JPH08325122A - Shampoo composition - Google Patents

Abstract

PURPOSE: To obtain a low stimulating shampoo composition excellent in time dependent stability and foamability, capable of easily passing fingers through the hair during washing and rinsing, easily combing during drying and finishing in a fresh and natural completion without sticking. CONSTITUTION: This shampoo composition contains (a) 1-30wt.% amphoteric surfactant and/or semipolar surfactant, (b) 1-30wt.% amide amine-type surfactant of the formula [R<1> is a 7-19C alkyl or alkenyl ; (m) is 2-4] and (c) 0.1-5% cationic surfactant and/or cationic polymer. The sum total of the components (a) to (c) is 10-60wt.%. The objective shampoo composition can be obtained by further adding 0.5-10wt.% alkanolamide type surfactant and usual components, dissolving the mixture uniformly in water or emulsifying to disperse the mixture by a usual means and adjusting the resulting composition to pH3-9.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention has a low irritation, excellent foaming property, good finger passage at the time of washing and rinsing, good comb passage at the time of drying, non-greasy, smooth and natural cohesion. To finish-composition.

[0002]

2. Description of the Related Art Conventionally, anionic surfactants such as alkyl sulfate ester salts, polyoxyethylene alkyl sulfate ester salts, alkylbenzene sulfonates and α-olefin sulfonates have been used as surfactants for Shampu-base. It has been widely used. However, all of these surfactants have skin irritation and not only cause skin roughness, but also form a complex by mixing with a cationic surfactant which is a conditioning component. However, it is known that the performance of both is significantly impaired. On the other hand, the amino acid-type, amidoamine-type and amidobetaine-type amphoteric surfactants are extremely mild surfactants with low irritation to the skin and ocular mucous membranes, and in addition to cationic surfactants. However, it is known that each performance is not impaired.

A detergent composition containing, as a main component, an alkyliminodiacetic acid salt which is an amino acid-type amphoteric surfactant is disclosed in JP-A-6-172785 and JP-A-6-172.
It is disclosed in Japanese Patent No. 786. Examples of the detergent composition containing an amidoamine type amphoteric surfactant as a main component include
JP-A-63-128100 and JP-A-2-2736
No. 12 publication. A detergent composition containing an amidobetaine type amphoteric surfactant as a main component is disclosed in JP-A-60-195200 and JP-A-4-6.
It is disclosed in Japanese Laid-Open Patent Publication No. 0085. However, none of these detergent compositions have sufficient foaming,
The foam was coarse and poor in creaminess, and the feel during washing and rinsing was not satisfactory.

[0004]

SUMMARY OF THE INVENTION In view of such problems of the prior art, the present invention has low irritation and excellent foaming property, and also has excellent foam creaming property, and when washing hair and rinsing. It is an object of the present invention to provide a shampoo composition which is good in passing through fingers when passing, and when passing through combs when dried, and which is not sticky and has a smooth and natural cohesive finish.

[0005]

Means for Solving the Problems The inventors of the present invention have conducted extensive studies in order to achieve the above object, and as a result, have found that an amphoteric surfactant and / or a semipolar surfactant and a specific amidoamine type surfactant are used. By using a combination of the above and a cationic surfactant and / or a cationic polymer in combination, a shampu composition satisfying all of the above-mentioned properties can be obtained, and further alkanolamide type surfactants can be added to these components. The present inventors have completed the present invention by knowing that the combination of agents increases the duration of foam and gives a more creamy sham foam composition.

That is, the present invention provides the following components a to c: a) one or more amphoteric surfactants and / or semipolar surfactants b) amidoamine type surfactants represented by the formula (I) One or more (R ¹ is an alkyl group or an alkenyl group having 7 to 19 carbon atoms, m is an integer of 2 to 4) c) One or more cationic surfactants and / or cationic polymers are contained, Component a = 1-30% by weight, component b = 1-30
% By weight, c component = 0.1-5% by weight, a component + b component +
The component c is 10 to 60% by weight, and the balance is water. The present invention further comprises d) an alkanolamide type surfactant in addition to the specific amounts of the components a to c, and the content of the component d is 0.5 to 10% by weight. It is also possible to provide a shampoo composition characterized by:

[0007]

The amphoteric surfactant and semipolar surfactant of the component a used in the present invention include all amphoteric surfactants and semipolar surfactants generally used as cosmetic bases. Can be used, specifically, amphoteric surfactants such as amino acid type, amidoamine type, amidobetaine type, alkylbetaine type, sulfobetaine type, phosphobetaine type, and tertiary amine oxide type semipolar surfactant. Is mentioned.

