JPH07100178A - Bathing agent containing natural calcium carbonate - Google Patents

Abstract

PURPOSE:To obtain a bathing agent containing natural calcium carbonate, which accelerates ion exchange of physico-chemical quality more than several times and alkalifies city water leaning to acidic side to stabilize the water in a state of alkali side by using a small amount thereof, and which is god for skin health and does not clog a sewage channel when discharged and purifies the water of rivers and seas. CONSTITUTION:The main component of this bathing agent is natural calcium carbonate consisting powdery fossil shells smaller than 10 micron, which are produced by processing fossil shells produced in Toyama mine, the mine of Nihonkai Kogyo Mining and Kokudo Takaoka mine in Takaoka City, Toyama Prefecture in the temperature of 200-300 deg.C to vaporize moisture contained in the fossil shells.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION The present invention relates to tap water used for bathing, which is sterilized with chlorine, causes a chemical reaction and is inclined to be acidic, and has residual chlorine in water. It is a bathing agent that removes water, protects the health of human skin, and activates subcutaneous cells.It is flushed into the sewage after use, and the Toyama mine is located in Takaoka City, Toyama Prefecture, which enhances the effect of purifying the sewer, rivers, and sea. The present invention relates to a bath agent composed of a fossil shell powder having a particle size of 10 microns or less by evaporating the water content of the shell fossil by heat-treating the shell fossil produced from a mine of the Japan Sea Mining Industry and the Takaoka Mine of Kokuchi Dome within 200 to 300 ° C.

[0002]

2. Description of the Related Art Conventionally, shellfish fossils have been used for soil improvement, water quality improvement, feed, fertilizer, deodorization, etc.
Make a powder of 0 micron or less, add a small amount to tap water used for bathing, cause chemical reaction by chlorine sterilization, transfer water inclined to acidity to weak alkaline, remove residual chlorine in water,
With the aim of protecting the health of human skin and activating subcutaneous cells, there was no use as a bath agent that was used and then poured into sewage to enhance the purification effect of sewer, river, and sea.

[0003]

The conventional fossil shell powder for improving water quality has a minimum size of about 70 μm, and the powder is coarse for use as a bathing agent, so it takes time to exert its effect. However, it was not possible to use it as a bathing agent because it required a large amount, it had a bad feel to the skin during bathing, it rapidly precipitated in water, and there was a risk of clogging the sewer after use.

[0004]

The present invention relates to shellfish fossils produced from the Toyama mine in Takaoka city, Toyama prefecture, the Japan Sea mining mine, and the Takaoka mine on the national land by thermal processing within 200 ° C to 300 ° C. It consists of shell fossil powder processed by evaporating water from fossil into ultrafine powder of 10 microns or less. It increases the surface area of porous particles and enhances physicochemical adsorption, and the main component calcium carbonate in water. From accelerating dissolution in
A small amount (20 grams per 2 cubic meters) of acidic tap water with a pH of 7.0-7.4 is weakly alkaline.
Stabilized to 7.6 to 7.8, it doesn't bother the skin to the touch during bathing, and even if it sediments in the sewer, it easily flows and there is no risk of clogging.

[0005]

According to the present invention, the shell fossil powder is powdered by the above-mentioned method, so that the physicochemical ion-exchange property and the adsorptive power of the conventional powder are increased by several times or more. Stabilize tap water leaning toward weak alkaline. Since tap water used for bathing is sterilized with chlorine, it causes a chemical reaction and becomes slightly acidic, and there is residual chlorine in the water, which is not very good for skin health. The present invention, calcium carbonate which is the main component of fossil shells turns into calcium ions in water, shifts the water quality to weak alkaline, reacts with residual chlorine to remove residual chlorine, and there are many types of shell fossils other than calcium carbonate. Contains well-balanced components that are useful to humans.They gradually elute in water, albeit in trace amounts, and change to a weakly basic water quality that contains many ions useful for skin health along with calcium ions, activating subcutaneous cells. To act.

[0006]

EXAMPLES In this specification, shell fossils are foraminiferal fossils by the archeological name and calcareous sandstones by the geological name, and are samples mined at Iwatsubo A, B, C mining sites in the Toyama Mine, Takaoka City, Toyama Prefecture. , August 7, 1979, the following quantitative analysis table 1 which had an analysis report (54 people Tsushin Kogyo No. 564) from the Nagoya Trade and Industry Bureau and the samples mined at the Takaoka Mine, Takaoka City, Toyama Prefecture. October 20, 1977 Analysis report from the Bureau of International Trade and Industry, Nagoya (52 people
No. 71), the quantitative analysis according to Table 2 below. In addition, the mine of the Japan Sea Mining Industry in Takaoka City, Toyama Prefecture is located between the Toyama mine and the Takaoka mine on the national land.

