JPH07206605A - Insect-proofing agent and its production and usage - Google Patents
Insect-proofing agent and its production and usageInfo
- Publication number
- JPH07206605A JPH07206605A JP6023690A JP2369094A JPH07206605A JP H07206605 A JPH07206605 A JP H07206605A JP 6023690 A JP6023690 A JP 6023690A JP 2369094 A JP2369094 A JP 2369094A JP H07206605 A JPH07206605 A JP H07206605A
- Authority
- JP
- Japan
- Prior art keywords
- insect repellent
- paradichlorobenzene
- powder
- cellulose
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Landscapes
- Catching Or Destruction (AREA)
- Processing Of Solid Wastes (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】この発明は、台所などから出る生
ゴミを堆肥化するに際して使用する防虫剤とその製法な
らびにその使用法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an insect repellent for use in composting kitchen garbage and the like, a method for producing the insect repellent, and a method for using the insect repellent.
【0002】[0002]
【従来の技術】家庭から排出されるゴミ減量化に絡み、
家庭園芸などに使用する目的で、台所から出る野菜くず
や茶がらなどの生ゴミを、たとえば直径が約70〜80
cm程度のプラスチック製容器(以下、これを単に「コ
ンポスト容器」という。)に収容して堆肥化することが
行われている。この生ゴミの堆肥化に際し、コンポスト
容器にはその臭気につられて虫が飛来すると共に、コン
ポスト容器内でも虫が発生するため、堆肥化によって発
生する虫の排除と臭気対策のために、コンポスト容器の
蓋の内側やその他の適宜の部位に防虫剤からなる賦形物
を配置することが行われている。2. Description of the Related Art In connection with reducing the amount of garbage discharged from homes,
Raw garbage such as vegetable scraps and tea leaves from the kitchen, for example, having a diameter of about 70 to 80, is used for home gardening.
A plastic container (hereinafter, simply referred to as "compost container") having a size of about cm is housed and composted. During composting of this garbage, insects fly into the compost container due to its odor, and insects are also generated in the compost container. A shaped object made of an insect repellent is placed on the inside of the lid or other appropriate portion.
【0003】虫の飛来や発生する虫の抑制などのために
コンポスト容器内に配置される賦形化された防虫剤は、
常温で揮発して強い防虫作用を発揮し、防虫の効力とし
ては樟脳やナフタリンよりも強い昆虫忌避作用を有し、
特有の芳香を発散するパラジクロルベンゼンが使用され
ている。しかしながら、このパラジクロルベンゼンは殺
虫効力はきわめて弱いので、たとえば、トリクロロホ
ン,セミトロチオン,ギリダフェンチオンなどの有機り
ん系殺虫剤や、フタルスリン,ぺルメトリンなどのピレ
スロイト系殺虫剤、あるいはカーバリール(carba
ryl),イソプロカーブ(isprocarb)など
のカルバマート系殺虫剤の少量を、パラジクロルベンゼ
ンと併用して使用することによってコンポスト容器内に
侵入する虫の殺虫や発生するこれらの幼虫等の殺虫対策
を講じている。A shaped insect repellent which is placed in a compost container for controlling insects coming in and insects generated is
It volatilizes at room temperature and exerts a strong insect repellent effect, and as an insect repellent effect, it has a stronger insect repellent action than camphor and naphthalene.
Paradichlorobenzene, which emits a unique aroma, is used. However, since this paradichlorobenzene is extremely weak in insecticidal activity, for example, organophosphorus insecticides such as trichlorophone, semitrothion, and gillidafenthion, pyrethreuto insecticides such as phthalthrin and permethrin, or carbaryl (carbaryl).
ryl), isprocarb and other small amounts of carbamate insecticides are used in combination with paradichlorobenzene to take measures against insects that invade into compost containers and those larvae that occur. ing.
