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JPH09166309A - Operating method of waste melting furnace - Google Patents

Operating method of waste melting furnace

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Publication number
JPH09166309A
JPH09166309A JP7326997A JP32699795A JPH09166309A JP H09166309 A JPH09166309 A JP H09166309A JP 7326997 A JP7326997 A JP 7326997A JP 32699795 A JP32699795 A JP 32699795A JP H09166309 A JPH09166309 A JP H09166309A
Authority
JP
Japan
Prior art keywords
gas
furnace
waste
melting furnace
combustible
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7326997A
Other languages
Japanese (ja)
Inventor
Takeshi Takamiya
健 高宮
Hideji Shibaike
秀治 芝池
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP7326997A priority Critical patent/JPH09166309A/en
Publication of JPH09166309A publication Critical patent/JPH09166309A/en
Pending legal-status Critical Current

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  • Chimneys And Flues (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Incineration Of Waste (AREA)

Abstract

(57)【要約】 【課題】 溶融炉から発生する熱分解ガスを湿式洗浄
し、ガス回収する際に回収するガスのカロリーを大幅に
向上させ、燃料としての利用価値を向上させる操業方法
を提供する。 【解決手段】 コークスベッド式廃棄物溶融炉で廃棄物
を処理する方法において、発生した可燃性ガスの一部を
下段羽口以上に配置した羽口から、ごみ1t当たり25
0Nm3 程度の空気により炉内の可燃性ガスの一部を燃
焼させる事によって、溶融炉炉頂部ガス温度を常に80
0〜1100℃の高温雰囲気に制御し、可燃性ダスト及
びタール含有の高温可燃性ガス中のタールを完全にガス
化熱分解させ、湿式ガス処理を行うことにより従来より
も高カロリーなガスを回収する様になり、更に、熱源と
して、集塵装置により可燃性ダストを回収することを特
徴とした廃棄物溶融炉の操業方法。
(57) [Abstract] [PROBLEMS] To provide a method of operation in which thermal decomposition gas generated from a melting furnace is wet-cleaned and the calorie of the gas recovered is significantly improved when the gas is recovered, thereby improving the utility value as a fuel. To do. SOLUTION: In a method of treating waste in a coke bed type waste melting furnace, a part of combustible gas generated from a tuyere arranged in a lower tuyere or more is 25
By burning a part of the combustible gas in the furnace with air of about 0 Nm 3, the temperature of the gas at the top of the melting furnace is constantly maintained at 80
By controlling to a high temperature atmosphere of 0 to 1100 ° C, the tar in the high temperature combustible gas containing combustible dust and tar is completely gasified and pyrolyzed, and the gas with higher calorific value than before is recovered by performing wet gas treatment. In addition, a method of operating a waste melting furnace characterized by recovering combustible dust by a dust collector as a heat source.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、コークスのような
塊状炭素系可燃物質もしくは廃棄物自身を熱源として、
酸素又は空気で加熱する、都市ごみ、各種産業廃棄物、
またはそれらを脱水、乾燥、焼却、破砕処理等によって
得られた中間処理物の加熱溶融処理方法に関するもので
ある。
TECHNICAL FIELD The present invention relates to a lumpy carbonaceous combustible substance such as coke or the waste itself as a heat source.
Heating with oxygen or air, municipal waste, various industrial wastes,
Alternatively, the present invention relates to a heating and melting treatment method of an intermediate treated product obtained by dehydration, drying, incineration, crushing treatment or the like.

【0002】[0002]

