JPH0941221A - Synthetic fiber excellent in comfortableness - Google Patents
Synthetic fiber excellent in comfortablenessInfo
- Publication number
- JPH0941221A JPH0941221A JP19286795A JP19286795A JPH0941221A JP H0941221 A JPH0941221 A JP H0941221A JP 19286795 A JP19286795 A JP 19286795A JP 19286795 A JP19286795 A JP 19286795A JP H0941221 A JPH0941221 A JP H0941221A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- synthetic fiber
- core
- synthetic
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002994 synthetic fiber Polymers 0.000 title claims abstract description 41
- 239000012209 synthetic fiber Substances 0.000 title claims abstract description 41
- 239000000835 fiber Substances 0.000 claims abstract description 69
- 238000010521 absorption reaction Methods 0.000 claims abstract description 42
- 238000003795 desorption Methods 0.000 claims abstract description 5
- 239000002131 composite material Substances 0.000 claims description 22
- 229920006146 polyetheresteramide block copolymer Polymers 0.000 claims description 22
- 229920000728 polyester Polymers 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000004952 Polyamide Substances 0.000 claims description 9
- 229920002647 polyamide Polymers 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 32
- 238000000034 method Methods 0.000 abstract description 22
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 5
- 150000002148 esters Chemical class 0.000 abstract description 5
- 229920000570 polyether Polymers 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000000306 component Substances 0.000 description 25
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- 239000004744 fabric Substances 0.000 description 11
- -1 amide compounds Chemical class 0.000 description 10
- 238000004043 dyeing Methods 0.000 description 10
- 239000008358 core component Substances 0.000 description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 7
- 229920002292 Nylon 6 Polymers 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 6
- 229920001169 thermoplastic Polymers 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 150000001991 dicarboxylic acids Chemical class 0.000 description 5
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 5
- 229920002302 Nylon 6,6 Polymers 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 238000006068 polycondensation reaction Methods 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 238000010036 direct spinning Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000012805 post-processing Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 230000000284 resting effect Effects 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000035900 sweating Effects 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- HASUJDLTAYUWCO-UHFFFAOYSA-N 2-aminoundecanoic acid Chemical compound CCCCCCCCCC(N)C(O)=O HASUJDLTAYUWCO-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 229920000572 Nylon 6/12 Polymers 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 229920002614 Polyether block amide Polymers 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- QFNNDGVVMCZKEY-UHFFFAOYSA-N azacyclododecan-2-one Chemical compound O=C1CCCCCCCCCCN1 QFNNDGVVMCZKEY-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229920003020 cross-linked polyethylene Polymers 0.000 description 1
- 239000004703 cross-linked polyethylene Substances 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- UHHKSVZZTYJVEG-UHFFFAOYSA-N oxepane Chemical compound C1CCCOCC1 UHHKSVZZTYJVEG-UHFFFAOYSA-N 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Multicomponent Fibers (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Artificial Filaments (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は快適性に優れた衣料
用の合成繊維に関するものであり、更に詳しくはインナ
ー、中衣、スポーツ衣料などの衣料用素材に特に好適に
使用することができる優れた吸湿性および吸水性の両性
能を有する合成繊維に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a comfortable synthetic fiber for clothing, and more particularly, it can be suitably used as a material for clothing such as inner garments, inner garments and sports clothing. It also relates to a synthetic fiber having both hygroscopic and water-absorbing properties.
【0002】[0002]
【従来の技術】ポリエステルやポリアミドに代表される
熱可塑性合成繊維は機械的強度、耐薬品性、耐熱性、樹
脂加工のしやすさ等に優れるため、衣料用途や産業用途
などを主体に広く使用されている。しかしながら、これ
らの合成繊維は極めて吸湿性が低いため、インナー、中
衣、スポーツ衣料などのように直接的に肌に触れてある
いは肌側に近い状態で着用される分野に使用する場合に
は、肌からの発汗によるムレ、ベタツキなどを生じ、快
適性の点で天然繊維よりも劣る。そのため、前記衣料用
途への進出は限定されているのが実状である。このた
め、たとえば特公昭60−475号公報、実公昭60−
40612号公報、あるいは特開昭60−215835
号公報に記載されているように、平衡水分率(吸湿率)
の高い繊維との各種の混繊、混撚、引揃えなどにより布
帛として吸湿快適性を得んとする試みが提案されてい
る。これらの方法を用いることで確かに快適性は向上す
るものの、その効果は十分とはいえず、逆に合成繊維を
染色する際に一般的に使用される分散染料によって汚染
を生じたり、同色性に劣ったり、合成繊維本来の物理的
特性が失われるという問題点があった。2. Description of the Related Art Thermoplastic synthetic fibers typified by polyesters and polyamides have excellent mechanical strength, chemical resistance, heat resistance, and ease of resin processing, so they are widely used mainly for clothing and industrial applications. Has been done. However, since these synthetic fibers have extremely low hygroscopicity, when used in a field such as an inner, inner garment, sports clothing, etc., which is directly worn on the skin or close to the skin, It causes stuffiness and stickiness due to sweating from the skin, and is inferior to natural fibers in terms of comfort. Therefore, it is the actual situation that the advancement to the clothing use is limited. Therefore, for example, Japanese Patent Publication No. 60-475 and Japanese Utility Model Publication No. 60-
40612, or JP-A-60-215835.
Equilibrium moisture content (moisture absorption rate)
Attempts have been proposed to obtain moisture-absorbing comfort as a cloth by various kinds of mixed fibers, mixed twists, and alignment with high-quality fibers. Although the use of these methods certainly improves comfort, its effect is not sufficient, and conversely, disperse dyes commonly used when dyeing synthetic fibers cause contamination or homogeneity. However, there is a problem in that the physical properties inherent to synthetic fibers are lost.
【0003】また、ポリエステルやポリアミド系繊維に
吸湿特性を付与する方法として、アクリル酸やメタクリ
ル酸などをグラフト重合し、繊維内部にアルカリ金属で
置換されたカルボキシル基を導入する方法や、アクリル
アミドなどのようなアミド系化合物を多量にグラフト重
合するなどが知られている。このアルカリ金属で置換さ
れたカルボキシル基の導入量を多くすれば吸湿特性は増
大し、木綿以上の吸湿特性が得られる。しかしながら、
該手法のような後加工法によって吸湿性を付与した布帛
は、多量の吸湿成分が繊維表面に存在するために染色斑
を生じやすく、さらにアルカリ金属で置換されたカルボ
キシル基の導入量が多くなると、水に濡れた場合にぬる
ぬる感が強くなるという欠点があることから、実用化に
は至っていない。As a method for imparting hygroscopic properties to polyester or polyamide fibers, a method of graft-polymerizing acrylic acid or methacrylic acid to introduce a carboxyl group substituted with an alkali metal into the fiber, or acrylamide or the like. It is known to graft-polymerize a large amount of such amide compounds. Increasing the introduction amount of the carboxyl group substituted with the alkali metal increases the hygroscopic property, and the hygroscopic property higher than that of cotton can be obtained. However,
A fabric imparted with hygroscopicity by a post-processing method such as the above method is likely to cause stains due to the presence of a large amount of hygroscopic component on the fiber surface, and when the amount of introduction of a carboxyl group substituted with an alkali metal increases. However, it has not been put to practical use because it has a drawback that it becomes slimy when wet.