【0004】[0004]
【発明が解決しようとする課題】生ゴミの堆肥化による
醗酵によって生ずる虫の飛来や虫の発生抑制などを防止
するために使用されるパラジクロルベンゼンは、ある程
度所期の目的を達成する効果を発揮するものである。し
かしながら、パラジクロルベンゼンは有効成分の揮散性
がきわめて高く短時間のうちに昇華してその効力を失う
難点があるので、パラジクロルベンゼンの賦形物をコン
ポスト容器に適用した場合、その効果に持続性がないた
め頻繁にパラジクロルベンゼンの賦形物をコンポスト容
器内に配置する必要がある。そのため、生ゴミの堆肥化
に際して絶えずコンポスト容器に注意を払い、タイムリ
ーにパラジクロルベンゼンの賦形物を追加しないと周囲
の環境を損なわれ易く、防虫剤に要する費用も嵩むの
で、防虫効果を阻害しない範囲で有効成分の揮散を抑制
することが要望されている。Paradichlorobenzene, which is used to prevent insects from coming in and suppressing the generation of insects caused by fermentation by composting raw garbage, has the effect of achieving the intended purpose to some extent. It is something to demonstrate. However, paradichlorobenzene has a very high volatility of the active ingredient and has a drawback that it sublimates and loses its efficacy in a short time.Therefore, when the excipient of paradichlorobenzene is applied to a compost container, its effect is sustained. Since it has no property, it is necessary to frequently place the paradichlorobenzene excipient in the compost container. Therefore, when composting raw garbage, paying attention to the composting container and adding paradichlorobenzene excipient in a timely manner will easily damage the surrounding environment and increase the cost of insect repellents. It is desired to suppress volatilization of the active ingredient within a range that does not hinder it.
【0005】この発明はかゝる現状に鑑み、防虫剤とし
て有効性を有するパラジクロルベンゼンの揮散を抑制し
て長期間に亘って防虫効果を持続させることができ、か
つ優れた消臭効果を有する防虫剤と、この防虫剤の製法
ならびに防虫剤の使用方法を提供せんとするものであ
る。In view of the present circumstances, the present invention can suppress the volatilization of paradichlorobenzene, which is effective as an insect repellent, and can maintain the insect repellent effect for a long period of time, and has an excellent deodorant effect. The present invention provides an insect repellent, a method for producing the insect repellent, and a method for using the insect repellent.
【0006】[0006]
【課題を解決するための手段】上記の目的を達成するた
めに、この発明の防虫剤は、パラジクロルベンゼンから
なる防虫成分に、セルロース系化合物を配合してなるこ
とを特徴とするものである。In order to achieve the above object, the insect repellent of the present invention is characterized in that it comprises a repellent component comprising paradichlorobenzene and a cellulose compound. .
【0007】この発明において、昆虫忌避作用を有する
パラジクロルベンゼンの揮散を抑制し、長期にわたる効
能を維持させるためのセルロース系化合物は、パラジク
ロルベンゼンを主体とする防虫成分に所定の割合で配合
するものである。かゝるセルロース系化合物としては、
メチルセルロース,エチルセルロース,カルボキシメチ
ルセルロース,ヒドロキシプロピルセルロース,ヒドロ
キシエチルセルロース,ヒドロキシプロピルメチルセル
ロースおよびエチルヒドロキシエチルセルロースから選
ばれた1種もしくは2種以上からなるものである。In the present invention, the cellulosic compound for suppressing the volatilization of paradichlorobenzene having an insect repellent effect and maintaining the long-term efficacy is blended in a predetermined ratio with an insect repellent component mainly comprising paradichlorobenzene. It is a thing. As such a cellulosic compound,
One or more selected from methyl cellulose, ethyl cellulose, carboxymethyl cellulose, hydroxypropyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose and ethyl hydroxyethyl cellulose.
