JPH07258699A - Pearl-like fluid detergent composition - Google Patents
Pearl-like fluid detergent compositionInfo
- Publication number
- JPH07258699A JPH07258699A JP7662594A JP7662594A JPH07258699A JP H07258699 A JPH07258699 A JP H07258699A JP 7662594 A JP7662594 A JP 7662594A JP 7662594 A JP7662594 A JP 7662594A JP H07258699 A JPH07258699 A JP H07258699A
- Authority
- JP
- Japan
- Prior art keywords
- pearl
- detergent composition
- liquid detergent
- fatty acid
- fluid detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000003599 detergent Substances 0.000 title claims abstract description 22
- 239000012530 fluid Substances 0.000 title abstract 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims description 19
- 239000000344 soap Substances 0.000 claims description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 8
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims description 7
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 claims description 6
- 229940100608 glycol distearate Drugs 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 12
- 238000005187 foaming Methods 0.000 abstract description 12
- 238000002156 mixing Methods 0.000 abstract description 5
- 239000002253 acid Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 2
- 230000000007 visual effect Effects 0.000 abstract 2
- HQSFGCUUTBCFPF-UHFFFAOYSA-N ethane-1,2-diol;octadecanoic acid Chemical compound OCCO.CCCCCCCCCCCCCCCCCC(O)=O HQSFGCUUTBCFPF-UHFFFAOYSA-N 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 16
- 239000000194 fatty acid Substances 0.000 description 16
- 229930195729 fatty acid Natural products 0.000 description 16
- 150000004665 fatty acids Chemical class 0.000 description 15
- 239000002932 luster Substances 0.000 description 12
- 239000011049 pearl Substances 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- -1 alkali metal salts Chemical class 0.000 description 5
- 235000019864 coconut oil Nutrition 0.000 description 5
- 239000003240 coconut oil Substances 0.000 description 5
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- KPRZOPQOBJRYSW-UHFFFAOYSA-N o-hydroxybenzylamine Natural products NCC1=CC=CC=C1O KPRZOPQOBJRYSW-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QKACYUNWMGTCNR-UHFFFAOYSA-N 3-(2-oxotridecylamino)propanoic acid Chemical class CCCCCCCCCCCC(=O)CNCCC(O)=O QKACYUNWMGTCNR-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- YOJORROXSMECGY-UHFFFAOYSA-N C[N+](C)(C)CC([O-])=O.CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC Chemical compound C[N+](C)(C)CC([O-])=O.CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC YOJORROXSMECGY-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 235000021536 Sugar beet Nutrition 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000003862 amino acid derivatives Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- UTBDYLQPXTWUDG-UHFFFAOYSA-N ethene;octadecanoic acid Chemical compound C=C.CCCCCCCCCCCCCCCCCC(O)=O UTBDYLQPXTWUDG-UHFFFAOYSA-N 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- UHUSDOQQWJGJQS-UHFFFAOYSA-N glycerol 1,2-dioctadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCCCCCCCC UHUSDOQQWJGJQS-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- SLBXZQMMERXQAL-UHFFFAOYSA-M sodium;1-dodecoxy-4-hydroxy-1,4-dioxobutane-2-sulfonate Chemical compound [Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O SLBXZQMMERXQAL-UHFFFAOYSA-M 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明はパール光沢に優れ、かつ
起泡力にすぐれたパール状液体洗浄剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pearl-like liquid detergent composition having excellent pearly luster and excellent foaming power.
【０００２】[0002]
【従来の技術】頭髪用液体洗浄剤分野では、従来から透
明タイプのものが主流であったが、近年、コンディショ
ニング効果を付与するタイプが望まれ、そのためカチオ
ン性高分子、カチオン性界面活性剤、油分等をおおく配
合した処方が開発されている。しかしながら、これらの
成分はアニオン界面活性剤と疎水性の複合塩を形成した
り、可溶化し難いために、パール状の外観にせざるを得
ない。一方、身体用液体洗浄剤分野においても、ヤシ脂
肪酸、パーム脂肪酸のアルカリ金属塩やアルカノールア
ミン塩を中心とするいわゆる石鹸は他の合成洗浄剤と比
べ、クラフト点が非常に高く、透明にすることが困難
で、パール化剤等を併用し、パール状とするのが一般的
である。しかし、これら液体洗浄剤では、パール化剤自
体が油成分であり、起泡力を妨げるほか、カチオン性界
面活性剤等のコンディショニング剤や石鹸と併用した場
合に良好なパール状を呈しないことがあり、製造上の課
題でもあった。2. Description of the Related Art In the field of liquid cleaners for hair, a transparent type has hitherto been mainly used, but in recent years, a type which imparts a conditioning effect has been desired. Therefore, a cationic polymer, a cationic surfactant, Formulations containing a large amount of oil have been developed. However, since these components are difficult to form a hydrophobic complex salt with an anionic surfactant and are difficult to be solubilized, they have to have a pearly appearance. On the other hand, also in the field of liquid detergents for the body, so-called soaps centering on palm fatty acids, alkali metal salts of palm fatty acids and alkanolamine salts have a very high craft point compared to other synthetic detergents, and should be transparent. Is difficult, and it is common to use a pearling agent and the like to form a pearl. However, in these liquid detergents, the pearling agent itself is an oil component, which hinders the foaming power, and may not exhibit a good pearly shape when used in combination with a conditioning agent such as a cationic surfactant or soap. Yes, it was a manufacturing issue.