【従来の技術】廃棄物溶融処理炉は、ごみを高温ガスに
より熱分解する熱分解炉と、燃焼により熱分解用高温ガ
スを造り、同時に灰分・無機物を溶融する溶融炉を上下
に一体化した効率の良いシャフト炉である。溶融炉内の
処理形態は大きく分けてごみの乾燥・予熱帯,乾留帯・
燃焼・溶融帯の3つのゾーンに分かれており、炉上部か
ら装入されたごみは乾燥帯(約300℃)で乾燥・予熱
され、熱分解帯でガス化し残りの灰分及び金属,陶磁
器,ガラス等の無機物が燃焼・溶融帯に降下し約200
0℃で溶融される。
2. Description of the Related Art A waste melting treatment furnace has a pyrolysis furnace that pyrolyzes waste with high-temperature gas, and a melting furnace that produces high-temperature gas for pyrolysis by combustion and at the same time melts ash and inorganic substances. It is an efficient shaft furnace. The processing modes in the melting furnace are roughly divided into drying of waste, pre-tropical zone, carbonization zone,
It is divided into three zones of combustion / melting zone. The dust charged from the upper part of the furnace is dried and preheated in the drying zone (about 300 ° C), gasified in the thermal decomposition zone, and the residual ash and metal, ceramics, glass Approximately 200
Melted at 0 ° C.

【0003】かかる廃棄物を溶融処理するために、コー
クスを配合した廃棄物をシャフト炉の頂部から装入し、
羽口から酸素含有ガスあるいは酸素富化ガスを炉内に吹
込み、コークスや熱分解によって生じた炭素質を高温炉
床において高温度で燃焼させ炉内の乾燥帯、乾留ガス化
帯および燃焼溶融帯を順次降下して溶融スラグ化し、高
温の燃焼排ガスは、シャフト内の廃棄物充填層を対向流
として上昇せしめ、タール・ダストを含んだ溶融炉から
の前記発生ガスを湿式処理し回収する技術は、特開昭5
4−94767号公報に開示されている。また、溶融炉
から発生するガスの浄化方法は特開昭54−10266
5号公報に開示されている。又、廃棄物の溶融炉の操業
方法は特開平6−231668号公報に開示されてい
る。
To melt-treat such waste, the coke-blended waste is charged from the top of the shaft furnace,
An oxygen-containing gas or an oxygen-rich gas is blown into the furnace from the tuyere, and the carbonaceous matter generated by coke and pyrolysis is burned at a high temperature in the high-temperature hearth, and the dry zone, carbonization gasification zone and combustion melting in the furnace are performed. Technology to recover the generated gas from the melting furnace containing tar and dust by wet treatment of the high temperature combustion exhaust gas, which rises as a counter flow in the waste packed bed in the shaft, by gradually descending the zone to form molten slag. Is JP-A-5
It is disclosed in Japanese Patent Publication No. 4-94767. A method for purifying gas generated from a melting furnace is disclosed in Japanese Patent Laid-Open No. 54-10266.
No. 5 discloses this. A method of operating a waste melting furnace is disclosed in Japanese Patent Laid-Open No. 6-231668.

【0004】前記した最初の公開技術は、溶融炉からの
発生ガスを湿式浄化せしめる方法において浄化過程に生
じた排水を、タールスラッジ,スカム等の微粒子を含む
濃縮廃液とし、炉内に圧送し溶融分解せしめることを特
徴とする廃棄物溶融処理における可燃性ガス洗浄排水の
処理方法であり、タールを高温でガス化させ、発生ガス
中のタールを完全に分解し高カロリーのガスを回収する
ものではない。
In the first disclosed technology, the wastewater generated in the purification process in the method of wet-cleaning the gas generated from the melting furnace is used as a concentrated waste liquid containing fine particles such as tar sludge and scum, and is pumped into the furnace for melting. It is a method of treating flammable gas cleaning wastewater in waste melting treatment that is characterized by decomposing, and it does not completely decompose tar in the generated gas and recover high calorie gas by gasifying tar at high temperature. Absent.