【0008】このセルロース系化合物は、防虫剤の主体
となるパラジクロルベンゼンの粉末95〜99.5重量
%に対し、その粉末0.5〜5.0重量%を配合し、所
定の形状に賦形するものである。この賦形は、前記両者
の粉末の混合物を打錠機で所定の大きさと形状に打錠す
ることによって容易に得ることができる。その際、必要
に応じて殺虫剤として、有機りん系殺虫剤やピレスロイ
ト系殺虫剤、あるはいカルバマート系殺虫剤を所定の割
合で配合してもよい。パラジクロルベンゼンに対してセ
ルロース系化合物の配合が0.5重量%未満の場合は、
パラジクロルベンゼンの蒸散遅延効果に乏しく、5重量
%を超えて使用しても特別な効果はなく、経済的に不利
なものとなる。This cellulosic compound is blended with powder of paradichlorobenzene, which is the main component of the insect repellent, in an amount of 0.5 to 5.0% by weight based on 95 to 99.5% by weight of the powder. It is a shape. This shaping can be easily obtained by tableting a mixture of the two powders into a predetermined size and shape with a tableting machine. At that time, if necessary, an organophosphorus insecticide, a pyrethroid insecticide, or a carbamate insecticide may be blended in a predetermined ratio. When the content of the cellulosic compound is less than 0.5% by weight with respect to paradichlorobenzene,
Paradichlorobenzene has a poor transpiration-retarding effect, and even if it is used in an amount of more than 5% by weight, it has no special effect and is economically disadvantageous.
【0009】前記殺虫剤を使用する場合には、防虫剤の
主体となるパラジクロルベンゼンの粉末90〜98.5
重量%に殺虫剤の原体の粉末5〜1重量%を添加して得
た防虫成分の95〜99.5重量%に、セルロース系化
合物の粉末50.〜0.5重量%を配合し、所定の形状
に賦形するものである。この殺虫剤の量が1重量%未満
の場合には殺虫効果が乏しくなり、5重量%を超えて多
量に添加すればそれなりの殺虫効果は期待できるが、コ
ンポスト容器による堆肥化に必ずしもよい影響を及ぼさ
ないので、5重量%以下の殺虫効果を阻害しない範囲で
極力少なく添加することが望ましい。When the above-mentioned insecticide is used, powder of paradichlorobenzene which is the main component of the insect repellent 90 to 98.5.
95 to 99.5% by weight of the insect repellent obtained by adding 5 to 1% by weight of the powder of the insecticide base to 50% by weight of the cellulose compound powder. ˜0.5 wt% is blended and shaped into a predetermined shape. If the amount of this insecticide is less than 1% by weight, the insecticidal effect is poor, and if it is added in excess of 5% by weight, some insecticidal effect can be expected, but it does not always have a good effect on composting in compost containers. Since it does not extend, it is desirable to add 5% by weight or less as much as possible within the range not inhibiting the insecticidal effect.
【0010】かくして得た防虫剤は、所定の形状の賦形
物としてコンポスト容器の内部に配置して使用するもの
である。コンポスト容器への適用は、たとえば、防虫剤
の賦形物をコンポスト容器の蓋体に固定するか、もしく
は吊り下げ、あるいはコンポスト容器の本体の内壁に固
定して、蒸散したパラジクロルベンゼンの蒸気をコンポ
スト容器内に充満させて使用するものである。The insect repellent thus obtained is used by being placed inside a compost container as a shaped article having a predetermined shape. For application to a compost container, for example, an insect repellent shaped product is fixed to the lid of the compost container, or suspended, or fixed to the inner wall of the main body of the compost container, and vaporized paradichlorobenzene vapor is removed. It is used by filling the compost container.
