JPH08244035A - Taking-up, annealing treatment and unwinding of strip like polymeric film and support for photosensitive material - Google Patents
Taking-up, annealing treatment and unwinding of strip like polymeric film and support for photosensitive materialInfo
- Publication number
- JPH08244035A JPH08244035A JP7708895A JP7708895A JPH08244035A JP H08244035 A JPH08244035 A JP H08244035A JP 7708895 A JP7708895 A JP 7708895A JP 7708895 A JP7708895 A JP 7708895A JP H08244035 A JPH08244035 A JP H08244035A
- Authority
- JP
- Japan
- Prior art keywords
- winding
- web
- strip
- thickness
- annealing treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Storage Of Web-Like Or Filamentary Materials (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は帯状高分子フィルムの巻
取方法、アニーリング処理方法、巻戻し方法、及び前記
方法による写真感光材料用支持体に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for winding a belt-shaped polymer film, an annealing treatment method, a rewinding method, and a support for a photographic light-sensitive material according to the above method.
【0002】[0002]
【従来の技術】高分子フィルム,特にポリエステル系フ
ィルムはその製造工程において受けた残留歪を解除する
ために熱処理を行うが、これをアニーリング処理と言っ
ている。このアニーリング処理はフィルムロールを高温
の恒温室内に一定時間以上保存する方法か、又は連続炉
中を低速度で通過させて処理する方法が行なわれてい
た。この工程において帯状高分子フィルムが巻芯側と外
周側とは不均一に加熱されたり、不均一な荷重を受けた
りすることはまぬがれない。又アニーリング処理後の帯
状高分子フィルム全域が室温(25℃前後)迄冷却後、
次工程のために巻戻されていた。一方帯状高分子フィル
ムの巻ズレを防止するために従来より成型された帯状高
分子フィルムの両縁部に凹凸をつける所謂「厚み出し加
工」、ナーリングが行なわれているが、このナーリング
は前記アニーリング処理においても重要な役目を果し、
帯状高分子フィルムの均一な加熱と、均一な荷重には、
欠かすことの出来ないものになっている。2. Description of the Related Art A polymer film, particularly a polyester film, is subjected to a heat treatment in order to release the residual strain received in its manufacturing process, which is called an annealing treatment. This annealing treatment has been carried out by storing the film roll in a high temperature thermostatic chamber for a certain period of time or by passing it through a continuous furnace at a low speed. In this step, it is inevitable that the strip-shaped polymer film is unevenly heated on the winding core side and the outer peripheral side and is subjected to uneven load. Also, after the annealing treatment, the entire band-shaped polymer film is cooled to room temperature (around 25 ° C),
It was rewound for the next step. On the other hand, in order to prevent winding deviation of the strip-shaped polymer film, a so-called "thickening process" in which unevenness is formed on both edges of the strip-shaped polymer film conventionally formed, knurling is performed. It also plays an important role in processing,
For uniform heating of the band-shaped polymer film and uniform load,
It is indispensable.
【0003】厚み出し加工、即ちナーリングについての
従来技術としては、代表的なものとして 「合成樹脂フィルムの巻取方法」として、フィルム
巾方向の一部フィルム表面に抗滑性増大処理を施した
後、巻取ることを特徴とする合成樹脂フィルムの巻取方
法、具体的にはコロナ放電処理による方法(特公昭50
−36459号公報参照)。 「厚み出し加工装置」として、成形された熱可塑性
シート材料の縁部を機械的に変形させて凹凸をつける厚
み出し加工装置、具体的には、該機械的変形手段が凹凸
面を有するローラ対とこれらを圧着させる手段から成
り、該凹凸面を有するローラ対の少くとも一方は凹凸面
がローラ周面の巾方向に縞状の空隙部を有する如く配列
されており、前記シート材料の厚み出し加工される部分
に空隙部を残すように構成された厚み出し加工装置(特
公昭57−36129号公報参照)。 「プラスチックフィルムの巻取装置」として、プラ
スチックフィルムの両耳部に臨んで、同フィルムの表面
に局部的に熱風を吹付けて凹凸を形成させる加熱装置を
設けてなるプラスチックフィルムの巻取装置(実開平1
−109045号公報)等が開示されている。As a conventional technique for thickening processing, that is, knurling, as a typical method, a "winding method for a synthetic resin film" is used, in which a part of the film surface in the width direction is subjected to anti-slip treatment. , A method for winding a synthetic resin film characterized by winding, specifically, a method by corona discharge treatment (Japanese Patent Publication No. Sho 50).
