JPH07306586A - One-component developing device - Google Patents
One-component developing deviceInfo
- Publication number
- JPH07306586A JPH07306586A JP10027894A JP10027894A JPH07306586A JP H07306586 A JPH07306586 A JP H07306586A JP 10027894 A JP10027894 A JP 10027894A JP 10027894 A JP10027894 A JP 10027894A JP H07306586 A JPH07306586 A JP H07306586A
- Authority
- JP
- Japan
- Prior art keywords
- developer
- inorganic compound
- developing device
- latent image
- electrostatic latent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000002484 inorganic compounds Chemical class 0.000 claims abstract description 51
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 51
- 229920005989 resin Polymers 0.000 claims abstract description 46
- 239000011347 resin Substances 0.000 claims abstract description 46
- 230000003746 surface roughness Effects 0.000 claims abstract description 17
- 230000005684 electric field Effects 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims description 105
- 229910044991 metal oxide Inorganic materials 0.000 claims description 11
- 150000004706 metal oxides Chemical class 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 150000001639 boron compounds Chemical class 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 150000003377 silicon compounds Chemical class 0.000 claims description 4
- 229910001038 basic metal oxide Inorganic materials 0.000 claims description 3
- 150000001722 carbon compounds Chemical class 0.000 claims description 3
- 229910017464 nitrogen compound Inorganic materials 0.000 claims description 3
- 150000002830 nitrogen compounds Chemical class 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 239000010410 layer Substances 0.000 abstract description 40
- 230000001105 regulatory effect Effects 0.000 abstract description 15
- 239000002344 surface layer Substances 0.000 abstract description 6
- 239000011248 coating agent Substances 0.000 description 15
- 238000000576 coating method Methods 0.000 description 15
- 238000011161 development Methods 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 230000002093 peripheral effect Effects 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- -1 ligroin Chemical compound 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 239000012744 reinforcing agent Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229910052580 B4C Inorganic materials 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- JHNCXGXWSIOXSX-UHFFFAOYSA-N [Nd+3].[O-2].[Fe+2] Chemical compound [Nd+3].[O-2].[Fe+2] JHNCXGXWSIOXSX-UHFFFAOYSA-N 0.000 description 1
- NEKNPTMOEUCRLW-UHFFFAOYSA-N [O-2].[Fe+2].[Gd+3] Chemical compound [O-2].[Fe+2].[Gd+3] NEKNPTMOEUCRLW-UHFFFAOYSA-N 0.000 description 1
- GZHZIMFFZGAOGY-UHFFFAOYSA-N [O-2].[Fe+2].[La+3] Chemical compound [O-2].[Fe+2].[La+3] GZHZIMFFZGAOGY-UHFFFAOYSA-N 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- WMDURRXBOBIUPJ-UHFFFAOYSA-N barium(2+) iron(2+) oxygen(2-) Chemical compound [Ba+2].[O-2].[Fe+2].[O-2] WMDURRXBOBIUPJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- LGLOITKZTDVGOE-UHFFFAOYSA-N boranylidynemolybdenum Chemical compound [Mo]#B LGLOITKZTDVGOE-UHFFFAOYSA-N 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- BAXLMRUQFAMMQC-UHFFFAOYSA-N cadmium(2+) iron(2+) oxygen(2-) Chemical compound [Cd+2].[O-2].[Fe+2].[O-2] BAXLMRUQFAMMQC-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- AOWKSNWVBZGMTJ-UHFFFAOYSA-N calcium titanate Chemical compound [Ca+2].[O-][Ti]([O-])=O AOWKSNWVBZGMTJ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005421 electrostatic potential Methods 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- IQKLAEINENLGAG-UHFFFAOYSA-N iron oxocopper Chemical compound [Fe].[Cu]=O IQKLAEINENLGAG-UHFFFAOYSA-N 0.000 description 1
- DMTIXTXDJGWVCO-UHFFFAOYSA-N iron(2+) nickel(2+) oxygen(2-) Chemical compound [O--].[O--].[Fe++].[Ni++] DMTIXTXDJGWVCO-UHFFFAOYSA-N 0.000 description 1
- ADCBYGNHJOLWLB-UHFFFAOYSA-N iron(2+) oxygen(2-) yttrium(3+) Chemical compound [Y+3].[O-2].[Fe+2] ADCBYGNHJOLWLB-UHFFFAOYSA-N 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- CUSDLVIPMHDAFT-UHFFFAOYSA-N iron(3+);manganese(2+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Mn+2].[Fe+3].[Fe+3] CUSDLVIPMHDAFT-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- ZTERWYZERRBKHF-UHFFFAOYSA-N magnesium iron(2+) oxygen(2-) Chemical compound [Mg+2].[O-2].[Fe+2].[O-2] ZTERWYZERRBKHF-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910001936 tantalum oxide Inorganic materials 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Dry Development In Electrophotography (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、電子写真複写機、プリ
ンタ等の画像形成装置に組み込まれ、現像剤を静電潜像
に付着させて可視化する一成分現像装置に関し、特に静
電潜像保持体と現像剤担持体との間で発生させた振動電
界内で一成分現像剤を飛翔させて静電潜像を現像する一
成分現像装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a one-component developing device which is incorporated in an image forming apparatus such as an electrophotographic copying machine or a printer to make a developer adhere to an electrostatic latent image for visualization, and more particularly to an electrostatic latent image. The present invention relates to a one-component developing device that develops an electrostatic latent image by causing a one-component developer to fly in an oscillating electric field generated between a holder and a developer carrier.
【0002】[0002]
【従来の技術】静電潜像保持体上に形成された静電潜像
を現像し、可視像を形成する現像装置としては、使用す
る現像剤のタイプ等に応じて、従来より各種タイプのも
のが知られている。例えば従来次の技術が知られてい
る。 (J01)米国特許第2,895,847号明細書記載の
技術 この特許明細書には、“ドナー”と呼ばれる現像剤担持
部材を使用した転写現像が記載されている。そこに記述
されている転写現像は、(1)現像剤であるトナーの層
と感光体とが非接触で、トナーが両者の間隙を飛翔する
場合、(2)トナー層が感光体と回転接触する場合、
(3)トナー層が感光体と回転接触し、画像部を滑る場
合を含む現像の総称であり、“タッチダウン現像法”と
してもよく知られている。このタッチダウン現像法を採
用した一成分現像装置としては、従来下記の技術が知ら
れている。2. Description of the Related Art As a developing device for developing an electrostatic latent image formed on an electrostatic latent image holding member to form a visible image, various types have been conventionally used depending on the type of developer used. Are known. For example, the following techniques are conventionally known. (J01) Technology disclosed in U.S. Pat. No. 2,895,847 This patent specification describes transfer development using a developer carrying member called a "donor". In the transfer development described therein, (1) when the toner layer, which is the developer, is not in contact with the photoconductor, and the toner flies in the gap between them, (2) the toner layer is in rotary contact with the photoconductor. If you do
(3) This is a general term for development including the case where the toner layer is in rotary contact with the photoconductor and slips on the image portion, and is also well known as the "touch-down development method". The following techniques are conventionally known as a one-component developing device employing the touch-down developing method.
【0003】(J02)図3に示す技術 図3は磁性一成分現像剤を用いた従来の現像装置であっ
て、例えば特開昭54−51848号公報、実開昭58
−146249号公報、米国特許第3,372,675
号明細書、米国特許第3,426,730明細書等に開
示された現像装置の断面図である。図3において、現像
装置01は、磁性一成分現像剤02を収納するホッパー
03と、複数のマグネットロール04の周囲に回転自在
に支持された円筒状の現像剤担持体05と、先端部に現
像剤担持体05表面を摺擦するゴム等の弾性部材06を
貼着した現像剤規制部材07とを備えている。現像剤担
持体05には高圧交流電源08および直流電源09が接
続されている。また、現像装置01に対向して配置され
た静電潜像保持体010は、電極上に光導電層を有し、
一様に帯電した後、像光を照射することにより、静電潜
像011が形成される。(J02) Technology shown in FIG. 3 FIG. 3 shows a conventional developing device using a magnetic one-component developer, for example, JP-A-54-51848 and JP-A-58.
