JPH0694192B2 - Polystyrene resin laminated sheet and manufacturing method thereof - Google Patents
Polystyrene resin laminated sheet and manufacturing method thereofInfo
- Publication number
- JPH0694192B2 JPH0694192B2 JP3290424A JP29042491A JPH0694192B2 JP H0694192 B2 JPH0694192 B2 JP H0694192B2 JP 3290424 A JP3290424 A JP 3290424A JP 29042491 A JP29042491 A JP 29042491A JP H0694192 B2 JPH0694192 B2 JP H0694192B2
- Authority
- JP
- Japan
- Prior art keywords
- polystyrene resin
- polystyrene
- resin
- foaming
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920005990 polystyrene resin Polymers 0.000 title claims description 46
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 229920005989 resin Polymers 0.000 claims description 82
- 239000011347 resin Substances 0.000 claims description 82
- 229920005669 high impact polystyrene Polymers 0.000 claims description 41
- 239000004797 high-impact polystyrene Substances 0.000 claims description 41
- 238000005187 foaming Methods 0.000 claims description 39
- 239000004793 Polystyrene Substances 0.000 claims description 35
- 229920002223 polystyrene Polymers 0.000 claims description 35
- 239000004088 foaming agent Substances 0.000 claims description 22
- 238000001816 cooling Methods 0.000 claims description 4
- 239000011342 resin composition Substances 0.000 claims description 4
- 229920006248 expandable polystyrene Polymers 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 229920006026 co-polymeric resin Polymers 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 6
- 239000006260 foam Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 238000005979 thermal decomposition reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004156 Azodicarbonamide Substances 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 3
- 235000019399 azodicarbonamide Nutrition 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000010097 foam moulding Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- CZGWDPMDAIPURF-UHFFFAOYSA-N (4,6-dihydrazinyl-1,3,5-triazin-2-yl)hydrazine Chemical compound NNC1=NC(NN)=NC(NN)=N1 CZGWDPMDAIPURF-UHFFFAOYSA-N 0.000 description 1
- ULUZGMIUTMRARO-UHFFFAOYSA-N (carbamoylamino)urea Chemical compound NC(=O)NNC(N)=O ULUZGMIUTMRARO-UHFFFAOYSA-N 0.000 description 1
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- -1 citric acid Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明はポリスチレン系樹脂積層
シートに関し、特に機械的強度と曲面印刷性を要求され
る食品容器用の素材として好適なものを提供しようとす
るものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a polystyrene resin laminated sheet, and particularly to provide a material suitable for a food container which is required to have mechanical strength and curved surface printability.
【０００２】[0002]
【従来の技術】近年、各種即席食品やスナック食品等を
収納する容器として、発泡ポリスチレン系樹脂シートを
加熱成形して成る容器が用いられて来ている。上記ポリ
スチレン等の発泡シートは軽量で安価であること、断熱
性が良好であることなどの長所を有しているが反面、深
絞り加工が困難であることや容器等の２次製品とした場
合に天地強度（上下強度）やリブ強度（横強度）などの
機械的強度に劣る点、或いは容器外側面が発泡シート面
となるため曲面印刷性に劣るなどの欠点があった。2. Description of the Related Art In recent years, a container formed by heat-molding an expanded polystyrene resin sheet has been used as a container for storing various instant foods, snack foods and the like. The above foamed sheet of polystyrene or the like has advantages such as light weight and low cost and good heat insulation, but on the other hand, it is difficult to perform deep drawing and is used as a secondary product such as a container. In addition, there are drawbacks such as inferior mechanical strength such as upside-down strength (vertical strength) and rib strength (lateral strength), or inferior curved surface printability because the outer surface of the container is a foamed sheet surface.
【０００３】上記欠点を解決するため、ハイインパクト
ポリスチレン樹脂を押出機内で溶融した後、該溶融ハイ
インパクトポリスチレン樹脂をＴダイから押出すと共に
ポリスチレン系樹脂発泡シート層とポリスチレン系樹脂
非発泡フイルムとの間に形成した積層構造から成るポリ
スチレン系樹脂積層シートを製造することも行なわれて
来た。In order to solve the above-mentioned drawbacks, a high-impact polystyrene resin is melted in an extruder, and then the molten high-impact polystyrene resin is extruded from a T die, and a polystyrene resin foam sheet layer and a polystyrene resin non-foam film are formed. It has also been practiced to manufacture a polystyrene-based resin laminated sheet having a laminated structure formed between them.
