JPH07139819A - Solar absorber - Google Patents
Solar absorberInfo
- Publication number
- JPH07139819A JPH07139819A JP5289133A JP28913393A JPH07139819A JP H07139819 A JPH07139819 A JP H07139819A JP 5289133 A JP5289133 A JP 5289133A JP 28913393 A JP28913393 A JP 28913393A JP H07139819 A JPH07139819 A JP H07139819A
- Authority
- JP
- Japan
- Prior art keywords
- plating layer
- copper
- black chrome
- stainless steel
- thickness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006096 absorbing agent Substances 0.000 title claims abstract description 28
- 238000007747 plating Methods 0.000 claims abstract description 114
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 60
- 229910052802 copper Inorganic materials 0.000 claims abstract description 41
- 239000010949 copper Substances 0.000 claims abstract description 41
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 40
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 29
- 239000010935 stainless steel Substances 0.000 claims abstract description 29
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 19
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 16
- 239000011651 chromium Substances 0.000 claims abstract description 16
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 5
- 230000005855 radiation Effects 0.000 abstract description 3
- 230000001747 exhibiting effect Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229910000365 copper sulfate Inorganic materials 0.000 description 5
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 239000005751 Copper oxide Substances 0.000 description 2
- 241001311547 Patina Species 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 2
- 229910000423 chromium oxide Inorganic materials 0.000 description 2
- 229910000431 copper oxide Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S70/00—Details of absorbing elements
- F24S70/20—Details of absorbing elements characterised by absorbing coatings; characterised by surface treatment for increasing absorption
- F24S70/25—Coatings made of metallic material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S70/00—Details of absorbing elements
- F24S70/20—Details of absorbing elements characterised by absorbing coatings; characterised by surface treatment for increasing absorption
- F24S70/225—Details of absorbing elements characterised by absorbing coatings; characterised by surface treatment for increasing absorption for spectrally selective absorption
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Thermal Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Electroplating Methods And Accessories (AREA)
- Laminated Bodies (AREA)
Abstract
(57)【要約】
【目的】吸収および放射のいずれにおいても優れた特性
を発揮し、且つ耐蝕性にも優れた太陽熱吸収体を提供す
ることを主な目的とする。
【構成】
１．ステンレス鋼板上に厚さ０．０５〜５μｍの銅メッ
キ層およびクロムとして１５〜３０ｍｇ／ｍ2 の黒色ク
ロムめっき層を順次設けた太陽熱吸収体。
２．ステンレス鋼板上にニッケルめっき層、厚さ０．０
５〜５μｍの銅めっき層およびクロムとして１５〜３０
ｍｇ／ｍ2 の黒色クロムめっき層を順次設けた太陽熱吸
収体。(57) [Summary] [Purpose] The main purpose of the present invention is to provide a solar heat absorber exhibiting excellent characteristics in both absorption and radiation and excellent in corrosion resistance. [Configuration] 1. A solar heat absorber in which a copper plating layer having a thickness of 0.05 to 5 μm and a black chromium plating layer having a thickness of 15 to 30 mg / m 2 as chromium are sequentially provided on a stainless steel plate. 2. Nickel plating layer on stainless steel plate, thickness 0.0
5 to 5 μm copper plating layer and 15 to 30 as chromium
A solar heat absorber in which mg / m 2 black chrome plating layers are sequentially provided.
Description
【０００１】[0001]
【産業上の利用分野】本発明は、太陽光を効率良く吸収
して集熱するための太陽熱吸収体に関する。この様な太
陽熱吸収体は、太陽温水器などの集熱部などとして有用
である。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a solar heat absorber for efficiently absorbing and collecting sunlight. Such a solar heat absorber is useful as a heat collecting part of a solar water heater or the like.