-146249, U.S. Pat. No. 3,372,675
FIG. 3 is a sectional view of the developing device disclosed in Japanese Patent No. 3,426,730 and the like. In FIG. 3, the developing device 01 includes a hopper 03 that stores a magnetic one-component developer 02, a cylindrical developer carrier 05 that is rotatably supported around a plurality of magnet rolls 04, and a developing device at the tip. A developer regulating member 07 to which an elastic member 06 such as rubber that rubs the surface of the agent carrier 05 is attached. A high voltage AC power supply 08 and a DC power supply 09 are connected to the developer carrier 05. Further, the electrostatic latent image holding member 010 arranged facing the developing device 01 has a photoconductive layer on the electrode,
After being uniformly charged, an electrostatic latent image 011 is formed by irradiating with image light.
【0004】前記図3に示す従来の現像装置01におい
て、ホッパー03に収納された磁性一成分現像剤02
は、マグネットロール04の磁力で現像剤担持体05上
に吸着され、現像剤規制部材07との間を通過する際
に、現像剤担持体05表面で摺擦される。これにより、
現像剤担持体05上の現像剤02の付着量が規制され
て、現像剤02は薄層化されると共に静電荷が付与され
る。現像剤規制部材07によって薄層化された現像剤0
2は、現像剤担持体05の回転に伴って、静電潜像保持
体010と現像剤担持体05とが近接した現像領域A′
へ搬送される。現像剤担持体05には、高圧交流電源0
8および直流電源09から直流重畳交流電圧が印加され
ているので、現像領域A′で生じる振動電界によって、
現像剤担持体05表面の静電荷を有する現像剤02が静
電潜像保持体010上の静電潜像011に飛翔して、前
記静電潜像011を可視化する。In the conventional developing device 01 shown in FIG. 3, the magnetic one-component developer 02 housed in the hopper 03 is used.
Is attracted onto the developer carrying member 05 by the magnetic force of the magnet roll 04 and rubs against the surface of the developer carrying member 05 when passing through between the developer regulating member 07. This allows
The adhered amount of the developer 02 on the developer carrier 05 is regulated, and the developer 02 is thinned and electrostatic charge is imparted. The developer 0 thinned by the developer regulating member 07
Reference numeral 2 denotes a development area A ′ in which the electrostatic latent image carrier 010 and the developer carrier 05 are close to each other as the developer carrier 05 rotates.
Be transported to. The developer carrier 05 has a high-voltage AC power source 0
8 and the DC superimposed AC voltage are applied from the DC power supply 09, the oscillating electric field generated in the developing area A ′ causes
The developer 02 having an electrostatic charge on the surface of the developer carrier 05 flies to the electrostatic latent image 011 on the electrostatic latent image holder 010 to visualize the electrostatic latent image 011.
【0005】(J03)図4に示す技術 図4は非磁性一成分現像剤を用いた従来の現像装置であ
って、例えば特開昭60−53975号公報等に開示さ
れた現像装置の断面図である。この図4において、図3
と同一の部材には便宜上同一の符号を付す。図4におい
て、現像装置01のホッパー03内には非磁性一成分現
像剤012が収納されており、この現像剤012は、現
像剤担持体05と同じ周速で逆方向に回転する供給ロー
ル013によって、現像剤担持体05へ供給される。現
像剤担持体05には所定の圧接力で接触するように現像
剤規制部材07が設けられており、現像剤担持体05に
供給された現像剤012は、現像剤担持体05の回転に
伴って現像剤規制部材07へ搬送される。ここで、現像
剤付着量が規制されて均一な薄層になると共に静電荷が
付与された現像剤012はさらに静電潜像保持体010
と現像剤担持体05とが近接した現像領域A′へ搬送さ
れる。現像剤担持体05には高圧交流電源08および直
流電源09から直流重畳交流電圧が印加されており、静
電潜像保持体010と現像剤担持体05との間隙に生じ
る振動電界によって、現像剤012は静電潜像保持体0
10へ飛翔して、静電潜像011を可視化する。(J03) Technique shown in FIG. 4 FIG. 4 is a cross-sectional view of a conventional developing device using a non-magnetic one-component developer, for example, the developing device disclosed in JP-A-60-53975. Is. In FIG. 4, FIG.
For convenience, the same members are designated by the same reference numerals. In FIG. 4, a non-magnetic one-component developer 012 is stored in the hopper 03 of the developing device 01, and the developer 012 is a supply roll 013 that rotates in the opposite direction at the same peripheral speed as the developer carrier 05. Is supplied to the developer carrier 05. A developer regulating member 07 is provided so as to come into contact with the developer carrier 05 with a predetermined pressure contact force, and the developer 012 supplied to the developer carrier 05 is accompanied by rotation of the developer carrier 05. And is conveyed to the developer regulating member 07. Here, the developer 012 to which the developer adhesion amount is regulated to form a uniform thin layer and the electrostatic charge is applied is further added to the electrostatic latent image holding member 010.
And the developer carrying member 05 are conveyed to the developing area A'which is adjacent to each other. A DC superimposed AC voltage is applied to the developer carrying member 05 from the high voltage AC power supply 08 and the DC power supply 09, and the developer is supported by the oscillating electric field generated in the gap between the electrostatic latent image holding member 010 and the developer carrying member 05. 012 is an electrostatic latent image carrier 0
The electrostatic latent image 011 is visualized by flying to 10.
【0006】次に、前記(J02),(J03)に記載され
た現像装置で使用される現像剤担持体について説明す
る。前記従来の一成分現像装置において、現像剤担持体
は、アルミニウムやステンレススチール等の導電性を有
する円筒状基材表面に、電気抵抗制御剤および補強剤を
分散した結着樹脂および溶剤からなる塗布液をコーティ
ングして、半導電性樹脂層を形成したスリーブが用いら
れる。前記電気抵抗制御剤としては、カーボンブラッ
ク、硫酸バリウム、チタニア、チタン酸カリウム(K2
O・6TiO2)等が用いられ、補強剤としては、シリ
カ、チタニア、アルミナ等の無機化合物がしばしば用い
られる。あるいは、前記半導電性樹脂コーティングスリ
ーブまたは内側を導電剤の塗布等で導電処理された半導
電性樹脂製スリーブにエメリー研磨等の機械研磨を施し
て、所望の表面粗さに加工したものが用いられる。Next, the developer carrier used in the developing device described in (J02) and (J03) will be described. In the conventional one-component developing device, the developer carrier is a coating of a binder resin and a solvent in which an electric resistance control agent and a reinforcing agent are dispersed on the surface of a cylindrical conductive substrate such as aluminum or stainless steel. A sleeve coated with a liquid to form a semiconductive resin layer is used. Examples of the electric resistance control agent include carbon black, barium sulfate, titania, potassium titanate (K 2
O.6TiO 2 ) or the like is used, and as the reinforcing agent, an inorganic compound such as silica, titania, or alumina is often used. Alternatively, the semi-conductive resin-coated sleeve or the inner surface of the semi-conductive resin sleeve, which has been subjected to a conductive treatment by applying a conductive agent, is subjected to mechanical polishing such as emery polishing and processed to a desired surface roughness. To be
【0007】前記従来の一成分現像装置で使用される現
像剤担持体として、従来下記の技術が知られている。 (J04)特開平1−142563号公報記載の技術 この公報には、粒径3〜100μm(好ましくは10〜
60μm)の正電荷を有する金属酸化物粒子を樹脂に分
散した塗布液を塗布して、スリーブ表面に5〜10μm
の凹凸を有する塗膜を形成した現像剤担持体が示されて
いる。このような塗膜が形成された現像剤担持体表面の
凹凸は、前記金属酸化物粒子等のフィラー径に影響を受
けることが知られている。また、現像剤担持体表面に露
出した粒子は、一成分現像剤との摩擦により、現像剤に
電荷を付与する重要な役割を果たすことが知られてい
る。このように、従来一般に使用されている高抵抗一成
分現像剤を用いる現像方式においては、主として現像剤
担持体との摩擦で一成分現像剤を帯電させるので、現像
剤担持体を構成する材料が重要である。例えば、負帯電
一成分現像剤の場合は、現像剤担持体表面に帯電極性が
正帯電しやすい金属酸化物粒子を樹脂に分散させる方法
は有効な手段である。The following techniques are conventionally known as a developer carrying member used in the conventional one-component developing device. (J04) Technology described in JP-A-1-142563. In this publication, the particle size is 3 to 100 μm (preferably 10 to 10 μm).