【0011】[0011]
【作用】この発明の防虫剤は、その主成分となるパラジ
クロルベンゼンに少量のセルロース系化合物を配合する
ことによって、パラジクロルベンゼンの蒸散を適宜に遅
延させて、長期に亘って防虫効果と消臭効果とを発揮す
ることができるものである。その蒸散遅延作用は、防虫
剤の主体となるパラジクロルベンゼンの粉末にセルロー
ス系化合物の粉末を配合し、その混合物を賦形すること
によって賦形の際の断熱圧縮でパラジクロルベンゼン粉
末の表面の一部が僅かに溶融してこれにセルロース粉末
が付着し溶解して、表面を適度にコーティングし、これ
によってパラジクロルベンゼンの表面からの蒸散を適度
に制限するものと考えられる。The insect repellent of the present invention mixes a small amount of a cellulosic compound with paradichlorobenzene, which is the main component, to appropriately delay the evaporation of paradichlorobenzene and to prevent the insect repellent effect from disappearing over a long period of time. It is possible to exert an odor effect. Its transpiration-retarding effect is that the powder of the cellulosic compound is blended with the powder of paradichlorobenzene, which is the main component of the insect repellent, and the mixture is shaped so that the surface of the paradichlorobenzene powder undergoes adiabatic compression during shaping. It is considered that a part thereof is slightly melted, and the cellulose powder is adhered to and dissolved therein to appropriately coat the surface, thereby appropriately limiting the evaporation of paradichlorobenzene from the surface.
【0012】[0012]
【実施例】以下、実施例および比較例によって、この発
明の防虫剤をより具体的に説明する。実施例1〜5及び比較例1、2 パラジクロルベンゼンの粉末に、セルロース系化合物の
粉末を配合して所定の形状に形成して得た防虫剤(実施
例1〜3)、パラジクロルベンゼンの粉末に殺虫成分と
してトリクロロホンの粉末を配合し、これにセルロース
系化合物を配合して所定の形状に形成して得た防虫剤
(実施例4、5)について、乾式蒸散試験を行った。こ
れに対して、比較例として前記セルロース系化合物を配
合することなく、パラジクロルベンゼンの粉末を単独で
賦形して得た防虫剤(比較例1)およびセルロース系化
合物を配合することなく、パラジクロルベンゼンの粉末
にトリクロロホンの粉末を添加して得た防虫剤(比較例
2)について同様の乾式蒸散試験を行った。各防虫剤の
成分配合比を〔表1〕に示し、乾式蒸散試験の結果を
〔表2〕に示す。なお、乾式蒸散試験は、下記の方法に
よって実施したものである。EXAMPLES Hereinafter, the insect repellent of the present invention will be described more specifically with reference to Examples and Comparative Examples. Examples 1 to 5 and Comparative Examples 1 and 2 Insect repellents (Examples 1 to 3) obtained by blending powders of paradichlorobenzene with powders of a cellulosic compound to form a predetermined shape, and paradichlorobenzenes. A dry transpiration test was carried out on the insect repellents (Examples 4 and 5) obtained by blending the powder with trichlorofon powder as an insecticidal component and blending this with a cellulose compound to form a predetermined shape. On the other hand, as a comparative example, without adding the cellulosic compound, without adding the insecticide (Comparative Example 1) and the cellulosic compound obtained by independently shaping the powder of paradichlorobenzene, The same dry evaporation test was performed on the insect repellent (Comparative Example 2) obtained by adding trichlorofon powder to chlorobenzene powder. The compounding ratio of each insect repellent is shown in [Table 1], and the results of the dry evaporation test are shown in [Table 2]. The dry evaporation test was carried out by the following method.