【０００２】[0002]
【従来技術とその問題点】太陽熱吸収体（以下単に吸収
体という）は、０．２５〜２．５μｍの波長域で照射さ
れる太陽光線を効率良く吸収するとともに、吸収された
太陽光線により加熱された熱水から約１００℃の温度で
放射される２．５μｍ以上の波長域の赤外線をできるだ
け反射する（換言すれば、この様な赤外線を放射しな
い）という波長選択吸収特性を備えていなければならな
い。より具体的には、実用的な吸収体は、吸収率０．９
０以上且つ放射率０．１３以下という特性を備えている
ことが望ましい。2. Description of the Related Art A solar heat absorber (hereinafter referred to simply as "absorber") efficiently absorbs the sun rays irradiated in the wavelength range of 0.25 to 2.5 μm and heats the sun rays absorbed. Unless it has a wavelength selective absorption characteristic of reflecting as much as possible infrared rays in the wavelength range of 2.5 μm or more emitted from the heated water at a temperature of about 100 ° C. (in other words, not emitting such infrared rays). I won't. More specifically, a practical absorber has an absorption rate of 0.9.
It is desirable to have characteristics of 0 or more and emissivity of 0.13 or less.
【０００３】通常、吸収体は、下地素材と選択吸収膜と
から構成されている。Usually, an absorber is composed of a base material and a selective absorption film.
【０００４】選択吸収膜は、照射された太陽光線を反射
しない特性（太陽光線を選択的に吸収する酸化物半導体
としての特性、サブミクロンの膜厚による光干渉効果、
キャビティー効果およびミー効果と呼ばれる散乱、多重
内部反射を制御する表面の微細形状特性など）を備える
とともに、下地素材自身は、赤外線放射率が低い、即ち
反射率が高いことが必要である。The selective absorption film has a characteristic that it does not reflect the irradiated sun rays (characteristics as an oxide semiconductor that selectively absorbs the sun rays, optical interference effect due to the submicron film thickness,
The base material itself must have a low infrared emissivity, that is, a high reflectivity, in addition to having the scattering and so-called cavity effect and the Mie effect, and the surface topography that controls multiple internal reflection.
【０００５】表１に各種金属材料の常温での放射率の代
表値を示す。Table 1 shows typical emissivity values of various metal materials at room temperature.
【０００６】[0006]
【表１】 [Table 1]
【０００７】選択吸収膜としては、黒色ニッケルめっき
皮膜、黒化したアルマイト皮膜、黒色酸化物皮膜、黒色
塗装膜、黒色クロムめっき皮膜などが実用化されてお
り、これらの中でも、黒色クロムめっき皮膜が耐熱性、
耐蝕性などに優れているので、特に有利であることが知
られている。As the selective absorption film, a black nickel plating film, a blackened alumite film, a black oxide film, a black coating film, a black chrome plating film and the like have been put into practical use. Among these, the black chrome plating film is used. Heat-resistant,
It is known to be particularly advantageous because it has excellent corrosion resistance and the like.
【０００８】一方、下地素材としては、ステンレス鋼板
および銅板が使用されている。On the other hand, stainless steel plates and copper plates are used as the base material.
【０００９】ステンレス鋼は、耐蝕性には優れているの
で、下地素材として有利である。しかしながら、ステン
レス鋼に黒色クロムめっき層を直接形成することは容易
ではないので、通常ニッケルめっき層を形成した後、黒
色クロムめっき層を形成している。この場合、ニッケル
めっきの放射率が０．０７と比較的高いので、ニッケル
めっき層上に黒色クロムめっき層を形成した二重めっき
層の状態で、放射率を０．１２以下の低い値に維持する
ことは、困難である。Stainless steel is excellent in corrosion resistance and is therefore advantageous as a base material. However, since it is not easy to directly form the black chrome plating layer on stainless steel, the black chrome plating layer is usually formed after the nickel plating layer is formed. In this case, since the nickel plating has a relatively high emissivity of 0.07, the emissivity is maintained at a low value of 0.12 or less in the state of the double plating layer in which the black chrome plating layer is formed on the nickel plating layer. It is difficult to do.