60 μm) and a coating solution in which metal oxide particles having a positive charge are dispersed in a resin is applied to the sleeve surface to be 5 to 10 μm.
The developer carrier having a coating film having the unevenness is shown. It is known that the irregularities on the surface of the developer bearing member on which such a coating film is formed are affected by the diameter of the filler such as the metal oxide particles. Further, it is known that the particles exposed on the surface of the developer carrying member play an important role of giving an electric charge to the developer by friction with the one-component developer. As described above, in the development method using the conventionally used high-resistance one-component developer, the one-component developer is charged mainly by friction with the developer carrier, so that the material constituting the developer carrier is is important. For example, in the case of a negatively charged one-component developer, a method of dispersing metal oxide particles, which tend to be positively charged with a positive polarity on the surface of the developer carrier, is an effective means.
【0008】[0008]
【発明が解決しようとする課題】しかしながら、前記従
来の技術(J04)には下記のような問題点がある。樹脂
層中に3〜100μmの金属酸化物粒子を分散させた上
述の現像剤担持体では、その表面に5〜10μmの凹凸
を形成することができるとしても、現像剤担持体表面に
露出する金属酸化物粒子は島状に点在するため、例えば
平均粒径9μm程度の一成分現像剤の一部が金属酸化物
粒子と接触できない場合があり、一成分現像剤に十分な
摩擦帯電電荷を付与することができない。その対策とし
て、金属酸化物粒子の添加量を増加させることも考えら
れるが、添加量を増加させると、バインダーとしての樹
脂含有量が低下して、塗膜強度が弱くなるため好ましい
方法ではない。また、現像剤担持体表面に露出する金属
酸化物粒子の相対密度を増加させるために、金属酸化物
粒子の粒径を小さくすることが考えられる。しかし、現
像剤担持体の表面粗さが小さくなりすぎて、現像剤搬送
量が少なくなり、所望の画像濃度が得られなくなるとい
う問題が生じる。However, the conventional technique (J04) has the following problems. In the above-mentioned developer carrying body in which metal oxide particles of 3 to 100 μm are dispersed in the resin layer, even if unevenness of 5 to 10 μm can be formed on the surface thereof, the metal exposed on the surface of the developer carrying body Since the oxide particles are scattered in an island shape, for example, a part of the one-component developer having an average particle size of about 9 μm may not be able to come into contact with the metal oxide particles, and the one-component developer is provided with sufficient triboelectric charge. Can not do it. As a countermeasure, increasing the addition amount of the metal oxide particles can be considered, but increasing the addition amount decreases the resin content as a binder and weakens the coating film strength, which is not a preferable method. Further, in order to increase the relative density of the metal oxide particles exposed on the surface of the developer carrying member, it is conceivable to reduce the particle size of the metal oxide particles. However, the surface roughness of the developer carrying member becomes too small, and the developer carrying amount becomes small, so that a desired image density cannot be obtained.
【0009】本発明は、前述の実情に鑑み、下記の記載
内容を課題とする。 (O01)現像剤規制部材により規制される現像剤担持体
上の現像剤の搬送量を適量化するために、現像剤担持体
に適切な表面粗さを形成すると共に、所望の画像濃度を
得るために、現像剤に十分な摩擦帯電電荷を付与するこ
と。In view of the above-mentioned circumstances, the present invention has the following contents. (O01) In order to optimize the transport amount of the developer on the developer carrier regulated by the developer regulating member, an appropriate surface roughness is formed on the developer carrier and a desired image density is obtained. In order to impart sufficient triboelectric charge to the developer.
【0010】[0010]
(第1発明)前記課題を解決するために、本出願の第1
発明は、静電潜像保持体(1)に対向して設けられ現像
剤(6,13)を表面に付着して搬送する現像剤担持体
(4)と、現像剤担持体(4)表面に付着する現像剤量
を規制して薄層化する現像剤規制部材(10)とを備
え、現像剤担持体(4)と静電潜像保持体(1)とが対
向して近接する現像領域(A)に発生させた電界内で、
現像剤担持体(4)表面の電荷を有する現像剤(6,1
3)を前記静電潜像保持体(1)上の静電潜像(2)に
付着させて可視化する一成分現像装置において、下記の
要件を有することを特徴とする、(Y01)前記現像剤担
持体(4)の表面層が、無機化合物粒子(8,9)およ
び結着樹脂を必須成分とした樹脂層(4b)で形成さ
れ、(Y02)前記無機化合物粒子(8,9)は、少なく
とも、必要な表面粗さを得ることが可能な大きな粒径範
囲に属する第1の無機化合物粒子(8)と、前記表面粗
さへの影響が小さく接触した現像剤(6,13)を摩擦
帯電させる小さな粒径範囲に属する第2の無機化合物粒
子粒子(9)とを有すること。(First Invention) In order to solve the above-mentioned problems, the first invention of the present application
The invention relates to a developer carrier (4) which is provided so as to face the electrostatic latent image carrier (1) and which conveys the developer (6, 13) by adhering to the surface thereof, and the surface of the developer carrier (4). And a developer control member (10) for controlling the amount of the developer attached to the toner layer to thin the layer, and the developer carrying member (4) and the electrostatic latent image holding member (1) are opposed to and close to each other. In the electric field generated in the area (A),
The developer carrying body (4) has a surface-charged developer (6, 1
In a one-component developing device for adhering 3) to the electrostatic latent image (2) on the electrostatic latent image holder (1) to visualize it, the following requirements are met: (Y01) The development The surface layer of the agent carrier (4) is formed of inorganic compound particles (8, 9) and a resin layer (4b) containing a binder resin as an essential component, and (Y02) the inorganic compound particles (8, 9) are At least the first inorganic compound particles (8) belonging to a large particle size range capable of obtaining the required surface roughness and the developer (6, 13) in contact with each other with little influence on the surface roughness. Second inorganic compound particles (9) belonging to a small particle size range to be triboelectrically charged.
【0011】(第2発明)また、本出願の第2発明の一
成分現像装置は、前記第1発明の一成分現像装置におい
て、下記の要件を備えたことを特徴とする、(Y03)前
記第1の無機化合物粒子(8)の平均粒径は1〜20μ
mの範囲にあり、第2の無機化合物粒子(9)の平均粒
径は5〜100nmの範囲にあること。(Second invention) Further, the one-component developing device of the second invention of the present application is characterized in that, in the one-component developing device of the first invention, the following requirements are satisfied: (Y03) The average particle size of the first inorganic compound particles (8) is 1 to 20 μm.
The average particle size of the second inorganic compound particles (9) is in the range of 5 to 100 nm.
【0012】(第3発明)また、本出願の第3発明の一
成分現像装置は、前記第1または第2発明の一成分現像
装置において、下記の要件を備えたことを特徴とする、
(Y04)前記第1および第2の無機化合物が、金属酸化
物、水酸化物、ホウ素化合物、珪素化合物、窒素化合
物、炭素化合物および塩基性金属酸化物から選ばれた1
種または2種以上の化合物であること。(Third Invention) Further, a one-component developing device of the third invention of the present application is characterized in that the one-component developing device of the first or second invention has the following requirements.
(Y04) The first and second inorganic compounds are selected from metal oxides, hydroxides, boron compounds, silicon compounds, nitrogen compounds, carbon compounds and basic metal oxides.
Be a compound or two or more compounds.