【0013】乾式蒸散試験 1個が5gの錠剤タイプの防虫剤2個をアルミ皿に載
せ、これらの5皿について平均重量を測定した。つい
で、それぞれ温度30℃の恒温槽中に放置して所定の日
数毎にその平均減量を求め、下式に基づいて錠剤中のパ
ラジクロルベンゼンの平均含有量に対する蒸散率を算出
した。 蒸散率(%)=各試料の平均減量÷(錠剤2個の重量×
パラジクロルベンゼンの含有率) なお、〔表1〕、〔表2〕おける記号は、以下のとおり
である。 P−DCB;パラジクロルベンゼン TC ;トリクロロホン HPC ;ヒドロキシプロピルセルロース MC ;メチルセルロース 〔以下余白〕 Dry evaporation test Two tablet-type insect repellents each having a weight of 5 g were placed on an aluminum dish, and the average weight of these five dishes was measured. Then, the sample was left in a constant temperature bath at a temperature of 30 ° C., the average weight loss was calculated every predetermined number of days, and the transpiration rate with respect to the average content of paradichlorobenzene in the tablet was calculated based on the following formula. Evaporation rate (%) = average weight loss of each sample / (weight of 2 tablets x
Paradichlorobenzene content) The symbols in [Table 1] and [Table 2] are as follows. P-DCB; paradichlorobenzene TC; trichlorophone HPC; hydroxypropylcellulose MC; methylcellulose [the following margins]
【0014】[0014]
【表1】 [Table 1]
【0015】[0015]
【表2】 [Table 2]
【0016】上記〔表2〕から判るように、各実施例1
〜5の防虫剤は、いずれも比較例の防虫剤に比べて同じ
期間内におけるパラジクロルベンゼンの蒸散率が圧倒的
に少くなっており、配合したセルロース系化合物によっ
て優れた蒸散遅延効果を発揮していることが明らかであ
る。As can be seen from the above [Table 2], each Example 1
Each of the insect repellents Nos. 5 to 5 has an overwhelmingly smaller transpiration rate of paradichlorobenzene in the same period as the insect repellents of Comparative Examples, and exhibits excellent transpiration retarding effect by the blended cellulosic compound. It is clear that
【0017】[0017]
【発明の効果】この発明の防虫剤は、パラジクロルベン
ゼンを主たる防虫成分とし、これにセルロース系化合物
を配合して賦形することによって、パラジクロルベンゼ
ンの蒸散を適宜に遅延させて、長期に亘って防虫効果を
持続させることができるものである。その際、パラジク
ロルベンゼンを主体としてこれに少量の殺虫剤を添加し
て得た防虫成分に、少量のセルロース系化合物を配合し
て賦形することによってパラジクロルベンゼンの蒸散を
遅延させて長期に亘って防虫効果を発揮させることがで
きると共に、殺虫剤の持つ殺虫効果によって虫の発生を
阻止することができるものである。The insect repellent of the present invention comprises paradichlorobenzene as a main insect repellent component, and by adding a cellulosic compound thereto and shaping the mixture, the evaporation of paradichlorobenzene is appropriately delayed to provide long-term protection. The insect repellent effect can be maintained throughout. At that time, paradichlorobenzene is mainly added to the insect repellent obtained by adding a small amount of insecticide to this, and a small amount of a cellulosic compound is added to the pesticide to shape it and delay evaporation of paradichlorobenzene over a long period of time. The insecticidal effect can be exerted throughout, and the insecticidal effect of the insecticide can prevent the generation of insects.
【0018】この発明の防虫剤の製法は、粉末状のパラ
ジクロルベンゼンに、少量の殺虫剤を必要に応じて添加
して、これに粉末状のセルロース系化合物を配合して賦
形物とすることによって、長期に亘る防虫作用と共に適
宜の殺虫効果をもたらすことができるものである。According to the method of producing an insect repellent of the present invention, a small amount of an insecticide is added to powdered paradichlorobenzene, if necessary, and a powdered cellulosic compound is added to form a shaped article. As a result, an appropriate insecticidal effect can be brought together with a long-term insect repellent action.
【0019】この発明の防虫剤の使用方法は、所定の形
状に形成した防虫剤をコンポスト容器の内部に配置する
ことによって、コンポスト容器内を長期に亘って防虫す
ると共に、必要に応じて殺虫し、同時に生ゴミから発生
する悪臭を消滅させることができるので、周囲の環境を
損なうことなく生ゴミを堆肥化することができる。In the method of using the insect repellent of the present invention, the insect repellent formed into a predetermined shape is placed inside the compost container so that the insect repellent can be protected from the inside of the compost container for a long period of time, and the insect repellent can be killed if necessary. At the same time, it is possible to eliminate the foul odor generated from the garbage, so that it is possible to compost the garbage without damaging the surrounding environment.
Claims (7)
に、セルロース系化合物を混合して賦形したことを特徴
とする防虫剤。1. An insect repellent characterized by being formed by mixing a cellulose compound with an insect repellent component consisting of paradichlorobenzene.