【００１０】銅は、実用材料中では最も優れた反射率
（０．０１）を有しているので、下地素材として実用化
もされている。しかしながら、吸収体を温水器の集熱部
として使用する場合には、水道水により銅が腐食して、
緑青水を生じたり、耐用期間が短くなるなどの問題点が
ある。このため、水道水と接触する銅表面にすずめっき
をしておく必要があり、加工費が著しく高くなる。ま
た、銅にニッケルめっき層および黒色クロムめっき層の
二重めっき層を形成する場合には、やはり上記のステン
レス鋼に二重めっき層を形成した場合と同様な問題が生
ずる。Since copper has the highest reflectance (0.01) among practical materials, it has been put to practical use as a base material. However, when the absorber is used as the heat collecting part of the water heater, copper is corroded by tap water,
There are problems such as generation of patina and shortened service life. For this reason, it is necessary to tin-plat the copper surface that comes into contact with tap water, which significantly increases the processing cost. Further, when the double plating layer of the nickel plating layer and the black chrome plating layer is formed on copper, the same problem as in the case of forming the double plating layer on the above stainless steel occurs.
【００１１】特公昭５２−２４２５２号公報は、銅の高
い反射率を使用した太陽熱温水器の熱吸収体を開示して
いる。この熱吸収体は、金属またはプラスチック素材に
ニッケルめっきおよび銅めっきを順次施した後、銅めっ
き表面を化成処理して黒色酸化銅に変化させた構成を備
えている。しかしながら、古くから良く知られている様
に、銅の酸化物については、どの様に材料を選択し、ど
の様に厳密に酸化条件を規定しても、得られる酸化物膜
の組成、酸化速度などが変化して、膜質および膜厚の再
現性に乏しいという実用上の大きな問題がある。また、
銅酸化物の皮膜は、銅素地から簡単に粉末状となって脱
落し、素地自体が傷つき易いという問題もある。Japanese Patent Publication No. 52-24252 discloses a heat absorber for a solar water heater using the high reflectance of copper. This heat absorber has a configuration in which a metal or plastic material is sequentially plated with nickel and copper, and then the surface of the copper plating is subjected to a chemical conversion treatment to change to black copper oxide. However, as is well known for a long time, no matter how the material is selected and how the oxidation conditions are strictly defined, the composition of the oxide film and the oxidation rate of the copper oxide are However, there is a large practical problem that the reproducibility of the film quality and film thickness is poor. Also,
There is also a problem that the copper oxide film easily falls into a powder form from the copper substrate and falls off, and the substrate itself is easily damaged.
【００１２】[0012]
【発明が解決しようとする課題】従って、本発明は、吸
収および放射のいずれにおいても優れた特性を発揮し、
且つ耐蝕性にも優れた太陽熱吸収体を提供することを主
な目的とする。Therefore, the present invention exhibits excellent characteristics in both absorption and radiation,
The main purpose is to provide a solar heat absorber excellent in corrosion resistance.
【００１３】[0013]
【課題を解決するための手段】本発明者は、前記の様な
従来技術の問題点に鑑みて鋭意研究を重ねた結果、ステ
ンレス鋼に特定厚さで特定のめっき層を順次形成する場
合には、上記の目的を達成し得ることを見出した。DISCLOSURE OF THE INVENTION As a result of intensive studies conducted by the present inventor in view of the above-mentioned problems of the prior art, in the case of sequentially forming a specific plating layer with a specific thickness on stainless steel, Have found that they can achieve the above objectives.
【００１４】即ち、本発明は、下記の太陽熱吸収体を提
供するものである；１．ステンレス鋼板上に厚さ０．０
５〜５μｍの銅メッキ層およびクロムとして１５〜３０
ｍｇ／ｍ2 の黒色クロムめっき層を順次設けた太陽熱吸
収体。That is, the present invention provides the following solar heat absorbers: Thickness on stainless steel plate 0.0
5 to 5 μm copper plating layer and 15 to 30 as chromium
A solar heat absorber in which mg / m 2 black chrome plating layers are sequentially provided.
【００１５】２．ステンレス鋼板上にニッケルめっき
層、厚さ０．０５〜５μｍの銅めっき層およびクロムと
して１５〜３０ｍｇ／ｍ2 の黒色クロムめっき層を順次
設けた太陽熱吸収体。2. A solar heat absorber in which a nickel plating layer, a copper plating layer having a thickness of 0.05 to 5 μm, and a black chrome plating layer having a thickness of 15 to 30 mg / m 2 as chromium are sequentially provided on a stainless steel plate.