【0013】(課題を解決するための詳細な説明)以
下、本発明を詳細に説明する。前記現像剤担持体(4)
の表面層を形成する結着樹脂としては、電気抵抗制御
剤、補強材等を分散させたフェノール樹脂、メラミン樹
脂、尿素樹脂、エポキシ樹脂、ポリエステル樹脂、ポリ
アミド樹脂、ポリイミド樹脂、ポリカーボネート樹脂、
アルキッド樹脂、アクリル樹脂、ポリスチレン樹脂、シ
リコーン樹脂等が用いられる。また、前記表面層を形成
する際に用いられる溶剤としては、ヘキサン、リグロイ
ン、ベンゼン、トルエン、キシレン等の炭化水素類、ア
セトン、メチルエチルケトン、メチルイソブチルケトン
等のケトン類、メタノール、エタノール、n−ブタノー
ル等のアルコール類、ジブチルエーテル、テトラヒドロ
フラン、ブチルセロソルブ等のエーテル類、酢酸エチ
ル、酢酸ブチル、酪酸エチル等のエステル類などが挙げ
られる。これらの結着樹脂および溶剤は、それぞれ単独
または2種以上を混合して用いてもよい。(Detailed Description for Solving the Problems) The present invention will be described in detail below. The developer carrier (4)
Examples of the binder resin forming the surface layer of the electric resistance control agent, a phenol resin having a reinforcing material dispersed therein, a melamine resin, a urea resin, an epoxy resin, a polyester resin, a polyamide resin, a polyimide resin, a polycarbonate resin,
Alkyd resin, acrylic resin, polystyrene resin, silicone resin and the like are used. The solvent used when forming the surface layer includes hydrocarbons such as hexane, ligroin, benzene, toluene and xylene, ketones such as acetone, methyl ethyl ketone and methyl isobutyl ketone, methanol, ethanol and n-butanol. And the like, ethers such as dibutyl ether, tetrahydrofuran and butyl cellosolve, and esters such as ethyl acetate, butyl acetate and ethyl butyrate. These binder resins and solvents may be used alone or in admixture of two or more.
【0014】前記樹脂層(4b)中に含まれる無機化合
物粒子(8,9)としては、酸化亜鉛、アルミナ、チタ
ニア、ジルコニア、マグネタイト、ベンガラ、ヘタマイ
ト、酸化錫、酸化タンタル、酸化鉄、酸化鉄亜鉛、酸化
鉄イットリウム、酸化鉄カドミウム、酸化鉄ガドリニウ
ム、酸化鉄銅、酸化鉄鉛、酸化鉄ニッケル、酸化鉄ネオ
ジウム、酸化鉄バリウム、酸化鉄マグネシウム、酸化鉄
マンガン、酸化鉄ランタン等の金属酸化物、酸化ホウ
素、ホウ化モリブデン等のホウ素化合物、シリカ、珪酸
マグネシウム等の珪素化合物、窒化ホウ素(ホウ素化合
物の1種でもある)、硝酸鉄等の窒素化合物、カーボラ
ンダム(珪素化合物の1種)、炭化ホウ素(ホウ素化合
物の1種)、黒鉛等の炭素化合物、塩基性炭酸銅、鉛
白、チタン酸カルシウム、チタン酸バリウム、タングス
テン酸カルシウム等の塩基性金属酸化物などの粒子が好
適である。この他、各種金属水酸化物や、石膏、硫化亜
鉛、硫化鉄等の粒子を用いることもできる。これらの無
機化合物粒子(8,9)は、予めシラノール基やアルキ
ル基等を有する有機化合物で表面処理したもの、予め樹
脂で被覆したものまたは樹脂を含浸させたものを使用し
てもよく、また2種以上の無機化合物の混合物を用いる
こともできる。As the inorganic compound particles (8, 9) contained in the resin layer (4b), zinc oxide, alumina, titania, zirconia, magnetite, red iron oxide, hetamite, tin oxide, tantalum oxide, iron oxide, iron oxide are used. Metal oxides such as zinc, yttrium iron oxide, cadmium iron oxide, gadolinium iron oxide, copper oxide iron, lead iron oxide, nickel iron oxide, iron oxide neodymium, iron barium oxide, magnesium iron oxide, manganese iron oxide, and lanthanum iron oxide. , Boron oxide, boron compounds such as molybdenum boride, silica, silicon compounds such as magnesium silicate, boron nitride (also one kind of boron compound), nitrogen compounds such as iron nitrate, carborundum (one kind of silicon compound), Boron carbide (a type of boron compound), carbon compounds such as graphite, basic copper carbonate, white lead, calcium titanate Particles of basic metal oxides such as barium titanate and calcium tungstate are preferred. In addition, various metal hydroxides and particles of gypsum, zinc sulfide, iron sulfide, etc. can be used. As these inorganic compound particles (8, 9), those which have been surface-treated with an organic compound having a silanol group, an alkyl group or the like in advance, those which have been previously coated with a resin or those which have been impregnated with a resin may be used. It is also possible to use a mixture of two or more inorganic compounds.
【0015】本発明において、第1または第2の無機化
合物粒子(8,9)の平均粒径は、粒径範囲が2種以上
の異なったものが任意に併用される。すなわち、大径粒
子間にそれより粒径の小さい粒子を存在させて、樹脂層
(4b )表面に大径粒子と小径粒子が混在した必要な表
面粗さの凹凸が形成されるように、且つ、表面に摩擦帯
電用の粒子が露出するように、樹脂層(4b )中に無機
化合物粒子(8,9)を分散させればよい。無機化合物
粒子間の配合割合は、例えば、結着樹脂100重量部に
対し、大径の第1の無機化合物粒子(8)10〜300
重量部および小径の第2の無機化合物粒子(9)1〜2
0重量部が好ましく、特に大径の粒子(8)50〜17
5重量部および小径の粒子(9)3〜10重量部が好適
である。In the present invention, the average particle size of the first or second inorganic compound particles (8, 9) may be any combination of two or more different particle size ranges. That is, particles having a smaller particle size are present between the large-diameter particles so that the surface of the resin layer (4b) is formed with irregularities having a required surface roughness in which the large-diameter particles and the small-diameter particles are mixed. The inorganic compound particles (8, 9) may be dispersed in the resin layer (4b) so that the triboelectric charging particles are exposed on the surface. The mixing ratio between the inorganic compound particles is, for example, 10 to 300 of the large-diameter first inorganic compound particles (8) with respect to 100 parts by weight of the binder resin.
Part by weight and small diameter second inorganic compound particles (9) 1-2
0 weight part is preferable, and especially large particle (8) 50-17
5 parts by weight and 3 to 10 parts by weight of small-diameter particles (9) are preferred.
【0016】樹脂層(4b )を形成するには、粒径範囲
が異なる第1および第2の無機化合物粒子(8,9)、
電気抵抗制御剤、結着樹脂および溶剤等を混合して、ま
ず塗布液を調製する。この際、溶剤の混合割合を調節し
て得られる塗布液の粘度、造膜性を調節する。次いで、
円筒状基材を回転させながら、その表面に塗布液をエア
スプレー等によりコーティングし、150〜250℃で
結着樹脂を硬化させる。所望の塗膜厚を得るために、前
記の操作を2〜3回繰り返してもよい。このようにして
形成された樹脂層(4b)は、その表面に無機化合物粒
子(8,9)が露出した凹凸状を呈し、表面粗さRzが
一般に0.5〜10.0μmの範囲にあり、現像剤(6,
13)を安定に付着させるには適当な粗さとなる。To form the resin layer (4b), first and second inorganic compound particles (8, 9) having different particle size ranges,
First, an electric resistance control agent, a binder resin, a solvent and the like are mixed to prepare a coating liquid. At this time, the viscosity and film-forming property of the coating liquid obtained by adjusting the mixing ratio of the solvent are adjusted. Then
While rotating the cylindrical base material, the surface thereof is coated with a coating solution by air spraying or the like, and the binder resin is cured at 150 to 250 ° C. The above procedure may be repeated 2-3 times in order to obtain the desired coating thickness. The resin layer (4b) thus formed has an uneven shape in which the inorganic compound particles (8, 9) are exposed on the surface, and the surface roughness Rz is generally in the range of 0.5 to 10.0 μm. , Developer (6,
The roughness is appropriate for attaching 13) stably.