【0004】このように後加工段階で吸湿性を付与する
方法では染色時あるいは得られた布帛特性の点で種々の
問題があることから、繊維を製造する段階で吸湿性を付
与し、かつ前記問題点を解消するため、吸湿率が10%
以上の吸湿性樹脂を芯部とし、それを鞘部であるポリエ
ステルで覆った芯鞘型複合繊維が特開平2−99612
号公報で提案されている。また、特開平4−36161
6号公報にはポリエーテルエステルアミドを芯部に用い
た芯鞘型複合繊維が、特開平4−361617号公報に
はポリエーテルエステルアミドと他の熱可塑性樹脂との
ブレンド物を芯部に用いた芯鞘型複合繊維が開示されて
いる。これらの芯鞘型複合繊維は、高吸湿成分を鞘成分
で覆っているため、吸湿性を有しながらも比較的さらっ
とした触感で、良好な風合いを有している。しかしなが
ら該芯鞘複合繊維の機能はいずれも吸湿性の付与であ
り、多量の発汗によって生じた水分を移送する機能(吸
水性)は低いものであった。As described above, the method of imparting hygroscopicity in the post-processing step has various problems at the time of dyeing or in the characteristics of the obtained fabric. Moisture absorption is 10% to eliminate problems
A core-sheath type composite fiber in which the above hygroscopic resin is used as a core part and covered with polyester which is a sheath part is disclosed in JP-A-2-99612.
It has been proposed in the publication. In addition, JP-A-4-36161
No. 6 discloses a core-sheath type composite fiber in which a polyether ester amide is used for the core, and JP-A-4-361617 discloses a blend of a polyether ester amide and another thermoplastic resin for the core. A core-sheath type composite fiber is disclosed. Since these core-sheath type composite fibers cover the highly hygroscopic component with the sheath component, they have a hygroscopic property, yet have a relatively dry feel and a good texture. However, all the functions of the core-sheath composite fiber are to impart hygroscopicity, and the function of transferring moisture generated by a large amount of perspiration (water absorption) is low.
【0005】[0005]
【発明が解決しようとする課題】本発明の目的は、前記
従来技術の問題点を克服し、工程トラブルがなく高次加
工性が良好であり、吸湿性および吸水性の2つの機能を
合わせ持った着用快適性が高い合成繊維を提供すること
にある。SUMMARY OF THE INVENTION The object of the present invention is to overcome the above-mentioned problems of the prior art, to have good processability without process trouble, and to have two functions of hygroscopicity and water absorption. It is to provide a synthetic fiber having high wearing comfort.
【0006】[0006]
【課題を解決するための手段】前記した本発明の目的
は、吸放湿係数(△MR)が1.5%以上の合成繊維で
あって、該合成繊維を構成する少なくとも一部が、1個
以上のスリットを有するフィラメントまたは短繊維であ
る快適性に優れた合成繊維によって達成できる。The above-mentioned object of the present invention is a synthetic fiber having a moisture absorption / release coefficient (ΔMR) of 1.5% or more, and at least a part of the synthetic fiber is 1 This can be achieved by a synthetic fiber having excellent comfort, which is a filament or a short fiber having one or more slits.
【0007】本発明では快適性、特に発汗などの際の快
適性を与えるためには合成繊維が△MR1.5%以上の
吸放湿機能を有し、かつ合成繊維を構成する少なくとも
一部が、1個以上のスリットを有するフィラメントまた
は短繊維であり、毛細管現象による吸水性を有する必要
がある。In the present invention, in order to provide comfort, particularly when sweating, the synthetic fiber has a moisture absorbing / releasing function of ΔMR 1.5% or more, and at least a part of the synthetic fiber is composed. It is a filament or a short fiber having one or more slits, and needs to have water absorption due to a capillary phenomenon.
【0008】[0008]
【発明の実施の形態】本発明の合成繊維が有する吸放湿
機能について以下の説明する。本発明の合成繊維に好ま
しく用いられる吸湿性成分は、ポリエーテルエステル、
ポリエーテルアミド、ポリエーテルイミドアミド、ポリ
エーテルエステルアミドであるが、特に好ましくはポリ
エーテルエステルアミドである。これらの吸湿性成分は
いずれも後述する吸放湿係数△MRが5%以上であり、
高い吸湿性を有している。BEST MODE FOR CARRYING OUT THE INVENTION The moisture absorbing / releasing function of the synthetic fiber of the present invention will be described below. The hygroscopic component preferably used in the synthetic fiber of the present invention is a polyether ester,
Polyether amide, polyether imide amide, and polyether ester amide are preferable, and polyether ester amide is particularly preferable. Each of these hygroscopic components has a moisture absorption / release coefficient ΔMR described later of 5% or more,
It has high hygroscopicity.
【0009】ここでポリエーテルエステルアミドとは同
一分子鎖内にエーテル結合、エステル結合およびアミド
結合を持つブロック共重合体である。より具体的にはラ
クタム、アミノカルボン酸、ジアミンとジカルボン酸の
塩から選ばれた1種もしくは2種以上のポリアミド形成
性成分(A)およびジカルボン酸とポリ(アルキレンオ
キシド)グリコールからなるポリエーテルエステル形成
性成分(B)を重縮合反応させて得られるブロック共重
合体ポリマである。本発明のポリエーテルエステルアミ
ドのポリアミド形成性成分(A)としては、カプロラク
タム、エナントラクタム、ドデカノラクタム、ウンデカ
ノラクタム等のラクタム類、アミノカプロン酸,11−
アミノウンデカン酸、12−アミノドデカン酸などのω
−アミノカルボン酸、ナイロン66、ナイロン610、
ナイロン612等の前駆体であるジアミン−ジカルボン
酸のナイロン塩類があり、これらを1種または2種以上
混合して用いることができる。好ましいポリアミド形成
性成分(A)はε−カプロラクタム、ナイロン66塩で
ある。Here, the polyether ester amide is a block copolymer having an ether bond, an ester bond and an amide bond in the same molecular chain. More specifically, one or more polyamide-forming components (A) selected from lactams, aminocarboxylic acids, salts of diamines and dicarboxylic acids, and polyether esters composed of dicarboxylic acids and poly (alkylene oxide) glycols. It is a block copolymer polymer obtained by polycondensation reaction of the forming component (B). Examples of the polyamide-forming component (A) of the polyether ester amide of the present invention include lactams such as caprolactam, enantolactam, dodecanolactam and undecanolactam, aminocaproic acid, 11-
Ω of aminoundecanoic acid, 12-aminododecanoic acid, etc.
-Aminocarboxylic acid, nylon 66, nylon 610,
There are nylon salts of diamine-dicarboxylic acid, which is a precursor of nylon 612 and the like, and these can be used alone or in combination of two or more. A preferred polyamide-forming component (A) is ε-caprolactam, nylon 66 salt.