【０００４】[0004]
【発明が解決しようとする課題】しかしながら、前記の
技術によって得られたポリスチレン系樹脂積層シート
は、深絞り加工性に優れると共に容器が天地強度やリブ
強度などに優れる長所を付与するものであったが、一方
で容器の外側面に曲面印刷を施す被印刷面（インキ受理
層）がポリスチレン系樹脂非発泡フイルムであり、更に
その下の層も非発泡のハイインクパクトポリスチレン系
樹脂層であるのでクッション性に劣るため、曲面印刷性
が充分ではなく一層の向上が望まれていた。また、ハイ
インパクトポリスチレン樹脂層は非発泡体であるため使
用量が多く（発泡に比べ）なり、省資源、廃棄時の環境
保護などに充分留意されていないなどの問題もあった。However, the polystyrene-based resin laminated sheet obtained by the above-mentioned technique has an advantage that the container is excellent in deep drawing workability and the container is superior in upside down strength and rib strength. However, on the other hand, the surface to be printed (ink receiving layer) on the outer surface of the container is the polystyrene resin non-foamed film, and the layer below it is also the non-foamed high ink pact polystyrene resin layer. Since the cushioning property is poor, the curved surface printability is not sufficient, and further improvement has been desired. Further, since the high-impact polystyrene resin layer is a non-foamed material, the amount used is large (compared to foaming), and there is a problem in that sufficient attention is not paid to resource saving and environmental protection at the time of disposal.
【０００５】そこで本発明者等は、ポリスチレン系樹脂
積層シート及びその製造法に就き鋭意研究を重ねた結
果、ハイインパクトポリスチレン樹脂を熱分解型発泡剤
と共に押出機内で溶融混練した後、該ハイインパクトポ
リスチレン樹脂組成物をＴダイから大気中に押出すと共
にポリスチレン系樹脂高発泡シート層とポリスチレン系
樹脂非発泡フイルムとの間に導き積層すること、及びこ
の様にして得られたポリスチレン系樹脂積層シートが深
絞り加工性、容器の天地強度やリブ強度などの性能及び
曲面印刷性にも優れ、且つ省資源化や環境保護にも寄与
することを見出し本発明に到達した。Accordingly, the inventors of the present invention have conducted extensive studies on a polystyrene resin laminated sheet and a method for producing the same, and as a result, after melt-kneading a high-impact polystyrene resin together with a pyrolytic foaming agent in an extruder, Extruding the polystyrene resin composition from the T-die into the atmosphere and guiding and laminating it between the polystyrene resin highly foamed sheet layer and the polystyrene resin non-foamed film, and the polystyrene resin laminated sheet thus obtained The present invention has been found to be excellent in deep drawing workability, performance such as top and bottom strength of a container and rib strength, and curved surface printability, and contributes to resource saving and environmental protection.
【０００６】従って本発明の第１の目的は深絞り加工
性、容器の天地強度やリブ強度などの性能及び曲面印刷
性にも優れ、且つ省資源化や環境保護にも貢献するポリ
スチレン系樹脂積層シートを提供することに在る。本発
明の第２の目的は深絞り加工性、容器の天地強度やリブ
強度などの性能及び曲面印刷性にも優れ、且つ省資源化
や環境保護にも貢献するポリスチレン系樹脂積層シート
を製造するための方法を提供することに在る。Therefore, a first object of the present invention is a polystyrene-based resin laminate which is excellent in deep-drawing workability, performance such as top and bottom strength of a container and rib strength, and curved surface printability, and contributes to resource saving and environmental protection. It consists in providing a seat. A second object of the present invention is to produce a polystyrene-based resin laminated sheet which is excellent in deep-drawing workability, performance such as container top and bottom strength and rib strength, and curved surface printability, and which also contributes to resource saving and environmental protection. To provide a way to do so.
【０００７】[0007]
【課題を解決するための手段】本発明の第１の目的は、
厚さが1.0〜3.5mmで発泡倍率が５〜15倍のポリスチレン
系樹脂高発泡シート層と、厚さが20〜70μmのポリスチ
レン系樹脂非発泡フイルムとが、厚さが50〜300μmで発
泡倍率が1.1〜2.5倍のハイインパクトポリスチレン樹脂
低発泡層を介して成る３層構造であることを特徴とする
ポリスチレン系樹脂積層シートによって達成された。The first object of the present invention is to:
A high expansion sheet layer of polystyrene resin with a thickness of 1.0 to 3.5 mm and a foaming ratio of 5 to 15 times, and a polystyrene resin non-foaming film with a thickness of 20 to 70 μm, a foaming ratio of 50 to 300 μm Was achieved by a polystyrene-based resin laminated sheet characterized by having a three-layer structure comprising a high-impact polystyrene resin low-foaming layer of 1.1 to 2.5 times.
【０００８】本発明の第２の目的は、ハイインパクトポ
リスチレン樹脂を熱分解型発泡剤と共に押出機内で溶融
混練した後、該ハイインパクトポリスチレン樹脂組成物
をＴダイから大気中に重力方向に押出すと共にポリスチ
レン系樹脂高発泡シート層とポリスチレン系樹脂非発泡
フイルムとの間に導き、次いでポリスチレン系樹脂フイ
ルム面から冷却することを特徴とするポリスチレン系樹
脂積層シートの製造法によって達成された。A second object of the present invention is to melt and knead a high-impact polystyrene resin together with a pyrolytic foaming agent in an extruder, and then extrude the high-impact polystyrene resin composition from a T-die into the atmosphere in the direction of gravity. It was achieved by a method for producing a polystyrene-based resin laminated sheet, which is characterized in that it is introduced between a polystyrene-based resin high-foaming sheet layer and a polystyrene-based resin non-foamed film, and then cooled from the surface of the polystyrene-based resin film.