【0005】二番目のものは溶融炉から発生したガス中
を移動充填層型浄化装置を通過せしめ、可燃ダスト、タ
ールを捕集するとともに、これらの可燃ダスト、タール
等を捕集したコークスもしくは石灰石を溶融炉に投入し
溶融処理する技術であり、タールを高温で分解しガス化
させるものではない。三番目のものは廃棄物を溶融処理
する溶融炉の炉床側に少なくとも下段羽口を備え、その
上方に上下に複数段の上段羽口を配列した溶融炉におい
て、上段羽口から供給した空気により、上段羽口を設置
した部分の炉内での廃棄物中可燃分の燃焼を促進させる
ものであり、炉内で発生したガスを燃焼させ、炉頂部ガ
ス温度を高くする為ではない。
The second one is to pass the gas generated from the melting furnace through a moving packed bed type purification device to collect combustible dust and tar, and also to collect coke or limestone of the combustible dust and tar. Is a technique for charging and melting in a melting furnace, and does not decompose tar into gas at high temperature. The third one is a melting furnace that has at least the lower tuyeres on the hearth side of the melting furnace that melts waste, and has a plurality of upper tuyeres arranged above and below it, and the air supplied from the upper tuyeres. This promotes the combustion of combustible components in the waste in the furnace where the upper tuyeres are installed, and is not for burning the gas generated in the furnace to raise the furnace top gas temperature.

【0006】[0006]

【発明が解決しようとする課題】一般に、廃棄物を溶融
処理する場合、溶融炉から発生する可燃性ガスの中には
可燃性ダスト及びタール分が含まれる。発生ガスを湿式
水洗処理及びバグフィルター処理する事により可燃性ガ
スとタールとを回収しそれぞれ利用するのも1つの方法
であるが、ガス単味のカロリーが低く、又回収したター
ルは燃焼性が悪く、更に回収の為の分離装置を必要とす
る等の問題がある。かかる条件下で、本発明が解決しよ
うとする課題は、溶融炉から発生する可燃性ガスに含有
されるタールを完全に熱分解・ガス化させることによ
り、ガスを湿式洗浄処理しガス回収する場合に、後流の
湿式ガス処理装置を簡易にし、回収するガス単味のカロ
リーを大幅に向上させ、燃料としての利用価値を向上さ
せる事にある。
Generally, in the case of melting and treating waste, combustible gas generated from a melting furnace contains combustible dust and tar. One method is to recover the combustible gas and the tar by using the generated gas with a wet water washing process and a bag filter, respectively, but the calorie of the gas alone is low, and the recovered tar is not combustible. However, there is a problem that a separation device for recovery is required. Under such conditions, the problem to be solved by the present invention is to perform a wet cleaning treatment of gas by completely pyrolyzing and gasifying tar contained in a combustible gas generated from a melting furnace. In addition, the downstream wet gas treatment device is simplified, the calorie of the recovered gas is greatly improved, and the utility value as a fuel is improved.

【0007】[0007]

【課題を解決するための手段】上記の課題を解決するた
めの、本発明の特徴とする手段は、コークスベッド式廃
棄物溶融炉で廃棄物を処理する方法において、発生した
可燃性ガスの一部を、下段羽口1以上に配置した羽口か
ら、ごみ1t当たり250Nm3 程度の空気により、炉
内の可燃性ガスの一部を燃焼させる事によって溶融炉炉
頂部ガス温度を常に800〜1100℃に制御し、可燃
性ダスト及びタール含有の高温可燃性ガス中のタールを
完全に分解させ、湿式ガス処理を行うことにより従来よ
りも高カロリーなガスを回収する方法を提供する事にあ
る。
Means for Solving the Problems In order to solve the above-mentioned problems, a feature of the present invention is that one of the combustible gases generated in a method of treating waste in a coke bed type waste melting furnace. Part from the tuyeres arranged in the lower tuyeres 1 or more, by burning about 250 Nm 3 of air per 1 ton of dust, a part of the combustible gas in the furnace is burned to keep the melting furnace furnace top gas temperature at 800 to 1100. It is an object of the present invention to provide a method of recovering a gas having a higher calorific value than before by controlling the temperature to 0 ° C., completely decomposing the tar in a high-temperature combustible gas containing combustible dust and tar, and performing a wet gas treatment.