【0010】一方、ポリエーテルエステルアミドのソフ
トセグメントを構成するポリエーテルエステル成分
(B)としては、ジカルボン酸とポリ(アルキレンオキ
シド)グリコールとからなる。ジカルボン酸としては、
炭素数4〜20のジカルボン酸で、例えばコハク酸、グ
ルタル酸、アジピン酸、ピメリン酸、スベリン酸、セバ
シン酸、ドデカジ酸等の脂肪族ジカルボン酸、テレフタ
ル酸、イソフタル酸、2,6−ナフタレンジカルボン酸
等の芳香族ジカルボン酸、1,4−シクロヘキサンジカ
ルボン酸等の脂環式ジカルボン酸をあげることができ、
1種または2種以上混合して用いることができる。好ま
しいジカルボン酸はアジピン酸、セバシン酸、ドデカジ
酸、テレフタル酸、イソフタル酸である。またポリ(ア
ルキレンオキシド)グリコールとしては、ポリエチレン
グリコール、ポリ(1,2−および1,3−プロピレン
オキシド)グリコール、ポリ(テトラメチレンオキシ
ド)グリコール、ポリ(ヘキサメチレンオキシド)グリ
コール、エチレンオキシドとプロピレンオキシドまたは
テトラヒドロフランとのランダムまたはブロック共重合
等が挙げられ、特にポリエチレングリコールが好まし
い。ポリ(アルキレンオキシド)グリコールの数平均分
子量は300 〜10000 、好ましくは500 〜4000の範囲で用
い得る。On the other hand, the polyether ester component (B) which constitutes the soft segment of the polyether ester amide comprises dicarboxylic acid and poly (alkylene oxide) glycol. As dicarboxylic acids,
Dicarboxylic acids having 4 to 20 carbon atoms, such as succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, sebacic acid, dodecadiic acid, and other aliphatic dicarboxylic acids, terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid Aromatic dicarboxylic acids such as acids, alicyclic dicarboxylic acids such as 1,4-cyclohexanedicarboxylic acid, and the like,
One kind or a mixture of two or more kinds can be used. Preferred dicarboxylic acids are adipic acid, sebacic acid, dodecadic acid, terephthalic acid, isophthalic acid. As the poly (alkylene oxide) glycol, polyethylene glycol, poly (1,2- and 1,3-propylene oxide) glycol, poly (tetramethylene oxide) glycol, poly (hexamethylene oxide) glycol, ethylene oxide and propylene oxide or Examples thereof include random or block copolymerization with tetrahydrofuran, and polyethylene glycol is particularly preferable. The number average molecular weight of poly (alkylene oxide) glycol can be used in the range of 300 to 10,000, preferably 500 to 4000.
【0011】本発明の吸湿性成分に好ましく用いられる
ポリエーテルエステルアミドブロック共重合体は、上記
したポリアミド形成性成分(A)とポリエーテルエステ
ル形成性成分(B)を重縮合することによって得られ
る。工業的に好ましい方法としては(A)および(B)
を減圧下、加熱重縮合する方法があげられるが、その
際、高重合度で着色の少ないポリマを得るためには例え
ば酸化アンチモン、チタン酸エステル等を重縮合触媒と
して、またリン酸、リン酸エステル等を着色防止剤とし
て添加することが好ましい。ポリエーテルエステルアミ
ド中の(A)と(B)の重量比は99:1〜5:95、好ましく
は80:20 〜10:90 の範囲で有効に利用することができ
る。The polyether ester amide block copolymer preferably used for the hygroscopic component of the present invention is obtained by polycondensing the above-mentioned polyamide-forming component (A) and polyether ester-forming component (B). . (A) and (B) are industrially preferable methods.
Examples of the polycondensation method include heating polycondensation under reduced pressure. In this case, in order to obtain a polymer having a high degree of polymerization and little coloring, for example, antimony oxide, titanic acid ester or the like is used as a polycondensation catalyst, phosphoric acid or phosphoric acid. It is preferable to add an ester or the like as a color preventing agent. The weight ratio of (A) to (B) in the polyether ester amide can be effectively utilized in the range of 99: 1 to 5:95, preferably 80:20 to 10:90.
【0012】該ポリエーテルエステルアミドは、本発明
で好ましく用いられる吸湿性成分であり、他の繊維形成
性重合体にブレンドまたは複合されるが、芯鞘型複合繊
維として芯部に配置されることが好ましい。芯部に配置
することによって表面のドライ感を保持しながら、吸放
湿機能を付与できる。吸湿性成分の複合比率は繊維全重
量に対し、5〜50重量%とすることが好ましい。さら
に好ましくは10〜40重量%、特に好ましくは15〜
30重量%である。該範囲は十分な吸湿性と染色のよう
な熱水雰囲気下で膨潤による繊維表面の割れが発生しや
すい等、高次加工性の観点から決定される。The polyether ester amide is a hygroscopic component that is preferably used in the present invention, and is blended or composited with other fiber-forming polymer, but it is arranged in the core portion as a core-sheath type composite fiber. Is preferred. By arranging it in the core part, it is possible to impart a moisture absorbing / releasing function while maintaining the dry feeling of the surface. The composite ratio of the hygroscopic component is preferably 5 to 50% by weight based on the total weight of the fiber. More preferably 10 to 40% by weight, especially preferably 15 to
30% by weight. The range is determined from the viewpoint of high-order processability such as sufficient hygroscopicity and the tendency of fiber surface cracking due to swelling in hot water atmosphere such as dyeing.
【0013】また、本発明の繊維形成性熱可塑性重合体
とは、ポリエチレン、ポリプロピレン等のポリオレフィ
ン、ナイロン6、ナイロン66等のポリアミド、ポリエ
チレンテレフタレート、ポリブチレンテレフタレート等
のポリエステルがいずれも使用可能であるが、ポリエー
テルエステルアミドとの界面相互接着性が高い点でポリ
アミドおよびポリエステルを用いることが好ましい。さ
らに繊維形成性熱可塑性重合体としては染色工程での熱
水処理温度を低下させ、ポリエーテルエステルアミドの
膨潤を抑制することが可能な常圧可染型重合体であるこ
とが望ましく、その点でナイロン6やナイロン66など
のポリアミドやポリ(アルキレンオキシド)グリコール
を共重合したポリエステル、5−ソジュームスルホイソ
フタル酸成分を共重合したポリエステル等の変性ポリエ
ステルを用いることが特に好ましい。該繊維形成性熱可
塑性重合体中には本発明の吸湿性成分を少量混合しても
よいが、10重量%以下に抑制するのが好ましい。As the fiber-forming thermoplastic polymer of the present invention, any of polyolefins such as polyethylene and polypropylene, polyamides such as nylon 6 and nylon 66, polyesters such as polyethylene terephthalate and polybutylene terephthalate can be used. However, it is preferable to use polyamide and polyester in terms of high interfacial mutual adhesion with polyetheresteramide. Further, the fiber-forming thermoplastic polymer is preferably an atmospheric dyeable polymer capable of lowering the hot water treatment temperature in the dyeing step and suppressing the swelling of the polyether ester amide. It is particularly preferable to use a modified polyester such as a polyester obtained by copolymerizing polyamide such as nylon 6 or nylon 66 or a poly (alkylene oxide) glycol, a polyester obtained by copolymerizing a 5-sodium sulfoisophthalic acid component. A small amount of the hygroscopic component of the present invention may be mixed in the fiber-forming thermoplastic polymer, but it is preferably suppressed to 10% by weight or less.