【０００９】本発明で用いることのできるポリスチレン
系樹脂高発泡シートは、一般に行なわれている押出発泡
成形法によって得られた発泡シートであり、スチレン系
樹脂は特に限定されないが、例えば汎用ポリスチレン樹
脂、ハイインパクトポリスチレン樹脂、スチレン−アク
リロニトリル共重合体樹脂、スチレン−メチルメタアク
リレート共重合体樹脂、スチレン−アクリル酸共重合体
樹脂、スチレン−無水マレイン酸共重合体樹脂及びこれ
等の混合物等の中から適宜選択して使用することができ
る。The polystyrene-based resin highly foamed sheet that can be used in the present invention is a foamed sheet obtained by a generally-used extrusion foam molding method. The styrene-based resin is not particularly limited, but for example, general-purpose polystyrene resin, From high-impact polystyrene resin, styrene-acrylonitrile copolymer resin, styrene-methylmethacrylate copolymer resin, styrene-acrylic acid copolymer resin, styrene-maleic anhydride copolymer resin and mixtures of these It can be appropriately selected and used.
【００１０】これ等のポリスチレン系樹脂にはタルク、
炭酸カルシウム等の無機物、可塑剤及び安定剤を所望す
る物性に応じて添加することができる。また発泡剤とし
てはポリスチレン系樹脂の発泡剤として公知の物理発泡
剤または化学発泡剤の中から適宜選択して使用すること
ができる。物理発泡剤としては、例えばプロパン、ブタ
ン、ヘキサン、ヘプタン等の炭化水素化合物、フレオン
−１１、フレオン−１２、フレオン−１１３、フレオン
−１１４（フレオンはデュポン社の商品名）、メチルク
ロライド、メチレンクロライド等のハロゲン化炭化水素
化合物を挙げることができる。These polystyrene resins include talc,
Inorganic substances such as calcium carbonate, plasticizers and stabilizers can be added depending on the desired physical properties. Further, as the foaming agent, a physical foaming agent or a chemical foaming agent known as a foaming agent for polystyrene resin can be appropriately selected and used. Examples of the physical blowing agent include hydrocarbon compounds such as propane, butane, hexane, heptane, Freon-11, Freon-12, Freon-113, Freon-114 (Freon is a trade name of DuPont), methyl chloride, methylene chloride. And other halogenated hydrocarbon compounds.
【００１１】化学発泡剤としては、例えばアゾジカルボ
ンアミド等の有機系熱分解型発泡剤、重炭酸塩とクエン
酸等の有機酸との組合わせ等を挙げることができる。本
発明で用いることのできるポリスチレン系樹脂非発泡フ
イルムは特に限定されないが、例えば汎用ポリスチレン
樹脂、ハイインパクトポリスチレン樹脂、スチレンーア
クリロニトリル共重合体樹脂、スチレンーメタルメタア
クリレート共重合体樹脂、スチレンーアクリル酸共重合
体樹脂、スチレンー無水マレイン酸共重合体樹脂及びこ
れ等の混合物から成るものを適宜選択して使用すること
ができる。本発明でポリスチレン系樹脂高発泡シート層
とポリスチレン系樹脂非発泡フイルムとの間に形成され
るハイインパクトポリスチレン樹脂層は特に限定されな
いが、例えばポリスチレン樹脂にブタジェン、ブテン等
のゴム成分を含有させたものを挙げることができる。こ
れ等のハイインパクトポリスチレン樹脂にはタルク、炭
酸カルシウム等の無機物、可塑剤、分散剤及び安定剤を
所望する物性に応じて添加することができる。Examples of the chemical foaming agent include organic pyrolyzable foaming agents such as azodicarbonamide, combinations of bicarbonate and organic acids such as citric acid, and the like. The polystyrene resin non-foamed film that can be used in the present invention is not particularly limited, and examples thereof include general-purpose polystyrene resin, high-impact polystyrene resin, styrene-acrylonitrile copolymer resin, styrene-metal methacrylate copolymer resin, styrene-acryl. A resin composed of an acid copolymer resin, a styrene-maleic anhydride copolymer resin and a mixture thereof can be appropriately selected and used. In the present invention, the high-impact polystyrene resin layer formed between the polystyrene-based resin high-foaming sheet layer and the polystyrene-based resin non-foamed film is not particularly limited. For example, the polystyrene resin contains a rubber component such as butadiene and butene. I can list things. Inorganic substances such as talc and calcium carbonate, a plasticizer, a dispersant, and a stabilizer can be added to these high-impact polystyrene resins according to desired physical properties.