Among these, the amino acid type,
Amphoteric surfactants such as midamine type and amidobetaine type
Is preferably used. As these amphoteric surfactants
Include the following components a-1 to a-3. a-1) Amino acid type amphoteric surfactant represented by formula (II)(R²Is an alkyl group or alkenyl having 7 to 19 carbon atoms
Group, n and o are each an integer of 1 to 3, M¹, M²Each is water
Elemental, alkali metal, alkaline earth metal, ammonium
Groups, basic amino acids or alkanolamine cations
A-2) Amidoamido represented by the formula (III) or (IV)
Type amphoteric surfactant [R³, R^FiveIs an alkyl group having 7 to 19 carbon atoms or
Alkenyl group, R^Four, R⁶Are each a group -CH₂COOM³
Or -CH₂CH₂COOM³(M³Is hydrogen, alk
Is a metal or alkanolamine), R⁷Is the base-
CH₂COOM³, -CH₂CH₂COOM³(M³Is
Same as above) or hydrogen] a-3) Amidobetaine-type amphoteric interface represented by formula (V)
Activator(R⁸Is an alkyl group or alkenyl having 7 to 19 carbon atoms
Group, p is an integer of 2 to 4)

Examples of the amino acid-type amphoteric surfactant represented by the above formula (II) include sodium lauryl iminodiacetic acid, potassium lauryl iminodiacetic acid, sodium myristyliminodiacetic acid, potassium myristyliminodiacetic acid, palmitylimino. Sodium diacetate, sodium stearyl imino diacetate, sodium lauryl imino dipropionate, potassium lauryl imino dipropionate, sodium myristyl imino dipropionate, potassium myristyl imino dipropionate, sodium palmityl imino dipropionate, stearyl imino dipropionate Sodium acid etc. are mentioned.

Examples of the amidoamine type amphoteric surfactant represented by the above formula (III) or (IV) include, for example, N
-Lauroyl-N'-carboxymethyl-N '-(2-
Hydroxyethyl) ethylenediamine, N-cocoyl-
Examples include N′-carboxymethyl-N ′-(2-hydroxyethyl) ethylenediamine and N-myristoyl-N′-carboxymethyl-N ′-(2-hydroxyethyl) ethylenediamine. Moreover, it is not limited to these, and N-lauroyl-N'-2-hydroxyethyl-N
′ -Carboxymethylethylenediamine, N-cocoyl-N′-2-hydroxyethyl-N′-carboxymethylethylenediamine, N-myristoyl-N′-2-hydroxyethyl-N′-carboxymethylethylenediamine, and salts thereof. Can also be mentioned.

Examples of the amidobetaine-type amphoteric surfactant represented by the above formula (V) include laurylamidopropyldimethylaminoacetic acid betaine, cocoamidopropyldimethylaminoacetic acid betaine, myristylamidopropyldimethylaminoacetic acid betaine, and palmitylamidopropyl. Examples include dimethylaminoacetic acid betaine.

As the component a, in addition to the above-mentioned amphoteric surfactant, a tertiary amine oxide type semipolar surfactant can be preferably used. Examples of this include lauryldimethylamine oxide, myristyldimethylamine oxide, palmityldimethylamine oxide, stearyldimethylamine oxide, lauryldi (2-hydroxyethyl) amine oxide, stearyldi (2-hydroxyethyl) amine oxide, and the like. Can be mentioned.

The amidoamine type surfactant of the component b used in the present invention is represented by the above formula (I), and specific examples thereof include laurylamidopropyldimethylamine, cocoamidopropyldimethylamine, Examples thereof include myristylamidopropyldimethylamine, palmitylamidopropyldimethylamine, stearylamidopropyldimethylamine and the like.

The component c used in the present invention is one or more of a cationic surfactant and / or a cationic polymer. Among these, as the cationic surfactant, for example, stearyl trimethyl ammonium chloride, stearyl trimethyl ammonium bromide, behenyl trimethyl ammonium chloride,
Examples thereof include oleyldimethylbenzylammonium chloride, cetyltrimethylammonium chloride, methylbis [2-hydroxyethyl] stearylammonium chloride, methylbis [2-hydroxyethyl] oleylammonium chloride, distearyldimethylammonium chloride and dioleyldimethylammonium chloride.