【0008】廃棄物が熱分解を起こす場合、一般的に残
渣,タール,熱分解ガス,乾留水に分解するが、高温度
で乾留を行うほどタールの生成量が減少し、発生ガス量
及び発生カロリーが高くなることが判明した。従って、
該溶融炉内の廃棄物の高さレベルを低下させ、発生する
可燃性ガスの温度を高くせしめ、更に、下段羽口よりも
上部に配置した羽口から装入する空気により燃焼させ、
炉頂部ガス温度を800℃以上に保持し、この高温ガス
雰囲気中の炉内に廃棄物を装入する事により、投入され
た廃棄物は直ちに乾燥し高温乾留を開始し、発生したタ
ールは炉内で熱により炭化水素系のガスに完全に分解さ
れる。
[0008] When a waste substance undergoes thermal decomposition, it is generally decomposed into a residue, tar, thermal decomposition gas, and dry distilled water. It turned out to be high in calories. Therefore,
Lowering the height level of the waste in the melting furnace, increasing the temperature of the combustible gas generated, further, burned by the air charged from the tuyere arranged above the lower stage tuyere,
By keeping the gas temperature at the furnace top at 800 ° C or higher and charging the waste into the furnace in this high-temperature gas atmosphere, the injected waste is immediately dried and high-temperature carbonization starts, and the tar generated is removed from the furnace. Inside, it is completely decomposed into hydrocarbon gas by heat.

【0009】つまり、従来、乾燥・予熱帯,乾留帯,燃
焼・溶融帯の3ゾーンで処理されていたが、本発明では
従来より高温でタールを完全にガス化させる為に炉内は
乾燥・乾留・予熱帯と燃焼・溶融帯の2ゾーンで処理さ
れる。又、タール分のガス化は800℃以上で有れば完
了するが、炉頂部ガス温度を1100℃以上にすると、
廃棄物の熱分解により生じた可燃性ダストが溶融炉壁に
融着し廃棄物の荷下がりを悪くする事が判明した。従っ
て羽口から装入する空気量により、炉頂部ガス温度を8
00℃以上1100℃以下に制御するのが望ましい。
That is, conventionally, the treatment was carried out in three zones of drying / pre-tropical zone, carbonization zone, combustion / melting zone, but in the present invention, the inside of the furnace is dried in order to completely gasify tar at a higher temperature than in the past. It is processed in two zones: carbonization / pre-tropics and combustion / melting zone. The gasification of tar is completed if the temperature is 800 ° C or higher, but if the gas temperature at the furnace top is 1100 ° C or higher,
It was found that the flammable dust generated by the thermal decomposition of the waste adheres to the wall of the melting furnace and deteriorates the unloading of the waste. Therefore, depending on the amount of air charged from the tuyere, the gas temperature at the furnace top can be set to 8
It is desirable to control the temperature to be not lower than 00 ° C and not higher than 1100 ° C.

【0010】[0010]

【発明の実施の形態】図1を基に炉の構成を以下に説明
する。すなわち、図1は本発明に係る廃棄物溶融炉の構
造を示す図である。炉下部は燃焼・溶融帯であり、下段
羽口1が配置されている。朝顔部(B)及びその上部に
上段羽口2を配置している。本発明では、炉頂部温度を
監視しながら、上段羽口2から250Nm3 /ごみtの
空気を吹き込み、炉頂部ガス温度を800℃〜1100
℃に制御した。又、ごみ充填高さを低くすることで、炉
頂部ガス温度が上昇し、上段から吹き込む空気量が減少
しガス単味カロリーの上昇に効果があった。
BEST MODE FOR CARRYING OUT THE INVENTION The structure of a furnace will be described below with reference to FIG. That is, FIG. 1 is a view showing the structure of the waste melting furnace according to the present invention. The lower part of the furnace is a combustion / melting zone, and the lower tuyeres 1 are arranged. The upper tuyeres 2 are arranged on the morning glory part (B) and the upper part thereof. In the present invention, while monitoring the furnace top temperature, air of 250 Nm 3 / dust t is blown from the upper tuyeres 2 to make the furnace top gas temperature from 800 ° C. to 1100.
C. was controlled. Further, by lowering the height of filling the refuse, the temperature of the gas at the top of the furnace was increased, the amount of air blown from the upper stage was decreased, and it was effective in increasing the gas simple calories.