【0017】本発明の現像装置において、一成分現像剤
(6,13)は、磁性、非磁性のいずれも使用可能であ
る。一成分現像剤(6,13)は、現像剤規制部材(1
0)と現像剤担持体(4)表面との間で薄層化される。
と同時に摩擦帯電により、現像剤(6,13)の帯電極
性に応じて、正または負の電荷が付与される。現像剤
(6,13)は現像剤担持体(4)表面の凹凸間に付着
して搬送されるが、その現像剤担持体(4)表面の凹凸
は粗さRzが0.5〜10.0μmの範囲にあることが好
ましい。粗さRzが0. 5μm未満であると、現像剤
(6,13)の搬送量が不足し、所望の画像濃度を得る
ことができない。一方、粗さRzが10.0μmより大
きいと、現像剤(6,13)の搬送量が多くなりすぎ
て、現像剤(6,13)と現像剤担持体(4)表面の無
機化合物粒子(8,9)との接触する機会が減り、十分
な摩擦帯電ができなくなる。In the developing device of the present invention, the one-component developer (6, 13) may be magnetic or non-magnetic. The one-component developer (6, 13) is the developer regulating member (1
0) and the surface of the developer carrying member (4) are thinned.
At the same time, triboelectric charging imparts a positive or negative charge depending on the charging polarity of the developer (6, 13). The developer (6, 13) adheres between the irregularities on the surface of the developer carrier (4) and is conveyed, and the irregularity on the surface of the developer carrier (4) has a roughness Rz of 0.5 to 10. It is preferably in the range of 0 μm. If the roughness Rz is less than 0.5 μm, the amount of the developer (6, 13) conveyed is insufficient, and the desired image density cannot be obtained. On the other hand, when the roughness Rz is greater than 10.0 μm, the amount of the developer (6, 13) conveyed becomes too large, and the developer (6, 13) and the inorganic compound particles (on the surface of the developer carrier (4) ( The chances of contact with 8 and 9) are reduced, and sufficient triboelectrification cannot be performed.
【0018】[0018]
【作用】次に、前述の特徴を備えた本発明の作用を説明
する。本発明の一成分現像装置によれば、現像剤担持体
(4)の表面層が、例えば平均粒径1〜20μmの粒子
と5〜100nmの粒子との粒径範囲の異なる少なくと
も2種の無機化合物粒子(8,9)を分散させた樹脂層
(4b)から形成されている。そのため、大径の第1の
無機化合物粒子(8)が樹脂層(4b )表面に一部露出
することにより、例えば前記粒径範囲の異なる無機化合
物粒子(8,9)を用いた場合は、樹脂層(4b )の表
面粗さRzが常に適切な範囲の0.5〜10.0μmとな
る。表面粗さは一成分現像剤(6,13)の種類と現像
条件によって異なり、平均粒径が大きい第1の無機化合
物粒子(8)の粒径を適切な値に設定することにより、
所望の表面粗さを得ることができるので、現像剤(6,
13)の搬送量を適量化することができる。しかも、平
均粒径が小さい第2の無機化合物粒子(9)が樹脂層
(4b)表面に一部露出することにより、樹脂層(4b)
表面の微小面積における無機化合物粒子(8,9)の露
出密度を高くすることができるので、現像剤(6,1
3)に十分な摩擦帯電電荷を付与することができる。Next, the operation of the present invention having the above features will be described. According to the one-component developing apparatus of the present invention, the surface layer of the developer carrying member (4) has, for example, at least two kinds of inorganic particles having different particle diameter ranges of particles having an average particle diameter of 1 to 20 μm and particles having an average particle diameter of 5 to 100 nm. It is formed of a resin layer (4b) in which compound particles (8, 9) are dispersed. Therefore, when the large-diameter first inorganic compound particles (8) are partially exposed on the surface of the resin layer (4b), for example, when the inorganic compound particles (8, 9) having different particle size ranges are used, The surface roughness Rz of the resin layer (4b) is always in an appropriate range of 0.5 to 10.0 μm. The surface roughness varies depending on the type of the one-component developer (6, 13) and the developing conditions, and by setting the particle size of the first inorganic compound particles (8) having a large average particle size to an appropriate value,
Since the desired surface roughness can be obtained, the developer (6,
It is possible to optimize the transport amount of 13). Moreover, the second inorganic compound particles (9) having a small average particle size are partially exposed on the surface of the resin layer (4b), so that the resin layer (4b)
Since the exposure density of the inorganic compound particles (8, 9) in a minute area of the surface can be increased, the developer (6, 1
Sufficient triboelectric charge can be applied to 3).
【0019】[0019]
【実施例】以下図面を参照しながら、本発明の実施例を
説明するが、本発明はこれらの実施例に限定されるもの
ではない。 (実施例1)図1は本発明の実施例1である磁性一成分
現像剤を用いる現像装置の説明図で、図1Aはその全体
説明図、図1Bは現像剤担持体の表面付近の部分拡大断
面図である。図1Aにおいて、静電潜像保持体1は、表
面に負帯電系の有機感光層を有する光導電性ドラムであ
り、帯電手段(図示せず)により一様に帯電させた後、
像光を照射することによって生じる静電電位の差により
静電潜像2が形成される。静電潜像2が形成された時の
表面電位は、例えば画像部で−600V、画像形成時に
白表示部となる背景部で−120Vである。一成分現像
装置3は、前記静電潜像保持体1に対向して配置された
現像剤担持体4を有している。Embodiments of the present invention will be described below with reference to the drawings, but the present invention is not limited to these embodiments. (Embodiment 1) FIG. 1 is an explanatory view of a developing device using a magnetic one-component developer which is Embodiment 1 of the present invention, FIG. 1A is an overall explanatory view thereof, and FIG. 1B is a portion near a surface of a developer carrier. It is an expanded sectional view. In FIG. 1A, the electrostatic latent image carrier 1 is a photoconductive drum having a negatively charged organic photosensitive layer on the surface thereof, and after being uniformly charged by a charging means (not shown),
An electrostatic latent image 2 is formed by the difference in electrostatic potential generated by irradiating the image light. The surface potential when the electrostatic latent image 2 is formed is, for example, −600V in the image portion and −120V in the background portion which becomes the white display portion during image formation. The one-component developing device 3 has a developer carrying member 4 arranged so as to face the electrostatic latent image holding member 1.
【0020】現像装置3のホッパー5は、現像剤担持体
4に供給する磁性一成分現像剤6を貯留するものであ
り、現像剤担持体4を収容すると共に、静電潜像保持体
1に対向して開口する部分で現像剤担持体4表面を露出
して、現像剤担持体4と静電潜像保持体1とが近接する
ように配置されている。現像剤担持体4は、その回転に
より、表面に付着した磁性一成分現像剤6を搬送し、静
電潜像保持体1と近接した現像領域Aにおける最小間隙
が200μm程度となるように設定されている。現像剤
担持体4の内部には、複数の磁石が周面に沿って配列さ
れ、回転しないように固定されたマグネットロール7が
設けられている。複数の磁石はS極とN極とを周面に沿
って配列した磁気パターンを形成しており、この磁気パ
ターンに従って、磁性現像剤6を現像剤担持体4の表面
に吸着することができるようになっている。The hopper 5 of the developing device 3 stores the magnetic one-component developer 6 to be supplied to the developer carrying member 4, and accommodates the developer carrying member 4 as well as the electrostatic latent image holding member 1. The surface of the developer carrying member 4 is exposed at the portions facing each other, and the developer carrying member 4 and the electrostatic latent image holding member 1 are arranged in close proximity to each other. The rotation of the developer carrier 4 conveys the magnetic one-component developer 6 attached to the surface thereof, and is set so that the minimum gap in the development area A adjacent to the electrostatic latent image carrier 1 is about 200 μm. ing. Inside the developer carrying member 4, a plurality of magnets are arranged along the peripheral surface, and a magnet roll 7 fixed so as not to rotate is provided. The plurality of magnets form a magnetic pattern in which S poles and N poles are arranged along the peripheral surface, and the magnetic developer 6 can be attracted to the surface of the developer carrier 4 according to the magnetic pattern. It has become.