【００１２】また、該ハイインパクトポリスチレン樹脂
に発泡能を具備させるために用いられる発泡剤としては
熱分解型の発泡剤が好ましい。熱分解型発泡剤の具体例
としては、例えば、アゾジカルボンアミド、トリヒロラ
ジノトリアジン、アゾジカルボン酸ストロンチウム、ヒ
ドラゾジカルボナミドなど公知の発泡剤を挙げることが
できる。Further, as the foaming agent used for providing the high-impact polystyrene resin with the foaming ability, a thermal decomposition type foaming agent is preferable. Specific examples of the thermal decomposition type foaming agent include known foaming agents such as azodicarbonamide, trihydrazinotriazine, strontium azodicarboxylate, and hydrazodicarbonamide.
【００１３】本発明のポリスチレン系樹脂積層シート
は、厚さが1.0〜3.5mmで発泡倍率が５〜15倍のポリスチ
レン系樹脂高発泡シート層と、厚さが20〜70μmのポリ
スチレン系樹脂非発泡フイルムとが、厚さが50〜300μm
で発泡倍率が1.1〜2.5倍のハイインパクトポリスチレン
樹脂低発泡層により積層された構成より成る。従って、
本発明のポリスチレン系樹脂積層シートを図示すると図
１の様になる。図中１はポリスチレン系樹脂高発泡シー
ト、２はポリスチレン系樹脂非発泡フイルム、３はハイ
インパクトポリスチレン樹脂低発泡層を指す。また、ポ
リスチレン系樹脂高発泡シート層の発泡倍率を５〜15倍
としたのは、５倍未満では断熱性が充分でなく、容器と
した場合の質感にも劣る。一方、15倍超では本発明のハ
イインパクトポリスチレン樹脂低発泡層を介してポリス
チレン系樹脂非発泡フイルムを積層しても容器の天地強
度やリブ強度が充分に付与されないためによる。The polystyrene resin laminated sheet of the present invention comprises a polystyrene resin highly foamed sheet layer having a thickness of 1.0 to 3.5 mm and an expansion ratio of 5 to 15 and a polystyrene resin non-foamed material having a thickness of 20 to 70 μm. The film has a thickness of 50-300 μm
The high-impact polystyrene resin having a foaming ratio of 1.1 to 2.5 times is laminated by a low-foaming layer. Therefore,
The polystyrene resin laminated sheet of the present invention is illustrated in FIG. In the figure, 1 is a high-foaming polystyrene resin sheet, 2 is a non-foaming polystyrene resin film, and 3 is a high-impact polystyrene resin low-foaming layer. In addition, the reason why the expansion ratio of the polystyrene-based resin high-foaming sheet layer is 5 to 15 times is that if it is less than 5 times, the heat insulating property is not sufficient and the quality of the container is poor. On the other hand, if it exceeds 15 times, even if the polystyrene resin non-foamed film is laminated through the high-impact polystyrene resin low-foaming layer of the present invention, the top and bottom strength and rib strength of the container are not sufficiently imparted.
【００１４】ポリスチレン系樹脂非発泡フイルムの厚さ
を20〜70μmとしたのは、20μm未満では積層時フイルム
にしわが発生し易く作業性に劣るためであり、また70μ
m超ではフイルム層自体が厚くなり過ぎ、ハイインパク
トポリスチレン樹脂低発泡層による曲面印刷性向上効果
が充分に発現されないなどのためである。ハイインパク
トポリスチレン樹脂低発泡層の発泡倍率を1.1〜2.5倍と
したのは、1.1倍未満では曲面印刷性の向上効果（クッ
ション性）が充分得られないためであり、また経済効果
も小さい。一方、2.5倍超では発泡により表面性が悪化
するため、却って曲面印刷性が低下するなどのためであ
る。The thickness of the polystyrene-based resin non-foamed film is set to 20 to 70 μm because wrinkles easily occur in the film at the time of lamination and workability is deteriorated when the thickness is less than 20 μm.
This is because if the thickness exceeds m, the film layer itself becomes too thick, and the effect of improving the curved surface printability due to the high-impact polystyrene resin low foam layer is not sufficiently exhibited. The reason why the foaming ratio of the high-impact polystyrene resin low-foaming layer is 1.1 to 2.5 times is that if it is less than 1.1 times, the effect of improving the curved surface printability (cushioning property) cannot be sufficiently obtained, and the economic effect is small. On the other hand, if it exceeds 2.5 times, the surface property is deteriorated due to foaming, so that the curved surface printability is rather deteriorated.