-36459 gazette). The "thickening device" is a thickening device that mechanically deforms the edge portion of a molded thermoplastic sheet material to make unevenness, specifically, a roller pair in which the mechanical deformation means has an uneven surface. At least one of the roller pair having the uneven surface is arranged so that the uneven surface has striped voids in the width direction of the roller peripheral surface. A thickening processing device configured to leave a void in a processed portion (see Japanese Patent Publication No. 57-36129). As a "plastic film winding device", a plastic film winding device is provided which faces both ears of the plastic film and is provided with a heating device for locally blowing hot air to form irregularities on the surface of the film ( Actual Kaihei 1
No. 109045) is disclosed.
【0004】[0004]
【発明が解決しようとする問題点】しかしながら、従来
の技術においては、一本のフィルムロール全体として不
均一な加熱,不均一な荷重に対する徹底的な対策は不充
分であり、又ナーリングに関する開示技術においても巻
ズレに対する対策は効果的であるが、一方アニーリング
処理の際の巻芯との関係において巻芯側と表層側に対す
る対策は記載がなく、更にアニーリング処理後の帯状高
分子フィルムの巻戻しに対しても効果が不充分であっ
た。その結果アニーング処理及びその後において巻芯の
ブツ故障,切口映り、巻芯映りと表層部の陥没状ベコ及
びアニーリング処理後の巻戻しにおいて巻ズレ,巻締シ
ワ,巻芯部シワが発生していた。However, in the prior art, a thorough countermeasure against uneven heating and uneven load of one film roll as a whole is insufficient, and the disclosed technique related to knurling is insufficient. However, there is no countermeasure against the winding core side and the surface layer side in relation to the winding core at the time of annealing treatment, and the rewinding of the strip-shaped polymer film after the annealing treatment is not described. Also, the effect was insufficient. As a result, there were defects in the core after the annealing process, cut edges, cut-in marks on the core and recesses on the surface layer, and winding misalignment, winding wrinkles, and core wrinkles during rewinding after the annealing process. .
【0005】本発明の目的は、帯状高分子フィルムの巻
取りフィルムロールにおいて、従来の欠点による巻芯部
のブツ故障、切口映り、巻芯映りそして外周部の陥没状
ベコ故障を減少させ、アニーリング処理の冷却過程にお
ける巻取り面状故障(巻ズレ、巻締シワ,巻芯部シワ)
の発生を軽減する、巻取方法,アニーリング処理方法並
びに前記方法による写真感光材料支持体を提供すること
にある。An object of the present invention is to reduce winding defects of a strip-shaped polymer film by reducing defects such as spot defects, cut edges, core defects and recessed bevel defects in the outer peripheral portion due to conventional defects. Winding surface failure in the cooling process (winding misalignment, winding wrinkles, winding core wrinkles)
It is an object of the present invention to provide a winding method, an annealing treatment method, and a photographic light-sensitive material support by the above method, which reduce the occurrence of
【0006】[0006]
【課題を解決するための手段及び作用】本発明の上記目
的は、 帯状高分子フィルムの巻取方法において、ウエブの
幅方向の両縁部に厚み出し加工されるナーリングの厚み
を、巻芯側から表層側にかけて漸減させて巻取ることを
特徴とする帯状高分子フィルムの巻取方法。 帯状高分子フィルムのアニーリングの方法におい
て、前記ウエブの幅方向の両縁部のナーリングの厚み
が、請求項1によることを特徴とする帯状高分子フイル
ムロールのアニーリング処理方法。 帯状高分子フィルムロールのアニーリング処理後の
次工程のための巻戻しを、ウエブがいまだ高い温度状態
において実施することを特徴とする帯状高分子ロールフ
ィルムの巻戻し方法。 前記帯状高分子フィルムがポリエチレンテレフタレ
ート又はポリエチレンナフタレートであり、前記帯状高
分子フィルムの巻取り方法,アニーリング処理方法及び
次工程のための巻戻しが、請求項1,2又は3の方法に
より行われたものであることを特徴とする写真感光材料