【0021】図1Bにおいて、現像剤担持体4は、肉厚
0.7mmのアルミニウム製円筒部材である基材4a
と、その周面上に形成された、半導電性樹脂からなる膜
厚80μm程度の樹脂層4b とから構成されている。前
記樹脂層4b 中には、大径の第1の無機化合物粒子8
と、小径の第2の無機化合物粒子9が分散している。前
記樹脂層4b は、結着樹脂および溶剤中に、少なくとも
粒径範囲が異なる第1および第2の無機化合物粒子
(8,9)を分散させた塗布液を基材4a 表面に塗布す
ることによって形成された塗膜からなる。塗布液の組成
は、一例として下記のような配合例を挙げることができ
る。これらの塗布液から形成される樹脂層4b の電気抵
抗は、7×105 〜2×106 Ω・cmであり、その表
面粗さはJISの10点平均粗さRzで4.0〜9.0μ
mである。In FIG. 1B, the developer carrying member 4 is a base material 4a which is a cylindrical member made of aluminum and having a thickness of 0.7 mm.
And a resin layer 4b made of semiconductive resin and having a film thickness of about 80 μm formed on the peripheral surface of the resin layer 4b. In the resin layer 4b, large-diameter first inorganic compound particles 8
And the small-sized second inorganic compound particles 9 are dispersed. The resin layer 4b is formed by coating the surface of the base material 4a with a coating liquid in which first and second inorganic compound particles (8, 9) having different particle size ranges are dispersed in a binder resin and a solvent. It consists of a formed coating film. The composition of the coating liquid may include the following formulation examples as an example. The electric resistance of the resin layer 4b formed from these coating solutions is 7 × 10 5 to 2 × 10 6 Ω · cm, and its surface roughness is 4.0 to 9 in terms of JIS 10-point average roughness Rz. 0.0μ
m.
【0022】 配合例i) 重量部 結着樹脂 ポリエステル樹脂 68 (大日本インキ化学(株):M6401−50S) メラミン樹脂(三井東圧化学(株):U−80S) 19 エポキシ樹脂(旭電化工業(株):EP−5100−75X) 13 第1および第2の無機化合物粒子 平均粒径1.5μmのシリカ粒子((株)龍森:VX−X) 115 平均粒径16nmのシリカ粒子(日本アエロジル(株):130) 7 電気抵抗制御剤 カーボン(デグサ社:FW−200) 9 溶剤 キシレン 85 メチルイソブチルケトン 85 n−ブタノール 28 ブチルセロソルブ 28 配合例ii)第1の無機化合物粒子として、平均粒径1.
5μmのシリカ粒子に代えて平均粒径2.5μmのシリ
カ粒子((株)龍森:VX−SR)を用いる以外は、前記
配合例i)と同様である。Formulation Example i) Parts by Weight Binder Resin Polyester Resin 68 (Dainippon Ink and Chemicals, Inc .: M6401-50S) Melamine Resin (Mitsui Toatsu Chemicals, Inc .: U-80S) 19 Epoxy Resin (Asahi Denka Kogyo) (Inc .: EP-5100-75X) 13 First and second inorganic compound particles Silica particles having an average particle size of 1.5 μm (Tatsumori: VX-X) 115 Silica particles having an average particle size of 16 nm (Japan Aerosil Co., Ltd .: 130) 7 Electric resistance control agent Carbon (Degussa Company: FW-200) 9 Solvent xylene 85 Methyl isobutyl ketone 85 n-Butanol 28 Butyl cellosolve 28 Formulation example ii) Average particle size as the first inorganic compound particles 1.
The same as the above-mentioned formulation example i) except that silica particles having an average particle size of 2.5 μm (Tatsumori Co., Ltd .: VX-SR) are used instead of the silica particles having a particle size of 5 μm.
【0023】図1Aに示す現像剤規制部材10は、前記
現像剤担持体4の表面に圧接される弾性部材10a とこ
の弾性部材10a を接着した板バネ10b とからなり、
板バネ10b の他端は現像装置3本体に固定支持されて
いる。現像剤担持体4に対する弾性部材10a の当接位
置は、現像剤担持体4が静電潜像保持体1に最も近接す
る表面位置とマグネットロール7の中心を結ぶ基準線に
対して、現像剤担持体4の回転方向上流側に80°の直
線上に配置されている。また、板バネ10b の自由端は
現像剤担持体4の回転方向の下流側に傾斜するように取
り付けられている。弾性部材10aは幅15mm、厚さ
1.00mm、ゴム硬度50°のシリコーンゴムからな
り、板バネ10bは厚さ0.1mmのステンレススチール
製板(SUS304CSP3/4材、引張強さ95kg
f/mm2、耐力68kgf/mm2)を用いている。 (↑ 「耐力」の意味は ? )明確な降伏点を捉えら
ることができないものについて、残留歪0.2%に相当
する応力を「耐力」と呼び、降伏点の代わりに用いてい
る。The developer regulating member 10 shown in FIG. 1A comprises an elastic member 10a that is pressed against the surface of the developer carrying member 4 and a leaf spring 10b to which the elastic member 10a is adhered.
The other end of the leaf spring 10b is fixedly supported by the main body of the developing device 3. The contact position of the elastic member 10a with respect to the developer carrying member 4 is the developer with respect to the reference line connecting the surface position where the developer carrying member 4 is closest to the electrostatic latent image holding member 1 and the center of the magnet roll 7. It is arranged on the straight line of 80 ° on the upstream side in the rotation direction of the carrier 4. Further, the free end of the leaf spring 10b is attached so as to be inclined to the downstream side in the rotation direction of the developer carrying member 4. The elastic member 10a is made of silicone rubber having a width of 15 mm, a thickness of 1.00 mm and a rubber hardness of 50 °, and the leaf spring 10b is a stainless steel plate having a thickness of 0.1 mm (SUS304CSP3 / 4 material, tensile strength 95 kg).
f / mm 2 and proof stress 68 kgf / mm 2 ) are used. (↑ What is the meaning of “proof stress”?) For those whose clear yield point cannot be grasped, the stress equivalent to 0.2% of residual strain is called “proof strength” and is used instead of the yield point.
【0024】前記現像剤担持体4の基材4a には、直列
に接続した高圧交流電源11および直流電源12によっ
てバイアス電圧である直流重畳交流電圧が印加され、現
像剤担持体4と静電潜像保持体1とが近接する現像領域
Aで、静電潜像保持体1の導電層(アルミニウム箔)に
接続された電極と基材4a の間に交番電界が発生するよ
うになっている。前記バイアス電圧は、交流成分の周波
数が2.4kHz、ピークツーピーク電圧が2200
V、直流成分が−270Vにそれぞれ設定されている。A DC superimposing AC voltage, which is a bias voltage, is applied to the base material 4a of the developer carrying member 4 by a high-voltage AC power supply 11 and a DC power supply 12 connected in series, so that the developer carrying member 4 and the electrostatic latent image are electrostatically charged. An alternating electric field is generated between the electrode connected to the conductive layer (aluminum foil) of the electrostatic latent image carrier 1 and the base material 4a in the developing area A where the image carrier 1 is in close proximity. The bias voltage has an AC component frequency of 2.4 kHz and a peak-to-peak voltage of 2200.
The V and DC components are set to -270V, respectively.