【０００３】[0003]
【発明が解決しようとする課題】このような事情を鑑
み、本発明では、液体洗浄剤組成物にあって、起泡力を
損なうことなく、良好なパール光沢を有するパール状液
体洗浄剤組成物の提供を目的とする。In view of such circumstances, the present invention provides a liquid detergent composition, which is a pearl liquid detergent composition having good pearly luster without impairing the foaming power. For the purpose of providing.
【０００４】[0004]
【課題を解決するための手段】本発明者は、鋭意検討し
た結果、トリメチルグリシンとパール化剤を組み合わせ
ることによって良好なパール光沢のある外観を有し、且
つ、起泡力に優れたパール状液体洗浄剤組成物を見出
し、本発明を完成するに至った。すなわち、本発明は、
トリメチルグリシンとパール化剤を配合し、優れた起泡
力と、パール光沢を呈するパール状液体洗浄剤組成物を
提供するものである。Means for Solving the Problems As a result of intensive studies, the present inventor has found that a combination of trimethylglycine and a pearling agent has a good pearly appearance and a pearly shape excellent in foaming power. The inventors have found a liquid detergent composition and completed the present invention. That is, the present invention is
The present invention provides a pearl-like liquid detergent composition containing trimethylglycine and a pearling agent, which has excellent foaming power and pearly luster.
【０００５】本発明に用いるトリメチルグリシンは砂糖
大根や海草類に含まれているアミノ酸誘導体であり、ア
ミノコート（旭フーズ社製）等として商業的に入手でき
る。トリメチルグリシンの配合量は組成物全量に基づい
て０．０１〜２０重量％配合され、特に優れた光沢を呈
するため０．５％〜５重量％が好ましい。配合量が２０
重量％より多いと洗浄剤組成物の界面活性剤の種類また
は脂肪酸組成によつては沈澱を生じ、０．０１重量％に
満たない良好なパール光沢が発現しない。Trimethylglycine used in the present invention is an amino acid derivative contained in sugar beets and seaweeds, and is commercially available as Aminocoat (manufactured by Asahi Foods Co., Ltd.). The amount of trimethylglycine added is 0.01 to 20% by weight based on the total amount of the composition, and 0.5% to 5% by weight is preferable because it exhibits particularly excellent gloss. Compounding amount is 20
If the content is more than 10% by weight, precipitation may occur depending on the type of the surfactant or the fatty acid composition of the detergent composition, and a good pearly luster of less than 0.01% by weight may not be exhibited.
【０００６】本発明に用いるパール化剤はモノステアリ
ン酸エチレングリコール、ジステアリン酸エチレングリ
コール、モノステアリン酸ポリエチレングリコール、ジ
ステアリン酸ポリエチレングリコール、ステアリン酸マ
グネシウムなどであり、特にモノステアリン酸エチレン
グリコール、ジステアリン酸エチレングリコール、モノ
ステアリン酸ポリエチレングリコール、ジステアリン酸
ポリエチレングリコールがパール光沢に優れ、好適であ
り、中でも、ステアリン酸エチレングリコールが最も良
好なパール光沢を発現するので好ましい。これらは、例
えばゲナポールＰＭＳ（ヘスキトジャパン社製）、ニッ
コールＥＧＭＳ−７０（日光ケミカルズ社製）、ＭＡＰ
ＥＧ ＥＧＭＳ（ＰＰＧインダストリー社製）、ＥＧＭ
Ｓ（ＫＥＳＳＣＯ社製）等として商業的に入手できる。
これらのパール化剤は組成物中に０．５〜５重量％配合
され、中でも１〜３重量％が起泡性を損なうことがなく
好ましい、特に１．５〜２．５重量％が好ましい。配合
量が５重量％を越えると、ゲル状を呈するなど、好まし
くなく、経済的にも不都合である。また、０．５重量％
を下回ると、パールの析出が充分でなく、良好なパール
光沢が得られない。The pearling agents used in the present invention are ethylene glycol monostearate, ethylene glycol distearate, polyethylene glycol monostearate, polyethylene glycol distearate, magnesium stearate and the like, and particularly ethylene glycol monostearate and ethylene distearate. Glycol, polyethylene glycol monostearate, and polyethylene glycol distearate are excellent in pearl luster and are preferable, and among them, ethylene glycol stearate is preferable because it exhibits the best pearl luster. These are, for example, Genapol PMS (manufactured by Heskito Japan), Nikkor EGMS-70 (manufactured by Nikko Chemicals), MAP.