用支持体。 によって達成される。Means and Actions for Solving the Problems The above object of the present invention is to provide a method for winding a strip-shaped polymer film, in which the thickness of the knurling to be thickened at both edges in the width direction of the web is adjusted to the core side. The tape-shaped polymer film winding method is characterized in that the tape-shaped polymer film is wound by gradually decreasing it from the surface layer to the surface layer side. In the method for annealing a strip-shaped polymer film, the thickness of the knurling at both edges in the width direction of the web is according to claim 1, and the annealing treatment method for a strip-shaped polymer film roll. A method for rewinding a strip-shaped polymer roll film, which comprises performing rewinding for the next step after the annealing treatment of the strip-shaped polymer film roll in a state where the web is still at a high temperature. The band-shaped polymer film is polyethylene terephthalate or polyethylene naphthalate, and the method for winding the band-shaped polymer film, the annealing treatment method, and the rewinding for the next step are performed by the method according to claim 1, 2, or 3. A support for a photographic light-sensitive material, characterized in that Achieved by
【0007】本発明に用いる帯状高分子フィルムの材質
としては、ポリエチレンテレフタレート、ポリエチレン
ナフタレート等のポリエステル、ポリエチレン、ポリス
チレン、ポリビニルアルコール、塩化ビニル、テフロ
ン、塩化ビニリデン、ナイロン、ポリプロピレン、ポリ
カーボネート、ポリイミド、ポリアミドイミド、ポリエ
ステルイミド等がある。本発明は、これらフィルムのう
ち、写真感光材料支持体としてのポリエチレンテレフタ
レート、ポリエチレンナフタレート等のポリエステルフ
ィルムを用いる場合に特に有用である。Examples of the material for the strip-shaped polymer film used in the present invention include polyesters such as polyethylene terephthalate and polyethylene naphthalate, polyethylene, polystyrene, polyvinyl alcohol, vinyl chloride, Teflon, vinylidene chloride, nylon, polypropylene, polycarbonate, polyimide and polyamide. Examples include imide and polyester imide. The present invention is particularly useful when a polyester film such as polyethylene terephthalate or polyethylene naphthalate is used as a photographic light-sensitive material support among these films.
【0008】本発明において、ウエブの幅方向の両縁部
に厚み出し加工されたナーリングの厚みを巻芯側から外
周側にかけて漸減させて巻取るということは、巻芯部は
ナーリングの厚みをウエブ厚×(10〜50%)厚く
し、それによってウエブを浮上保持して面圧を下げ、伝
熱ムラ,巻芯に付着した異物に起因するブツ故障の他,
切口映り,巻芯映りを防止し、外周側はウエブ厚×(1
〜20%)で巻芯部よりナーリングを薄くして、ウエブ
層間に介在する空気膜厚を減少させ、それによって経時
による陥没状ベコ故障を防止する、即ち、ナーリングの
厚みとして例えば巻芯側のナーリング厚みをウエブ厚×
30%とした場合、外周側のナーリング厚がウエブ厚×
5%になるように漸減させるということである。厚みの
比はフィルムの材質,厚み,巻長等によって最適が異な
る。ナーリングの漸減のさせ方としては、コロナ放電の
場合は電圧の調節によって、機械的場合は凸凹面,加圧
力の調節によって、又熱風吹付の場合は熱風温度によっ
て調節することが出来る。本発明において、アニーリン
グ処理後の次工程のための巻戻しをウエブがまだ高い温
度状態において実施することは、好ましくは前記高分子
フィルムのガラス転移点温度−20℃以内の状態で実施
することによって冷却過程における収縮による巻ズレ、
巻締りシワ,巻芯部シワを軽減さすことが出来る。それ
はロール状態で冷却を行うことなく、巻戻し時に冷却を
行うことにより、温度低下による収縮歪をロール状態に
加えることを避けるためである。ここで、次工程とは下
塗液の塗布又は裁断時等の作業工程のことである。In the present invention, the thickness of the knurling, which is thickened at both edges in the width direction of the web, is gradually reduced from the core side to the outer peripheral side to wind the knurling. Thick x (10 to 50%) thicker, which keeps the web floating and lowers the surface pressure, which causes uneven heat transfer and foreign matter adhered to the core.