【0025】(実施例1の作用)次に、前述の構成を備
えた現像装置の実施例1の作用を説明する。前記一成分
現像装置3に正帯電性の磁性一成分現像剤6を充填し、
電子写真複写機に装着して使用する。静電潜像保持体1
上の静電潜像2を現像する際、ホッパー5内の一成分現
像剤6は、回転する現像剤担持体4の表面に付着し、現
像剤規制部材10の弾性部材10aおよび表面に凹凸を
形成した前記樹脂層4bにより摺擦される。この場合、
前記樹脂層4b に分散した前記平均粒径の大きい第1の
無機化合物粒子8が樹脂層表面に一部露出することによ
り、現像剤担持体の表面粗さを適度な粗さ、例えばRz
を0.5〜10.0μmの範囲に調整されているので、静
電潜像を現像するに十分な現像剤層厚を現像剤担持体4
上に形成することができる。同時に、平均粒径が小さい
第2の無機化合物粒子9が樹脂層4b 表面に一部露出す
ることにより、現像剤担持体4表面の微小面積における
無機化合物粒子8,9の露出密度を高くすることがで
き、一成分現像剤6に均一かつ十分な摩擦帯電電荷を付
与することができる。(Operation of First Embodiment) Next, the operation of the first embodiment of the developing device having the above-described structure will be described. The one-component developing device 3 is filled with a positively-charged magnetic one-component developer 6,
Used by mounting on an electrophotographic copying machine. Electrostatic latent image holder 1
At the time of developing the electrostatic latent image 2 above, the one-component developer 6 in the hopper 5 adheres to the surface of the rotating developer carrier 4 and causes unevenness on the elastic member 10a of the developer regulating member 10 and the surface. The formed resin layer 4b is rubbed. in this case,
The first inorganic compound particles 8 having a large average particle size dispersed in the resin layer 4b are partially exposed on the surface of the resin layer, whereby the surface roughness of the developer carrying member is adjusted to an appropriate roughness, for example, Rz.
Is adjusted in the range of 0.5 to 10.0 μm, so that the developer carrying member 4 has a sufficient developer layer thickness for developing the electrostatic latent image.
Can be formed on. At the same time, the second inorganic compound particles 9 having a small average particle size are partially exposed on the surface of the resin layer 4b, so that the exposure density of the inorganic compound particles 8 and 9 in a minute area on the surface of the developer carrier 4 is increased. Therefore, it is possible to impart a uniform and sufficient triboelectric charge to the one-component developer 6.
【0026】薄層化された現像剤6は、現像剤担持体4
の回転に伴って現像領域Aに搬送され、現像剤担持体4
と静電潜像保持体1との間隙に発生する交番電界内で、
十分な電荷を有する多くの現像剤6粒子が飛翔して往復
運動をする。また、この往復運動によって、現像剤6の
粒子同志が衝突し現像剤6全体がクラウド状となる。こ
の現像剤6のクラウドが、バイアス電圧の直流成分によ
って、静電潜像保持体1上の静電潜像2部分に引き寄せ
られて現像が終了する。The thinned developer 6 is the developer carrier 4
Is conveyed to the developing area A with the rotation of the developer carrier 4
In the alternating electric field generated in the gap between the electrostatic latent image carrier 1 and
Many particles of developer 6 having a sufficient charge fly and reciprocate. Further, due to this reciprocating motion, the particles of the developer 6 collide with each other and the entire developer 6 becomes cloud-like. The cloud of the developer 6 is attracted to the electrostatic latent image 2 portion on the electrostatic latent image holder 1 by the DC component of the bias voltage, and the development is completed.
【0027】(実施例2)図2は本発明の実施例2であ
る非磁性一成分現像剤を用いる現像装置の説明図で、図
2Aはその全体説明図、図2Bは現像剤担持体の表面付
近の部分拡大断面図である。なお、図2において、図1
と同一の部材には便宜上同一の符号を付している。図2
Aにおいて、現像剤として非磁性一成分現像剤13を用
い、現像剤担持体4の内部に配置されたマグネットロー
ル7を取り除くと共に、供給ロール14を現像剤担持体
4と回転接触するように配置した以外は、前記図1Aに
示す一成分現像装置と同一の構成になっている。(Embodiment 2) FIG. 2 is an explanatory view of a developing device using a non-magnetic one-component developer which is Embodiment 2 of the present invention, FIG. 2A is an overall explanatory view thereof, and FIG. 2B is a developer carrier. It is a partial expanded sectional view near the surface. In addition, in FIG.
For convenience, the same members are designated by the same reference numerals. Figure 2
In A, the non-magnetic one-component developer 13 is used as the developer, the magnet roll 7 arranged inside the developer carrier 4 is removed, and the supply roll 14 is arranged so as to be in rotary contact with the developer carrier 4. Except for the above, it has the same configuration as the one-component developing device shown in FIG. 1A.
【0028】前記非磁性一成分現像装置(3)の現像条
件を示すと、下記のとおりである。 ・画像部の電位−450Vおよび背景部の電位−100
V ・現像領域Aの最小間隙200μm ・基材4aの材質 ; 肉厚3mmのアルミニウム ・樹脂層4b 膜厚110μm,電気抵抗7×105〜2×106Ω・c
m,表面粗さRz4.0〜9.0μm ・塗布液の組成 … 実施例1と同じ 第1の無機化合物粒子8 ; 平均粒径2.5μmのシリ
カ粒子 第2の無機化合物粒子9 ; 平均粒径10nmのシリカ
粒子 ・現像剤担持体4に対する弾性部材7aの当接角度80
° ・弾性部材7aの材質 幅10mm,厚さ1.00mm,ゴム硬度50°のシリ
コーンゴム ・板バネ7bの材質 ; 厚さ0.1mmのステンレスス
チール ・バイアス電圧 交流成分の周波数3.5kHz,ピークツーピーク電圧
2600V,直流成分−220VThe developing conditions of the non-magnetic one-component developing device (3) are shown below.・ Potential of image part −450V and potential of background part −100
V ・ Minimum gap of development area A 200 μm ・ Material of base material 4a; Aluminum with thickness 3 mm ・ Resin layer 4b Film thickness 110 μm, electric resistance 7 × 10 5 to 2 × 10 6 Ω · c
m, surface roughness Rz 4.0 to 9.0 μm-Composition of coating liquid ... Same as in Example 1 First inorganic compound particles 8; Silica particles having an average particle size of 2.5 μm Second inorganic compound particles 9; Average particle Silica particles having a diameter of 10 nm-Abutting angle 80 of the elastic member 7a to the developer carrying member 4
° ・ Material of elastic member 7a Width 10mm, thickness 1.00mm, silicone rubber with rubber hardness 50 ° ・ Material of leaf spring 7b; Thickness 0.1mm of stainless steel ・ Bias voltage AC component frequency 3.5kHz, peak Two-peak voltage 2600V, DC component -220V
【0029】(実施例2の作用)次に、前述の構成を備
えた現像装置の作用を説明する。静電潜像保持体1上の
静電潜像2を現像する際、ホッパー5内の非磁性一成分
現像剤13は、現像剤担持体4と同じ周速で逆方向に回
転する供給ロール14によって現像剤担持体4に供給さ
れ、回転する現像剤担持体4の表面に付着する。そし
て、弾性部材10aによって樹脂層4bに摺擦されると、
現像剤13は、薄層化されると同時に電荷が付与され、
現像剤担持体4の回転に伴って現像領域Aに搬送され
る。以下実施例1と同様にして、現像剤13は静電潜像
保持体1上の潜像2部分に引き寄せられて現像が終了す
る。この実施例2によれば、実施例1と同様の鮮明な画
像が得られる。(Operation of Second Embodiment) Next, the operation of the developing device having the above-described structure will be described. When developing the electrostatic latent image 2 on the electrostatic latent image carrier 1, the non-magnetic one-component developer 13 in the hopper 5 rotates in the opposite direction at the same peripheral speed as the developer carrier 4. Is supplied to the developer carrying member 4 and adheres to the surface of the rotating developer carrying member 4. When the elastic member 10a rubs against the resin layer 4b,
The developer 13 is thinned and at the same time, is given an electric charge,
The developer carrier 4 is conveyed to the developing area A as the developer carrier 4 rotates. Thereafter, in the same manner as in Example 1, the developer 13 is attracted to the latent image 2 portion on the electrostatic latent image holder 1 to complete the development. According to the second embodiment, a clear image similar to that of the first embodiment can be obtained.
