JPH09509888A - イオン性液体 - Google Patents
イオン性液体Info
- Publication number
- JPH09509888A JPH09509888A JP8518427A JP51842796A JPH09509888A JP H09509888 A JPH09509888 A JP H09509888A JP 8518427 A JP8518427 A JP 8518427A JP 51842796 A JP51842796 A JP 51842796A JP H09509888 A JPH09509888 A JP H09509888A
- Authority
- JP
- Japan
- Prior art keywords
- lead
- ionic liquid
- solution
- cation
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002608 ionic liquid Substances 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 claims abstract description 17
- -1 cation halide Chemical class 0.000 claims abstract description 15
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- 239000002244 precipitate Substances 0.000 claims abstract description 9
- 150000001450 anions Chemical class 0.000 claims abstract description 7
- 150000004820 halides Chemical class 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 20
- 150000001768 cations Chemical class 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 claims description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims description 3
- JDIIGWSSTNUWGK-UHFFFAOYSA-N 1h-imidazol-3-ium;chloride Chemical compound [Cl-].[NH2+]1C=CN=C1 JDIIGWSSTNUWGK-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- 239000012266 salt solution Substances 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 150000001805 chlorine compounds Chemical class 0.000 claims 1
- 150000003891 oxalate salts Chemical group 0.000 claims 1
- REJGOFYVRVIODZ-UHFFFAOYSA-N phosphanium;chloride Chemical class P.Cl REJGOFYVRVIODZ-UHFFFAOYSA-N 0.000 claims 1
- 238000005804 alkylation reaction Methods 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 230000029936 alkylation Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 238000006317 isomerization reaction Methods 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 description 5
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- STCBHSHARMAIOM-UHFFFAOYSA-N 1-methyl-1h-imidazol-1-ium;chloride Chemical compound Cl.CN1C=CN=C1 STCBHSHARMAIOM-UHFFFAOYSA-N 0.000 description 2
- XALWTPNRISPPIZ-UHFFFAOYSA-O 1-methyl-1h-imidazol-1-ium;nitrate Chemical compound [O-][N+]([O-])=O.C[N+]=1C=CNC=1 XALWTPNRISPPIZ-UHFFFAOYSA-O 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- USJRLGNYCQWLPF-UHFFFAOYSA-N chlorophosphane Chemical group ClP USJRLGNYCQWLPF-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- AOJFQRQNPXYVLM-UHFFFAOYSA-N pyridin-1-ium;chloride Chemical group [Cl-].C1=CC=[NH+]C=C1 AOJFQRQNPXYVLM-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
- B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
- B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
- B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
- B01J31/0287—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing atoms other than nitrogen as cationic centre