Further, as the cationic polymer, for example, Mark Coat 100, 280, 550 (manufactured by Merck), Celcoat H-100, L-200 (manufactured by National Starch) are representative. Dimethyldiallylammonium chloride derivative, quaternary nitrogen-containing polyvinylpyrrolidone represented by Gaffcoat # 755 (manufactured by Gaff), polymers JR-125, JR-400, LR-40.
0, a quaternary nitrogen-containing cellulose ether derivative represented by JR-30M (manufactured by Union Carbide Co., Ltd.), polyethyleneimine represented by Epomin P-1000 (manufactured by Nippon Shokubai Kagaku Co., Ltd.), Narco 600 (Narco) (Chemical company)
Water-soluble cationic polymers of tetraethylpentamine and epichlorohydrin represented by Sumiflot (manufactured by Sumitomo Chemical Co., Ltd.), quaternary nitrogen-containing poly (trialkylaminoethyl methacrylate) derivatives represented by COSMEDIA C- Examples include quaternary nitrogen-containing guar gum derivatives represented by H.261 (manufactured by Henkel).

In the present invention, the above-mentioned component a is 1 to 30% by weight, preferably 3 to 20% by weight based on the entire shampoo composition.
Used in a weight percentage. If it is less than 1% by weight, stability with time deteriorates, and if it exceeds 30% by weight, sufficient bubble force cannot be obtained. Further, the above-mentioned b component is a jump-
It is used in a proportion of 1 to 30% by weight, preferably 3 to 20% by weight, based on the entire composition. If it is less than 1% by weight, sufficient bubble strength cannot be obtained, and if it exceeds 30% by weight, the stability with time deteriorates. Further, the component c is used in a proportion of 0.1 to 5% by weight, preferably 0.5 to 3% by weight, based on the entire shampoo composition. If it is less than 0.1% by weight, a sufficient conditioning effect cannot be obtained, and if it exceeds 5% by weight,
Foaming becomes extremely bad.

Further, in the present invention, the above-mentioned a component, b
As for the component and the c component, the total amount of these three components is 10 to 60% by weight, preferably 15 to 60% by weight based on the entire shampoo composition.
The amount used is determined so as to be 40% by weight. If the total amount is less than 10% by weight, sufficient foaming power and detergency cannot be obtained, and if it exceeds 60% by weight, it becomes difficult to maintain stability.

In the present invention, by using the above-mentioned components a to c in the above-mentioned specific proportions, the composition has a low irritation and an excellent foaming property, and also has an excellent cream-creasing property, so that the hair is washed and rinsed. It has good finger combing properties when dry, and good combing properties when dry, giving a shampoo composition that is not sticky and has a smooth, natural cohesiveness. In addition to the above-mentioned components a to c, alkanolamides of the component d are also obtained. When used in combination with a type surfactant, the foam retention rate is increased, and a more creamy sham foam composition is obtained, which is desirable.

Examples of such alkanolamide type surfactants of component d include lauric acid diethanolamide,
Examples thereof include coconut oil fatty acid dietanolamide and myristic acid dietanolamide. The usage amount is
It is 0.5 to 10% by weight, preferably 2 to 7% by weight, based on the entire composition. If it is less than 0.5% by weight, a sufficient effect cannot be obtained, and if it exceeds 10% by weight, foaming becomes poor.

The pH of the shampoo composition of the present invention is preferably in the range of 3 to 9, more preferably 4.5 to 7.
It is 5. When the pH is less than 3 or exceeds 9, the irritation to the skin and hair becomes strong. As the pH adjuster, it is possible to use all of the inorganic acids and organic acids generally used as a blending component of cosmetics. Examples thereof include hydrochloric acid, sulfuric acid, phosphoric acid, acetic acid, lactic acid, citric acid, malic acid, oxalic acid, succinic acid, tartaric acid and higher fatty acids. In addition, even if these acids are used alone,
You may use 2 or more types together.

The shampoo composition of the present invention comprises the above a.
In addition to the component (c) or component (d) and the component (d), components and additives that are commonly used in detergents can be added.
For example, higher alcohols, silicone derivatives, protein derivatives, squalane, jojoba oil, olive oil, castor oil,
Lanolin, lecithin, oily ingredients such as fatty acid esters of polyethylene glycol, humectants such as glycerin, ethylene glycol, propylene glycol, nonionic surfactants such as polyoxyethylene alkyl ether, acyl Methyl taurine salt, fatty acid amide ether sulfate, anionic surfactant such as acylglutamate, water-soluble polymer such as hydroxypropylmethyl cellulose, hydroxyethyl cellulose, bactericide,
A chelating agent, an ultraviolet absorber, a pH adjusting agent, a natural extract derived from animals and plants, a pigment, a fragrance and the like can be included.