【００１６】以下においては、上記項１および２の発明
をそれぞれ本願第１発明および本願第２発明といい、両
発明を総括して単に本願発明という。In the following, the inventions of the above-mentioned items 1 and 2 are referred to as the first invention and the second invention of the present application, respectively, and both inventions are collectively referred to as the present invention.
【００１７】本願発明では、水と接触する下地素材とし
て、ステンレス鋼を使用する。ステンレス鋼の使用によ
り、水に対する十分な耐蝕性が確保されるので、緑青水
の発生が防止され、吸収体の耐用期間も著しく延長され
る。In the present invention, stainless steel is used as the base material that comes into contact with water. Since the use of stainless steel ensures sufficient corrosion resistance to water, generation of patina is prevented and the service life of the absorber is significantly extended.
【００１８】本願第１発明においては、下地素材として
のステンレス鋼の上に厚さ０．０５〜５μｍ程度の銅め
っき層を形成する。この銅めっき層の形成により、２．
５μｍ以上の長波長域での赤外線の低放射率が確保され
る。また、中間層としての銅めっき層の存在は、下記に
説明する黒色クロムめっき層の形成を容易にする。銅め
っき層の厚さが０．０５μｍ未満である場合には、放射
率の高いステンレス鋼（ε＝０．１３）の影響が現われ
て、所望の低い放射率（ε≦０．１２）が確保できな
い。銅めっき層の厚さは、生産性の点から５μｍ程度が
上限である。銅めっき層は、２．５μｍ以上の長波長域
での赤外線を反射し得る程度の平滑性を備えていること
が好ましい。In the first invention of the present application, a copper plating layer having a thickness of about 0.05 to 5 μm is formed on stainless steel as a base material. By the formation of this copper plating layer, 2.
A low infrared emissivity in a long wavelength region of 5 μm or more is secured. Further, the presence of the copper plating layer as the intermediate layer facilitates the formation of the black chrome plating layer described below. If the thickness of the copper plating layer is less than 0.05 μm, the effect of stainless steel with high emissivity (ε = 0.13) appears, and the desired low emissivity (ε ≦ 0.12) is secured. Can not. From the viewpoint of productivity, the upper limit of the thickness of the copper plating layer is about 5 μm. The copper plating layer preferably has smoothness enough to reflect infrared rays in a long wavelength region of 2.5 μm or more.
【００１９】本願第１発明においては、銅めっき層の上
にクロムに換算して厚さ１５〜３０ｍｇ／ｍ2 程度（よ
り好ましくは２０〜２５ｍｇ／ｍ2 程度）の黒色クロム
めっき層を形成する。なお、黒色クロムめっき皮膜は、
薄い非化学量論組成のクロム酸化物からなっており、微
細な燐片状を呈しているので、厚さを直接測定すること
は困難である。従って、本発明においては、銅めっきし
たステンレス鋼板に所定の条件で黒色クロムめっきを形
成した後、濃塩酸で黒色クロムめっきを溶解し、原子吸
光分析法によりクロム量を求め、単位面積当たりのクロ
ム量を黒色クロムめっき層の厚さに代わる指標とした。
この黒色クロムめっき層の形成により、０．２５〜２．
５μｍの波長域の太陽光線を０．９０以上という高い吸
収率で吸収することができる。黒色クロムめっき層が薄
すぎる場合には、吸収率が低下するのに対し、厚すぎる
場合には、吸収率は高くなるものの、銅めっき層の特徴
である低い放射特性が次第に失われて、放射率が高くな
る。[0019] In the first invention, in terms of chromium on the copper plated layer thickness 15-30 mg / m 2 about (more preferably about 20-25 mg / m 2) to form a black chrome plating layer . The black chrome plating film is
Since it consists of thin non-stoichiometric chromium oxide and has fine scaly shape, it is difficult to directly measure the thickness. Therefore, in the present invention, after forming a black chrome plating under predetermined conditions on a copper-plated stainless steel plate, dissolve the black chrome plating with concentrated hydrochloric acid, determine the amount of chromium by atomic absorption spectrometry, chromium per unit area The amount was used as an index instead of the thickness of the black chrome plating layer.
Due to the formation of this black chrome plating layer, 0.25-2.