【0014】このほか本発明の吸放湿性合成繊維には、
ポリアクリル酸ソーダ、ポリNビニルピロリドン、ポリ
アクリル酸およびその共重合体、ポリメタアクリル酸お
よびその共重合体、ポリビニルアルコールおよびその共
重合体、ポリアクリルアミドおよびその共重合体、架橋
ポリエチレンオキサイド系ポリマなどの吸湿・吸水物質
やポリアミド、ポリエステル、ポリオレフィン等の汎用
熱可塑性樹脂が本発明の目的を阻害しない程度含有され
ていてもよい。また吸放湿性合成繊維および繊維形成性
熱可塑性重合体には、酸化チタン、カーボンブラック等
の顔料のほか従来公知の抗酸化剤、着色防止剤、耐光
剤、帯電防止剤等が添加されても勿論良い。In addition, the moisture absorbing / releasing synthetic fiber of the present invention includes
Sodium polyacrylate, poly-N-vinylpyrrolidone, polyacrylic acid and its copolymer, polymethacrylic acid and its copolymer, polyvinyl alcohol and its copolymer, polyacrylamide and its copolymer, crosslinked polyethylene oxide polymer A moisture-absorbing or water-absorbing substance such as or a general-purpose thermoplastic resin such as polyamide, polyester, or polyolefin may be contained to such an extent that the object of the present invention is not impaired. Further, in addition to pigments such as titanium oxide and carbon black, conventionally known antioxidants, anti-coloring agents, light stabilizers, antistatic agents, etc. may be added to the moisture-absorbing and desorbing synthetic fibers and the fiber-forming thermoplastic polymer. Of course good.
【0015】本発明の合成繊維は吸湿性成分と繊維形成
性熱可塑性重合体を配したものである。複合した場合の
形態としては芯鞘型、偏芯芯鞘型、海島型等が上げられ
るが芯鞘型が特に好ましい。The synthetic fiber of the present invention comprises a hygroscopic component and a fiber-forming thermoplastic polymer. Examples of the combined form include a core-sheath type, an eccentric core-sheath type, and a sea-island type, but the core-sheath type is particularly preferable.
【0016】さらに芯鞘型複合繊維では繊維内部に中空
部を設けることもできる。該中空部は吸湿性成分、また
は該吸湿性成分と繊維形成性重合体の界面に形成されて
いることが好ましい。Further, in the core-sheath type composite fiber, a hollow portion may be provided inside the fiber. The hollow portion is preferably formed at the hygroscopic component or at the interface between the hygroscopic component and the fiber-forming polymer.
【0017】本発明の合成繊維は、以下のような方法に
よって得ることができる。例えばポリアミド(鞘部)と
ポリエーテルエステルアミド(芯部)をそれぞれ別々に
溶融し、紡糸パックに導き、口金装置内で芯鞘複合流を
形成させ、吐出孔から紡出する。紡出したフィラメント
糸は所定の速度で引取った後、一旦パッケージに巻上
げ、得られた未延伸糸を通常の延伸機にて延伸する。ま
た、紡出糸を引取った後、そのまま連続して延伸し、巻
上げてもよいし(直接紡糸延伸法)、4000m/分以上の
高速で引取り一挙に所望の繊維性能を得る方法をとって
もよい。直接紡糸延伸法としては、例えば、紡出糸を10
00〜5000m/分で引取り、引続いて3000〜7000m/分で
延伸・熱固定する方法が挙げられる。The synthetic fiber of the present invention can be obtained by the following method. For example, polyamide (sheath part) and polyetheresteramide (core part) are separately melted, introduced into a spinning pack, a core-sheath composite flow is formed in a spinneret device, and spun from a discharge hole. The spun filament yarn is taken up at a predetermined speed, once wound up in a package, and the obtained undrawn yarn is drawn by a usual drawing machine. Further, after the spun yarn is taken up, it may be continuously drawn as it is and wound up (a direct spinning drawing method), or a method of obtaining a desired fiber performance at a high speed of 4000 m / min or more may be adopted. Good. As the direct spinning and drawing method, for example, spun yarn is
A method of taking it off at 00 to 5000 m / min, followed by stretching and heat setting at 3000 to 7000 m / min can be mentioned.
【0018】次にスリットについて説明する。ここでス
リットとは繊維表面の凹部であり、見かけ状凸部と凸部
に挟まった部分をいう。本発明の合成繊維は布帛とした
際、合成繊維中に多数の毛細管状の空隙により水分移送
機能を付与するものである。そのためには、合成繊維を
構成する少なくても一部が、1個以上のスリットを有す
るフィラメントまたは短繊維である必要があり、該スリ
ットは繊維長手方向に連続して形成されていることが好
ましい。Next, the slit will be described. Here, the slit means a concave portion on the surface of the fiber, and means a portion sandwiched between the apparent convex portion and the convex portion. When the synthetic fiber of the present invention is made into a cloth, it has a water-transporting function due to a large number of capillary voids in the synthetic fiber. For that purpose, at least a part of the synthetic fiber must be a filament or a short fiber having one or more slits, and the slits are preferably formed continuously in the fiber longitudinal direction. .
【0019】本発明の合成繊維は、スリットを有する繊
維とスリットを有さない繊維の混繊状態であることがさ
らに好ましい。混繊比率としては、スリットを有さない
繊維が混繊糸全量の20〜80重量%であることが好ま
しい。The synthetic fiber of the present invention is more preferably a mixed fiber state of a fiber having a slit and a fiber having no slit. As the mixed fiber ratio, it is preferable that the fibers having no slits account for 20 to 80% by weight of the total amount of the mixed fiber.
【0020】図1のように繊維断面形状が3〜8個の凹
部と凸部とを有するマルチローバル断面であることがさ
らに好ましい。該マルチローバル断面の中では、ペンタ
ローバル断面(5葉)またはヘキサローバル断面(6
葉)が特に好ましい。また、断面の異形度が高いほど吸
水性能が良好であり、毛細管状の空隙形成と良好な紡糸
性の観点から異形度が1.3〜5.0の範囲とすること
が好ましい。より好ましくは異形度が1.8〜4.0の
範囲である。ここで、異形度とは図2で示されるように
異形断面の外接円R1と、内接円R2の半径比R1/R
2を言う。As shown in FIG. 1, it is more preferable that the fiber cross-sectional shape is a multi-lobal cross section having 3 to 8 concave portions and convex portions. Among the multi-lobal cross-sections, penta-lobal cross-section (5 lobes) or hexa-lobal cross-section (6
Leaves) are particularly preferred. Further, the higher the degree of irregularity of the cross section, the better the water absorption performance, and it is preferable that the degree of irregularity is in the range of 1.3 to 5.0 from the viewpoint of forming capillary voids and good spinnability. More preferably, the degree of irregularity is in the range of 1.8 to 4.0. Here, the degree of irregularity means the radius ratio R1 / R of the circumscribed circle R1 and the inscribed circle R2 of the irregularly shaped cross section as shown in FIG.
Say two.
【0021】例えば丸断面糸(異形度1.0)と異形度
1.3以上の繊維から構成された糸とを混繊した場合、
マルチローバル断面と丸断面とが隣合わさることによっ
て繊維間に効率よく毛細管状空隙が形成され、吸水性が
さらに向上する。For example, when a yarn having a round cross section (variant degree 1.0) and a yarn composed of fibers having a degree of irregularity of 1.3 or more are mixed,
Since the multi-lobal cross section and the round cross section are adjacent to each other, capillary voids are efficiently formed between the fibers, and the water absorption is further improved.
【0022】ここで、水分を移送する機能を具備するの
は吸放湿機能を有する複合繊維のみからなることは必ず
しも必要ではなく、吸放湿機能機能を有さない繊維が水
分移送機能を担っていてもよい。Here, it is not always necessary that the composite fiber having the function of transferring moisture has only the composite fiber having the moisture absorbing / releasing function, and the fiber having no moisture absorbing / releasing function has the moisture transferring function. May be.