【0030】[0030]
【発明の効果】本発明の一成分現像装置は、下記の効果
を奏する。 (E01) 本発明の一成分現像装置における現像剤担持
体の表面層は、粒径範囲の異なる少なくとも2種の無機
化合物粒子、すなわち平均粒径が異なる2種以上の無機
化合物粒子を分散させた樹脂層から形成されている。そ
の結果、前記2種以上の無機化合物粒子のうち、平均粒
径の大きい無機化合物粒子が樹脂層表面に一部露出する
ことにより、現像剤担持体の表面粗さを適度な粗さ、例
えばRzを0.5〜10.0μmの範囲に調整することが
できるため、静電潜像を現像するに十分な現像剤層厚を
現像剤担持体上に形成することができる。同時に、平均
粒径が小さい無機化合物粒子が樹脂層表面に一部露出す
ることにより、現像剤担持体表面の微小面積における無
機化合物粒子の露出密度を高くすることができ、一成分
現像剤に均一かつ十分な摩擦帯電電荷を付与することが
できる。したがって、静電潜像を現像する方式の複写機
やプリンタ等の画像形成装置に本発明の一成分現像装置
を適用することにより、鮮明な画像を安定的に得ること
ができるようになる。The one-component developing device of the present invention has the following effects. (E01) In the surface layer of the developer carrier in the one-component developing apparatus of the present invention, at least two kinds of inorganic compound particles having different particle diameter ranges, that is, two or more kinds of inorganic compound particles having different average particle diameters are dispersed. It is formed of a resin layer. As a result, among the two or more kinds of inorganic compound particles, some of the inorganic compound particles having a large average particle size are exposed on the surface of the resin layer, so that the surface roughness of the developer carrying member is adjusted to an appropriate roughness, for example, Rz. Can be adjusted in the range of 0.5 to 10.0 μm, so that a developer layer thickness sufficient for developing the electrostatic latent image can be formed on the developer carrying member. At the same time, by exposing a part of the inorganic compound particles having a small average particle size to the surface of the resin layer, it is possible to increase the exposure density of the inorganic compound particles in a minute area on the surface of the developer carrier, and to make it uniform in the one-component developer. In addition, sufficient triboelectric charge can be applied. Therefore, by applying the one-component developing device of the present invention to an image forming apparatus such as a copying machine or a printer that develops an electrostatic latent image, a clear image can be stably obtained.
【図1】 図1は磁性一成分現像剤を用いた本発明の現
像装置の実施例1の説明図であり、図1Aはその現像装
置と静電潜像保持体表面の一部を示す断面図で、図1B
は図1Aに示す現像剤担持体の表面付近の拡大断面図で
ある。FIG. 1 is an explanatory diagram of a first embodiment of a developing device of the present invention using a magnetic one-component developer, and FIG. 1A is a sectional view showing the developing device and a part of the surface of an electrostatic latent image carrier. Figure, Figure 1B
FIG. 1B is an enlarged cross-sectional view near the surface of the developer carrying member shown in FIG. 1A.
【図2】 図2は非磁性一成分現像剤を用いた本発明の
現像装置の実施例2の説明図であり、図2Aはその現像
装置と静電潜像保持体表面の一部を示す断面図で、図2
Bは図2Aに示す現像剤担持体の表面付近の拡大断面図
である。FIG. 2 is an explanatory diagram of Embodiment 2 of the developing device of the present invention using a non-magnetic one-component developer, and FIG. 2A shows the developing device and a part of the surface of the electrostatic latent image carrier. 2 is a cross-sectional view.
2B is an enlarged cross-sectional view near the surface of the developer carrier shown in FIG. 2A.
【図3】 磁性一成分現像剤を用いた従来の現像装置の
断面図である。FIG. 3 is a sectional view of a conventional developing device using a magnetic one-component developer.
【図4】 非磁性一成分現像剤を用いた従来の現像装置
の断面図である。FIG. 4 is a sectional view of a conventional developing device using a non-magnetic one-component developer.
A…現像領域 1…静電潜像保持体、2…静電潜像、3…一成分現像装
置、4…現像剤担持体、4a…基材、4b…樹脂層、5…
ホッパー、6…磁性一成分現像剤、7…マグネットロー
ル、8…第1の無機化合物粒子、9…第2の無機化合物
粒子、10…現像剤規制部材、10a…弾性部材、10b
…板バネ、11…高圧交流電源、12…直流電源、13
…非磁性一成分現像剤、14…供給ロールA ... Development area 1 ... Electrostatic latent image holder, 2 ... Electrostatic latent image, 3 ... One-component developing device, 4 ... Developer carrier, 4a ... Base material, 4b ... Resin layer, 5 ...
Hopper, 6 ... Magnetic one-component developer, 7 ... Magnet roll, 8 ... First inorganic compound particles, 9 ... Second inorganic compound particles, 10 ... Developer regulating member, 10a ... Elastic member, 10b
... leaf spring, 11 ... high-voltage AC power supply, 12 ... DC power supply, 13
... non-magnetic one-component developer, 14 ... supply roll
Claims (3)
剤を表面に付着して搬送する現像剤担持体と、現像剤担
持体表面に付着する現像剤量を規制して薄層化する現像
剤規制部材とを備え、現像剤担持体と静電潜像保持体と
が対向して近接する現像領域に発生させた電界内で、現
像剤担持体表面の電荷を有する現像剤を前記静電潜像保
持体上の静電潜像に付着させて可視化する一成分現像装
置において、下記の要件を有することを特徴とする一成
分現像装置、(Y01)前記現像剤担持体の表面層が、無
機化合物粒子および結着樹脂を必須成分とした樹脂層で
形成され、(Y02)前記無機化合物粒子は、少なくと
も、必要な表面粗さを得ることが可能な大きな粒径範囲
に属する第1の無機化合物粒子と、前記表面粗さへの影
響が小さく接触した現像剤を摩擦帯電させる小さな粒径
範囲に属する第2の無機化合物粒子とからなること。1. A developer carrying member which is provided so as to face an electrostatic latent image holding member and which adheres and conveys a developer onto the surface thereof, and a thin layer which regulates the amount of the developer adhering to the surface of the developer carrying member. And a developer control member that changes to a charge, and a developer having a charge on the surface of the developer carrier is generated in an electric field generated in a developing region in which the developer carrier and the electrostatic latent image carrier face each other. A one-component developing device which is visualized by being attached to an electrostatic latent image on the electrostatic latent image holding member, wherein the one-component developing device has the following requirements: (Y01) Surface of the developer carrying member The layer is formed of a resin layer containing inorganic compound particles and a binder resin as essential components, and (Y02) the inorganic compound particles belong to at least a large particle size range capable of obtaining a required surface roughness. The contact between the inorganic compound particles of No. 1 and the surface roughness is small. It is made of the second inorganic compound particles belonging to a small particle size range for triboelectric charging of the agent.
分現像装置、(Y03)前記第1の無機化合物粒子の平均
粒径は1〜20μmの範囲にあり、第2の無機化合物粒
子の平均粒径は5〜100nmの範囲にあること。2. The one-component developing device according to claim 1, wherein the following requirements are satisfied: (Y03) The average particle size of the first inorganic compound particles is in the range of 1 to 20 μm, and the second inorganic compound particles are The average particle size of is in the range of 5 to 100 nm.
記載の一成分現像装置、(Y04)前記第1および第2の
無機化合物が、金属酸化物、水酸化物、ホウ素化合物、
珪素化合物、窒素化合物、炭素化合物および塩基性金属
酸化物から選ばれた1種または2種以上の化合物である
こと。3. The one-component developing device according to claim 1 or 2, which has the following requirements, (Y04) wherein the first and second inorganic compounds are a metal oxide, a hydroxide, a boron compound,
One or more compounds selected from silicon compounds, nitrogen compounds, carbon compounds and basic metal oxides.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10027894A JPH07306586A (en) | 1994-05-13 | 1994-05-13 | One-component developing device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10027894A JPH07306586A (en) | 1994-05-13 | 1994-05-13 | One-component developing device |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH07306586A true JPH07306586A (en) | 1995-11-21 |
Family
ID=14269741
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10027894A Pending JPH07306586A (en) | 1994-05-13 | 1994-05-13 | One-component developing device |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH07306586A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5862444A (en) * | 1996-04-18 | 1999-01-19 | Minolta Co., Ltd. | Developing roller having another coating of fine particles |
-
1994
- 1994-05-13 JP JP10027894A patent/JPH07306586A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5862444A (en) * | 1996-04-18 | 1999-01-19 | Minolta Co., Ltd. | Developing roller having another coating of fine particles |
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