- B01J31/0288—Phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/52—Isomerisation reactions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/077—Ionic Liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9425105.5A GB9425105D0 (en) | 1994-12-13 | 1994-12-13 | Ionic liquids |
| GB9425105.5 | 1994-12-13 | ||
| PCT/GB1995/002781 WO1996018459A1 (en) | 1994-12-13 | 1995-11-28 | Ionic liquids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH09509888A true JPH09509888A (ja) | 1997-10-07 |
Family
ID=10765851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8518427A Pending JPH09509888A (ja) | 1994-12-13 | 1995-11-28 | イオン性液体 |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0743878A1 (xx) |
| JP (1) | JPH09509888A (xx) |
| CN (1) | CN1140422A (xx) |
| AU (1) | AU3986495A (xx) |
| CA (1) | CA2182894A1 (xx) |
| FI (1) | FI963134L (xx) |
| GB (1) | GB9425105D0 (xx) |
| NO (1) | NO963294D0 (xx) |
| WO (1) | WO1996018459A1 (xx) |
| ZA (1) | ZA9510411B (xx) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7605271B2 (en) | 2005-03-29 | 2009-10-20 | Dai-Ichi Kogyo Seiyaku Co., Ltd | Superhigh purity ionic liquid |
| JP2012518524A (ja) * | 2009-02-23 | 2012-08-16 | ビーエーエスエフ ソシエタス・ヨーロピア | 蒸留助剤の使用下でのイオン性液体の蒸留 |
| JP2013538256A (ja) * | 2010-07-30 | 2013-10-10 | シェブロン ユー．エス．エー． インコーポレイテッド | 炭化水素フィードの処理 |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9616264D0 (en) * | 1996-08-02 | 1996-09-11 | British Nuclear Fuels Plc | Reprocessing irradiated fuel |
| GB9802852D0 (en) * | 1998-02-11 | 1998-04-08 | British Nuclear Fuels Plc | Nuclear fuel reprocessing |
| GB9820698D0 (en) * | 1998-09-24 | 1998-11-18 | Bp Chem Int Ltd | Ionic liquids |
| GB9821628D0 (en) * | 1998-10-06 | 1998-11-25 | Bp Chem Int Ltd | Ionic salts |
| US6998152B2 (en) | 1999-12-20 | 2006-02-14 | Micron Technology, Inc. | Chemical vapor deposition methods utilizing ionic liquids |
| GB0008707D0 (en) | 2000-04-07 | 2000-05-31 | Bp Chem Int Ltd | Imidazole carbenes |
| FR2808268B1 (fr) | 2000-04-26 | 2002-08-30 | Atofina | Liquides ioniques derives d'acides de lewis a base de titane, niobium, tantale, etain ou antimoine, et leurs applications |
| US6339182B1 (en) * | 2000-06-20 | 2002-01-15 | Chevron U.S.A. Inc. | Separation of olefins from paraffins using ionic liquid solutions |
| EP1346768B1 (en) | 2002-03-22 | 2005-08-17 | Haldor Topsoe A/S | Process for paraffin hydrocarbon isomerization and composite catalyst therefore, comprising ionic liquid and metal salt additive |
| FR2843110B1 (fr) * | 2002-08-05 | 2004-09-24 | Inst Francais Du Petrole | Procede d'isomerisation d'olefines |
| CN100424259C (zh) * | 2002-12-12 | 2008-10-08 | 中国科学院化学研究所 | 一种含不饱和双键的室温离子液体及制备方法和应用 |
| DE10333239A1 (de) | 2003-07-21 | 2005-03-10 | Basf Ag | Verfahren zur Herstellung von gereinigten 1,3- substituierten Imidazoliumsalzen |
| FR2860170B1 (fr) | 2003-09-29 | 2006-04-21 | Atofina Res | Liquides ioniques pour catalyseurs de polymerisation d'olefines |
| EP1571163A1 (en) | 2004-03-02 | 2005-09-07 | Total Petrochemicals Research Feluy | Ionic liquids as solvents in metallocene catalysis |