【0023】本発明の合成繊維の糸形態は、フィラメン
ト、ステープルのどちらでも良く、仮撚加工を行っても
良い。The synthetic fiber of the present invention may be in the form of filament or staple, and may be false twisted.
【0024】[0024]
【実施例】以下本発明を実施例により、さらに詳細に説
明する。実施例中の各特性値は次の方法によって求め
た。 A.繊維の吸放湿係数△MR 吸湿率は、試料原糸で編み立てられた約1gの編地を絶
乾時の重量と20℃×65%RHあるいは30℃×90%RHの雰囲
気下、恒温恒湿器(タバイ製PR−2G)中に24時間放
置後の重量との重量変化から、次式で求めた。 吸湿率(%)=[(吸湿後の重量−絶乾時の重量)/
(絶乾時の重量)]×100 上記測定した20℃×65%RHおよび30℃×90%RHの条件で
の吸湿率(それぞれMR1およびMR2とする)から、
吸放湿係数△MR(%)=MR2−MR1を求める。こ
こで吸放湿係数△MRは衣服着用時の衣服内の湿気を外
気に放出することにより快適性を得るためのドライビン
グフォースであり、軽〜中作業あるいは軽〜中運動を行
った際の30℃×90%RHに代表される衣服内温度と20℃×
65%RHに代表される外気温湿度との吸湿率差である。本
発明では吸湿性評価の尺度としてこの△MRをパラメー
ターとして用いるが、△MRは大きければ大きいほど吸
湿性が高く、着用時の快適性が良好であることに対応す
る。The present invention will be described in more detail with reference to the following examples. Each characteristic value in the examples was obtained by the following method. A. Moisture absorption and desorption coefficient of fiber △ MR Moisture absorption rate is about 1 g of knitted fabric knitted with sample yarn and the temperature at 20 ℃ × 65% RH or 30 ℃ × 90% RH under constant temperature It was determined by the following formula from the weight change with the weight after standing for 24 hours in a humidity chamber (PR-2G manufactured by Tabai). Moisture absorption rate (%) = [(weight after moisture absorption-weight at absolute dryness) /
(Weight at absolute dryness)] × 100 From the measured moisture absorption rates under the conditions of 20 ° C. × 65% RH and 30 ° C. × 90% RH (MR1 and MR2, respectively),
Moisture absorption and desorption coefficient ΔMR (%) = MR2-MR1 is calculated. Here, the moisture absorption / desorption coefficient ΔMR is a driving force for obtaining comfort by releasing moisture in clothes when the clothes are worn to the outside, and is 30 when performing light-medium work or light-medium exercise. ℃ × 90% RH and clothes temperature represented by 20 ℃ ×
This is the difference in moisture absorption rate from the ambient temperature and humidity represented by 65% RH. In the present invention, this ΔMR is used as a parameter for evaluation of hygroscopicity, and the larger ΔMR corresponds to the higher hygroscopicity and the better wearing comfort.
【0025】B.繊維の吸水特性 吸水性の測定(吸水高さ)はJIS規格のバイレック法
に準じて求めた。ただし測定時間は5分間とした。ま
た、拡散性(速乾性)はJIS規格の滴下法に準じて求
めた。それぞれの特性において、綿のレベル以上の場合
を合格とした。綿の吸水高さは82mm、拡散性は9.
5cm2 である。B. Water Absorption Properties of Fiber The water absorption (height of water absorption) was determined according to the JIS standard Bayrek method. However, the measurement time was 5 minutes. The diffusivity (quick drying) was determined according to the JIS standard dropping method. In each of the characteristics, the case where the cotton level was higher than or equal to was judged to be acceptable. The water absorption height of cotton is 82 mm, and the diffusivity is 9.
It is 5 cm 2 .
【0026】C.高次工程通過後の芯成分流出の有無 染色・還元洗浄を終えた後の試料を分解して1本の複合
糸(マルチフィラメント )を取り出し、繊維断面を薄片状にサン
プリングして顕微鏡により単繊維一本一本について繊維
のひび割れの有無を観察し、芯部から繊維の表面までひ
び割れが生じ、芯成分の流出がみられる単糸がマルチフ
ィラメント5本中1本もない場合を○、ひび割れが生
じ、芯成分の流出がみられる単糸が1〜2本の場合は
△、3本以上である場合を×とした。C. Presence or absence of outflow of core component after passing through higher-order process Disassemble the sample after dyeing and reduction washing, take out one composite yarn (multifilament), sample the cross section of the fiber into flakes, and use a microscope to observe single fibers. Observe the presence or absence of cracks in the fibers one by one. When there is no single yarn among the five multifilaments in which cracks occur from the core to the surface of the fiber and the core component is seen to flow out, cracks occur. A case where the number of single yarns in which the core component was generated and outflow was observed was 1-2, and a case where the number of yarns was 3 or more was indicated by x.
【0027】D.染め斑判定 編み立てた筒編地を、市販の酸性染料で定法に従って約
95℃×60分間浸漬10後、約10分間水洗してから
風乾し、目視により標準比較サンプルと比較し○、△、
×の判定を行なった。D. Judgment of Dyeing Spots A knitted tubular knitted fabric was soaked with a commercially available acid dye in accordance with a standard method at about 95 ° C. for 60 minutes, after which it was washed with water for about 10 minutes, air-dried, and visually compared with a standard comparative sample.
The judgment of x was made.
【0028】E.着用快適性 試料原糸からトリコット編地を編立し、その編地からイ
ンナーを縫製した。このインナーを5人の被験者に着用
してもらい、20℃×65%RHの温湿度条件にした人
工気象室で1時間安静後、高さ20cmのブロック上へ2
0分間の踏み台昇降運動を行い、その後20分間安静状
態を保った後、着用感についてのアンケートをとった。
ムレ、ベタツキがなく快適であると回答した人数が5人
以上の場合を◎、4人以上の場合を○、3人の場合を
△、2人以下の場合を×とした。E. Wearing comfort A tricot knitted fabric was knitted from the sample yarn and the inner was sewn from the knitted fabric. Five test subjects wear this inner, and after resting for 1 hour in an artificial weather room under the temperature and humidity conditions of 20 ° C x 65% RH, they are placed on a block 20 cm in height.
After a 0 minute step up and down exercise, and after maintaining a resting state for 20 minutes, a questionnaire about the feeling of wearing was taken.
The number of people who answered that they were comfortable with no stuffiness and stickiness was 5 or more. ◎, 4 or more was ○, 3 was Δ, and 2 or less was ×.
【0029】参考例1(ポリエーテルエステルアミドブ
ロック共重合体の合成) ε−カプロラクタム340部、テレフタル酸18部、数
平均分子量が1000のポリエチレングリコール100部、
さらに「イルガノックス1330」(チバガイギー社
製)0.1部およびトリメチルフォスフェート0.01
部とともに重合反応容器に仕込み、窒素気流下に240
℃で1時間加熱撹拌した後、三酸化アンチモン0.1部
を添加し、昇温減圧プログラム下250℃、0.5mm
Hg以下の条件で4時間重合反応を行うことにより、ポ
リアミド形成性成分(A)の割合が45重量%、ポリエ
ーテルエステル形成性成分(B)が55重量%であるポ
リエーテルエステルアミドブロック共重合体を得た。こ
の共重合体のオルトクロロフェノール溶液(濃度:0.