Prevents cut edges and core reflections, and the outer peripheral side is web thickness x (1
˜20%) to make the knurling thinner than the core to reduce the air film thickness interposed between the web layers, thereby preventing a recessed bevel failure over time, that is, the knurling thickness on the core side, for example. Knurling thickness x web thickness
If it is 30%, the knurling thickness on the outer peripheral side is the web thickness ×
It means to gradually reduce it to 5%. The optimum thickness ratio depends on the film material, thickness, and winding length. The knurling can be gradually reduced by adjusting the voltage in the case of corona discharge, by adjusting the uneven surface and the pressing force in the case of mechanical discharge, and by adjusting the hot air temperature in the case of blowing hot air. In the present invention, the unwinding for the next step after the annealing treatment is carried out in a state where the web is still at a high temperature, preferably by carrying out in a state where the glass transition temperature of the polymer film is within -20 ° C. Winding displacement due to shrinkage in the cooling process,
Wrinkles and winding core wrinkles can be reduced. This is because cooling is performed at the time of rewinding without performing cooling in a roll state, so that shrinkage strain due to temperature decrease is prevented from being applied to the roll state. Here, the next step is a working step such as applying or cutting the undercoat liquid.
【0009】[0009]
【実施例】以下、本発明を実施例によって具体的に説明
する。 (実施例−1)帯状ポリエチレンテレフタレートフィル
ムの厚み100μm,巾1500mm,巻取り径700
mmのフイルムロールをアニーリング処理する場合、巻
芯側ナーリング厚をウエブ厚×30%とし、外周側ナー
リング層がウエブ厚×5%になる様に漸減してウエブを
巻取り、アニーリング処理をすることで、巻芯部のブツ
故障、切口映りは巻周で5周に抑えられ、外周部の陥没
状のベコ故障の発生もなくなった。EXAMPLES The present invention will be specifically described below with reference to examples. (Example-1) A strip-shaped polyethylene terephthalate film having a thickness of 100 µm, a width of 1500 mm and a winding diameter of 700.
When annealing a film roll of mm, the core side knurling thickness is set to the web thickness x 30%, and the outer peripheral side knurling layer is gradually reduced so that the web thickness x 5%, and the web is wound and annealed. Then, the trouble of the core and the reflection of the cut were suppressed to five laps at the winding circumference, and the occurrence of the recessed bevel failure at the outer circumference was eliminated.
【0010】(比較例−1)実施例−1と同様の帯状高
分子フィルムをナーリング厚がウエブ厚×20%でウエ
ブ長さ方向に一定のウエブを使用すると、巻芯部の故障
は100周,外周部の故障は150周まで発生してしま
った。(Comparative Example-1) If a web having the same knurling thickness as the web thickness x 20% and a constant web length direction is used for the same strip-shaped polymer film as in Example-1, the failure of the winding core portion is 100 laps. The outer peripheral failure occurred up to 150 laps.
【0011】(実施例−2)帯状ポリエチレンテレフタ
レートフィルムの巾1500mm巻取径700mmのフ
イルムロールを、ウエブのガラス転移点温度で熱処理し
た後、ウエブ温度がガラス転移点温度−20℃以内の状
態で次工程のための巻戻しを実施することで、ウエブの
熱収縮による巻ズレ・巻締シワの発生はなかった。Example 2 A film roll having a width of 1500 mm and a winding diameter of 700 mm of a strip-shaped polyethylene terephthalate film was heat-treated at the glass transition temperature of the web, and then the web temperature was within the glass transition temperature of -20 ° C. By performing the unwinding for the next step, the winding misalignment and the winding wrinkle due to the heat shrinkage of the web did not occur.
【0012】(比較例−2)実施例−2と同様な帯状高
分子フィルムを室温度(25℃)まで冷却した後に巻戻
すと、フイルムロール内部に巻締りジワが発生し、巻戻
し中に巻ズレが発生。さらに巻芯部で巻芯材料の寸法変
化が起こり、巻芯と製品ロールとの間でスリップが発生
し、巻戻し不能となってしまった。(Comparative Example-2) When a strip-shaped polymer film similar to that of Example-2 was rewound after being cooled to a room temperature (25 ° C), winding wrinkles were generated inside the film roll, and during rewinding. Volume deviation occurs. Further, the dimensional change of the core material occurs in the core portion, slip occurs between the core and the product roll, and rewinding is impossible.
【0013】[0013]
【発明の効果】本発明の巻芯側と外周側のナーリング厚
みの調節により、巻芯側のブツ故障・切口映り,巻芯肌
映りを0しく軽減させ、又、外周側の陥没状ベコ故障を
防止することが出来た。又本発明のアニーリング後の工
程のための巻戻しを、高温において始めることにより、
ウエブの冷却過程における熱収縮に起因する巻ズレ,巻
締シワの発生を皆無にすることが出来た。EFFECTS OF THE INVENTION By adjusting the knurling thicknesses on the core side and the outer peripheral side according to the present invention, it is possible to reduce the troubles on the core side such as cuts and cuts, and the appearance of the core surface to zero. Could be prevented. Also, by starting the unwinding for the post-annealing step of the invention at elevated temperature,
It was possible to eliminate winding misalignment and winding wrinkles due to heat shrinkage during the web cooling process.