It is possible to absorb sunlight in the wavelength range of 5 μm with a high absorptance of 0.90 or more. If the black chrome plating layer is too thin, the absorptivity will decrease, whereas if it is too thick, the absorptivity will be high, but the low radiation characteristics characteristic of the copper plating layer will gradually be lost, and The rate is high.
【００２０】本願第２発明における下地素材としてのス
テンレス鋼および銅めっき層は、本願第１発明と同様で
ある。The stainless steel and the copper plating layer as the base material in the second invention of the present application are the same as in the first invention of the present application.
【００２１】本願第２発明においては、ニッケルめっき
層の上に銅めっき層を形成する。このニッケルめっき層
の形成により、銅めっき層と下地素材であるステンレス
鋼との密着性が向上し、ひいては最上層となる黒色クロ
ムめっき層の密着性乃至耐久性も改善される。このニッ
ケルめっき層は、銅めっき層を覆っていれば良く、特に
限定されないが、通常０．１〜１μｍ程度で十分であ
る。In the second invention of the present application, the copper plating layer is formed on the nickel plating layer. By forming this nickel plating layer, the adhesion between the copper plating layer and the stainless steel as the base material is improved, and thus the adhesion or durability of the uppermost black chrome plating layer is also improved. The nickel plating layer is not particularly limited as long as it covers the copper plating layer, but usually about 0.1 to 1 μm is sufficient.
【００２２】本願第２発明における黒色クロムめっき層
は、本願第１発明におけると同様であれば良い。The black chrome plating layer in the second invention of the present application may be the same as in the first invention of the present application.
【００２３】本願発明による吸収体の製造方法（浴組
成、めっき条件など）は、下地素材であるステンレス鋼
に所定のめっき層を形成し得る限り、特に限定されるも
のではない。The method of manufacturing the absorber according to the present invention (bath composition, plating conditions, etc.) is not particularly limited as long as a predetermined plated layer can be formed on the stainless steel as the base material.
【００２４】例えば、本願第１発明の吸収体は、下地素
材としてのステンレス鋼を電解脱脂し、塩酸により活性
化処理した後、硫酸銅浴を使用して銅めっき層を形成
し、次いで黒色クロムめっき浴を使用して黒色クロムめ
っき層を形成すれば良い。For example, in the absorber of the first invention of the present application, stainless steel as a base material is electrolytically degreased, activated with hydrochloric acid, and then a copper plating layer is formed using a copper sulfate bath, and then black chrome is used. The black chrome plating layer may be formed using a plating bath.
【００２５】また、本願第２発明の吸収体は、下地素材
としてのステンレス鋼を電解脱脂し、塩酸により活性化
処理した後、ストライクニッケルめっき浴を使用してニ
ッケルめっき層を形成し、硫酸銅浴を使用して銅めっき
層を形成し、次いで黒色クロムめっき浴を使用して黒色
クロムめっき層を形成すれば良い。In the absorber of the second invention of the present application, stainless steel as a base material is electrolytically degreased and activated by hydrochloric acid, and then a nickel plating layer is formed by using a strike nickel plating bath. A bath may be used to form the copper plating layer, and then a black chrome plating bath may be used to form the black chrome plating layer.
【００２６】表２に硫酸銅浴の組成およびめっき条件の
代表的な例を示し、表３にストライクニッケルめっき浴
の組成およびめっき条件の代表的な例を示し、表４に黒
色クロムめっき浴の組成およびめっき条件の代表的な例
を示す。本願発明吸収体に所定のめっき層を形成するこ
とができる限り、めっき浴およびめっき条件がこれらに
限定されないことは、いうまでもない。Table 2 shows a typical example of the composition and plating conditions of the copper sulfate bath, Table 3 shows a typical example of the composition and plating conditions of the strike nickel plating bath, and Table 4 shows that of the black chrome plating bath. Representative examples of composition and plating conditions are shown. It goes without saying that the plating bath and the plating conditions are not limited to these as long as a predetermined plating layer can be formed on the absorber of the present invention.