5g/100ml)の25℃での相対粘度ηrは2.1
であった。またポリマ単独のMR1は6.0%、MR2
は17.4%で△MR=11.4%であった。Reference Example 1 (Synthesis of Polyether Esteramide Block Copolymer) 340 parts of ε-caprolactam, 18 parts of terephthalic acid, 100 parts of polyethylene glycol having a number average molecular weight of 1000,
Furthermore, 0.1 part of "Irganox 1330" (manufactured by Ciba Geigy) and 0.01 of trimethyl phosphate
Was charged into a polymerization reaction vessel together with the parts, and was put under a nitrogen stream for 240
After heating and stirring at 1 ° C for 1 hour, 0.1 part of antimony trioxide was added, and the temperature was reduced under reduced pressure program at 250 ° C, 0.5 mm.
By carrying out the polymerization reaction for 4 hours under the condition of Hg or less, the proportion of the polyamide-forming component (A) is 45% by weight and the proportion of the polyetherester-forming component (B) is 55% by weight. Got united. A solution of this copolymer in orthochlorophenol (concentration: 0.
5 g / 100 ml) has a relative viscosity ηr at 25 ° C. of 2.1.
Met. MR1 of polymer alone is 6.0%, MR2
Was 17.4% and ΔMR = 11.4%.
【0030】実施例1 参考例1で合成したポリエーテルエステルアミドブロッ
ク共重合体を芯成分とし、硫酸中の相対粘度が2.50であ
るナイロン6を鞘成分とし、紡糸温度270℃にて放射
状5スリット吐出孔を有する芯鞘型複合口金から重量比
率が芯部/鞘部=20/80となるように吐出して直接
紡糸延伸法により紡糸速度3000m/分、延伸速度5000m
/分で巻き取ることにより、50デニール24フィラメ
ントの芯鞘型複合糸を得た。該複合繊維の断面形状はペ
ンタローバル(5葉)であり、異形度は約1.8であっ
た。また、筒編地の△MRは4.7%と良好な吸湿特性
を有していた。さらに吸水性(吸水高さ)は120m
m、滴下法による拡散性は19cm2 といずれの吸水特
性も高い水準であった。また、該複合糸を編み立ててト
リコット編地とし、さらにこの編地を縫製してインナー
とした。このインナーを市販の酸性染料で定法に従って
約95℃×60分間浸漬した後、約10分間水洗し、さ
らに約80℃で10分間色止めを行い適当な色彩に染色
し、再度約10分間水洗するようにした。仕上がった製
品の外観品位は良好であり、5人の被験者による着用評
価でもムレ、ベトツキを感じる人はなく、極めて良好な
着用快適性を示した。Example 1 The polyether ester amide block copolymer synthesized in Reference Example 1 was used as the core component, nylon 6 having a relative viscosity of 2.50 in sulfuric acid as the sheath component, and 5 radial slits at a spinning temperature of 270 ° C. A core-sheath type composite spinneret having a discharge hole is discharged so that the weight ratio is 20/80 in the core / sheath part, and the spinning speed is 3000 m / min and the drawing speed is 5000 m by the direct spinning / drawing method.
The core / sheath type composite yarn of 50 denier 24 filaments was obtained by winding at a speed of about 1 / min. The cross-sectional shape of the composite fiber was pentalobal (5 leaves), and the degree of irregularity was about 1.8. The ΔMR of the tubular knitted fabric was 4.7%, which was a good hygroscopic property. Furthermore, water absorption (water absorption height) is 120m
m, the diffusivity by the dropping method was 19 cm 2, and all the water absorption characteristics were at a high level. The composite yarn was knitted to form a tricot knitted fabric, and this knitted fabric was sewn to form an inner. This inner is soaked with a commercially available acid dye according to a standard method at about 95 ° C. for 60 minutes, then washed with water for about 10 minutes, further colored at about 80 ° C. for 10 minutes by dyeing to an appropriate color, and again washed with water for about 10 minutes. I did it. The finished product had a good appearance quality, and even when evaluated by five test subjects, no one felt stuffy or sticky, and exhibited extremely good wearing comfort.
【0031】実施例2〜4および比較例1〜2 ポリエーテルエステルアミドブロック共重合体とポリア
ミドとの芯鞘複合比率を変更した以外は実施例1と同じ
方法でトリコットを編み立て、この編地の各特性を実施
例1と同様の方法で評価した結果を表1に示す。実施例
2〜4は吸湿特性、吸水特性ともに良好であり、かつ熱
水処理による割れは全く認められなかった。一方、比較
例1では芯成分のポリエーテルエステルアミドの比率が
少なかったため吸湿性が低く、比較例2については芯成
分のポリエーテルエステルアミド量が多いため、吸湿性
は高いものの熱水処理時に繊維表面に多数のヒビわれが
発生し、ポリエーテルエステルアミドが繊維表面に流出
したためにベタツキが生じ、実用に耐えなかった。Examples 2 to 4 and Comparative Examples 1 to 2 Tricots were knitted in the same manner as in Example 1 except that the core-sheath composite ratio of the polyether ester amide block copolymer and the polyamide was changed. Table 1 shows the results obtained by evaluating the respective properties of Example 1 in the same manner as in Example 1. In Examples 2 to 4, both the hygroscopic property and the water absorbing property were good, and cracks due to hot water treatment were not observed at all. On the other hand, in Comparative Example 1, since the proportion of the polyether ester amide as the core component was small, the hygroscopicity was low, and in Comparative Example 2, the amount of the polyether ester amide as the core component was large, so that the hygroscopicity was high but the fiber was not treated during hot water treatment. Many cracks were generated on the surface, and the polyether ester amide flowed out to the surface of the fiber, resulting in stickiness, which was not practical.
【0032】実施例5 芯成分としてポリエーテルエステルアミドとナイロン6
の重量比が80:20である混合物を用い、重量比率を
芯部/鞘部=30/70とした以外は実施例1と同様な
方法でトリコットを編み立てた。吸湿特性、吸水特性と
もに良好であり、着用快適性も高いものであった。Example 5 Polyether ester amide and nylon 6 as core components
A tricot was knitted in the same manner as in Example 1 except that the mixture having a weight ratio of 80:20 was used and the weight ratio was changed to core / sheath = 30/70. Both the moisture absorption property and the water absorption property were good, and the wearing comfort was also high.
【0033】実施例6 鞘成分としてポリエーテルエステルアミドとナイロン6
の重量比が5:95である混合物を用いた以外は実施例
1と同様な方法でトリコットを編み立てた。吸湿特性、
吸水特性ともに良好であり、着用快適性も高いものであ
った。Example 6 Polyether ester amide and nylon 6 as sheath components
A tricot was knitted in the same manner as in Example 1 except that a mixture having a weight ratio of 5:95 was used. Moisture absorption characteristics,
The water absorption characteristics were good, and the wearing comfort was also high.
【0034】実施例7 鞘成分として5−ソジュームスルホイソフタル酸ジメチ
ルを3モル%共重合した変性ポリエステルを用い、染色
工程でカチオン染料を用いた以外は実施例1と同様な方
法でトリコットを編み立てた。吸湿特性、吸水特性とも
に良好であり、着用快適性も高いものであった。Example 7 A tricot was knitted in the same manner as in Example 1 except that a modified polyester obtained by copolymerizing 3 mol% of dimethyl 5-sodiumsulfoisophthalate as a sheath component was used and a cationic dye was used in the dyeing step. I stood. Both the moisture absorption property and the water absorption property were good, and the wearing comfort was also high.