【００１５】本発明でハイインパクトポリスチレン樹脂
に発泡能を具備させるために用いる発泡剤として熱分解
型発泡剤が好ましいとしたのは、該ハイインパクトポリ
スチレン樹脂低発泡層を積層した本発明から成るポリス
チレン系樹脂積層シートを容器などの２次製品に加工す
る際の加熱成形工程での、ハイインパクトポリスチレン
樹脂低発泡層の２次発泡を防止或いは極力抑えるためで
ある。In the present invention, the thermal decomposition type foaming agent is preferred as the foaming agent used for providing the high-impact polystyrene resin with foaming ability, because the polystyrene of the present invention in which the high-impact polystyrene resin low foam layer is laminated is preferred. This is to prevent or suppress secondary foaming of the high-impact polystyrene resin low-foaming layer in the heat molding step when processing the resin-based resin laminated sheet into a secondary product such as a container.
【００１６】次に、本発明のポリスチレン系樹脂積層シ
ートの製造法を図に従って説明する。図２は本発明の製
造法に用いる押出積層装置の概略図である。Next, a method for producing the polystyrene resin laminated sheet of the present invention will be described with reference to the drawings. FIG. 2 is a schematic view of an extrusion laminating apparatus used in the manufacturing method of the present invention.
【００１７】図に於いてポリスチレン系樹脂高発泡シー
ト層１とポリスチレン系樹脂非発泡フイルム層２は夫々
図外のアンワインダーから繰り出され加圧ロール５と冷
却ロール６の間に通され一定の速度で走行している。次
いで、ハイインパクトポリスチレン樹脂に熱分解型発泡
剤を予め分散させた混合物を押出機７内で溶融混練させ
た後、押出機７の先端に取付けられたＴダイ８のオリフ
ィス９から大気中に押出し、該ハイインパクトポリスチ
レン樹脂低発泡層３をポリスチレン系樹脂高発泡シート
層１とポリスチレン系樹脂非発泡フイルム２との間に導
いた。この場合、ポリスチレン系樹脂高発泡シート層１
とポリスチレン系樹脂非発泡フイルム２は、ハイインパ
クトポリスチレン樹脂低発泡層３により融着積層すると
共にハイインパクトポリスチレン樹脂低発泡層３はポリ
スチレン樹脂非発泡フイルム２面から冷却ロール５によ
り急冷され、固化する。その後ポリスチレン系樹脂高発
泡シート層とポリスチレン系樹脂非発泡フイルムとがハ
イインパクトポリスチレン樹脂低発泡層により積層され
たポリスチレン系樹脂積層シート４は図外のワインダー
により巻き取られる。In the figure, a polystyrene resin highly foamed sheet layer 1 and a polystyrene resin non-foamed film layer 2 are respectively fed from an unwinder (not shown) and passed between a pressure roll 5 and a cooling roll 6 at a constant speed. Are running in. Then, a mixture of a high-impact polystyrene resin and a pyrolytic foaming agent previously dispersed therein is melt-kneaded in the extruder 7, and then extruded into the atmosphere from an orifice 9 of a T-die 8 attached to the tip of the extruder 7. The high-impact polystyrene resin low-foamed layer 3 was led between the polystyrene-based resin high-foamed sheet layer 1 and the polystyrene-based resin non-foamed film 2. In this case, the polystyrene-based resin highly foamed sheet layer 1
The polystyrene-based resin non-foamed film 2 and the high-impact polystyrene resin low-foamed layer 3 are fused and laminated, and the high-impact polystyrene resin low-foamed layer 3 is rapidly cooled from the surface of the polystyrene resin non-foamed film 2 by the cooling roll 5 to be solidified. . Thereafter, the polystyrene-based resin laminated sheet 4 in which the polystyrene-based resin high-foaming sheet layer and the polystyrene-based resin non-foaming film are laminated by the high-impact polystyrene resin low-foaming layer is wound by a winder (not shown).
【００１８】本発明の製造法の特徴は、ポリスチレン系
樹脂高発泡シート層とポリスチレン系樹脂非発泡フイル
ムとの間に熱分解型発泡で低発泡化させたハイインパク
トポリスチレン樹脂層を積層化する点にある。即ち、該
熱分解型発泡剤はハイインパクトポリスチレン樹脂低発
泡層を形成することのみに作用する（発泡剤は完全に分
解する）ため、容器等の２次製品に成形する際の加熱成
形過程では作用しない（２次発泡が生じない）。そのた
め、２次製品のポリスチレン系樹脂非発泡フイルム面の
表面性は加熱成形前と変わらない。従って２次製品とし
ても表面性に優れ、且つ適度なクッション性を有する被
印刷面となるので曲面印刷性も優れたものとなるのであ
る。The feature of the production method of the present invention is that a high-impact polystyrene resin layer, which has been reduced in foaming rate by thermal decomposition type foaming, is laminated between a polystyrene resin highly foamed sheet layer and a polystyrene resin non-foamed film. It is in. That is, since the heat-decomposable foaming agent acts only to form a high-impact polystyrene resin low-foaming layer (the foaming agent is completely decomposed), in the heat molding process when molding into a secondary product such as a container. Does not work (no secondary foaming). Therefore, the surface property of the non-foamed polystyrene resin film surface of the secondary product is the same as that before heat molding. Therefore, as a secondary product, the surface to be printed has an excellent cushioning property and also has an appropriate cushioning property, so that the curved surface printability is also excellent.