The shampoo composition of the present invention comprises the above a.
The component (c) or the component (d) and the component (d) are contained as essential components, optionally containing the above-mentioned additive components, etc., and these and water are uniformly dissolved or emulsified and dispersed by a conventional method.

[0023]

EXAMPLES Next, the present invention will be described in more detail by way of examples.

Examples 1 to 11 According to the compounding compositions shown in Tables 1 to 3, 11 kinds of jump-
A composition was prepared. In each table, the component "cationic polymer A" is the product name "Mark Coat 10" manufactured by Merck & Co., Inc.
0 "and" Cationic Polymer B "are trade names" Gierna-QH300 "manufactured by Daicel Chemical Industries, Ltd., and" Cationic Polymer C "are trade names" Gaff Cut 73 "manufactured by Gaff.
4 ”. Further, hydrochloric acid and / or citric acid was used as the pH adjuster (acid).

[0025]

[Table 1]

[0026]

[Table 2]

[0027]

[Table 3]

Comparative Examples 1 to 16 16 kinds of jumps were prepared according to the composition shown in Tables 4 to 8.
A composition was prepared. In each table, the “cationic polymers A to C” and the pH adjuster (acid) of the component c are the same as those described in Examples 1 to 11 above.

[0029]

[Table 4]

[0030]

[Table 5]

[0031]

[Table 6]

[0032]

[Table 7]

[0033]

[Table 8]

Examples 1 to 11 and Comparative Examples 1 to 1 above
For each of the 6-champ-compositions,
The pH, viscosity, stability over time, skin irritation, foaming property, foam cleansing property, finger combability during hair wash, comb combability after hair wash, and conditioning property after hair wash were evaluated. The results were as shown in Tables 9 to 12 below.

(1) pH The pH of the sample (Shamp-composition) at 25 ° C. was measured.

(2) Viscosity The viscosity of the sample (Shamp composition) at 25 ° C. was measured with a B type viscometer.

(3) Stability with time A sample (Shamp-composition) was stored at -5 ° C, 25 ° C and 45 ° C for 1 month, and its appearance was observed and evaluated according to the following three grades. ◯: Good stability (transparent or slightly turbid state, no change in appearance) Δ: Slightly poor stability (slightly turbidity or coloration) ×: Poor stability (precipitation or solidification,
(Coloring is remarkable)

(4) Skin irritation Evaluation was made by the protein denaturation rate. That is, using an aqueous high-performance liquid chromatograph, ovalbumin 0.02
Using a pH 7 buffer solution having a concentration of 5% by weight, the height of the absorption peak at 220 nm was measured when the sample was added so that the concentration of the sample was 1% by weight, and the protein denaturation rate was calculated by the following formula. . Protein denaturation rate = [(H0-HS) / H0] × 100 H0: Height of absorption peak when sample is not added HS: Height of absorption peak when sample is added The rate of protein denaturation was used to evaluate the following 4 levels. Protein denaturation rate less than 30%: Very low skin irritation Protein denaturation rate 30% to less than 60%: Weak skin irritation Protein denaturation rate 60% to less than 80%: Medium skin irritation Protein denaturation rate 80% Above: Strong skin irritation

(5) Foaming property An aqueous solution having a sample concentration of 1% by weight was prepared, and the foam height was measured at 25 ° C. immediately after the sample was charged and after 5 minutes by the Ross Miles method. The height of the foam immediately after the sample is loaded is 150 mm or more, and the foam persistence rate calculated by the following formula is 90%.
The above was evaluated as a detergent with good foaming. Persistence of foam = [(foam height after 5 minutes) / (foam height immediately after sample introduction)] × 100

(6) Cream Creamy Property The creamy property of 20 women as panelers was evaluated when the hair was washed with 5 ml of the sample (shamp composition). If you feel the bubbles are creamy, you get 2 points; if you feel the bubbles are slightly creamy, you get 1 point; if you feel the bubbles are not creamy, you get 0 points. The average value of the names was calculated. Clear the bubbles with an average value of 1.5 or more.
It was evaluated as having good meability.