[0007]

[Table 1]

[0008]

[Table 2]

The shell fossils mined in Takaoka City, Toyama Prefecture are characterized by a large difference in composition and molecular assembly form from shell fossils mined in other regions of Japan, and in particular, a high proportion of calcium carbonate. Further, the shell fossil of the present invention is a burial of various types of nectons such as calcareous and silicic acid, plankton, algae, seagrass, etc. due to the change of the crust, burial and accumulation, and about 8,000 years have passed. , It was found that these seafood and organic matter were not fossilized but turned into waste, touch-soluble crystals. From these causes, the main component, calcium carbonate, is an aggregate of extremely fine particles secreted and formed by proteins, and in the form of aragonite and calcite, it is formed by calcite alone. The fact that they are more active than those present is a major characteristic of shell fossils mined in Takaoka City, Toyama Prefecture. Therefore, it is designated as a national resource because it is different from other similar shell fossils.

The above shellfish fossil has already been used as a water quality improver, fertilizer,
It has been put to practical use as a soil conditioner and feed for livestock. This is because the active adsorption, odor absorption, water absorption and at the same time ion exchange and physicochemical action of the extremely fine porous aragonite and calcite are promoted in parallel with the components of this fossil shell. Further, since the pH is 8.6 to 10.0, it has an effect function of stabilizing them in a weak alkali by mixing them in acidic soil and acidic water quality.

[0011]

EFFECTS OF THE INVENTION According to the present invention, physicochemical adsorption force, water absorption and ion exchange action are concurrently performed by the above-mentioned constitution, and tap water that has been inclined to be acidic due to chlorine sterilization is stabilized to be a weak alkali. The residual chlorine contained is adsorbed and the residual chlorine is efficiently removed by a chemical reaction.

[0012]

[PH control action effect] Generally, tap water is subjected to chlorine sterilization in accordance with the regulations, so that it shifts to a weak acid side as shown in the following formula. H ₂ O + Cl ₂ → HCl + HCl 0
Hydrochloric acid generated at this time is a strong acidic substance, but it has no bactericidal action. It is hypochlorous acid that has a bactericidal action. It decomposes and kills viable bacteria by the following formula. It is believed that. HCl0 → HCl + 0 ↑ Oxygen from this generator oxidizes live bacteria and acts as a bactericidal action, but in both formulas, a strong acid called chlorine is generated and tap water or sewage is acidified, which is not desirable for human health. For the health of this person, by adding the fossil shell powder of the present invention to tap water, the acid called hydrochloric acid is neutralized as shown in the following formula, and at the same time it is transferred to the alkaline side, which is useful for health as calcium ion. Transformed into tap water containing a lot of ions. Ca
CO ₃ + 2HCl → Ca ²⁺ + 2Cl ⁻ + CO ₂ ↑ + H ₂
O

Ca ²⁺ (calcium ion) contained in the tap water penetrates the skin of a person who bathes, stimulates subcutaneous cells (intracellular Ca ²⁺ ) and produces a physiologically active effect. In addition, a small amount of the components contained in the fossil shellfish of the present invention is eluted in tap water, and these ions also bring a beneficial effect to the living body.

As one of the effects, among the monitors using the bath salt of the present invention, there were reports of 5 symptoms of athlete's foot that suffered for many years. The fact that the symptoms disappeared after 1 week to 10 days of use was reported. There was found. This effect is considered to be an antibacterial effect due to the action of calcium dissolved in the bath water and other trace components.

In addition, since the tap water (hot water) in the bathtub becomes a weak alkali, there is an effect of preventing rust due to the oxidation of the metals attached to the bathtub. Usually, when 4 to 5 people bathe, the hot water in the bathtub becomes odorous, but even if 10 people bathe, the hot water in the bathtub is odorless, and even if the hot water in the bathtub is left as it is for several days, it is odorless. That is, it has the effect of adsorbing and decomposing the odor caused by body fluid, dirt, etc. secreted from the skin of a person taking a bath. In addition, draining after bathing has a beneficial effect as an auxiliary effect for purification of sewers, rivers, and seas by decomposing phosphorus and nitrogen contained in domestic wastewater that precipitates in sewers and sewers by physical chemical adsorption. Give birth.