【００２７】[0027]
【表２】 [Table 2]
【００２８】[0028]
【表３】 [Table 3]
【００２９】[0029]
【表４】 [Table 4]
【００３０】[0030]
【発明の効果】本発明によれば、耐久性に優れるととも
に、高い吸収率および低い放射率を発揮する太陽熱吸収
体が得られる。EFFECTS OF THE INVENTION According to the present invention, a solar heat absorber having excellent durability and exhibiting high absorptivity and low emissivity can be obtained.
【００３１】[0031]
【実施例】以下に実施例および比較例を示し、本発明の
特徴とするところをより一層明確にする。EXAMPLES Examples and comparative examples will be shown below to further clarify the features of the present invention.
【００３２】実施例１ ステンレス鋼（ＳＵＳ３０４材、６ｍｍ×１０ｍｍ×
０．５ｍｍ）を電解脱脂し、２０％塩酸に室温で３０秒
間浸漬して活性化処理した後、光沢硫酸銅めっき浴を使
用して銅めっき層を形成し、次いで黒色クロムめっき浴
を使用して黒色クロムめっき層を形成した。Example 1 Stainless steel (SUS304 material, 6 mm × 10 mm ×
0.5 mm) is electrolytically degreased, immersed in 20% hydrochloric acid for 30 seconds at room temperature for activation, and then a copper plating layer is formed using a bright copper sulfate plating bath, and then a black chrome plating bath is used. To form a black chrome plating layer.
【００３３】硫酸銅めっき浴の組成およびめっき条件を
表５に示し、黒色クロムめっき浴の組成およびめっき条
件を表６に示す。Table 5 shows the composition and plating conditions of the copper sulfate plating bath, and Table 6 shows the composition and plating conditions of the black chromium plating bath.
【００３４】[0034]
【表５】 [Table 5]
【００３５】[0035]
【表６】 [Table 6]
【００３６】表７に銅めっき層および黒色クロムめっき
層の厚さと吸収率および放射率との関係を示す。なお、
吸収率は（株）島津製作所製の積分反射球付き分光光度
計（ＵＶ３１００）により波長範囲０。２５〜２．５μ
ｍで測定し、放射率はＤ＆Ｓ社製の放射率計により測定
した。Table 7 shows the relationship between the thickness of the copper plating layer and the black chrome plating layer and the absorptance and emissivity. In addition,
The absorptance was measured with a spectrophotometer (UV3100) with an integrating reflection sphere manufactured by Shimadzu Corporation in the wavelength range of 0.25 to 2.5 μ.
The emissivity was measured by an emissivity meter manufactured by D & S.
【００３７】[0037]
【表７】 [Table 7]
【００３８】なお、先述の様に、黒色クロムめっき皮膜
は、薄い非化学量論組成のクロム酸化物からなってお
り、微細な燐片状を呈しているので、厚さを直接測定す
ることは困難である。従って、銅めっきしたステンレス
鋼板に所定の条件で黒色クロムめっきを形成した後、濃
塩酸で黒色クロムめっきを溶解し、原子吸光分析法によ
りクロム量を求め、単位面積当たりのクロム量で厚さを
表わした。クロム量と電解時間とはほぼ比例しているの
で、黒色クロムめっき皮膜の厚さと電解時間もほぼ比例
関係にあることが明らかである。As described above, the black chrome plating film is composed of a thin non-stoichiometric chromium oxide and has a fine scaly shape. Therefore, the thickness cannot be directly measured. Have difficulty. Therefore, after forming a black chrome plating on a copper-plated stainless steel plate under predetermined conditions, dissolve the black chrome plating with concentrated hydrochloric acid, determine the amount of chromium by atomic absorption spectrometry, and determine the thickness by the amount of chromium per unit area. Represented. Since the amount of chromium and the electrolysis time are almost proportional to each other, it is clear that the thickness of the black chrome plating film and the electrolysis time are also substantially proportional to each other.
【００３９】実施例２ 実施例１と同様にしてステンレス鋼の電解脱脂および活
性化処理を行なった後、ストライクニッケルめっき浴を
使用してニッケルめっき層を形成し、光沢硫酸銅めっき
浴を使用して銅めっき層を形成し、次いで黒色クロムめ
っき浴を使用して黒色クロムめっき層を形成した。Example 2 After electrolytically degreasing and activating stainless steel in the same manner as in Example 1, a strike nickel plating bath was used to form a nickel plating layer, and a bright copper sulfate plating bath was used. To form a copper plating layer, and then a black chrome plating bath was used to form a black chrome plating layer.