【0011】廃棄物溶融炉からの排ガスの処理フローを
図2に説明する。溶融炉3内で熱分解されたダスト混じ
りのガスは、サイクロン4を通過し、ダストの大半を除
去され、洗浄塔5及びベンチュリースクラバ6を通過す
ることで、HClが除去される。清浄化したガスは、バ
グフィルター7通過後、別に設けた燃焼炉12で燃焼さ
れ、高効率に廃熱回収されるサイクロン4で回収された
可燃性ダストは、一旦ホッパ8に貯められた後、定量的
に溶融炉の羽口2から熱源として吹き込まれる。ガス洗
浄に使用された洗浄液は貯液槽9で貯められた後、洗浄
液処理槽10で処理され、洗浄液循環ポンプ11を介し
て洗浄液として循環再利用される。
The processing flow of the exhaust gas from the waste melting furnace will be described with reference to FIG. The dust-mixed gas pyrolyzed in the melting furnace 3 passes through the cyclone 4, most of the dust is removed, and the cleaning tower 5 and the venturi scrubber 6 are passed, whereby HCl is removed. The purified gas is burned in a separate combustion furnace 12 after passing through the bag filter 7, and the combustible dust collected in the cyclone 4 for highly efficiently recovering waste heat is once stored in the hopper 8, It is blown quantitatively from the tuyere 2 of the melting furnace as a heat source. The cleaning liquid used for gas cleaning is stored in the liquid storage tank 9, processed in the cleaning liquid processing tank 10, and circulated and reused as the cleaning liquid via the cleaning liquid circulation pump 11.

【0012】又、回収された清浄な高カロリーガスを、
隣接した製鐡所の設備を利用し燃焼させれば、設備コス
トを低減した熱回収が可能となる。廃棄物を熱分解溶融
処理した時に溶融炉から発生する可燃性ガスのカロリー
及びガス中タール量を、炉頂部ガス温度を従来通りの温
度に保持したときの値と共に表1に示す。
In addition, the collected clean high-calorie gas is
Combustion using the equipment of the adjacent steelworks enables heat recovery with reduced equipment costs. Table 1 shows the calorific value of the combustible gas generated from the melting furnace and the amount of tar in the gas when the waste is pyrolyzed and melted, together with the values when the gas temperature at the furnace top is kept at the conventional temperature.

【0013】[0013]

【表1】 [Table 1]

【0014】[0014]

【発明の効果】本発明によって、以下の効果を実現する
ことができる。 (1)本発明により、湿式処理によりガス回収する場
合、その分離回収に手間がかかっていたタールを、ハン
ドリング性の良いガスとして回収する事ができる。 (2)タールを高温で熱分解させる事により、炭化水素
系のガスとして回収することが可能となり従来より高カ
ロリーの可燃性ガスを回収でき、工業的価値が大きい。 (3)本発明により溶融炉から発生する可燃性ガス中タ
ールをガス化させる為に、従来の溶融炉からの発生ガス
を湿式処理する際に必要であったタール分離装置が不要
となり、後流の湿式ガス処理装置が簡易で経済的にな
る。
According to the present invention, the following effects can be realized. (1) According to the present invention, in the case of recovering a gas by a wet process, it is possible to recover tar, which has been troublesome in separating and recovering it, as a gas having good handleability. (2) By thermally decomposing tar at a high temperature, it is possible to recover it as a hydrocarbon-based gas, and a flammable gas having a higher calorie than before can be recovered, which is of great industrial value. (3) In order to gasify the tar in the flammable gas generated from the melting furnace according to the present invention, the tar separation device, which was necessary when the generated gas from the conventional melting furnace is wet-processed, becomes unnecessary, and the downstream flow The wet gas treatment device of is simple and economical.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明に係る廃棄物溶融炉の構造を示す図、FIG. 1 is a view showing a structure of a waste melting furnace according to the present invention,

【図2】廃棄物溶融炉からの排ガスの処理フローを示す
図である。
FIG. 2 is a diagram showing a processing flow of exhaust gas from a waste melting furnace.