| CN100344380C (zh) * | 2004-12-08 | 2007-10-24 | 北京化工大学 | 室温离子液体及其制备方法 |
| DE102005032837A1 (de) * | 2005-07-14 | 2007-02-08 | Merck Patent Gmbh | Verfahren zur Herstellung von Onium-Alkylsulfiten |
| DE102005032836A1 (de) | 2005-07-14 | 2007-01-18 | Merck Patent Gmbh | Verfahren zur Herstellung von Onium-Alkylsulfonaten |
| US7732651B2 (en) | 2006-06-01 | 2010-06-08 | Chevron Oronite Company, Llc | Method of making an alkylated aromoatic using acidic ionic liquid catalyst |
| CN101230041B (zh) * | 2006-09-29 | 2013-04-17 | 亚申科技研发中心（上海）有限公司 | 高纯度离子液体制程及系统 |
| CN100443157C (zh) * | 2006-11-16 | 2008-12-17 | 中国科学院长春应用化学研究所 | 一种微波连续反应设备的应用 |
| CN101337938B (zh) * | 2007-07-04 | 2012-03-21 | 中国纺织科学研究院 | 醋酸盐离子液体的合成方法 |
| DE102008059702A1 (de) | 2008-12-01 | 2010-06-02 | Byk-Chemie Gmbh | Verfahren zur Herstellung rheologisch wirksamer Harnstoffurethane in organischen Salzen |
| ES2524437T3 (es) | 2011-11-29 | 2014-12-09 | Total Research & Technology Feluy | Cromatografía plana con elución en gradiente inverso |
| CN103934023B (zh) * | 2014-04-25 | 2016-02-03 | 中国石油大学(华东) | 用于c5/c6烷烃异构化的离子液体催化剂及其制备和使用方法 |
| CN105203372A (zh) * | 2014-05-26 | 2015-12-30 | 中国科学院大连化学物理研究所 | 样品溶液中离子液体的去除方法 |
| CN105552235B (zh) * | 2015-12-24 | 2017-11-03 | 上海博暄能源科技有限公司 | 一种提高钙钛矿太阳能电池效率的方法 |
| CN110646272B (zh) * | 2019-09-26 | 2022-04-12 | 武汉海关技术中心 | 一种亲水性离子液体的纯化方法 |
| KR102760980B1 (ko) | 2022-03-02 | 2025-02-03 | 피이 주식회사 | 금속 함유 이온성 액체 촉매를 이용한 올레핀계 중합체 제조방법 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3175004A (en) * | 1961-03-24 | 1965-03-23 | Armour & Co | Preparation of quaternary ammonium nitrates |
| JPS5928588A (ja) * | 1982-08-09 | 1984-02-15 | Meidensha Electric Mfg Co Ltd | 亜鉛―臭素二次電池 |
| FR2626572B1 (fr) * | 1988-02-02 | 1990-05-18 | Inst Francais Du Petrole | Procede d'alkylation d'hydrocarbures aliphatiques |
| DE4005762A1 (de) * | 1990-02-23 | 1991-08-29 | Bayer Ag | Trimerisierungskatalysatoren, ein verfahren zu ihrer herstellung und ihre verwendung bei der herstellung von isocyanuratgruppen aufweisenden polyisocyanaten |
| FR2659871B1 (fr) * | 1990-03-20 | 1992-06-05 | Inst Francais Du Petrole | Composition liquide non aqueuse a caractere ionique et son utilisation comme solvant. invention de mm. yves chauvin, dominique commereuc, isabelle guibard, andre hirschauer, helene olivier, lucien saussine. |
| EP0558187B1 (en) * | 1992-02-19 | 1996-04-10 | BP Chemicals Limited | Butene polymers |
-
1994
- 1994-12-13 GB GBGB9425105.5A patent/GB9425105D0/en active Pending
-
1995
- 1995-11-28 CA CA002182894A patent/CA2182894A1/en not_active Abandoned
- 1995-11-28 WO PCT/GB1995/002781 patent/WO1996018459A1/en not_active Application Discontinuation
- 1995-11-28 EP EP95938493A patent/EP0743878A1/en not_active Withdrawn
- 1995-11-28 AU AU39864/95A patent/AU3986495A/en not_active Abandoned
- 1995-11-28 JP JP8518427A patent/JPH09509888A/ja active Pending
- 1995-11-28 CN CN95191587A patent/CN1140422A/zh active Pending