EG EGMS (manufactured by PPG Industry), EGM
It is commercially available as S (manufactured by KESSCO) or the like.
These pearlizing agents are blended in the composition in an amount of 0.5 to 5% by weight, preferably 1 to 3% by weight without impairing the foaming property, and particularly preferably 1.5 to 2.5% by weight. If the blending amount exceeds 5% by weight, it is not preferable, such as gelation, and it is economically inconvenient. Also, 0.5% by weight
If it is below the range, the pearls are not sufficiently deposited and good pearl luster cannot be obtained.
【０００７】本発明のパール状洗浄剤組成物中に用いる
界面活性剤のはラウリル硫酸塩、ポリオキシエチレンラ
ウリル硫酸塩、ヤシ油脂肪酸サルコシン塩、アシルグル
タミン酸塩、ラウロイルメチル−β−アラニン塩、高級
脂肪酸石鹸等のアニオン界面活性剤があげられる。高級
脂肪酸石鹸は、ヤシ脂肪酸、パーム核脂肪酸、パーム脂
肪酸、牛脂脂肪酸、及びラウリン酸、ミリスチン酸、パ
ルミチン酸、ステアリン酸等単蒸留した脂肪酸あるいは
オレイン酸、リノール酸等を単独または混合した脂肪酸
と、水酸化カリウム、水酸化ナトリウム等のアルカリ金
属、またはトリエタノールアミン、アミノメチルフェノ
ール等のアルカノールアミンで適量中和して本発明組成
物の成分とすることができる。 本発明のパール状液体
洗浄剤組成物は、特に石鹸を主体にした組成物が好適で
あり、この石鹸の配合濃度は５〜３０重量％が好まし
い。配合濃度が５重量％より濃度が低いと洗浄剤として
の機能を果たさず、３０重量％を上回ると粘度が高くな
りすぎてゲル化を生じる等、液状を維持できなくなる。
またポンプ容器とした場合、ノズル部分で詰まりを生じ
る等の問題が生じる。本発明の液状洗浄剤組成物の粘度
は２５℃で５００〜８０００ｃｐｓであれば良く、好ま
しくは、５００〜３０００ｃｐｓ、更に好ましくは６０
０から１５００ｃｐｓである。Surfactants used in the pearly detergent composition of the present invention include lauryl sulfate, polyoxyethylene lauryl sulfate, coconut oil fatty acid sarcosine salt, acylglutamate, lauroylmethyl-β-alanine salt, and higher salts. Anionic surfactants such as fatty acid soaps can be mentioned. Higher fatty acid soap, coconut fatty acid, palm kernel fatty acid, palm fatty acid, beef tallow fatty acid, and lauric acid, myristic acid, palmitic acid, monodistilled fatty acid such as stearic acid or oleic acid, fatty acid alone or mixed with linoleic acid, It can be used as a component of the composition of the present invention by neutralizing an appropriate amount with an alkali metal such as potassium hydroxide or sodium hydroxide or an alkanolamine such as triethanolamine or aminomethylphenol. The pearl-like liquid detergent composition of the present invention is preferably a composition mainly composed of soap, and the blending concentration of this soap is preferably 5 to 30% by weight. If the concentration is less than 5% by weight, it will not function as a detergent, and if it exceeds 30% by weight, the viscosity will be too high and gelation will occur, making it impossible to maintain the liquid state.
Further, in the case of a pump container, problems such as clogging of the nozzle portion occur. The viscosity of the liquid detergent composition of the present invention may be 500 to 8000 cps at 25 ° C., preferably 500 to 3000 cps, and more preferably 60.
It is 0 to 1500 cps.