Claims (4)
て、ウエブの幅方向の両縁部に厚み出し加工されるナー
リングの厚みを、巻芯側から外周側にかけて漸減させて
巻取ることを特徴とする帯状高分子フィルムの巻取方
法。1. A method for winding a strip-shaped polymer film, characterized in that the thickness of a knurl that is thickened at both edges in the width direction of the web is gradually reduced from the core side to the outer peripheral side. A method for winding a strip-shaped polymer film.
法において、前記ウエブの幅方向の両縁部のナーリング
の厚みが、請求項1によることを特徴とする帯状高分子
フイルムのアニーリング処理方法。2. The method for annealing a strip-shaped polymer film according to claim 1, wherein the knurling thickness at both edges of the web in the width direction is according to claim 1.
グ処理後の次工程のための巻戻しを、ウエブがいまだ高
い温度状態において実施することを特徴とする帯状高分
子フィルムロールの巻戻し方法。3. A method for rewinding a belt-shaped polymer film roll, wherein the rewinding for the next step after the annealing treatment of the belt-shaped polymer film roll is carried out in a state where the web is still at a high temperature.
テレフタレート又はポリエチレンナフタレートであり、
前記帯状高分子フィルムの巻取方法,アニーリング処理
方法及び次工程のための巻戻しが、請求項1,2又は3
の方法で行われたものであることを特徴とする写真感光
材料用支持体。4. The belt-shaped polymer film is polyethylene terephthalate or polyethylene naphthalate,
The method of winding the strip-shaped polymer film, the method of annealing treatment, and the rewinding for the next step are performed by the method of claim 1, 2, or 3.
A support for a photographic light-sensitive material, which is produced by the method described in 1.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7708895A JPH08244035A (en) | 1995-03-09 | 1995-03-09 | Taking-up, annealing treatment and unwinding of strip like polymeric film and support for photosensitive material |
DE69613731T DE69613731T2 (en) | 1995-03-09 | 1996-03-07 | Wrapping, tempering and unwinding processes of a polymer film, a tempering device and a photographic film support produced by this process or device |
EP96103575A EP0730949B1 (en) | 1995-03-09 | 1996-03-07 | Methods of winding, annealing and unwinding a polymer film web, an annealing apparatus and a photographic film support prepared using said method or apparatus |
US08/612,435 US5895212A (en) | 1995-03-09 | 1996-03-07 | Methods of winding, annealing and unwinding a polymer film web, an annealing apparatus and a photographic film support prepared using said method or apparatus |
US09/228,394 US6017212A (en) | 1995-03-09 | 1999-01-12 | Methods of winding, annealing and unwinding a polymer film web, an annealing apparatus and photographic film support prepared using said method or apparatus |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7708895A JPH08244035A (en) | 1995-03-09 | 1995-03-09 | Taking-up, annealing treatment and unwinding of strip like polymeric film and support for photosensitive material |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH08244035A true JPH08244035A (en) | 1996-09-24 |
Family
ID=13624035
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7708895A Pending JPH08244035A (en) | 1995-03-09 | 1995-03-09 | Taking-up, annealing treatment and unwinding of strip like polymeric film and support for photosensitive material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH08244035A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100390864C (en) * | 2003-07-31 | 2008-05-28 | 富士胶片株式会社 | Tape winding method |
JP2009525895A (en) * | 2006-02-09 | 2009-07-16 | デュポン テイジン フィルムズ ユー.エス.リミテッド パートナーシップ | Process for producing polyester film exhibiting low heat shrinkage |
JP2013129090A (en) * | 2011-12-21 | 2013-07-04 | Okura Ind Co Ltd | Method of manufacturing film roll with improved buckling |
-
1995
- 1995-03-09 JP JP7708895A patent/JPH08244035A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100390864C (en) * | 2003-07-31 | 2008-05-28 | 富士胶片株式会社 | Tape winding method |
JP2009525895A (en) * | 2006-02-09 | 2009-07-16 | デュポン テイジン フィルムズ ユー.エス.リミテッド パートナーシップ | Process for producing polyester film exhibiting low heat shrinkage |
JP2013129090A (en) * | 2011-12-21 | 2013-07-04 | Okura Ind Co Ltd | Method of manufacturing film roll with improved buckling |
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