[0016]

[Experimental Example 1] [Bathing method using the bathing agent of the present invention] When the hot water to be bathed has reached an appropriate temperature (around 42 ° C), a small amount of the bathing agent of the present invention is put in a small amount of hot water (20 g) and placed on the bottom of the bath Precipitation (specific gravity 1.
7) Lightly stir the resulting powder with a hand or a vat, and mix well in the whole hot water in 10 seconds, and then take a bath. Bathing with hot water → Bathing (5 minutes) → Washing body → Bathing (5 minutes) → Do not use rising water (tap water) (Note) Hot water in the bathtub will decrease when several people bathe, and tap water will be added However, the addition of the bathing agent of the present invention is unnecessary. However, if the hot water in the bathtub is reduced to less than half and you want to add it, add half (10 g) to a small spoon and stir gently to mix it with the hot water.

[Bathing Monitor Configuration Using Bath Agent of the Present Invention] (1) "Children's Swimming Club Coach" suffering from rough skin
Housewives in their thirties: 3 (2) “Salarymen” who have been suffering from athlete's foot for over 10 years 4
Males in their 0s: 3 people (3) “Construction workers who have been suffering from athlete's foot for over 10 years”
Men in their 40s: 2 people (4) "Keeping a tailor" 5 with fatigue from the knees and eczema
Men and women in their 0's ... 2 people

[Report of monitor after 10 months of use by 10 persons] (1) Housewives in their thirties: 3 persons / weekly twice / once = 3 hours or more because of entering a strong chlorine sterilized pool Commonly, the skin of the whole body was bulky, but even when scratching the skin with nails by using the bath agent of the present invention, white line marks have been made until now, but it disappears I no longer feel the rough weather. (From half a month after the start of use) (2) (3) Males in their 40s 5/5 have been common for many years and have blisters between the soles and fingers of the feet, itching, crushing the bubbles and becoming white. Every day, the skin was stripped off, but by using the bath preparation of the present invention, the symptoms of athlete's foot disappeared in a person for 1 week and after 10 days at the latest. In addition, more than one person reported that his son's itching due to atopy disappeared and he did not have to go to the hospital recently. (4) Two men and women in their 50s / more than 8 hours a day in common every day,
Since I sit down and work at home, the instep of the instep and the front part of the skin below the knees cause itching due to eczema caused by pressure on the body, sweat, etc. However, by using the bath salt of the present invention, the symptoms disappeared in the two patients after about half a month.

[Common report by monitors by the above 10 persons] (a) Even if all the family members who lived together took a bath, there was no bad smell of the remaining hot water in the bathtub the next day. (B) The stench that came from the sewer was gone after the remaining hot water had run off. (C) After bathing, the skin feels smooth and comfortable. (D) After taking a bath, my sweat feels different than before.

[Other reports by monitors of 10 persons] (e) On the second day after use, when the hot water in the bathtub was drained to the sewer, a lot of stains on the bathtub came out of the bathtub. After that, there was no such thing. (Reported by 2 people) (F) The inside of the bathtub was cleaned. (Reported by 6 people) (g) My wife disliked me at first, but after seeing a child (3 years old) happily bathing for some reason, I started bathing, and now my wife takes the initiative. Because the skin is smooth. (Reported by 1 person) (h) At first, my wife hated, but now my wife takes the initiative. (Reported by 3 people) (i) The symptoms of athlete's foot of the husband disappeared. (Reported by 1 person) (Nu) I feel that my muscles can be relieved. (Reported by 6 people) (L) I feel that the cosmetic paste is good. (Report from 3 people) + (2 wives of the monitor) The people who became the monitors of this test are the people who live in Nishikasai, Edogawa-ku, Tokyo, where Minoru Sano, one of the inventors of the present invention, lives. In addition, prior to use, the physical properties of this bath agent are explained, and it is a known fact that they are not toxic substances, but they are strictly cautioned not to increase the amount used due to the high pH, and those who have obtained sufficient understanding and consent.

[0021]

[Experimental Example 2] [Bathing method using a bathing agent of the present invention as a monitor] Experimental Example 1
The bathing method was the same, but the amount of the bathing agent of the present invention was set to one large spoonful (30 g).