(7) Finger-passing property at the time of washing hair Using 20 women as panelers, the finger-passing property when the sample (Shamp-composition) was washed with 5 ml of hair was evaluated. 2 points when you feel that your fingers are smooth and your hair does not get stuck,
The average value of 20 persons was calculated with 1 point when the hair was felt to be slightly hit by the finger and 0 point when the finger was felt to be very poor in finger passage. Those having an average value of 1.5 points or more were evaluated as having good finger passage when washing hair.

(8) Combability after Washing Hair 20 women were used as panelers and the combability after hair washing and drying with 5 ml of a sample (Shamp composition) was evaluated. 2 points if the hair does not feel squeaky and feels that the comb passage is smooth, 1 point if the hair feels slightly combed, and 0 if the comb passage feels very bad. As points, the average value of 20 people was obtained. Those having an average value of 1.5 or more were evaluated to have good combability after washing hair.

(9) Conditioning Property After Washing Hair 20 women were used as panelers, and the conditioning effect after washing and drying hair with 5 ml of the sample (Champe composition) was evaluated. 2 points if you feel that the conditioning effect is excellent, 1 point if you feel that the conditioning effect is slightly obtained, and 0 point if you feel that the conditioning effect cannot be obtained. The average value of 20 persons was calculated. Those having an average value of 1.5 or more were evaluated as having a good conditioning effect after washing hair.

[0044]

[Table 9]

[0045]

[Table 10]

[0046]

[Table 11]

[0047]

[Table 12]

As is clear from the above evaluation results, all of the shampu compositions of the present invention of Examples 1 to 11 were
It has an appropriate viscosity and pH, excellent stability over time, low irritation to the skin, excellent foaming and foam stability, and a creamy foam.
Further, it was good in finger combability after washing and rinsing and comb combing after drying, and was excellent in conditioning effect.

On the other hand, in Comparative Examples 1 to 16, sufficient performance was not obtained. That is, in Comparative Example 1, b component was not blended, and thus foaming was insufficient. In Comparative Example 2, since the component a was not blended, not only the viscosity was low, but also the skin irritation was high. In Comparative Example 7, since the component c was not blended, the feel during and after washing the hair was extremely poor.

Further, in Comparative Examples 3 and 4, since the component a or the component b was blended beyond the range of the present invention, the viscosity was high, the foaming was bad, and the stability over time was poor. In Comparative Example 5, the blending amounts of the components a, b and c were less than the range of the present invention, so that the foaming was extremely poor. In Comparative Example 6, since the components a, b and c are mixed beyond the range of the present invention, the stability with time is poor. In Comparative Example 8, since the component c was blended beyond the range of the present invention, foaming and stability over time deteriorated. In Comparative Example 9, since the d component was blended beyond the range of the present invention, problems occurred in foaming and stability over time.

Further, in Comparative Examples 10 to 16, the components a and / or b were replaced by components other than the components of the present invention, and therefore, skin irritation, foaming, foam stability and foam clearing were obtained. The characteristics such as meability were not sufficient, and the feel during and after hair washing was not good.

Example 12 Monosodium lauryl iminodiacetic acid 3% by weight, N-cocoyl-N'-carboxymethyl-N '-(2-hydroxyethyl) ethylenediamine 3% by weight, cocoamidopropyldimethylaminoacetic acid betaine 2% by weight , 8% by weight laurylamidopropyldimethylamine, 3% by weight lauric acid diethylanolamide, 0.3% by weight stearyltrimethylammonium chloride, 0.6% by weight distearyldimethylammonium chloride, cationic polymer A (manufactured by Merck) (Product name "Mercote 100")
0.7% by weight, ethylene glycol distearate 1.
7% by weight, pH adjuster (35% by weight hydrochloric acid, pH = 5.3
Adjusted to -6.3) A suitable amount, a suitable amount of preservative, a suitable amount of perfume, and the balance of purified water to prepare a shampu composition.