【００４０】銅めっき浴は、実施例１と同じ組成のもの
を使用して、めっき時間を変化させて銅めっきの厚さを
調整した。なお、銅めっき時間と銅めっき厚さとは、ほ
ぼ比例していた。The copper plating bath having the same composition as in Example 1 was used, and the thickness of the copper plating was adjusted by changing the plating time. The copper plating time and the copper plating thickness were almost proportional.
【００４１】また、黒色クロムめっきは、実施例１と同
じ組成のものを使用して、同じ条件でめっきを行なっ
て、形成させた。The black chrome plating was formed by using the same composition as in Example 1 and plating under the same conditions.
【００４２】表８にストライクニッケルめっき浴の組成
およびめっき条件を示し、表９に銅めっき層の厚さおよ
び黒色クロムめっき層の厚さと吸収率および放射率との
関係を示す。Table 8 shows the composition of the strike nickel plating bath and plating conditions, and Table 9 shows the relationship between the thickness of the copper plating layer and the thickness of the black chrome plating layer and the absorptivity and emissivity.
【００４３】[0043]
【表８】 [Table 8]
【００４４】[0044]
【表９】 [Table 9]
【００４５】表９に示す結果から、銅めっきの厚さを
０．０６４μｍ以上とすることにより、吸収率が高く且
つ放射率の低い吸収体が得られることが明らかである。From the results shown in Table 9, it is clear that by setting the thickness of the copper plating to 0.064 μm or more, an absorber having a high absorptivity and a low emissivity can be obtained.
【００４６】比較例１ ステンレス鋼に直接黒色クロムめっき層を形成した。即
ち、ステンレス鋼を実施例１と同様にして電解脱脂した
後、室温の２０％塩酸中で５Ａ／ｄｍ2 、１０秒間の条
件で陰極電解を行ない、次いで実施例１とほぼ同様にし
て所定時間黒色クロムめっきを行なった。Comparative Example 1 A black chrome plating layer was directly formed on stainless steel. That is, after stainless steel was electrolytically degreased in the same manner as in Example 1, cathodic electrolysis was performed in 20% hydrochloric acid at room temperature under the conditions of 5 A / dm 2 and 10 seconds, and then, similarly to Example 1, for a predetermined time. Black chrome plating was performed.
【００４７】表１０に結果を示す。なお、本比較例で
は、実施例１と同様にして黒色クロムめっき層の溶解を
はかる場合には、ステンレス鋼からのクロム溶解が起こ
って、黒色クロムめっき層に由来するクロム含有量を正
確に測定することができなかったので、黒色クロムめっ
き時間と吸収率および放射率との関係を示してある。Table 10 shows the results. In this comparative example, when the black chrome plating layer is dissolved in the same manner as in Example 1, chromium dissolution from the stainless steel occurs and the chromium content derived from the black chrome plating layer is accurately measured. Therefore, the relationship between the black chrome plating time and the absorptance and emissivity is shown.
【００４８】[0048]
【表１０】 [Table 10]
【００４９】表１０に示す結果から、ステンレス鋼上に
銅めっき層を形成しない場合には、放射率がかなり高く
なるので、吸収体として実用的でないことが明らかであ
る。 比較例２ 銅めっき層を形成しない以外は実施例２とほぼ同様にし
てステンレス鋼上に順次ニッケルめっき層および黒色ク
ロムめっき層を形成した。From the results shown in Table 10, it is clear that when the copper plating layer is not formed on the stainless steel, the emissivity is considerably high, and therefore it is not practical as an absorber. Comparative Example 2 A nickel plating layer and a black chrome plating layer were sequentially formed on stainless steel in the same manner as in Example 2 except that the copper plating layer was not formed.
【００５０】表１１に黒色クロムめっき層の厚さと吸収
率および放射率との関係を示す。Table 11 shows the relationship between the thickness of the black chrome plating layer and the absorptance and emissivity.