【００１９】[0019]
【実施例】以下に本発明を実施例により詳述するが、本
発明はこれ等によって限定されるものではない。 実施例１ ポリスチレン系樹脂高発泡シートは、一般に行なわれて
いる押出発泡成形法により得られた幅が300mm、厚さが
2.6mm、坪量260g/m2、発泡倍率10倍のシートを使用し
た。またポリスチレン系樹脂非発泡フイルムは厚さが30
μmの汎用のポリスチレン樹脂非発泡フイルムを使用
し、前記のポリスチレン系樹脂高発泡シートと共に図２
に示した加圧ロール５と10℃の冷却水が循環している冷
却ロール６間に５m/分の速度で通した。EXAMPLES The present invention is described in detail below with reference to examples, but the present invention is not limited to these. Example 1 A polystyrene-based resin high-foaming sheet has a width of 300 mm and a thickness of 300 mm obtained by a generally-used extrusion foam molding method.
A sheet having a diameter of 2.6 mm, a basis weight of 260 g / m 2 , and an expansion ratio of 10 was used. The thickness of the non-foamed polystyrene resin film is 30
A general-purpose polystyrene resin non-foaming film of μm is used, and it is used together with the above polystyrene resin high foaming sheet.
It was passed at a speed of 5 m / min between the pressure roll 5 shown in FIG.
【００２０】次いで、ハイインパクトポリスチレン樹脂
100重量部に分散剤として流動パラフィン0.05重量部を
添加した後、更に発泡剤としてアゾジカルボンアミド0.
4重量部及び気泡調整剤として炭酸カルシウム粉末1.0重
量部とを添加して分散させた。Next, high impact polystyrene resin
After adding 0.05 part by weight of liquid paraffin as a dispersant to 100 parts by weight, azodicarbonamide as a foaming agent was further added.
4 parts by weight and 1.0 part by weight of calcium carbonate powder as a bubble control agent were added and dispersed.
【００２１】この様にして得られたハイインパクトポリ
スチレン樹脂組成物を、220℃に加熱した直径40mmの押
出機を用いて溶融混練しながら押出機の先端に取付けら
れた幅400mmのＴダイから押出量15.3kg/時で押出すと共
にポリスチレン系樹脂高発泡シート層とポリスチレン系
樹脂非発泡フイルムとの間に導き（この時のハイインパ
クトポリスチレン樹脂低発泡層の厚さは170μmで、坪量
は85g/m2、発泡倍率は２倍であった。）、厚さが2.9m
m、坪量が375g/m2の本発明によるポリスチレン系樹脂積
層シートを作製した。The high-impact polystyrene resin composition thus obtained is extruded from a T-die having a width of 400 mm attached to the tip of the extruder while melt-kneading with an extruder having a diameter of 40 mm heated to 220 ° C. It is extruded at an amount of 15.3 kg / hour and guided between the polystyrene resin high-foaming sheet layer and the polystyrene resin non-foaming film (the thickness of the high-impact polystyrene resin low-foaming layer at this time is 170 μm, and the basis weight is 85 g. / m 2 , the expansion ratio was 2 times), and the thickness was 2.9 m.
A polystyrene-based resin laminated sheet according to the present invention having m and basis weight of 375 g / m 2 was produced.
【００２２】この様にして得られたポリスチレン系樹脂
積層シートを、口径140mm、深さが105mmのどんぶりに成
形した。得られたどんぶりの天地強度（どんぶりの上下
強度）及びリブ強度（どんぶりの横強度）は引張試験機
（テンシロンＨＴＭ−100；東洋ボールドウィン社製）
で50mm/分でどんぶりを夫々の方向から10mm変形させた
時の最大加重から求めた。天地強度は31kgであり、リブ
強度は320gであった。また曲面印刷性はどんぶりの側面
を切取り印刷機（ＲＩテスター；明製作所）でポリスチ
レン系樹脂非発泡フィルム面に印刷を施し、印刷面濃度
（マクベス濃度計；KollmorgenCorp製）と印刷面光沢度
（75°/75°光沢度計；村上色彩研究所製）から評価し
た。印刷面濃度は1.7ポイント、印刷面光沢度は85％で
あった。印刷面はインキの着肉性が良く印刷性に優れた
ものであった。The polystyrene resin laminate sheet thus obtained was molded into a bowl having a diameter of 140 mm and a depth of 105 mm. The top and bottom strength of the obtained bowl (the vertical strength of the bowl) and the rib strength (the transverse strength of the bowl) were measured by a tensile tester (Tensilon HTM-100; manufactured by Toyo Baldwin).