The sample composition was evaluated in the same manner as above. However, with respect to the stability over time, the sample was stored at -5 ° C, 25 ° C, and 45 ° C for one month, the appearance was observed, and the following three levels were evaluated. ◯: Good stability (flowability without solidification, no change in appearance) Δ: Slightly poor stability (no solidification, but coloration) X: Poor stability (solidification or significant coloring)

As a result, the pH was 5.5 (25 ° C.), the viscosity was 1,162 cps (25 ° C.), the stability over time was ◯, the protein denaturation rate was 20%, the height immediately after the introduction of the sample was 257 mm, and the continuous foaming. The rate is 96%, the foam creaminess is 1.9, the finger combability when washing hair is 2.0, the comb combing ability after washing is 2.0, and the conditioning performance after washing is 1. It was 9. As is clear from this result, this shampu composition has an appropriate pH and viscosity, is excellent in stability over time, has low irritation, has a good foaming property, and has a good foaming property. It was a creamy product, and it was easy to pass through the fingers when using it and combing after using it, and the conditioning effect was excellent.

Example 13 2.5% by weight monosodium lauryl iminodiacetic acid, N
-Cocoyl-N'-carboxymethyl-N '-(2-hydroxyethyl) ethylenediamine 4% by weight, cocoamidopropyldimethylaminoacetic acid betaine 1.5% by weight,
Cocoamidopropyl dimethylamine 8% by weight, coconut oil fatty acid dietanolamide 3% by weight, behenyltrimethylammonium chloride 0.3% by weight, distearyl dimethylammonium chloride 0.5% by weight, cationic polymer C (Daicel Chemical Industries Ltd. 0.3% by weight of trade name "Gielna-QH300"), 1.7% by weight of ethylene glycol distearate, pH adjusting agent (citric acid.
Monohydrate, adjusted to pH = 5.3 to 6.3) A proper amount, a proper amount of preservative, a proper amount of perfume, and a balance of purified water to prepare a shampu composition.

When this sham-pump composition was evaluated in the same manner as described above, the pH was 5.5 (25 ° C.), the viscosity was 1012 cps (25 ° C.), the temporal stability was ◯, and the protein denaturation rate was 20%. The height immediately after the sample is loaded is 263 mm,
The foam retention rate is 96%, the foam creaminess is 2.0, the finger combability when washing hair is 1.9, the combing combability after washing is 1.9, and the conditioning performance after washing. Was 1.9. As is clear from this result, this shampu composition has an appropriate pH and viscosity, is excellent in stability over time, has low irritation, has a good foaming property, and has a good foaming property. It was a creamy product, and it was easy to pass through the fingers when using it and combing after using it, and it was also excellent in the conditioning effect.

[0057]

Industrial Applicability As described above, according to the present invention, excellent stability over time, low irritation, and excellent foaming power, the foam is creamy, and at the time of use It is possible to provide a sham-pump composition which is good in finger combing and combing after use and has an excellent conditioning effect on hair.

Claims (3)

[Claims] 1. The following components a to c; a) one or more amphoteric surfactants and / or semipolar surfactants b) one or two amidoamine type surfactants represented by formula (I). More than seed (R ¹ is an alkyl group or an alkenyl group having 7 to 19 carbon atoms, m is an integer of 2 to 4) c) One or more cationic surfactants and / or cationic polymers are contained, a component = 1 to 3
0% by weight, b component = 1 to 30% by weight, c component = 0.1
5% by weight, a component + b component + c component = 10 to 60% by weight
And the balance is water. 2. An amino acid-type amphoteric surfactant represented by formula (II), wherein the component a is the following components a-1 to a-3; (R ² is an alkyl or alkenyl group having 7 to 19 carbon atoms, n and o are each an integer of ^{1 to} 3, M ¹ and M ² are each hydrogen, an alkali metal, an alkaline earth metal, an ammonium group, and a basic amino acid. Or a cation residue of alkanolamine) a-2) Amidoamine type amphoteric surfactant represented by formula (III) or (IV) [R ³ and R ⁵ are each an alkyl group or an alkenyl group having 7 to 19 carbon atoms, and R ⁴ and R ⁶ are each a group —CH ₂ COOM ³
Or —CH ₂ CH ₂ COOM ³ (M ³ is hydrogen, an alkali metal or an alkanolamine), R ⁷ is a group —
CH ₂ COOM ³ , —CH ₂ CH ₂ COOM ³ (M ³ is the same as above) or hydrogen] a-3) Amidobetaine-type amphoteric surfactant represented by the formula (V) 2. The jump composition according to claim 1, wherein R ⁸ is an alkyl group or an alkenyl group having 7 to 19 carbon atoms and p is an integer of 2 to 4 or more. 3. In addition to components a to c, d) an alkanolamide type surfactant is contained, and the content thereof is 0.5 to 1.
The shampoo composition according to claim 1 or 2, which is 0% by weight.