【００５１】[0051]
【表１１】 [Table 11]
【００５２】表１１に示す結果から、銅めっき層を形成
しない場合には、放射率がかなり高くなり、やはり吸収
体として実用的でないことが明らかである。From the results shown in Table 11, it is clear that when the copper plating layer is not formed, the emissivity is considerably high, which is also not practical as an absorber.
フロントページの続き (72)発明者 森河 務 奈良県香芝市上中1183−１−９−304Continued Front Page (72) Inventor Tsutomu Morikawa 1183-1-9-304 Kaminaka, Kashiba City, Nara Prefecture
Claims (2)
の銅メッキ層およびクロムとして１５〜３０ｍｇ／ｍ2
の黒色クロムめっき層を順次設けた太陽熱吸収体。1. A thickness of 0.05 to 5 μm on a stainless steel plate.
15 to 30 mg / m 2 as the copper plating layer and chromium
A solar heat absorber in which the black chrome plated layers of are sequentially provided.
さ０．０５〜５μｍの銅めっき層およびクロムとして１
５〜３０ｍｇ／ｍ2 の黒色クロムめっき層を順次設けた
太陽熱吸収体。2. A nickel plating layer, a copper plating layer having a thickness of 0.05 to 5 μm, and chromium as 1 on a stainless steel plate.
A solar heat absorber in which a black chrome plating layer of 5 to 30 mg / m 2 is sequentially provided.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28913393A JP3194064B2 (en) | 1993-11-18 | 1993-11-18 | Solar heat absorber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28913393A JP3194064B2 (en) | 1993-11-18 | 1993-11-18 | Solar heat absorber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07139819A true JPH07139819A (en) | 1995-06-02 |
| JP3194064B2 JP3194064B2 (en) | 2001-07-30 |
Family
ID=17739189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP28913393A Expired - Fee Related JP3194064B2 (en) | 1993-11-18 | 1993-11-18 | Solar heat absorber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3194064B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010121181A (en) * | 2008-11-20 | 2010-06-03 | Jfe Steel Corp | Steel plate for hot press working |
| CN102102918A (en) * | 2011-02-16 | 2011-06-22 | 北京天瑞星真空技术开发有限公司 | Cr series high-temperature solar selective absorbing coating and preparation method thereof |
| JP2011145053A (en) * | 2010-01-15 | 2011-07-28 | Dalian Sievert Testing Equipment Co Ltd | Heat collecting module of metal-glass set heat collecting pipe and connection method |
| JP2018083072A (en) * | 2016-11-16 | 2018-05-31 | 大日本印刷株式会社 | Bactericide gasifier |
| US10018377B2 (en) | 2009-03-06 | 2018-07-10 | University Of The Ryukyus | Solar light (heat) absorption material and heat absorption/accumulation material and solar light (heat) absorption/control building component using the same |
| CN115198322A (en) * | 2022-06-28 | 2022-10-18 | 山西柴油机工业有限责任公司 | Stainless steel copper plating process |
-
1993
- 1993-11-18 JP JP28913393A patent/JP3194064B2/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010121181A (en) * | 2008-11-20 | 2010-06-03 | Jfe Steel Corp | Steel plate for hot press working |
| US10018377B2 (en) | 2009-03-06 | 2018-07-10 | University Of The Ryukyus | Solar light (heat) absorption material and heat absorption/accumulation material and solar light (heat) absorption/control building component using the same |
| JP2011145053A (en) * | 2010-01-15 | 2011-07-28 | Dalian Sievert Testing Equipment Co Ltd | Heat collecting module of metal-glass set heat collecting pipe and connection method |
| CN102102918A (en) * | 2011-02-16 | 2011-06-22 | 北京天瑞星真空技术开发有限公司 | Cr series high-temperature solar selective absorbing coating and preparation method thereof |
| JP2018083072A (en) * | 2016-11-16 | 2018-05-31 | 大日本印刷株式会社 | Bactericide gasifier |
| CN115198322A (en) * | 2022-06-28 | 2022-10-18 | 山西柴油机工业有限责任公司 | Stainless steel copper plating process |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3194064B2 (en) | 2001-07-30 |
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