【0035】実施例8 図3に示すような放射状6スリット吐出孔(15ホー
ル)と丸孔(9ホール)とが分散して配列された芯鞘型
複合口金を用いた以外は実施例1と同様な方法でトリコ
ットを編み立てた。得られた混繊糸は図4に示す断面形
状であり、吸湿特性は良好であった。また、吸水特性は
実施例1よりもさらに優れていた。Example 8 Example 1 was repeated except that a core-sheath type composite spinneret in which radial 6-slit discharge holes (15 holes) and round holes (9 holes) were arranged dispersedly as shown in FIG. A tricot was knitted in a similar manner. The mixed fiber thus obtained had the cross-sectional shape shown in FIG. 4 and had good moisture absorption characteristics. In addition, the water absorption characteristics were even better than in Example 1.
【0036】実施例9 吐出孔のスペックを変更し、繊維断面の異形度を変えた
以外は実施例2と同様な方法でトリコットを編み立て
た。繊維の異形度は3.8であり、吸水特性が極めて優
れていた。Example 9 A tricot was knitted in the same manner as in Example 2 except that the specifications of the discharge holes were changed and the irregularity of the fiber cross section was changed. The irregularity of the fiber was 3.8, and the water absorption property was extremely excellent.
【0037】実施例10 異形度1.0である丸断面の芯鞘型複合繊維と異形度
1.8のナイロン6からなるペンタローバル繊維の混繊
状態(複合繊維/ペンタローバル繊維=70/30)と
した以外は実施例1と同様な方法でトリコットで編み立
てた。吸湿、吸水特性は良好であった。Example 10 Mixed state of a core-sheath type composite fiber having a roundness of 1.0 with a degree of irregularity and a pentalobal fiber composed of nylon 6 with a degree of variation of 1.8 (composite fiber / pentalobal fiber = 70/30) ) Was used for knitting with a tricot in the same manner as in Example 1. The moisture absorption and water absorption characteristics were good.
【0038】比較例3 吐出孔形状を変更し、丸孔とした以外は実施例1と同様
な方法でトリコットを編み立てた。繊維の異形度は1.
0であり、吸水特性は吸水高さ65mm、拡散性9.2
cm2 であり、いずれも綿より劣っていた。着用快適性
も不十分であった。Comparative Example 3 A tricot was knitted in the same manner as in Example 1 except that the shape of the discharge hole was changed to a round hole. The degree of fiber irregularity is 1.
The water absorption characteristics are 0, the water absorption height is 65 mm, and the diffusivity is 9.2.
It was cm 2 , and both were inferior to cotton. The wearing comfort was also insufficient.
【0039】比較例4 吐出孔形状を変更し、放射状9スリット吐出孔とした以
外は実施例1と同様な方法でトリコットを編み立てた。
得られた繊維の断面はノナローバル(9葉)であり、異
形度は1.5であった。この試料は吸湿特性は高いもの
の、吸水特性は吸水高さ80mm、拡散性9.4cm2
であり、いずれも綿より劣っていた。Comparative Example 4 A tricot was knitted in the same manner as in Example 1 except that the shape of the discharge hole was changed to a radial 9-slit discharge hole.
The cross section of the obtained fiber was nonalobal (9 leaves), and the degree of irregularity was 1.5. Although this sample has a high moisture absorption property, it has a water absorption property of a water absorption height of 80 mm and a diffusivity of 9.4 cm 2.
And both were inferior to cotton.
【0040】[0040]
【表1】 [Table 1]
【0041】[0041]
【発明の効果】本発明によって得られた合成繊維は、着
用快適性を得るのに十分な吸湿性および吸水性を有して
おり、ドライタッチな風合いと高い染色堅牢性や耐光性
を有している。また、染色条件のような過酷な雰囲気下
でも繊維表面にひびや割れが発生しないため、広い用途
に展開可能である。Industrial Applicability The synthetic fiber obtained by the present invention has sufficient hygroscopicity and water absorption to obtain wearing comfort, and has dry touch feeling, high dyeing fastness and light fastness. ing. Further, since the fiber surface is not cracked or cracked even under a harsh atmosphere such as dyeing conditions, it can be applied to a wide range of applications.
【0042】本発明の合成繊維は、下着、シャツ・ブラ
ウス類、中衣、スポーツウェア、スラックス類、外衣、
裏地、さらには、シーツ、フトンカバー等の寝装用に適
しており、極めて実用性の高いものである。The synthetic fiber of the present invention is used in underwear, shirts / blouses, inner garments, sportswear, slacks, outer garments,
It is suitable for lining, as well as for bedding such as sheets and futon covers, and is extremely practical.
【0043】[0043]
【図面の簡単な説明】[Brief description of drawings]
【0044】[0044]
【図1】本発明の繊維の横断面図の一例1 is an example of a cross-sectional view of a fiber of the present invention.
【0045】[0045]
【図2】本発明の繊維の異形度を説明するための繊維の
横断面図FIG. 2 is a cross-sectional view of a fiber for explaining the irregularity of the fiber of the present invention.
【0046】[0046]
【図3】本発明に用いられる口金の吐出孔配列の一例を
示す平面概略図FIG. 3 is a schematic plan view showing an example of an array of ejection holes of a die used in the present invention.
【0047】[0047]
【図4】図3の口金より得られた本発明の混繊した合成
繊維の一例を示す繊維の横断面図4 is a cross-sectional view of fibers showing an example of the mixed fiber of the present invention obtained from the die of FIG.
【0048】[0048]
【符号の説明】 1;トライローバル断面 2;テトラローバル断面 3;ペンタローバル断面 4;ヘキサローバル断面 5;ヘプタローバル断面 6;オクタローバル断面[Explanation of symbols] 1; Tri-lobal section 2; Tetra-lobal section 3; Penta-roval section 4; Hexa-lobal section 5; Hepta-lobal section 6; Octa-lobal section
Claims (8)
合成繊維であって、該合成繊維を構成する少なくとも一
部が、1個以上のスリットを有するフィラメントまたは
短繊維である快適性に優れた合成繊維。1. A synthetic fiber having a moisture absorption and desorption coefficient (ΔMR) of 1.5% or more, and at least a part of the synthetic fiber is a filament or a short fiber having one or more slits. Synthetic fiber with excellent comfort.
形成性重合体に複合またはブレンドされてなる吸放湿性
合成繊維が、少なくとも一部を構成する請求項1記載の
合成繊維。2. The synthetic fiber according to claim 1, wherein the hygroscopic / desorbable synthetic fiber in which a hygroscopic component having ΔMR of 5.0% or more is mixed or blended with a fiber-forming polymer constitutes at least a part.
に配し、鞘部に繊維形成性重合体を配した芯鞘型複合繊
維であって、芯部/鞘部の重量比率が5/95〜50/
50である該複合繊維が少なくとも一部を構成する請求
項1または2記載の合成繊維。3. A core-sheath type composite fiber in which a hygroscopic component having a MR of 5.0% or more is arranged in a core portion and a fiber-forming polymer is arranged in a sheath portion, and a weight ratio of the core portion / sheath portion. Is 5/95 to 50 /
The synthetic fiber according to claim 1 or 2, wherein the composite fiber of 50 constitutes at least a part.
リエーテルエステルアミドであることを特徴とする請求
項3記載の合成繊維。4. The synthetic fiber according to claim 3, wherein the main component of the hygroscopic component forming the core is polyetheresteramide.