- 1995-12-07 ZA ZA9510411A patent/ZA9510411B/xx unknown
-
1996
- 1996-08-07 NO NO963294A patent/NO963294D0/no unknown
- 1996-08-09 FI FI963134A patent/FI963134L/fi unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7605271B2 (en) | 2005-03-29 | 2009-10-20 | Dai-Ichi Kogyo Seiyaku Co., Ltd | Superhigh purity ionic liquid |
| JP2012518524A (ja) * | 2009-02-23 | 2012-08-16 | ビーエーエスエフ ソシエタス・ヨーロピア | 蒸留助剤の使用下でのイオン性液体の蒸留 |
| JP2013538256A (ja) * | 2010-07-30 | 2013-10-10 | シェブロン ユー．エス．エー． インコーポレイテッド | 炭化水素フィードの処理 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU3986495A (en) | 1996-07-03 |
| FI963134A0 (fi) | 1996-08-09 |
| NO963294L (no) | 1996-08-07 |
| CA2182894A1 (en) | 1996-06-20 |
| ZA9510411B (en) | 1997-06-09 |
| CN1140422A (zh) | 1997-01-15 |
| NO963294D0 (no) | 1996-08-07 |
| FI963134L (fi) | 1996-08-09 |
| WO1996018459A1 (en) | 1996-06-20 |
| EP0743878A1 (en) | 1996-11-27 |
| GB9425105D0 (en) | 1995-02-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH09509888A (ja) | イオン性液体 | |
| Messerle et al. | Multiple metal-carbon bonds. 17. Preparation of monocyclopentadienyl benzylidene complexes of tantalum and the crystal structure of Ta (. eta. 5-C5Me5)(CHPh)(CH2Ph) 2 | |
| JP2002544133A (ja) | ククルビツリルおよび合成方法 | |
| EP0127411B1 (en) | Method of preparing alpha-l-aspartyl-l-phenylalanine methyl ester and its hydrochloride | |
| JP4672657B2 (ja) | ルイス酸を含むイオン液体の混合物 | |
| Butler et al. | The synthesis of α-N, N-dimethyl-1′-diphenylphosphinoferrocenylethylamine and related ligands | |
| CN1214002C (zh) | 羟苯磺酸钙水合物的合成工艺 | |
| JP2003529576A (ja) | 亜硝酸アルキルの製造方法 | |
| JP2002515471A (ja) | ジメチルスルホキシドによる１−クロロ−３，３−ジメチルブタンの酸化による３，３−ジメチルブチルアルデヒドの合成及び精製 | |
| JPS63174954A (ja) | テトラアルキル四級無機酸塩の製造方法 | |
| CN1028169C (zh) | 直接分离巯甲丙脯酸的方法 | |
| KR20020091077A (ko) | α-(2-4-디술포페닐)-Ｎ-ｔｅｒｔ-부틸니트론 및 제약상허용되는 그의 염의 신규 제조 방법 | |
| JPS63192750A (ja) | アルカンスルホンアミドの改良された製造方法 | |
| Johnston et al. | Nucleophilic attack on carbon monoxide in carbonyl phosphine complexes of rhodium (I) and ruthenium (II): a novel route to complexes of rhodium (-I) | |
| Chetcuti et al. | Bis [benzylbis (dimethylamido) molybdenum] and-tungsten (M. tplbond. M) compounds and their reactions with carbon dioxide and 1, 3-diaryltriazenes. A radical difference | |
| CA1144558A (en) | Process for making sodium hydrogen divalproate | |
| JPH04247064A (ja) | ５−スルホイソフタル酸誘導体の製造法 | |
| US5442095A (en) | Catalysts, process for their preparation, and their use | |
| Zvilichovsky | Crystal structure and tautomerism in 4‐phenylisoxazoles with two potential hydroxyl groups at positions 3 and 5 | |
| JP3300623B2 (ja) | テトラアンミン白金（ｉｉ）ジクロライド結晶の製造方法 | |
| US5750716A (en) | Method of producing platinum (II) complex | |
| US6020284A (en) | Preparation of Lucas reagent of enhanced utility and its use in synthesis of cycloaliphatic chlorides | |
| JP2002536426A (ja) | 対称及び非対称の炭酸エステルの製造方法 | |
| CN106660827A (zh) | 制备和/或提纯三氯化钌(iii)的方法 | |
| JPH06100490A (ja) | 光学活性α−メチルコハク酸の製造方法 |