【０００８】本発明のパール状液体洗浄剤組成物は、シ
ャンプー、ハンドソープ、ボディシャンプーなどに利用
でき、その発明を妨げない範囲で、公知のアニオン界面
活性剤、両性界面活性剤、カチオン界面活性剤、非イオ
ン界面活性剤、湿潤剤、防腐剤、色素、保湿剤、水溶性
高分子、キレート剤、紫外線吸収剤、薬効剤、着香剤等
を適宜配合することができる。The pearl-like liquid detergent composition of the present invention can be used in shampoos, hand soaps, body shampoos and the like, and within a range not hindering the invention, known anionic surfactants, amphoteric surfactants and cationic surfactants are used. Agents, nonionic surfactants, wetting agents, preservatives, pigments, humectants, water-soluble polymers, chelating agents, ultraviolet absorbers, medicinal agents, flavoring agents and the like can be appropriately added.
【０００９】[0009]
【実施例】以下に、実施例をあげ、本発明を詳細に説明
するがこれら実施例に限定されるものではない。また、
実施例中の［％］は重量％を示す。表１に示す、実施例
１〜１１および比較例１〜２を常法により製造し、評価
した。評価方法を以下に示す。 （評価方法） １. 起泡力 ３枚羽フォームテスターを用い、実施例（および比較
例）の１％溶液２００ｍｌを４０℃の条件下で１５００
ｒｐｍで攪拌し、泡の体積（ｃｍ3）を測定した。 ２. パール光沢 肉眼判定により、パールの析出度、光沢を下記の基準に
より、総合的に判定した。 ＜基準＞ × 悪い △ 普通 ○ 良い ◎ 非常に良い 表１に示すように、実施例は比較例に比べて起泡力に優
れ、且つ良好なパール光沢を有することが認められた。The present invention will be described in detail below with reference to examples, but the invention is not limited to these examples. Also,
[%] In the examples indicates% by weight. Examples 1 to 11 and Comparative Examples 1 and 2 shown in Table 1 were manufactured by a conventional method and evaluated. The evaluation method is shown below. (Evaluation method) 1. Foaming power Using a three-blade foam tester, 200 ml of the 1% solution of the example (and comparative example) was subjected to 1500 at 40 ° C.
The mixture was stirred at rpm, and the volume of foam (cm 3 ) was measured. 2. Pearl luster The degree of pearl precipitation and luster were evaluated comprehensively by the naked eye. <Criteria> × Poor Δ Normal ○ Good ◎ Very good As shown in Table 1, it was confirmed that the examples had a better foaming power and good pearly luster than the comparative examples.
【００１０】[0010]
【表１】 [Table 1]
【００１１】 実施例１２ （ボディシャンプー） 成分 配合量（％） ラウリン酸 １０．０ ミリスチン酸 １０．０ パルミチン酸 ２．０ 水酸化カリウム 適量（ｐＨ９．６に調整） トリメチルグリシン １．２ ジステアリン酸エチレングリコール ０．５ ヤシ油脂肪酸ジエタノールアミド ４．０ パラオキシ安息香酸メチル ０．２ プロピレングリコール ６．０ 香料 ０．５ 精製水 残部 合計 １００．０Example 12 (Body shampoo) Ingredients Amount (%) Lauric acid 10.0 Myristic acid 10.0 Palmitic acid 2.0 Potassium hydroxide Appropriate amount (adjusted to pH 9.6) Trimethylglycine 1.2 Ethylene distearate Glycol 0.5 Coconut oil fatty acid diethanolamide 4.0 Methyl paraoxybenzoate 0.2 Propylene glycol 6.0 Perfume 0.5 Purified water balance Total 100.0
【００１２】 実施例１３（ハンドソープ） 成分 配合量（％） ヤシ油脂肪酸 １０．０ トリエタノールアミン 適量（ｐＨ８．５に調整） ヤシ油脂肪酸サルコシンナトリウム ５．０ トリメチルグリシン ３．０ モノステアリン酸エチレングリコール ３．０ 濃グリセリン １２．０ パラオキシ安息香酸メチル ０．１ 青色１号 微量 トリクロサン ０．３ 精製水 残部 合計 １００．０Example 13 (Hand soap) Component Blending amount (%) Coconut oil fatty acid 10.0 Triethanolamine Suitable amount (adjusted to pH 8.5) Coconut oil fatty acid sarcosine sodium 5.0 Trimethylglycine 3.0 Ethylene monostearate Glycol 3.0 Concentrated glycerin 12.0 Methyl paraoxybenzoate 0.1 Blue No. 1 Trace amount triclosan 0.3 Purified water Balance 100.0
【００１３】 実施例１４（シャンプー） 成分 配合量（％） ポリオキシエチレン（３ＥＯ） ３０．０ ラウリルスルホコハク酸ナトリウム（３０％） カチオン化セルロース ０．５ カチオン化ラノリン ０．３ トリメチルグリシン １．０ ジステアリン酸エチレングリコール １．５ パラオキシ安息香酸メチル ０．２ 安息香酸ナトリウム ０．５ ヤシ油脂肪酸ジエタノールアミド ４．０ ラウリルジメチルベタイン（３０％） ５．０ 香料 ０．５ 精製水 残部 合計 １００．０ 実施例１２〜１４においても、優れた起泡力と良好なパ
ール光沢を有する液体洗浄剤組成物を得ることができ
た。Example 14 (shampoo) Component Blending amount (%) Polyoxyethylene (3EO) 30.0 Sodium lauryl sulfosuccinate (30%) Cationized cellulose 0.5 Cationized lanolin 0.3 Trimethylglycine 1.0 Distearin Acid ethylene glycol 1.5 Methyl paraoxybenzoate 0.2 Sodium benzoate 0.5 Coconut oil fatty acid diethanolamide 4.0 Lauryl dimethyl betaine (30%) 5.0 Perfume 0.5 Purified water balance 100.0 Examples Even in Nos. 12 to 14, a liquid detergent composition having excellent foaming power and good pearl luster could be obtained.
