugar residue or sugar alcohol residue include a 1-deoxysorbicyl group, a 1-deoxyerythrityl group, a 1-deoxyxylicyl group, a 1-deoxy-4-glycoside-sorbicyl group, Examples include a deoxymannityl group, a 1-deoxyarabityl group, and a 1-deoxygalactyl group.

[Procedure amendment 4]

[Document name to be amended] Statement

[Correction target item name] 0021

[Correction method] Change

[Correction contents]

Next, as the component (B) of the detergent composition of the present invention, an anionic surfactant, a nonionic surfactant,
What is usually used for a detergent, such as an amphoteric surfactant, can be used. Examples of the anionic surfactant (B) include a sulfonic acid type or sulfate ester type anionic surfactant, a carboxylic acid type anionic surfactant, and a phosphate ester type anionic surfactant. As the sulfonic acid type or sulfate ester type anionic surfactant, olefin sulfonic acid type, alkane sulfonic acid type, α-sulfofatty acid ester type, sulfosuccinic acid type, isethionate type, taurate type, amide ether sulfonic acid type,
Surfactants such as alkyl or alkenyl sulfates and alkyl ether sulfates are exemplified. Preferred examples include sulfosuccinic acids, earthionates, and taurates. Examples of the carboxylic acid type anionic surfactants, higher fatty acid salts, N - acylamino acid salts, N - A <br/> Sil - N - alkylamino acid salts, alkylether carboxylic acid salts, amide ether carboxylates, mono -N - alkylamide polycarboxylic acid salts, and the like. Preferred examples include N - acyl - N-alkyl amino acid salts,
N - acyl amino acid salts and higher fatty acid salts. Preferred carboxylic acid-type anionic surfactants are preferred because of their lower impact on the environment.

[Procedure amendment 5]

[Document name to be amended] Statement

[Correction target item name] 0029

[Correction method] Change

[Correction contents]

Next, as the (D) a cationic polymer which is a component of the detergent composition of the present invention, for example, dimethyl diallyl ammonium-a click Riruamido chloride copolymer, cationized cellulose, cationized guar gum, dimethyl adipate Aminohydroxypropyl diethylene tria
Min copolymers , polyethyleneimine, polyethylene glycol / epichlorohydrin / tallow alkylamine / dipropylenetriamine condensate, and the like. Of these, dimethyldiallylammonium chloride / acrylamide copolymer and cationized cellulose are preferred.

 ──────────────────────────────────────────────────の Continued on the front page (72) Inventor Hiromi Shimizu 1-3-7 Honjo, Sumida-ku, Tokyo Inside Lion Corporation (72) Inventor Rieko Yamagishi 1-3-7 Honjo, Sumida-ku, Tokyo Inside Rion Co., Ltd. (72) Inventor Ryuta Tsubagawa 1-3-7 Honjo, Sumida-ku, Tokyo Inside Rion Co., Ltd. (72) Inventor Seiji Ito 1-3-7, Honjo, Sumida-ku, Tokyo Rion Inside the corporation

Claims (3)

[Claims] 1. A cleaning composition comprising the following components (A) and (B). (A) at least one selected from the group consisting of an amide carboxylic acid represented by the following general formula (1) or a salt thereof, and a dicarboxylic imide represented by the following general formula (2): (B) a surfactant (Wherein, R ^{1 is} a straight-chain or branched-chain alkyl group, alkenyl group or hydroxyalkyl group having 8 to 22 carbon atoms A: a hydrogen atom, a straight-chain or branched alkyl group or hydroxyalkyl group having 1 to 6 carbon atoms) Or 4 carbon atoms
To 7 sugar residues or sugar alcohol residues M: hydrogen atom, alkali metal ion, monovalent alkaline earth metal ion, ammonium ion or organic ammonium ion) (Wherein, R ¹ and X are the same as described above) 2. A cleaning composition comprising the following components (A) and (B). (A) at least one member selected from the group consisting of an amide carboxylic acid represented by the following general formula (1) or a salt thereof, and a dicarboxylic acid imide represented by the following general formula (2); Species 1 (Wherein R ¹ , A, X, and M are the same as described above). (Wherein, R ¹ and X are the same as described above) 3. A cleaning composition comprising the following components (A) and (B). (A) at least one selected from the group consisting of an amide carboxylic acid represented by the following general formula (1) or a salt thereof, and a dicarboxylic imide represented by the following general formula (2): (D) at least one type of a cationized polymer Embedded image (Wherein R ¹ , A, X, and M are the same as described above). (Wherein, R ¹ and X are the same as described above)