ンを主体とする防虫成分に、セルロース系化合物を混合
して賦形したことを特徴とする防虫剤。2. An insect repellent characterized by being formed by mixing a cellulosic compound with an insect repellent component mainly containing paradichlorobenzene containing an insecticidal component.
ロース,エチルセルロース,カルボキシメチルセルロー
ス,ヒドロキシプロピルセルロース,ヒドロキシエチル
セルロース,ヒドロキシプロピルメチルセルロースおよ
びエチルヒドロキシエチルセルロースから選ばれた1種
もしくは2種以上からなることを特徴とする請求項1又
は2記載の防虫剤。3. The cellulosic compound comprises one or more selected from methyl cellulose, ethyl cellulose, carboxymethyl cellulose, hydroxypropyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose and ethyl hydroxyethyl cellulose. Item 1. An insect repellent according to item 1 or 2.
9.5重量%に、セルロース系化合物の粉末5.0〜
0.5重量%を配合し、所定の形状に賦形することを特
徴とする防虫剤の製法。4. Paradichlorobenzene powder 95-9
Cellulose-based compound powder 5.0 to 9.5% by weight
A method for producing an insect repellent, which comprises blending 0.5% by weight and shaping into a predetermined shape.
8.5重量%に、殺虫剤の原体の粉末5〜1重量%を添
加したパラジクロルベンゼンを主体とする防虫成分の粉
末95〜99.5重量%に、セルロース系化合物の粉末
5.0〜0.5重量%を配合し、所定の形状に賦形して
なることを特徴とする防虫剤の製法。5. Paradichlorobenzene powder 90 to 9
Insecticide powder consisting mainly of paradichlorobenzene, in which 8.5 to 1% by weight of powdered insecticide powder is added to 95 to 99.5% by weight, and 5.0 to 5.0% of cellulose compound powder. A method for producing an insect repellent, which comprises blending up to 0.5% by weight and shaping it into a predetermined shape.
9.5重量%に、セルロース系化合物の粉末5.0〜
0.5重量%を添加し、所定の形状に賦形して得た防虫
剤を、コンポスト製造用容器の内部に配置することを特
徴とする防虫剤の使用方法。6. Paradichlorobenzene powder 95-9
Cellulose-based compound powder 5.0 to 9.5% by weight
A method of using an insect repellent, which comprises adding 0.5% by weight and shaping the insect repellent into a predetermined shape inside a container for compost production.
8.5重量%に、殺虫剤の原体の粉末5〜1重量%を添
加したパラジクロルベンゼンを主体とする防虫成分の粉
末95〜99.5重量%に、セルロース系化合物の粉末
5.0〜0.5重量%を配合し、所定の形状に賦形して
得た防虫剤を、コンポスト製造用容器の内部に配置する
ことを特徴とする防虫剤の使用方法。7. Paradichlorobenzene powder 90 to 9
Insecticide powder consisting mainly of paradichlorobenzene, in which 8.5 to 1% by weight of powdered insecticide powder is added to 95 to 99.5% by weight, and 5.0 to 5.0% of cellulose compound powder. A method of using an insect repellent, comprising: mixing 0.5% by weight of the mixture and shaping the insect repellent into a predetermined shape inside a container for compost production.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP02369094A JP3168331B2 (en) | 1994-01-26 | 1994-01-26 | Insect repellents, their production and use |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP02369094A JP3168331B2 (en) | 1994-01-26 | 1994-01-26 | Insect repellents, their production and use |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH07206605A true JPH07206605A (en) | 1995-08-08 |
JP3168331B2 JP3168331B2 (en) | 2001-05-21 |
Family
ID=12117433
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP02369094A Expired - Lifetime JP3168331B2 (en) | 1994-01-26 | 1994-01-26 | Insect repellents, their production and use |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3168331B2 (en) |
-
1994
- 1994-01-26 JP JP02369094A patent/JP3168331B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP3168331B2 (en) | 2001-05-21 |
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