Was calculated from the maximum load when the bowl was deformed by 10 mm from each direction at 50 mm / min. The upside-down strength was 31 kg and the rib strength was 320 g. Also, the curved surface printability is obtained by printing on the polystyrene resin non-foamed film surface with a cutting machine (RI tester; Akira Seisakusho) on the side of the bowl and printing surface density (Macbeth densitometer; made by Kollmorgen Corp) and printing surface glossiness (75 ° / 75 ° gloss meter; manufactured by Murakami Color Research Laboratory). The print surface density was 1.7 points, and the print surface glossiness was 85%. The print surface had good ink receptivity and excellent printability.
【００２３】比較例１ 実施例１と全く同一の装置で、ハイインパクトポリスチ
レン樹脂のみを押出機内で溶融した後、該ハイインパク
トポリスチレン樹脂をＴダイから押出すと共にポリスチ
レン系樹脂高発泡シート層とポリスチレン系樹脂非発泡
フイルムとの間に導き（この時、ハイインパクトポリス
チレン樹脂層の厚さは170μmとなる様に押出量を調整し
た。坪量は170g/mであった。）厚さが2.9mm、坪量が460
g/m2のシートを作製した。Comparative Example 1 In the same apparatus as in Example 1, only the high-impact polystyrene resin was melted in the extruder, the high-impact polystyrene resin was extruded from the T die, and the polystyrene resin high foam sheet layer and polystyrene were used. It was introduced into a non-foamed film of a base resin (at this time, the extrusion amount was adjusted so that the thickness of the high-impact polystyrene resin layer was 170 μm. The basis weight was 170 g / m.) The thickness was 2.9 mm. , The basis weight is 460
A g / m 2 sheet was prepared.
【００２４】得られたポリスチレン系樹脂積層シートを
用いて、実施例１と全く同様の口径140mm、深さが105mm
のどんぶりに成形した処、得られたどんぶりの天地強度
は31kgであり、リブ強度は320gであった。また得られた
どんぶりの曲面印刷性は印刷面濃度が1.4ポイント、印
刷面光沢度が53％であった。印刷面はインキの着肉性が
悪く印刷性に劣るものであった。Using the obtained polystyrene-based resin laminated sheet, the same bore diameter of 140 mm and depth of 105 mm as in Example 1 was used.
When the bowl was molded into a bowl, the top and bottom strength of the obtained bowl was 31 kg and the rib strength was 320 g. As for the surface printability of the obtained bowl, the print surface density was 1.4 points and the print surface glossiness was 53%. The print surface had poor ink receptivity and poor printability.
【００２５】以上の実施例及び比較例の結果から、従来
のものと比べ本発明の積層シートは、ハイインパクトポ
リスチレン樹脂の使用量が少なくなり省資源化や廃棄量
の減少化による環境保護にも貢献できる一方、容器の天
地強度やリブ強度は問題なく、且つ容器外側面の曲面印
刷性に優れたものを提供できるということが実証され
た。From the results of the above-mentioned Examples and Comparative Examples, the laminated sheet of the present invention has a smaller amount of high-impact polystyrene resin used than conventional ones, and can be used for environmental protection by saving resources and reducing the amount of waste. It has been proved that, while contributing to the contribution, the top and bottom strength and the rib strength of the container can be provided without any problem, and the outer surface of the container can be excellent in curved surface printability.
【００２６】[0026]
【発明の効果】本発明のポリスチレン系樹脂積層シート
は、ポリスチレン系樹脂高発泡シート層とポリスチレン
系樹脂非発泡フイルムとが、熱分解型発泡剤により形成
されるハイインパクトポリスチレン樹脂低発泡層により
積層される構成であるため、深絞り加工性や容器の天地
強度及びリブ強度等の性能は問題なく、且つ印刷面の表
面性が良好で適度なクッション性を有するため曲面印刷
性にも優れたものとなる。またハイインパクトポリスチ
レン樹脂層を発泡させているため使用樹脂量が低減さ
れ、省資源化や廃棄量の低減による環境保護にも貢献で
きる特徴を有している。EFFECT OF THE INVENTION In the polystyrene resin laminated sheet of the present invention, a polystyrene resin highly foamed sheet layer and a polystyrene resin non-foamed film are laminated by a high impact polystyrene resin low foamed layer formed by a thermal decomposition type foaming agent. Since it is a structure that is deeply drawn, there is no problem in performance such as deep drawing workability and top and bottom strength and rib strength of the container, and the surface property of the printing surface is good and it has an appropriate cushioning property and is also excellent in curved surface printability. Becomes In addition, since the high-impact polystyrene resin layer is foamed, the amount of resin used is reduced, which has the feature of contributing to environmental protection by saving resources and reducing the amount of waste.
【図１】本発明はポリスチレン系樹脂積層シートの横断
面模式図である。FIG. 1 is a schematic cross-sectional view of a polystyrene resin laminated sheet according to the present invention.