【符号の説明】[Explanation of symbols]

1 下段羽口 2 上段羽口 3 溶融炉 4 サイクロン 5 洗浄塔 6 ベンチュリースクラバ 7 バグフィルター 8 ホッパ 9 貯液槽 1 0 洗浄液処理槽 1 1 洗浄液循環ポンプ 1 2 燃焼炉 1 Lower tuyeres 2 Upper tuyeres 3 Melting furnace 4 Cyclone 5 Washing tower 6 Venturi scrubber 7 Bag filter 8 Hopper 9 Storage tank 1 0 Washing liquid treatment tank 1 1 Washing liquid circulation pump 1 2 Combustion furnace

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 F23J 15/02 F23J 15/00 C 15/00 J ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical display location F23J 15/02 F23J 15/00 C 15/00 J

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 炉床部に下段羽口を、その上方の朝顔部
には上段羽口を有するコークスベッド方式の溶融炉で廃
棄物を処理する方法において、前記溶融炉の炉頂部内の
温度を800℃〜1100℃の高温雰囲気に保持し、投
入された廃棄物を直ちに高温乾留することにより、炉内
で発生する可燃性ガス中のタールを、ガス化することを
特徴とする廃棄物溶融炉の操業方法。
1. A method for treating waste in a coke bed type melting furnace having a lower tuyeres in the hearth and an upper tuyer in the upper bosh, and the temperature in the furnace top of the melting furnace. Is kept in a high temperature atmosphere of 800 ° C to 1100 ° C, and the charged waste is immediately subjected to high temperature dry distillation to gasify the tar in the combustible gas generated in the furnace, thereby melting the waste. How to operate the furnace.
【請求項2】 上段羽口より吹き込んだ空気により炉内
の可燃ガスの一部を燃焼させ、炉頂部内の雰囲気温度を
800℃〜1100℃に保持することを特徴とする請求
項1記載の廃棄物溶融炉の操業方法。
2. The air blown from the upper tuyere burns a part of the combustible gas in the furnace to maintain the ambient temperature in the furnace top at 800 ° C. to 1100 ° C. Operation method of waste melting furnace.
【請求項3】 炉外へ排出した熱分解ガス中の可燃性ダ
ストは集塵装置により回収し、一方、ガスは水洗処理を
施し高カロリーガスとして回収することを特徴とする請
求項1又は2記載の廃棄物溶融炉の操業方法。
3. The combustible dust in the pyrolysis gas discharged to the outside of the furnace is recovered by a dust collector, while the gas is washed with water and recovered as a high-calorie gas. Operation method of the waste melting furnace described.
JP7326997A 1995-12-15 1995-12-15 Operating method of waste melting furnace Pending JPH09166309A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7326997A JPH09166309A (en) 1995-12-15 1995-12-15 Operating method of waste melting furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7326997A JPH09166309A (en) 1995-12-15 1995-12-15 Operating method of waste melting furnace

Publications (1)

Publication Number Publication Date
JPH09166309A true JPH09166309A (en) 1997-06-24

Family

ID=18194163

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7326997A Pending JPH09166309A (en) 1995-12-15 1995-12-15 Operating method of waste melting furnace

Country Status (1)

Country Link
JP (1) JPH09166309A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0905213A2 (en) * 1997-09-13 1999-03-31 Shawton Engineering Limited A method of producing a clean gas from biodegradable waste material
WO2000016009A1 (en) * 1998-09-11 2000-03-23 Nkk Corporation Method and device for melt-treating incineration residue containing salts
KR100752791B1 (en) * 2007-02-08 2007-08-29 (주)대성그린테크 Ds-vt-2

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0905213A2 (en) * 1997-09-13 1999-03-31 Shawton Engineering Limited A method of producing a clean gas from biodegradable waste material
EP0905213A3 (en) * 1997-09-13 1999-08-11 Shawton Engineering Limited A method of producing a clean gas from biodegradable waste material
WO2000016009A1 (en) * 1998-09-11 2000-03-23 Nkk Corporation Method and device for melt-treating incineration residue containing salts
US6379416B1 (en) 1998-09-11 2002-04-30 Nkk Corporation Method and device for melt-treating incineration residue containing salts
KR100752791B1 (en) * 2007-02-08 2007-08-29 (주)대성그린테크 Ds-vt-2

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