【００１４】[0014]
【発明の効果】本発明によれば、優れた起泡力と良好な
パール光沢を有する液体洗浄剤組成物を提供できる。According to the present invention, it is possible to provide a liquid detergent composition having an excellent foaming power and a good pearl luster.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ１１Ｄ 9:26） ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location C11D 9:26)
Claims (3)
ール化剤を含有することを特徴とするパール状液体洗浄
剤組成物。1. A pearl-like liquid detergent composition comprising (a) trimethylglycine and (b) a pearling agent.
エチレングリコール、ジステアリン酸エチレングリコー
ル、モノステアリン酸ポリエチレングリコール、および
ジステアリン酸ポリエチレングリコールから選ばれる１
種または２種以上である請求項第１項に記載のパール状
液体洗浄剤組成物。2. The pearlizing agent of (b) is selected from ethylene glycol monostearate, ethylene glycol distearate, polyethylene glycol monostearate, and polyethylene glycol distearate.
The pearl-like liquid detergent composition according to claim 1, which is one kind or two or more kinds.
物である請求項第１項および第２項のいずれか１項に記
載のパール状液体洗浄剤組成物。3. The pearl-like liquid detergent composition according to any one of claims 1 and 2, wherein the pearl-like liquid detergent composition is a liquid soap composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7662594A JP3405475B2 (en) | 1994-03-22 | 1994-03-22 | Pearl liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7662594A JP3405475B2 (en) | 1994-03-22 | 1994-03-22 | Pearl liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07258699A true JPH07258699A (en) | 1995-10-09 |
| JP3405475B2 JP3405475B2 (en) | 2003-05-12 |
Family
ID=13610552
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7662594A Expired - Lifetime JP3405475B2 (en) | 1994-03-22 | 1994-03-22 | Pearl liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3405475B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11180855A (en) * | 1997-12-19 | 1999-07-06 | Kao Corp | Skin cleansing composition |
| WO2004015048A1 (en) * | 2002-08-09 | 2004-02-19 | Kao Corporation | Detergents |
| WO2004061071A1 (en) * | 2002-12-27 | 2004-07-22 | Kao Corporation | Detergent composition |
| KR100448241B1 (en) * | 2001-12-18 | 2004-09-10 | 주식회사 엘지생활건강 | Pearl composition and cosmetic composition having pearl-like feeling comprising them thereof |
-
1994
- 1994-03-22 JP JP7662594A patent/JP3405475B2/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11180855A (en) * | 1997-12-19 | 1999-07-06 | Kao Corp | Skin cleansing composition |
| KR100448241B1 (en) * | 2001-12-18 | 2004-09-10 | 주식회사 엘지생활건강 | Pearl composition and cosmetic composition having pearl-like feeling comprising them thereof |
| WO2004015048A1 (en) * | 2002-08-09 | 2004-02-19 | Kao Corporation | Detergents |
| US7354891B2 (en) | 2002-08-09 | 2008-04-08 | Kao Corporation | Pearlescent detergent composition comprising a mixture of ethylene glycol alkylates |
| WO2004061071A1 (en) * | 2002-12-27 | 2004-07-22 | Kao Corporation | Detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3405475B2 (en) | 2003-05-12 |
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