分が繊維形成性ポリアミドまたは繊維形成性ポリエステ
ルであることを特徴とする請求項3または4記載の合成
繊維。5. The synthetic fiber according to claim 3, wherein the main component of the fiber-forming polymer forming the sheath is fiber-forming polyamide or fiber-forming polyester.
繊維が3〜8個のスリット部と同数の凸部とを有するマ
ルチローバル断面であることを特徴とする快適性に優れ
た請求項1〜5のいずれか1項記載の合成繊維。6. A filament having a slit or a short fiber has a multi-lobal cross section having 3 to 8 slit portions and the same number of convex portions, and is excellent in comfort, and any one of claims 1 to 5 is provided. The synthetic fiber according to item 1.
繊維の繊維横断面の異形度が1.3〜5.0であること
を特徴とする請求項1〜6のいずれか1記載の合成繊
維。7. The synthetic fiber according to claim 1, wherein the filament having a slit or the short fiber has a degree of irregularity of 1.3 to 5.0 in a cross section of the fiber.
リットを有するフィラメントまたは短繊維が構成割合2
0〜80重量%である請求項1〜7のいずれか1記載の
合成繊維。8. A filament or a short fiber having a slit which constitutes at least a part of a synthetic fiber has a composition ratio of 2.
The synthetic fiber according to any one of claims 1 to 7, which is 0 to 80% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19286795A JPH0941221A (en) | 1995-07-28 | 1995-07-28 | Synthetic fiber excellent in comfortableness |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19286795A JPH0941221A (en) | 1995-07-28 | 1995-07-28 | Synthetic fiber excellent in comfortableness |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0941221A true JPH0941221A (en) | 1997-02-10 |
Family
ID=16298298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19286795A Pending JPH0941221A (en) | 1995-07-28 | 1995-07-28 | Synthetic fiber excellent in comfortableness |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0941221A (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11269724A (en) * | 1998-03-19 | 1999-10-05 | Toray Ind Inc | Sheath-core type conjugate fiber and blended yarn |
| US6403216B1 (en) | 1999-02-12 | 2002-06-11 | Asahi Kasei Kabushiki Kaisha | Moisture-absorbing/releasing synthetic fiber and fabric using the same |
| JP2006274473A (en) * | 2005-03-29 | 2006-10-12 | Toray Ind Inc | Combined filament conjugated fiber and woven or knitted fabric using the same fiber |
| WO2010070491A3 (en) * | 2008-12-16 | 2010-09-02 | Kimberly-Clark Worldwide, Inc. | Three-dimensional wiping substrate and method therefor |
| WO2016098717A1 (en) * | 2014-12-18 | 2016-06-23 | 東レ株式会社 | Moisture absorbent core sheath composite yarn |
| JP2016117979A (en) * | 2014-12-18 | 2016-06-30 | 東レ株式会社 | Hygroscopic sheath-core conjugated yarn excellent in washing durability |
| JP2016132828A (en) * | 2015-01-15 | 2016-07-25 | 東レ株式会社 | Hygroscopic core-sheath conjugated yarn |
| JP2016196709A (en) * | 2015-04-02 | 2016-11-24 | 東レ株式会社 | Sheath-core composite cross section fiber excellent in moisture absorbing and releasing performance |
| WO2017170546A1 (en) * | 2016-03-30 | 2017-10-05 | 東レ株式会社 | Fiber material and purification column |
| JP2017186722A (en) * | 2016-03-31 | 2017-10-12 | 東レ株式会社 | Fiber material and purification column |
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-
1995
- 1995-07-28 JP JP19286795A patent/JPH0941221A/en active Pending
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| JPH11269724A (en) * | 1998-03-19 | 1999-10-05 | Toray Ind Inc | Sheath-core type conjugate fiber and blended yarn |
| US6403216B1 (en) | 1999-02-12 | 2002-06-11 | Asahi Kasei Kabushiki Kaisha | Moisture-absorbing/releasing synthetic fiber and fabric using the same |
| JP2006274473A (en) * | 2005-03-29 | 2006-10-12 | Toray Ind Inc | Combined filament conjugated fiber and woven or knitted fabric using the same fiber |
| WO2010070491A3 (en) * | 2008-12-16 | 2010-09-02 | Kimberly-Clark Worldwide, Inc. | Three-dimensional wiping substrate and method therefor |
| WO2016098717A1 (en) * | 2014-12-18 | 2016-06-23 | 東レ株式会社 | Moisture absorbent core sheath composite yarn |
| JP2016117979A (en) * | 2014-12-18 | 2016-06-30 | 東レ株式会社 | Hygroscopic sheath-core conjugated yarn excellent in washing durability |
| CN107002304A (en) * | 2014-12-18 | 2017-08-01 | 东丽株式会社 | Hygroscopicity core sheath composite filament |
| JP2016132828A (en) * | 2015-01-15 | 2016-07-25 | 東レ株式会社 | Hygroscopic core-sheath conjugated yarn |
| JP2016196709A (en) * | 2015-04-02 | 2016-11-24 | 東レ株式会社 | Sheath-core composite cross section fiber excellent in moisture absorbing and releasing performance |
| JPWO2017082110A1 (en) * | 2015-11-10 | 2017-11-16 | 東レ株式会社 | Core-sheath composite cross-section fiber with excellent hygroscopic and anti-mold properties |
| CN108350608A (en) * | 2015-12-08 | 2018-07-31 | 东丽株式会社 | Hygroscopicity core sheath composite filament and cloth and silk |
| EP3388562A4 (en) * | 2015-12-08 | 2019-09-18 | Toray Industries, Inc. | Moisture-absorbing core-sheath composite yarn, and fabric |
| JP2017185221A (en) * | 2016-03-30 | 2017-10-12 | 東レ株式会社 | Adsorption column |
| WO2017170546A1 (en) * | 2016-03-30 | 2017-10-05 | 東レ株式会社 | Fiber material and purification column |
| CN108883223A (en) * | 2016-03-30 | 2018-11-23 | 东丽株式会社 | Fibrous material and purification column |
| RU2692888C1 (en) * | 2016-03-30 | 2019-06-28 | Торэй Индастриз, Инк. | Fibrous material and cleaning column |
| JP2017186722A (en) * | 2016-03-31 | 2017-10-12 | 東レ株式会社 | Fiber material and purification column |
| JP2017203234A (en) * | 2016-05-12 | 2017-11-16 | 帝人フロンティア株式会社 | Spun yarn and fabric and textile products |
| JP2018059215A (en) * | 2016-09-30 | 2018-04-12 | Kbセーレン株式会社 | Fabric |
| JP2018184674A (en) * | 2017-04-24 | 2018-11-22 | Kbセーレン株式会社 | Composite fiber, fabric, method for producing fiber structure, and garment |
| JP2024545893A (en) * | 2021-12-20 | 2024-12-13 | コーロン インダストリーズ インク | Modified cross-section polyethylene yarn and functional fabric containing the same |
| CN116590804A (en) * | 2023-07-17 | 2023-08-15 | 江苏新视界先进功能纤维创新中心有限公司 | A special-shaped fiber with multi-level wicking structure and its application in geotextile |
| CN116590804B (en) * | 2023-07-17 | 2024-03-22 | 江苏新视界先进功能纤维创新中心有限公司 | A kind of special-shaped fiber with multi-level wicking structure and its application in geotextiles |
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