[Bathing Monitor Configuration with Bath Agent of the Present Invention] (1) Long-standing shoulder stiffness ... 73 year old female (2) Intercostal neuralgia "Company president" worries about pain: 65-year-old man (3) Knee joint has been hurt since 3 years ago and he cannot sit down ... 63-year-old housewife (4) When I get tired, I cannot sleep because of muscle pain in my legs .... 59 years old woman (5) My first finger joint of my hand hurts in the early stages of rheumatism .... 46 years old. Housewife (6) I can't sleep well due to cold limbs even in the summer ... 43-year-old woman (7) I suffer from itching of atopic dermatitis ...・ ・ 60-year-old housewife (8) "OL" worried about wheal rash around the tail ... ・ 23-year-old woman (9) "Single office worker" worried about strong body odor 28-year-old man (10) "OL" who had a hard time suffering from axillary odors ... 27-year-old woman (11) suffered from athlete's foot on the nails with blackened toenails ······························································································································································

[Report of Monitors After Use by 12 People] (1) 73-year-old woman / Massage attendance was a daily routine due to stiff shoulders for many years, but shoulders started from half a month after using the bath salt of the present invention. The stiffness is removed naturally and I do not go to massage. (2) A 65-year-old male / man who suffered from intercostal neuralgia pain for many years, but using the bath preparation of the present invention, the pain was halved from 1 week later, and the pain recovered from 3 weeks later to the occasional pain level, and sometimes thereafter. Has become longer. (3) 63-year-old housewife / I couldn't sit in a sitting position because I had a pain in my knee joint from 3 years ago, but I couldn't sit in the "tea room". I was in a state. (4) 59-year-old woman / When tired, she was unable to sleep due to muscle pain in her legs, and became able to sleep well after one week using the bath agent of the present invention. (5) 46-year-old housewife / In the early stages of rheumatism, the bones of the first finger joint of the hand were swollen, and the part became red and painful and hard to work at all. The pain has been relieved for about half a month. (6) 43-year-old woman / I was worried that I could not get a good night's sleep due to the cold limbs even in the summer, but I was able to get a good night's sleep from the 3rd week using the bath salt of the present invention. It was (7) 60-year-old housewife / I was diagnosed with atopic dermatitis and used a steroid ointment to eliminate itching.
After hearing about the side effects, we stopped applying and switched to the bath salt of the present invention, and it was about 4 months, but itching also relieved,
The skin gradually returned to normal and became beautiful. (It has been reported that daily bathing time takes 1 hour and 30 minutes.) (8) A 23-year-old woman / I was worried about the rash of wheal that regularly forms around Hatoo. Said the wheal had disappeared. (9) Male, 28 years old / A strong body odor disappeared from the third time by using the bathing agent of the present invention, and it became possible to perform business work in a refreshing mood. (10) 27-year-old woman / I had a hard time dealing with anxiety due to the axillary odor, but I was free from the anxiety of axillary odor from the first week after using the bathing agent of the present invention, and my body's skin became smooth and mental. It was also stable. (11) 58-year-old housewife / A toenail had been diagnosed by a doctor for about two and a half years, because he was worried about darkening, and the nail was not a bone but a change in the stratum corneum of the skin. I was diagnosed and received an applied drug, but it was not gradual, and when I tried to try the bath agent of the present invention, the black toenail became a normal healthy color from about one and a half months. (12) 51-year-old man / profession, I have been worried about athlete's foot for many years because I wear rubber boots every day, but by using the bathing agent of the present invention, the symptoms of athlete's foot disappeared in about one month, and at the same time the eyes of fish also disappeared. I got it.

The people who became the monitors of this test were those who were selected from among those who lived in Takaoka City, Toyama Prefecture, where Sadako Ueda, one of the inventors of the present invention, lived, and acquaintances in work across the country. is there. In addition, prior to use, the physical properties of this bath agent are explained, and as a known fact, it is not a toxic substance, but due to its high pH, be careful not to increase the amount used,
Those who have a sufficient understanding.

As a result of X-ray diffraction, it was found by the laboratory of a university hospital that the bathing agent of the present invention had no reaction of harmful substances to humans, and it was reported that it has excellent physical properties for ionization.

[0026]

[Effect of Experimental Example 1.2] In the case of Experimental Example 1, 10 persons requested to monitor, and all of them confirmed the effect of the bath agent of the present invention. Also, in the case of Experimental Example 2, all the 12 persons who requested the monitor confirmed the effect of the bath salt of the present invention. That is, the effect is 100%.

It has been known for 100 years that calcium ions are regulators of the living body, but the object is the effects in the body, and the close relationship between calcium ions and the living body has been established. It's been said for the last 10 years. It is a new discovery that calcium ions activated cells as a regulator of the living body from outside the body and exerted its effect as in this experimental example. In addition to the calcium ions, the bathing agent of the present invention contains components necessary for the living body in a well-balanced manner, and it is considered that these ions are combined to fulfill the effect.

Claims (1)

[Claims] 1. Shell fossils produced from the Toyama mine, the Japan Sea mining mine, and the national land Takaoka mine in Takaoka, Toyama Prefecture
A natural calcium carbonate bath agent consisting of fossil shell powder of 10 microns or less that evaporates the water content of the shell fossil by heat processing within ℃ to 300 ℃.