【図２】本発明の製造法に用いる装置の概略図である。FIG. 2 is a schematic view of an apparatus used in the manufacturing method of the present invention.
１ ポリスチレン系樹脂高発泡シート層 ２ ポリスチレン系樹脂非発泡フイルム ３ ハイインパクトポリスチレン樹脂低発泡層 ４ ポリスチレン系樹脂積層シート ５ 加圧ロール ６ 冷却ロール ７ 押出機 ８ Ｔダイ ９ オリフィス 1 Polystyrene-based resin high-foaming sheet layer 2 Polystyrene-based resin non-foaming film 3 High-impact polystyrene resin low-foaming layer 4 Polystyrene-based resin laminated sheet 5 Pressure roll 6 Cooling roll 7 Extruder 8 T-die 9 Orifice
フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 // Ｂ２９Ｋ 25:00 Ｂ２９Ｌ 9:00 4Ｆ Continuation of front page (51) Int.Cl. 5 Identification number Office reference number FI technical display location // B29K 25:00 B29L 9:00 4F
Claims (3)
のポリスチレン系樹脂高発泡シート層と厚さが20〜70μ
mのポリスチレン系樹脂非発泡フイルムとが、厚さが50
〜300μmで発泡倍率が1.1〜2.5倍のハイインパクトポリ
スチレン樹脂低発泡層を介して積層して成る３層構造で
あることを特徴とするポリスチレン系樹脂積層シート。1. A highly foamed polystyrene resin sheet layer having a thickness of 1.0 to 3.5 mm and an expansion ratio of 5 to 15 and a thickness of 20 to 70 μm.
50 m thick polystyrene resin non-foamed film
A high-impact polystyrene resin having a foaming ratio of 1.1 to 2.5 times and a low expansion layer of 300 to 300 μm, and a polystyrene resin laminated sheet having a three-layered structure.
剤と共に押出機内で溶融混練した後、該ハイインパクト
ポリスチレン樹脂組成物をＴダイから大気中に重力方向
に押出すと共にポリスチレン系樹脂高発泡シート層とポ
リスチレン系樹脂非発泡フイルムとの間に導き、次いで
ポリスチレン系樹脂非発泡フイルム面から冷却すること
を特徴とするポリスチレン系樹脂積層シートの製造法。2. A high-impact polystyrene resin is melt-kneaded together with a foaming agent in an extruder, and then the high-impact polystyrene resin composition is extruded from a T-die into the atmosphere in the direction of gravity and a polystyrene-based resin high-foaming sheet layer and polystyrene are used. A method for producing a polystyrene-based resin laminated sheet, which comprises introducing the resin-based resin non-foamed film and then cooling from the surface of the polystyrene-based resin non-foamed film.
される発泡剤が熱分解型発泡剤であることを特徴とする
請求項２に記載のポリスチレン系樹脂積層シートの製造
法。3. The method for producing a polystyrene-based resin laminated sheet according to claim 2, wherein the foaming agent used for the high-impact polystyrene resin is a pyrolytic foaming agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3290424A JPH0694192B2 (en) | 1991-10-11 | 1991-10-11 | Polystyrene resin laminated sheet and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3290424A JPH0694192B2 (en) | 1991-10-11 | 1991-10-11 | Polystyrene resin laminated sheet and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0596673A JPH0596673A (en) | 1993-04-20 |
| JPH0694192B2 true JPH0694192B2 (en) | 1994-11-24 |
Family
ID=17755858
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3290424A Expired - Fee Related JPH0694192B2 (en) | 1991-10-11 | 1991-10-11 | Polystyrene resin laminated sheet and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0694192B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012176533A (en) * | 2011-02-25 | 2012-09-13 | Kaneka Corp | Styrene-based resin extrusion foamed laminate, and method for manufacturing the same |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0957885A (en) * | 1995-08-25 | 1997-03-04 | Atena Kogyo Kk | Manufacture of foamed resin container |
| JPH10252719A (en) | 1997-03-18 | 1998-09-22 | Togo Seisakusho Corp | Pipe clamp |
| DE19920916A1 (en) | 1999-05-06 | 2000-11-16 | Basf Ag | Laminated sheet or film for refrigerators |
| US6869901B2 (en) | 2001-02-20 | 2005-03-22 | Pactiv Corporation | Protective drainage wraps |
| US9656445B2 (en) | 2001-02-20 | 2017-05-23 | Kingspan Insulation Llc | Protective drainage wraps |
| JP4516869B2 (en) * | 2005-03-23 | 2010-08-04 | 積水化成品工業株式会社 | Polystyrene resin laminated foam sheet, method for producing the same, and method for producing a molded product |
-
1991
- 1991-10-11 JP JP3290424A patent/JPH0694192B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012176533A (en) * | 2011-02-25 | 2012-09-13 | Kaneka Corp | Styrene-based resin extrusion foamed laminate, and method for manufacturing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0596673A (en) | 1993-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |