JPH0659654B2 - Continuous vulcanization equipment for unvulcanized rubber extruded products - Google Patents
Continuous vulcanization equipment for unvulcanized rubber extruded productsInfo
- Publication number
- JPH0659654B2 JPH0659654B2 JP63249104A JP24910488A JPH0659654B2 JP H0659654 B2 JPH0659654 B2 JP H0659654B2 JP 63249104 A JP63249104 A JP 63249104A JP 24910488 A JP24910488 A JP 24910488A JP H0659654 B2 JPH0659654 B2 JP H0659654B2
- Authority
- JP
- Japan
- Prior art keywords
- unvulcanized rubber
- rubber
- heating furnace
- conveying
- extruded product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001971 elastomer Polymers 0.000 title claims description 145
- 239000005060 rubber Substances 0.000 title claims description 145
- 235000012438 extruded product Nutrition 0.000 title claims description 41
- 238000004073 vulcanization Methods 0.000 title claims description 21
- 238000010438 heat treatment Methods 0.000 claims description 108
- 238000005187 foaming Methods 0.000 claims description 43
- 238000006243 chemical reaction Methods 0.000 claims description 32
- 238000001125 extrusion Methods 0.000 description 14
- 238000010586 diagram Methods 0.000 description 7
- 230000007246 mechanism Effects 0.000 description 7
- 239000007787 solid Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 125000006850 spacer group Chemical group 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001821 foam rubber Polymers 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 235000004035 Cryptotaenia japonica Nutrition 0.000 description 1
- 244000146493 Cryptotaenia japonica Species 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 230000007723 transport mechanism Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/10—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation for articles of indefinite length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/91—Heating, e.g. for cross linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0855—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using microwave
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2021/00—Use of unspecified rubbers as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
Landscapes
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Toxicology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Molding Of Porous Articles (AREA)
Description
【発明の詳細な説明】 「産業上の利用分野」 本発明は、押出成形機より押出された未加硫ゴム押出成
形品をマイクロ波エネルギーと熱風エネルギーを利用し
て連続的に発泡加硫させ、特に均質の発泡状態を有する
形状の発泡体ゴムを製造する装置に関する。DETAILED DESCRIPTION OF THE INVENTION "Industrial field of application" The present invention continuously foams and vulcanizes an unvulcanized rubber extruded product extruded from an extruder using microwave energy and hot air energy. In particular, the present invention relates to an apparatus for producing a foam rubber having a shape having a homogeneous foam state.
「従来の技術」 従来から、未加硫ゴム押出成形品を連続して発泡加硫さ
せて発泡成形品として発泡体ゴム(以下「スポンジゴ
ム」という)を製造する場合、押出成形機より押出され
た被加熱ゴムの発泡加硫工程において、マイクロ波及び
熱風エネルギーを使用して連続的に均一加熱する装置が
一般に用いられている。"Prior art" Conventionally, when an unvulcanized rubber extruded product is continuously foamed and vulcanized to produce foam rubber (hereinafter referred to as "sponge rubber"), it is extruded from an extruder. In the foaming and vulcanizing step of the heated rubber, a device for continuously and uniformly heating using microwave and hot air energy is generally used.
また、押出成形機より押出された被加熱ゴムの加硫成形
品(以下「ソリッドゴム」という)も上記同様の装置に
より製造される。Also, a vulcanized molded product of the heated rubber extruded from the extruder (hereinafter referred to as "solid rubber") is manufactured by the same apparatus as above.
第7図はこの種の未加硫ゴム押出成形品の連続加硫装置
(以下「加硫装置」という)の代表的な構成図である。FIG. 7 is a typical configuration diagram of a continuous vulcanizing apparatus (hereinafter referred to as “vulcanizing apparatus”) for this type of unvulcanized rubber extruded product.
加硫装置50は押出成形機11、マイクロ波加熱炉5
1、二次加熱炉48及び連続引取機16から構成されて
いる。The vulcanizer 50 is an extruder 11 and a microwave heating furnace 5.
The secondary heating furnace 48 and the continuous take-up machine 16 are provided.
押出成形機11の供給口17より投入された原料は、シ
リンダ18内でモータ19により回転駆動されるスクリ
ュー20によって成形ダイス21に移送される。The raw material charged through the supply port 17 of the extrusion molding machine 11 is transferred to the molding die 21 by the screw 20 which is rotationally driven by the motor 19 in the cylinder 18.
続いて、成形ダイス21から押出された細長形の未加硫
ゴム押出成形品22(以下「押出ゴム22」という)は
マイクロ波加熱炉51及び二次加熱炉48の各ベルトコ
ンベア49により移送され、連続引取機16で引取られ
る。Subsequently, the elongated unvulcanized rubber extruded product 22 (hereinafter referred to as “extruded rubber 22”) extruded from the molding die 21 is transferred by each belt conveyor 49 of the microwave heating furnace 51 and the secondary heating furnace 48. The continuous take-up machine 16 picks it up.
上記工程の間に、押出ゴム22がマイクロ波加熱炉51
内でマイクロ波発振機24より発生したマイクロ波エネ
ルギーと、ヒーター27及び送風機28からなる熱風発
生機による熱風エネルギーを受けて適正な加硫温度まで
急速に昇温する。さらに、二次加熱炉48では、押出ゴ
ム22が熱風発生機による熱風エネルギーを受けて加硫
温度を保ちつつ加硫反応が終了する。During the above process, the extruded rubber 22 is heated in the microwave heating furnace 51.
The microwave energy generated by the microwave oscillator 24 and the hot air energy generated by the hot air generator including the heater 27 and the blower 28 are received therein to rapidly raise the temperature to an appropriate vulcanization temperature. Furthermore, in the secondary heating furnace 48, the vulcanization reaction is completed while the extruded rubber 22 receives the hot air energy from the hot air generator to maintain the vulcanization temperature.
マイクロ波加熱炉51及び二次加熱炉48に備えるベル
トコンベア49は共に同じ構成のもので、モータ36の
回転制御によって任意の速度に調整され、これらは、押
出成形機11の押出速度に合せて同じ搬送速度となるよ
うに調整されている。The belt conveyor 49 provided in the microwave heating furnace 51 and the secondary heating furnace 48 both have the same configuration, and are adjusted to an arbitrary speed by the rotation control of the motor 36, and these are adjusted according to the extrusion speed of the extruder 11. It is adjusted to have the same transport speed.
ところで、押出ゴム22がソリッドゴムを対象とする場
合は、加硫反応させるのみであるから、上記のように各
ベルトコンベア49は共に押出成形時の押出速度に同調
させればよいが、発泡成形品となるスポンジゴムを生産
する場合は、加硫反応に加えて発泡反応が起きるため、
押出ゴム22が膨張によって伸長し、その結果、各ベル
トコンベア49を上記のように同一速度としたのでは生
産されたスポンジゴムの形状が変形してしまうという問
題がある。By the way, when the extruded rubber 22 is a solid rubber, only the vulcanization reaction is performed. Therefore, both belt conveyors 49 may be synchronized with the extrusion speed at the time of extrusion molding as described above. When producing sponge rubber as a product, since a foaming reaction occurs in addition to the vulcanization reaction,
The extruded rubber 22 expands due to expansion, and as a result, there is a problem that the shape of the sponge rubber produced will be deformed if the belt conveyors 49 are set to the same speed as described above.
この問題を解決するために、実際にはスポンジゴムを生
産する場合は、マイクロ波加熱炉以後に配置する二次加
熱炉のベルトコンベア49は搬送方向に並べた数本のベ
ルトに分割し、分解した各コンベアの素度を搬送方向に
したがって順次増加させる構成として、発泡反応の膨張
による伸びを伴って搬送し、生産されたスポンジゴムの
形状を均一に保つようにしてある。In order to solve this problem, in the case of actually producing sponge rubber, the belt conveyor 49 of the secondary heating furnace arranged after the microwave heating furnace is divided into several belts arranged in the conveying direction and decomposed. As a constitution in which the basicity of each of the conveyors is sequentially increased in the conveying direction, the conveyer is conveyed with the expansion due to the expansion of the foaming reaction so that the shape of the sponge rubber produced is kept uniform.
「発明が解決しようとする課題」 上記のように加硫装置50においては、押出成形機11
より押出された熱を持った押出ゴム22が直接にマイク
ロ波加熱炉に搬入されて加熱されるわけではなく、ベル
トコンベアなどの搬送機構を介してマイクロ波加熱炉へ
搬入されるため、スポンジゴムを製造する上で次の3点
の問題があある。[Problems to be Solved by the Invention] As described above, in the vulcanizing apparatus 50, the extruder 11 is used.
The extruded rubber 22 having more extruded heat is not directly carried into the microwave heating furnace and heated, but is carried into the microwave heating furnace via a conveyor mechanism such as a belt conveyor, so that sponge rubber is used. There are the following three problems in manufacturing the.
第1の問題点は、ベルトコンベア49と接触している押
出ゴム22の部分がこのベルトコンベア49によって温
度低下を生ずることである。The first problem is that the portion of the extruded rubber 22 that is in contact with the belt conveyor 49 causes a temperature drop due to the belt conveyor 49.
これは、ベルトコンベア49と接触する押出ゴム22の
部分には、熱風発生機による熱風がベルトコンベア49
によって遮断されて有効に作用しないこと、また、ベル
トコンベア49は一旦外部に出てマイクロ波加熱炉に入
るため、ほぼ常温で押出ゴム22を送致することとな
り、押出ゴム22より熱を奪うことに原因する。In the portion of the extruded rubber 22 that comes into contact with the belt conveyor 49, hot air generated by the hot air generator is conveyed to the belt conveyor 49.
Is blocked by the belt conveyor 49 and does not work effectively, and since the belt conveyor 49 once exits the outside and enters the microwave heating furnace, the extruded rubber 22 is delivered at about room temperature, and heat is taken from the extruded rubber 22. To cause.
その上、ゴム、プラスチックなどの誘電体は温度上昇と
共に高周波損失が増大する傾向を持っており、また、マ
イクロ波は高周波損失の大きい方に選択的に吸収される
性質を有するため、マイクロ波加熱以前に押出ゴム22
に温度差が生じておれば、マイクロ波加熱時には偏加熱
が増々大きくなり、如何に均一なマイクロ波電場で加熱
を行なっても偏加熱はさけられないことになる。In addition, dielectric materials such as rubber and plastic tend to increase high-frequency loss with increasing temperature, and because microwaves have the property of being selectively absorbed by the ones with higher high-frequency loss, microwave heating Previously extruded rubber 22
If there is a temperature difference between the two, uneven heating will increase more and more during microwave heating, and even if heating is performed in a uniform microwave electric field, uneven heating cannot be avoided.
一般にマイクロ波加熱炉51内では、150〜300℃
の熱風を併用したり、マイクロ波加熱炉51に入る直前
でベルトコンベア49の接触面となる押出ゴム個所を近
赤外線のエネルギーで予熱するなどの手段を講じて押出
ゴム22の均一加熱化を計っているが、ベルトコンベア
49が接触する押出ゴム22の部分はコンベアに対して
移動せずに同一個所となって加硫と発泡が進行するた
め、この影響による偏加熱を省くことできなかった。特
に、この現象は高発泡のスポジゴムを生産するときに顕
著に見られ、例えば、第8図(a)に示す如く、押出ゴ
ム22を均一な肉厚のホース状チューブに押出した場合
でも、第8図(b)に示すように大きく偏肉してしま
う。この現象はベルト接触部の数度の温度差でも発泡倍
率の違いによって発生し、また、長さ方向では直線状で
はなく大きく湾曲(キャンバー)してしまい良好なスポ
ンジゴム製品を生産することが難しい。Generally, in the microwave heating furnace 51, 150 to 300 ° C.
The heating of the extruded rubber 22 is made uniform by using such hot air as well as preheating the extruded rubber portion which becomes the contact surface of the belt conveyor 49 with the energy of near infrared rays immediately before entering the microwave heating furnace 51. However, the portion of the extruded rubber 22 with which the belt conveyor 49 comes into contact does not move with respect to the conveyor, but remains in the same place, and vulcanization and foaming proceed, so that it was not possible to eliminate uneven heating due to this effect. This phenomenon is particularly noticeable when producing a highly foamed spigot rubber. For example, as shown in FIG. 8 (a), even when the extruded rubber 22 is extruded into a hose-shaped tube having a uniform wall thickness, As shown in FIG. 8 (b), the thickness is largely uneven. This phenomenon occurs due to the difference in foaming ratio even at a temperature difference of several degrees at the belt contact portion, and it is difficult to produce a good sponge rubber product because it is not linear but is greatly curved (camber) in the length direction. .
第2の問題点は、押出ゴム22が発泡反応によって断面
方向(径方向)に膨張して伸長する際、ベルトコンベア
49との摩擦抵抗に起因して生ずるスポンジゴム製品の
変形である。The second problem is the deformation of the sponge rubber product caused by the frictional resistance with the belt conveyor 49 when the extruded rubber 22 expands and expands in the cross-sectional direction (radial direction) by the foaming reaction.
押出ゴム22はマイクロ波加熱炉51でマイクロ波と熱
風のエネルギーを受けて昇温する。このとき、原料に配
合されている発泡剤が分解を始め、ガスが発生して発泡
体へと進行を開始し、二次加熱炉48でスポンジ状の押
出成形体となる。The extruded rubber 22 is heated in the microwave heating furnace 51 by receiving microwaves and hot air energy. At this time, the foaming agent mixed in the raw material starts to decompose, gas is generated and starts to progress to the foamed body, and in the secondary heating furnace 48, a sponge-like extruded body is formed.
しかしながら、ベルトコンベア49と接触している押出
ゴム22の部分には摩擦抵抗があるため、このゴム22
がスムーズに滑ることができず、例えば、押出成形機1
1からは第9図(a)に示すような正確な矩形断面の押
出ゴム22が押出された場合でも、第9図(b)に示し
たように扇状断面に変形する。However, since the portion of the extruded rubber 22 that is in contact with the belt conveyor 49 has frictional resistance, this rubber 22
Cannot slide smoothly, for example, extruder 1
Even if the extruded rubber 22 having an accurate rectangular cross section as shown in FIG. 9 (a) is extruded from No. 1, it is transformed into a fan-shaped cross section as shown in FIG. 9 (b).
これは、発泡反応による膨張が自由な個所は正規な発泡
となるが、摩擦抵抗を受ける個所は膨張が抑制されるた
めである。具体的には、第9図上のL、R点、つまり、
ベルトコンベア49の左右側に当るところでは滑りが抑
制されるために、中央部c点が上方に伸び上げられるよ
うになって図示するように断面形状が湾曲する。This is because the part where the expansion is free due to the foaming reaction becomes the normal foaming, but the part where the frictional resistance is applied suppresses the expansion. Specifically, points L and R on FIG. 9, that is,
Since slippage is suppressed where the belt conveyor 49 hits the left and right sides, the central portion c is extended upward and the cross-sectional shape is curved as shown in the figure.
この現象はゴム原料の配合によって当然異なり、ゴム粘
度の低いゴムほど大きく顕著に表われる。現在、この滑
り抵抗を可能なかぎり少なくして変形を防止するため、
炭酸カルシウムの粉を付けたりしているが、粉塵による
作業環境の面から好ましくなく、また、充分な対策とは
言えない。This phenomenon naturally varies depending on the compounding of the rubber raw material, and is more remarkable when the rubber has a lower rubber viscosity. Currently, in order to prevent this deformation by reducing this slip resistance as much as possible,
Calcium carbonate powder is added, but it is not preferable from the viewpoint of working environment due to dust, and it cannot be said that it is a sufficient countermeasure.
第3の問題点は、押出ゴム22の長さ方向の伸びによっ
て生ずる変形である。The third problem is the deformation caused by the elongation of the extruded rubber 22 in the length direction.
この伸びは上記した断面方向の伸びよりも大きく、この
伸びによる変形を防止するためには、ベルトコンベア4
9上で発泡する押出ゴム22をいかに蛇行させないで搬
送させるかと言う点につきる。This elongation is greater than the above-mentioned elongation in the cross-sectional direction, and in order to prevent deformation due to this elongation, the belt conveyor 4
The point is how the extruded rubber 22 foamed on the sheet 9 is conveyed without meandering.
したがって、ソリッドゴムを生産する場合のように、各
加熱炉の一体のベルトコンベア49ではその蛇行を防ぐ
ことができないため、既に述べたように、数本のベルト
コンベアに分解し、各々のコンベアを順次増速させ、押
出ゴム22を引っ張りぎみに搬送するようにし上記蛇行
を防止している。ベルトコンベアの分割数は押出ゴム2
2の発泡倍率によって異なるが、3〜6分割程度が一般
的である。Therefore, as in the case of producing solid rubber, the meandering belt conveyor 49 of each heating furnace cannot prevent the meandering, so as already mentioned, it is disassembled into several belt conveyors and each conveyor is The above-mentioned meandering is prevented by gradually increasing the speed to convey the extruded rubber 22 to the tension. The number of divisions of the belt conveyor is extruded rubber 2
Although it depends on the foaming ratio of 2, it is generally about 3 to 6 divisions.
しかし、安定した良好なスポジゴムを生産するには、各
ベルトコンベア49、引取機16の速度、温度条件など
の調整に高度の熟練を要し、また、歩留まりの点、ゴム
自身の自重による変形からくる形状の限界があり、現在
の加硫装置の設備では問題が多い。However, in order to produce a stable and good spigot rubber, a high level of skill is required to adjust the speed of each belt conveyor 49 and the take-off machine 16, temperature conditions, and the like, and in terms of yield and deformation due to the weight of the rubber itself. Since there is a limit to the shape of the vulcanizer, there are many problems with the current equipment of vulcanization equipment.
そこで、本発明の目的は上記した問題点を解決し、均一
の形状で安定したスポンジゴムの生産が可能な加硫装置
を開発することにある。Therefore, an object of the present invention is to solve the above-mentioned problems and to develop a vulcanizing apparatus capable of stably producing sponge rubber with a uniform shape.
「課題を解決するための手段」 本発明は上記課題を解決するため、第1の発明として、
マイクロ波の照射及び熱風により未加硫ゴム押出成形品
を連続に加硫、発泡させる装置において、マイクロ波加
熱炉内及び二次加熱炉内、未加硫ゴムの押出成形品を搬
送させる多数の搬送ローラを搬送方向に沿って順次所定
の間隔で配置すると共に、これら搬送ローラ各々には各
々の加熱炉内でモータ駆動されるチエーンまたは歯付ベ
ルトによって一連に回転駆動するスプロケツトを軸支
し、未加硫ゴム押出成形品が発泡反応によって変形する
搬送路部所に位置する搬送ローラをそのスプロケツトの
歯数を変えて回転速度を変える構成としたことを特徴と
する未加硫ゴム押出成形品の連続加硫装置を提案する。"Means for Solving the Problems" The present invention is to solve the above problems, and as a first invention,
In an apparatus for continuously vulcanizing and foaming unvulcanized rubber extruded products by microwave irradiation and hot air, a large number of devices for conveying unvulcanized rubber extruded products in a microwave heating furnace and a secondary heating furnace are used. The transport rollers are sequentially arranged at predetermined intervals along the transport direction, and a sprocket, which is rotatably driven in series by a chain or a toothed belt driven by a motor in each heating furnace, is axially supported on each of the transport rollers. The unvulcanized rubber extruded product is characterized in that the unrolled rubber extruded product is configured to change the rotation speed by changing the number of teeth of the sprocket of the carrying roller located in the carrying path portion where it is deformed by the foaming reaction. We propose a continuous vulcanization system.
第2の発明として、マイクロ波の照射及び熱風により未
加硫ゴム押出成形品を連続に加硫、発泡させる装置にお
いて、マイクロ波加熱炉内及び二次加熱炉内、未加硫ゴ
ムの押出成形品を搬送させる多数の搬送ローラを搬送方
向に沿って順次所定の間隔で配置すると共に、未加硫ゴ
ム押出成形品が発泡反応によって変形する搬送路部所に
位置する搬送ローラのローラ径を変え、多数の搬送ロー
ラを同じ回転数で駆動する構成としたことを特徴とする
未加硫ゴム押出成形品の連続加硫装置を提案する。As a second invention, in an apparatus for continuously vulcanizing and foaming an unvulcanized rubber extruded product by irradiation of microwaves and hot air, extrusion molding of unvulcanized rubber in a microwave heating furnace and a secondary heating furnace. A large number of transport rollers for transporting the product are sequentially arranged at predetermined intervals along the transport direction, and the roller diameter of the transport roller located in the transport path where the unvulcanized rubber extruded product is deformed by the foaming reaction is changed. The present invention proposes a continuous vulcanization apparatus for unvulcanized rubber extruded products, characterized in that a large number of conveying rollers are driven at the same number of revolutions.
第3の発明として、マイクロ波の照射及び熱風により未
加硫ゴム押出成形品を連続に加硫、発泡させる装置にお
いて、マイクロ波加熱炉内及び二次加熱炉内に、未加硫
ゴムの押出成形品を搬送させる多数の搬送ローラを搬送
方向に沿って順次所定の間隔で配置すると共に、未加硫
ゴム押出成形品が発泡反応による膨張が大きい部所の一
定の範囲に配列された各搬送ローラを搬送方向に沿って
順次低く配置して未加硫ゴム押出成形品の搬送路を水平
面より所定の角度で傾斜させる構成としたことを特徴と
する未加硫ゴム押出成形品の連続加硫装置を提案する。As a third invention, in an apparatus for continuously vulcanizing and foaming an unvulcanized rubber extruded product by irradiation of microwaves and hot air, extrusion of unvulcanized rubber into a microwave heating furnace and a secondary heating furnace. A large number of conveying rollers for conveying molded products are sequentially arranged at predetermined intervals along the conveying direction, and the unvulcanized rubber extruded products are arranged in a certain range where expansion due to the foaming reaction is large. Continuous vulcanization of an unvulcanized rubber extruded product, characterized in that rollers are sequentially arranged lower along the conveying direction and the conveying path of the unvulcanized rubber extruded product is inclined at a predetermined angle from the horizontal plane. Suggest a device.
「作 用」 押出成形機から押出された未加硫ゴム押出成形品はマイ
クロ波加熱炉及び二次加熱炉の加熱室内を搬送ローラに
よって移送され、この間にマイクロ波エネルギーと熱風
エネルギーにより加硫反応と発泡反応が行なわれる。"Working" The unvulcanized rubber extruded product extruded from the extruder is transferred by the conveyor rollers in the heating chamber of the microwave heating furnace and the secondary heating furnace, during which vulcanization reaction is caused by microwave energy and hot air energy. And a foaming reaction is carried out.
そして、発泡反応が生ずる搬送炉部所の搬送ローラがス
プロケツトの歯数にしたがつて回転速度を変え、また、
スプロケツト径にしたがって周速を変えるので、発泡反
応による伸びに応じて未加硫ゴム押出成形品が搬送さ
れ、均一の形状の製品が得られる。上記工程では、押出
された未加硫ゴム押出成形品が回転する搬送ローラの面
上を次々と移って搬送されるため、各搬送ローラと接し
ている時間が瞬時となり、また、前段の搬送ローラから
次段の搬送ローラに乗り移る間発泡による伸びが自由に
なる。Then, the conveying roller in the conveying furnace where the foaming reaction occurs changes the rotation speed according to the number of teeth of the sprocket, and
Since the peripheral speed is changed according to the diameter of the sprocket, the unvulcanized rubber extruded product is conveyed according to the elongation due to the foaming reaction, and a product having a uniform shape is obtained. In the above process, since the extruded unvulcanized rubber extruded product is successively transferred and conveyed on the surface of the rotating conveying roller, the time in contact with each conveying roller is instantaneous, and the conveying roller of the preceding stage is also present. The expansion due to foaming becomes free during transfer from the next transfer roller to the transfer roller.
このことから、未加硫ゴム押出成形品の断面方向に伸び
が平均した膨張となる。From this, the expansion is averaged in the cross-sectional direction of the unvulcanized rubber extruded product.
また、各搬送ローラ間では未加硫ゴム押出成形品がロー
ラに対して非接触となるから、マイクロ波加熱する上に
も、熱風加熱する上にも搬送機構によって熱が奪われず
偏加熱を起すことがなく、その上、各搬送ローラは加熱
炉内にあるので、熱風の雰囲気温度まで昇温されてお
り、各搬送ローラから未加硫ゴム押出成形品に対して熱
を与える傾向に働く。その結果、加熱むらから生ずる発
泡むらが生ぜず、生産されたスポンジゴムに形状のバラ
ツキがない。In addition, since the unvulcanized rubber extruded product does not come into contact with the rollers between the transport rollers, heat is not taken away by the transport mechanism in both microwave heating and hot air heating, which causes uneven heating. In addition, since each conveying roller is in the heating furnace, the temperature is raised to the atmospheric temperature of the hot air, and the conveying rollers tend to apply heat to the unvulcanized rubber extruded product. As a result, uneven foaming caused by uneven heating does not occur, and the produced sponge rubber has no variation in shape.
また、発泡反応による膨張が最も大きい部所の各搬送ロ
ーラを水平面より、例えば、15〜45度範囲内で搬送
方向に沿って順次低くなるように構成すれば、未加硫ゴ
ム押出成形品の自重の影響が少なくなり発泡反応による
長さ方向の伸びが均一となり、未加硫ゴム押出成形品が
蛇行なしに全体が直線状に伸びる。Further, if each conveying roller at the portion where the expansion due to the foaming reaction is the largest is gradually lowered from the horizontal plane along the conveying direction within the range of, for example, 15 to 45 degrees, an unvulcanized rubber extruded product can be obtained. The influence of its own weight is reduced and the expansion in the length direction due to the foaming reaction becomes uniform, and the entire unvulcanized rubber extruded product expands linearly without meandering.
「実施例」 次に、本発明の実施例について図面に沿って説明する。[Examples] Next, examples of the present invention will be described with reference to the drawings.
第1図は第1実施例を示す加硫装置の構成図である。FIG. 1 is a block diagram of a vulcanizing apparatus showing the first embodiment.
本加硫装置10は押出成形機11、マイクロ波加熱炉1
2、NO.1二次加熱炉13、NO.2二次加熱炉1
4、NO.3二次加熱炉15及び連続引取機16から構
成されている。The main vulcanizer 10 is an extrusion molding machine 11 and a microwave heating furnace 1.
2, NO. 1 secondary heating furnace 13, NO. 2 Secondary heating furnace 1
4, NO. It is composed of 3 secondary heating furnaces 15 and a continuous take-up machine 16.
上記構成において、押出成形機11、連続引取機16は
第7図に示した従来例のものと同じ構成であり、また、
同様にマイクロ波加熱炉12のマイクロ波発振器24、
NN.1〜NO.3の二次加熱炉の熱風発生機は従来例
に示したマイクロ波加熱炉51、二次加熱炉48に用い
られているものと同じ構成である。In the above structure, the extrusion molding machine 11 and the continuous take-up machine 16 have the same structure as that of the conventional example shown in FIG.
Similarly, the microwave oscillator 24 of the microwave heating furnace 12,
NN. 1-NO. The hot air generator of the secondary heating furnace of No. 3 has the same configuration as that used in the microwave heating furnace 51 and the secondary heating furnace 48 shown in the conventional example.
したがつて、従来例に示した部所と同じ構成の部所は同
一符号を付し、既に従来例にて説明した個所は省略す
る。Therefore, the parts having the same configurations as those shown in the conventional example are designated by the same reference numerals, and the parts already described in the conventional example are omitted.
第2図はマイクロ波加熱炉12の正面図、第3図は第2
図上のA−A線に沿って切断した簡略断面図である。2 is a front view of the microwave heating furnace 12, and FIG. 3 is a second view.
It is the simplified sectional drawing cut | disconnected along the AA line on a figure.
この図のように、マイクロ波加熱炉12はマイクロ波発
振器24、導波管25、加熱室26、ヒータ27と送風
機28からなる熱風発生機、搬送ローラ駆動機構29な
どから構成してある。As shown in this figure, the microwave heating furnace 12 is composed of a microwave oscillator 24, a waveguide 25, a heating chamber 26, a hot air generator including a heater 27 and a blower 28, a transport roller driving mechanism 29, and the like.
マイクロ波発振機24は別設されており、導波管29を
通じて加熱室26内に、その上部からマイクロ波エネル
ギーを照射する。The microwave oscillator 24 is separately provided and irradiates microwave energy from above into the heating chamber 26 through the waveguide 29.
加熱室26は第2図において左側面から右側面に貫通す
るトンネル状の室で、左右側面に近接する部所は外部へ
の導波漏洩を防ぐため狭い空間である入口26a、出口
26bを形成し、加熱室26の全周囲は保温部材による
保温壁30で囲まれている。The heating chamber 26 is a tunnel-shaped chamber that penetrates from the left side surface to the right side surface in FIG. 2, and portions near the left and right side surfaces form an inlet 26a and an outlet 26b that are narrow spaces to prevent waveguide leakage to the outside. However, the entire circumference of the heating chamber 26 is surrounded by a heat insulating wall 30 formed by a heat insulating member.
また、加熱室26の天井中央にはマイクロ波エネルギー
を照射するための導波管25の先端25aが接続してあ
り、加熱室26の底面には、熱風通路31に通じる2ケ
所の熱風口31a,31bが設けてある。Further, a tip end 25a of a waveguide 25 for irradiating microwave energy is connected to the center of the ceiling of the heating chamber 26, and two hot air outlets 31a communicating with the hot air passage 31 are provided on the bottom surface of the heating chamber 26. , 31b are provided.
さらに、加熱室26は、正面中央に保守点検用の扉32
が取付けられ、この扉32は支持軸金具32a,32b
を支点としてハンドル32c,32dによって手前に開
閉自在にしてある。Furthermore, the heating chamber 26 has a door 32 for maintenance and inspection at the center of the front.
Is attached, and the door 32 is provided with support shaft metal fittings 32a, 32b.
With the fulcrum as a fulcrum, the handles 32c and 32d are openable and closable forward.
なお、加熱室26は架台33上に固定されており、架台
33は底面に取付た固定金具33aによって地面に固定
される。The heating chamber 26 is fixed on a pedestal 33, and the pedestal 33 is fixed to the ground by a fixing fitting 33a attached to the bottom surface.
ヒータ27は、その内部に設けた電熱ヒータエレメント
27a,27bへの給電によって熱を発生させるもの
で、この熱エネルギーは、送風機28によって熱風通路
31を経て熱風口31a,31bから加熱室26に放出
される。The heater 27 generates heat by supplying power to the electrothermal heater elements 27a and 27b provided therein, and this heat energy is discharged to the heating chamber 26 from the hot air outlets 31a and 31b by the blower 28 through the hot air passage 31. To be done.
なお、ヒータ27、熱風通路31は加熱室26と同窓に
保温部材により囲まれている。The heater 27 and the hot air passage 31 are surrounded by a heat insulating member in the same window as the heating chamber 26.
また、ヒータ27及び送風機28からなる熱風発生機は
架台33の底面上に固定される。The hot air generator including the heater 27 and the blower 28 is fixed on the bottom surface of the pedestal 33.
搬送ローラ駆動機構29は、本実施例においては18個
の搬送ローラユニット34と、チエーン35、モータ3
6などから構成してある。In this embodiment, the transport roller drive mechanism 29 includes 18 transport roller units 34, a chain 35, and a motor 3.
It is composed of 6 and the like.
搬送ローラユニット34は搬送ローラ23、カップリン
グ39、スプロケット37などからなり、このユニット
34が加熱室26のトンネルの長手方向と直交する方向
に、トンネルの入口26aから出口26bにかけて一定
の間隔で加熱室26の底面上に18個配設され、さら
に、各々の搬送ローラユニット34に備える搬送ローラ
23は加熱室26に位置させ、スプロケット37は加熱
室26の外部(第2図の裏面側)に設けてある。The transport roller unit 34 includes a transport roller 23, a coupling 39, a sprocket 37, and the like. The unit 34 heats the tunnel in the heating chamber 26 at a constant interval from the entrance 26a to the exit 26b in the direction orthogonal to the longitudinal direction of the tunnel. Eighteen chambers are provided on the bottom surface of the chamber 26, and further, the transport rollers 23 provided in each of the transport roller units 34 are located in the heating chamber 26, and the sprockets 37 are provided outside the heating chamber 26 (on the rear surface side in FIG. 2). It is provided.
すなわち、搬送ローラ23の両側のシャフト23a、2
3bは加熱室26の底面より立ち上らせた一対の支持具
38a、38bの軸受に軸支し、搬送ローラ23の一方
のシャフト23bがカップリング39を介して外部シャ
フト40と連結している。That is, the shafts 23a, 2 on both sides of the transport roller 23
3b is rotatably supported by bearings of a pair of supporting members 38a and 38b raised from the bottom surface of the heating chamber 26, and one shaft 23b of the conveying roller 23 is connected to an external shaft 40 via a coupling 39. .
さらに、この外部シャフト40はマイクロ波シール41
を経て加熱室26の外側部の第1回転軸受42、第2回
転軸受43を貫通してスプロケット37に連結してい
る。In addition, the outer shaft 40 has a microwave seal 41.
Through the first rotary bearing 42 and the second rotary bearing 43 on the outer side of the heating chamber 26, and is connected to the sprocket 37.
したがって、スプロケット37が回転すれば、搬送ロー
ラ23を回転することができる。Therefore, when the sprocket 37 rotates, the transport roller 23 can rotate.
なお、搬送ローラ23は、金属性の円柱表面にテフロン
チューブの被覆加工を施したもので、ゴム材がローラ表
面に付着して汚れないように配慮してある。The transport roller 23 has a metal cylinder surface coated with a Teflon tube so that the rubber material does not adhere to the roller surface and become dirty.
また、各々の搬送ローラユニット34の搬送ローラ23
の間隔は100〜180mmとしてある。In addition, the transport roller 23 of each transport roller unit 34
Is 100 to 180 mm.
第4図は搬送ローラ駆動機構29の説明図である。この
図は、マイクロ波加熱炉12の裏側から見た図で、図示
する左側のスプロケット37−18がトンネルの出口26
b側、右側のスプロケット37−1がトンネルの入口2
6a側に各々位置し、合計18個のスプロケットが所定
間隔で配置してある。FIG. 4 is an explanatory diagram of the transport roller driving mechanism 29. This figure is a view seen from the back side of the microwave oven 12, the left side of the sprocket 37-18 tunnel illustrated outlet 26
b side, the right side of the sprocket 37 - 1 is the tunnel ingress 2
Each of them is located on the 6a side, and a total of 18 sprockets are arranged at predetermined intervals.
これらスプロケット37−1〜37−18にはモータ36
の回転歯車36aを経てチエーン35が掛けられてい
る。These sprockets 37- 1 ~37- 18 motor 36
The chain 35 is hung via the rotary gear 36a of the.
したがって、モータ36が回転するとチエーン35が図
示矢印方向に移行し、モータ36の回転数に比例してス
プロケット37−1〜37−18を連動回転させる。Thus, the chain 35 when the motor 36 rotates is shifted to the arrow direction, in proportion to the rotational speed of the motor 36 is interlocked rotation of the sprocket 37- 1 ~37- 18.
ここで、スプロケット37−1〜37−18の歯数が同数
であれば、スプロケツトは全て同一の回転数となり、特
定のスプロケットの歯数を増加させれば、歯数に比例し
て該当するスプロケット37の回転数が増加する。Here, if the sprocket 37 - 1 ~37- 18 number of teeth of the same number, sprockets become all the same rotational speed, by increasing the number of teeth of a particular sprocket corresponds proportionally to the number of teeth sprocket The number of rotations of 37 increases.
また、スプロケット37は個々独立に歯数の異なるスプ
ロケット37に容易に交換できるようになっている。The sprockets 37 can be easily replaced individually with sprockets 37 having different numbers of teeth.
すなわち、加硫と発泡とが起る部所では、発泡反応によ
る押出ゴム22の伸びを伴って搬送できるように搬送ロ
ーラユニット34毎に各スプロケット37の歯数を定
め、該当する搬送ローラユニット34毎に定められた歯
数のスプロケット37を取付ける。That is, at the place where vulcanization and foaming occur, the number of teeth of each sprocket 37 is determined for each transport roller unit 34 so that the extruded rubber 22 can be transported along with the expansion due to the foaming reaction, and the corresponding transport roller unit 34 is determined. The sprocket 37 having a predetermined number of teeth is attached.
なお、複数の搬送ローラユニット34を単位としたグル
ープを設け、各グループ毎に搬送ローラ23の回転数を
変えるように、スプロケット37を取付けてもよい。It should be noted that a group may be provided in which a plurality of transport roller units 34 are used as a unit, and the sprocket 37 may be attached so that the rotation speed of the transport roller 23 is changed for each group.
また、押出ゴム22を同一速度で搬送する必要のある部
所では押出し時の押出ゴム22の速度と同一の速度とな
るようにスプロケット37の歯数を定め、この歯数のス
プロケット37を上記部所にある全部の搬送ローラユニ
ット34に取付る。例えば、マイクロ波エネルギーが与
えられるまでは押出ゴム22の発泡が少ないから、押出
成形機11とマイクロ波エネルギーを照射する位置との
間に配置した各搬送ローラは同一の回転速度とすること
ができる。Further, at a portion where it is necessary to convey the extruded rubber 22 at the same speed, the number of teeth of the sprocket 37 is determined so that the speed is the same as the speed of the extruded rubber 22 at the time of extruding, and the sprocket 37 having the number of teeth is set to the above-mentioned part Attach to all transport roller units 34 in place. For example, since the foaming of the extruded rubber 22 is small until the microwave energy is applied, the conveying rollers arranged between the extruder 11 and the position where the microwave energy is irradiated can have the same rotation speed. .
なお、モータ36は架台33の底面に設けた取付台33
b上に固定すると共に、チエーン35のガイド歯車44
及びタルミ防止ガイド45が設けてある。The motor 36 is mounted on the bottom surface of the pedestal 33.
b and the guide gear 44 of the chain 35
And a tarmi prevention guide 45 is provided.
本実施例ではスプロケット37をチエーンによって回転
させているが歯付ベルトで回転させる構成でもよい。Although the sprocket 37 is rotated by the chain in this embodiment, it may be rotated by the toothed belt.
次に、NO.1〜NO.3二次加熱炉13、14、15
について説明する。Next, NO. 1-NO. 3 Secondary heating furnaces 13, 14, 15
Will be described.
これら二次加熱炉13、14、15は上記したマイクロ
波加熱炉12からマイクロ波発振器24と導波管25と
を除いた構成となっており、第1図で共通の符号で示し
たように加熱室26、ヒータ27と送風機28からなる
熱風発生機、搬送ローラ駆動機構29を備えている。These secondary heating furnaces 13, 14 and 15 have a configuration in which the microwave oscillator 24 and the waveguide 25 are removed from the microwave heating furnace 12 described above, and as shown by common reference numerals in FIG. A heating chamber 26, a hot air generator including a heater 27 and a blower 28, and a transport roller driving mechanism 29 are provided.
ただし、押出ゴム22の種類によって発泡反応による伸
びとその発生個所が異なるから、発泡反応による伸びに
応じて上記同様に搬送ローラ23の回転数を調整する必
要がある。However, since the elongation due to the foaming reaction and the location where it is generated differ depending on the type of the extruded rubber 22, it is necessary to adjust the rotation speed of the transport roller 23 in the same manner as above according to the elongation due to the foaming reaction.
次に、以上のように構成した第1実施例の加硫装置10
の動作について説明する。Next, the vulcanizing apparatus 10 of the first embodiment configured as described above.
The operation of will be described.
先ず、従来例で説明したように、押出成形機11の供給
口17からシリンダ18内に投入された押出ゴム22の
原料は、モータ19の回転駆動によるスクリュー20に
よって移送され成形ダイス21から成形され押出され
る。First, as described in the conventional example, the raw material of the extruded rubber 22 charged into the cylinder 18 from the supply port 17 of the extrusion molding machine 11 is transferred by the screw 20 driven by the rotation of the motor 19 and molded from the molding die 21. Extruded.
押出成形機11から押出された細長形の押出ゴム22
は、搬送ローラ駆動機構29の搬送ローラ23の回転に
よって順次マイクロ波加熱室12、NO.1〜NO.3
二次加熱炉13、14、15の各加熱室26内を通過し
て連続引取機16で引き取られる。Elongated extruded rubber 22 extruded from the extrusion molding machine 11
The microwave heating chamber 12, the NO. 1-NO. Three
After passing through the respective heating chambers 26 of the secondary heating furnaces 13, 14, 15 and taken by the continuous take-up machine 16.
成形工程において、マイクロ波加熱炉12の加熱室26
内では、押出ゴム22がマイクロ波発振器24からのマ
イクロ波の照射による内部発熱エネルギーと熱風発生機
からの熱風エネルギーにより適正な加硫温度まで急速に
加温される。In the molding process, the heating chamber 26 of the microwave heating furnace 12
In the inside, the extruded rubber 22 is rapidly heated to an appropriate vulcanization temperature by the internal heating energy due to the irradiation of microwaves from the microwave oscillator 24 and the hot air energy from the hot air generator.
続いて、NO.1〜NO.3二次加熱炉13、14、1
5の各加熱室26内では、押出ゴム22が熱風発生機か
らの熱風エネルギーによって上記加硫温度を維持して加
硫反応が行なわれ、同時に発泡反応が行なわれる。Then, NO. 1-NO. 3 Secondary heating furnaces 13, 14, 1
In each heating chamber 26 of No. 5, the extruded rubber 22 performs the vulcanization reaction while maintaining the vulcanization temperature by the hot air energy from the hot air generator, and at the same time the foaming reaction is performed.
上記において、加硫反応工程だけの部所の各搬送ローラ
23は同一の回転としてあり、押出ゴム22は同一速度
で搬送される。また、加硫反応工程に加えて発泡反応工
程がある部所の各搬送ローラ23は発泡反応による押出
ゴム22の伸びを伴って搬送するように搬送方向に順次
回転数を増加させてあり、押出ゴム22の搬送速度が早
められる。これにより、押出ゴム22は発泡反応により
膨張して伸びても、その部所の押出ゴム22は搬送速度
が増加しているから、蛇行せずに良好な形状のスポンジ
ンゴムが生産される。In the above description, the respective conveying rollers 23 at the portions only in the vulcanization reaction step are rotated in the same manner, and the extruded rubber 22 is conveyed at the same speed. In addition, in each of the conveying rollers 23 at a portion having a foaming reaction step in addition to the vulcanization reaction step, the number of rotations is sequentially increased in the conveying direction so as to convey the extruded rubber 22 along with the expansion due to the foaming reaction. The conveyance speed of the rubber 22 is increased. Thus, even if the extruded rubber 22 expands and expands due to the foaming reaction, the conveying speed of the extruded rubber 22 at that portion increases, so that a sponge rubber having a good shape can be produced without meandering.
さらに、押出ゴム22は所定間隔に配置された各々の搬
送ローラ23を順次乗り移っていくので、各搬送ローラ
23との接触面で熱を奪われることが少なく偏加熱の原
因となる温度差の発生が軽減される。Further, since the extruded rubber 22 successively moves over the respective conveying rollers 23 arranged at a predetermined interval, heat is not taken away at the contact surface with the respective conveying rollers 23, and a temperature difference that causes uneven heating is generated. Is reduced.
その上、各搬送ローラ23間では押出ゴム22の伸びが
自由となり発泡反応による膨張が均一化される。In addition, the extruded rubber 22 is allowed to expand freely between the conveying rollers 23, and the expansion due to the foaming reaction is made uniform.
このように、第1実施例の加硫装置10により均一な形
状のスポンジゴムを生産することができる。Thus, the vulcanizing apparatus 10 of the first embodiment can produce sponge rubber having a uniform shape.
第5図(a)、(b)は第2実施例を示す加硫装置の搬
送ローラ部の説明図である。FIGS. 5 (a) and 5 (b) are explanatory views of the conveying roller portion of the vulcanizing apparatus showing the second embodiment.
第2実施例は第1実施例における搬送ローラ23の部分
を特殊形状としたもので、この部分以外は第1実施例と
同じ構成である。In the second embodiment, the portion of the transport roller 23 in the first embodiment has a special shape, and has the same configuration as that of the first embodiment except for this portion.
すなわち、第1実施例では、円柱形状の搬送ローラ23
を使用しているが、第2実施例では第1実施例の搬送ロ
ーラ23に第5図(a)、(b)に示すスペーサリング
を一体的に設けた構成としてある。That is, in the first embodiment, the cylindrical conveying roller 23
However, in the second embodiment, the conveying roller 23 of the first embodiment is integrally provided with the spacer ring shown in FIGS. 5 (a) and 5 (b).
第1実施例の加硫装置10では、押出ゴム22の形状に
起因して自重によってその形状の一部が垂れ下がり変形
してしまうことがある。このため、第2実施例では、搬
送ローラ23に設けたスペーサリングによって押出ゴム
22の垂れ下がり部分を保持する。In the vulcanizer 10 of the first embodiment, due to the shape of the extruded rubber 22, part of the shape may sag and deform due to its own weight. Therefore, in the second embodiment, the hanging portion of the extruded rubber 22 is held by the spacer ring provided on the conveying roller 23.
スペーサリングの形状は押出ゴム22の形状によって異
なり、第5図(a)、(b)はその一例を示すもので、
押出ゴム22は断面形状を示している。The shape of the spacer ring depends on the shape of the extruded rubber 22, and FIGS. 5 (a) and 5 (b) show an example thereof.
The extruded rubber 22 has a sectional shape.
第5図(a)はスポンジゴムを生産する場合を示し、搬
送ローラ23に設けたスペーサリング46aの周囲面が
回転して押出ゴム22の一部22aを保持する。FIG. 5A shows a case where sponge rubber is produced, and the peripheral surface of the spacer ring 46a provided on the conveying roller 23 rotates to hold a part 22a of the extruded rubber 22.
第5図(b)はソリッドゴムを生産する場合を示し、搬
送ローラ23の両側にスペーサリング46b、46cを
一体的に設け、スポンジゴムの場合と同じように押出ゴ
ム22の一部22b、22cを保持する。FIG. 5 (b) shows a case where solid rubber is produced. Spacer rings 46b and 46c are integrally provided on both sides of the conveying roller 23, and the portions 22b and 22c of the extruded rubber 22 are the same as in the case of sponge rubber. Hold.
このようにして押出ゴム22の自重により変形しやすい
形状のものでも、良好な形状とすることができる。In this way, a good shape can be obtained even if the extruded rubber 22 has a shape that is easily deformed by its own weight.
第6図は第3実施例を示す加硫装置の構成図である。FIG. 6 is a block diagram of a vulcanizing apparatus showing a third embodiment.
この加硫装置47は、第1実施例に示した本装置10に
おいて、NO.1、NO.2二次加熱炉13、14の搬
送ローラ23の配列方法を水平面より角度θ(例えば、
15〜45度)の範囲で図のように傾斜させることと
し、その他は第1実施例に示す本装置10とほぼ同じ構
成としてある。This vulcanizer 47 is the same as the vulcanizer 47 of the present apparatus 10 shown in the first embodiment. 1, NO. 2 The arrangement method of the transport rollers 23 of the secondary heating furnaces 13 and 14 is changed from the horizontal plane by an angle θ (
The angle is in the range of 15 to 45 degrees as shown in the figure, and the other configurations are almost the same as those of the present apparatus 10 shown in the first embodiment.
第1実施例及び第2実施例においては、押出ゴム22が
水平に配列された搬送ローラ23上を搬送されていたた
め、比重が0.1前後の高発泡品であるスポンジゴムの
場合には単純な形状のものでも自重のため、変形を生じ
良好な形状とならなかった。In the first and second embodiments, since the extruded rubber 22 is conveyed on the horizontally arranged conveying rollers 23, it is simple in the case of sponge rubber which is a highly foamed product having a specific gravity of about 0.1. Even if the shape was good, it was deformed due to its own weight, and the shape was not good.
本実施例ではNO.1、NO.2二次加熱炉13、14
の搬送ローラ23上を移動する押出ゴム22の自重は垂
直方向に小さくなるから自重による変形が軽減される。In this embodiment, NO. 1, NO. 2 Secondary heating furnace 13, 14
Since the self-weight of the extruded rubber 22 moving on the conveying roller 23 is reduced in the vertical direction, the deformation due to the self-weight is reduced.
また、発泡反応による伸びに対しては搬送方向へ自重の
一部が均等に加えられるから蛇行現象が生じなく搬送方
向に直進する。Further, with respect to the elongation due to the foaming reaction, a part of its own weight is evenly applied in the carrying direction, so that the meandering phenomenon does not occur and the vehicle goes straight in the carrying direction.
なお、第3実施例ではNO.3二次加熱炉48はベルト
コンベア49により押出ゴム22を搬送している。In the third embodiment, NO. The third secondary heating furnace 48 conveys the extruded rubber 22 by a belt conveyor 49.
これは、NO.1、NO.2二次加熱炉13、14にお
いて押出ゴム22の変形の起因となる発泡現象が終了
し、NO.3二次加熱炉48では押出ゴム22を同一速
度で搬送すればよいからである。ただし、NO.3二次
加熱炉48は搬送ローラ方式でも構わない。This is NO. 1, NO. 2 In the secondary heating furnaces 13 and 14, the foaming phenomenon that causes the deformation of the extruded rubber 22 is completed, and NO. This is because the extruded rubber 22 may be conveyed at the same speed in the third secondary heating furnace 48. However, NO. The 3 secondary heating furnace 48 may be of a conveyance roller type.
最後に上記第3実施例の具体的なデータを上げて参考に
供することにする。Finally, the concrete data of the above-mentioned third embodiment will be raised for reference.
(1) 押出成形機、(株)三葉製作所製 * スクリュー径:φ70mm * 真空タイプ * ヘッド温度:50℃ (2) スポンジゴムの仕様 * ベースゴムポリマー:クロロプレンゴム * スポンジゴムの断面形状: 幅68mm×厚さ12mm(矩形) * スポンジゴムの比重:0.25 (3) マイクロ波加熱炉 * 出力:3.5KW * 周波数:2450±30MHz * 熱風温度:200℃ * 搬送ローラの条件 a)ローラ径:φ50mm b)ローラピッチ:150mm c)ローラ本数:25本 d)初段の搬送ローラと終段の搬送ロー ラまでの長さ:150×24=3600mm * ローラの速度:3m/min (4) 二次加熱炉 * NO.1二次加熱炉の条件 a)熱風温度:200℃ b)ローラ径:φ50mm c)ローラピッチ:150mm d)ローラ本数:12本 e)初段の搬送ローラと終段の搬送ロー ラまでの長さ:150×20=3000mm f)ローラの速度:3.6m/min * NO.2二次加熱炉の条件 a)熱風温度:200℃ b)ローラ径:φ50mm c)ローラピッチ:150mm d)ローラ本数:21本 e)初段の搬送ローラと終段の搬送ロー ラまでの長さ:150×20=3000mm f)ローラの速度:4.9m/min * NO.3二次加熱炉の条件 a)熱風温度:200℃ b)ベルトコンベア方式 c)ベルトコンベアの長さ: 8,000mm d)ベルトコンベアの速度: 5.2m/min (5) 連続引取機 * キャタビラ方式 * 取引速度:5.5m/min 以上、各実施例について説明したが、本発明を実施する
に際しては、各搬送ローラ23の回転数を変えずに、こ
れら各搬送ローラ23のローラ径を増減して搬送速度を
変える構成としてもよい。さらに、第1図〜第4図に示
す第1実施例の場合、押出ゴム22の形状が定まり伸び
がなくなることを条件にNO.3二次加熱炉15をベル
トコンベアの搬送機構に換えることも可能であり、ま
た、押出ゴム22の自重による変形を防ぐためにはマイ
クロ波加熱炉12を第3実施例同様に所定の角度で傾斜
させる構成とすることができる。(1) Extruder, manufactured by Mitsuba Seisakusho Co., Ltd. * Screw diameter: φ70 mm * Vacuum type * Head temperature: 50 ° C (2) Sponge rubber specifications * Base rubber polymer: Chloroprene rubber * Sponge rubber cross-sectional shape: Width 68mm × thickness 12mm (rectangle) * Specific gravity of sponge rubber: 0.25 (3) Microwave heating furnace * Output: 3.5KW * Frequency: 2450 ± 30MHz * Hot air temperature: 200 ° C * Conveyor roller condition a) Roller Diameter: φ50 mm b) Roller pitch: 150 mm c) Number of rollers: 25 d) Length between the first stage conveyor roller and the last stage conveyor roller: 150 x 24 = 3600 mm * Roller speed: 3 m / min (4) Secondary heating furnace * NO. 1 Secondary heating furnace conditions a) Hot air temperature: 200 ° C b) Roller diameter: φ50 mm c) Roller pitch: 150 mm d) Number of rollers: 12 e) Length between the first stage conveyor roller and the last stage conveyor roller : 150 × 20 = 3000 mm f) Roller speed: 3.6 m / min * NO. 2 Secondary heating furnace conditions a) Hot air temperature: 200 ° C b) Roller diameter: φ50 mm c) Roller pitch: 150 mm d) Number of rollers: 21 e) Length between the first stage conveyor roller and the last stage conveyor roller : 150 × 20 = 3000 mm f) Roller speed: 4.9 m / min * NO. 3 Conditions of secondary heating furnace a) Hot air temperature: 200 ° C b) Belt conveyor system c) Belt conveyor length: 8,000 mm d) Belt conveyor speed: 5.2 m / min (5) Continuous take-up machine * Caterpillar system * Transaction speed: 5.5 m / min Above, each embodiment has been described. However, when carrying out the present invention, the roller diameter of each of the transport rollers 23 is increased or decreased without changing the rotation speed of each of the transport rollers 23. Alternatively, the transport speed may be changed. Further, in the case of the first embodiment shown in FIG. 1 to FIG. 4, NO. 3 The secondary heating furnace 15 can be replaced with a conveyor mechanism of a belt conveyor, and in order to prevent the extruded rubber 22 from being deformed by its own weight, the microwave heating furnace 12 is inclined at a predetermined angle as in the third embodiment. It can be configured to.
なお、本発明の連続加硫装置はソリッドゴムの生産にも
利用することができる。The continuous vulcanizer of the present invention can also be used for producing solid rubber.
「発明の効果」 上記したように、本発明は連続加硫装置の加硫、発泡工
程において押出し成形された未加硫ゴム押出成形品を搬
送する手段として所定間隔に配置した多数の搬送ローラ
を使用したので、マイクロ波と熱風によって加熱される
前に起る未加硫ゴム成形品の温度むらや、マイクロ波加
熱炉内で生ずる偏加熱の問題が解決され、その上、これ
ら搬送ローラを回転させるスプロケツトの歯数を変え、
また、搬送ローラのローラ径を変えることによって搬送
ローラの搬送速度を搬送方向に進むに連れて増速する構
成とすることにより、未加硫ゴム押出成形品の発泡によ
る伸びが抑制されることによって起るスポンジゴムの変
形が極めて少なく、押出成形機の形成ダイスによって決
められる形状とほぼ相似形の製品が効果的に生産される
と供に、高発泡のゴム製品について容易に生産すること
ができる。"Effects of the Invention" As described above, the present invention includes a large number of conveying rollers arranged at predetermined intervals as a means for conveying the unvulcanized rubber extruded product extruded in the vulcanization and foaming process of the continuous vulcanizer. Since it was used, the problem of uneven temperature of the unvulcanized rubber molded product before being heated by microwaves and hot air and uneven heating that occurs in the microwave heating furnace are solved. Change the number of teeth on the sprocket,
Further, by changing the roller diameter of the carrying roller to increase the carrying speed of the carrying roller in the carrying direction, the expansion of the unvulcanized rubber extruded product due to foaming is suppressed. The sponge rubber deformation is extremely small, and it is possible to effectively produce a product having a shape similar to the shape determined by the forming die of the extruder, and it is possible to easily produce a highly foamed rubber product. .
また、比重が0.1前後の高発泡のスポンジゴムの生産
では、発泡反応による膨張が最も大きい部所の各々の搬
送ローラを水平面より所定角度で搬送方向に沿って順次
低くするように実施することによって、未加硫ゴム押出
成形品の自重による影響が少なくなり、生産が困難であ
った高発泡スポンジゴムでも偏肉したり、変形すること
なしに製造することが可能になる。Further, in the production of highly foamed sponge rubber having a specific gravity of around 0.1, the respective conveyance rollers at the portion where the expansion due to the foaming reaction is the largest are sequentially lowered at a predetermined angle from the horizontal plane along the conveyance direction. As a result, the influence of the unvulcanized rubber extruded product due to its own weight is reduced, and it is possible to manufacture even a highly foamed sponge rubber which has been difficult to produce without uneven thickness or deformation.
以上のように本発明の連続加硫装置は、未加硫ゴム押出
成形品の加硫製品はもとより発泡製品の製造に適し、し
かも、生産が困難とされていた特殊形状のゴム製品や高
発泡のゴム製品にも有効な加硫装置である。As described above, the continuous vulcanizing apparatus of the present invention is suitable for the production of not only vulcanized products of unvulcanized rubber extruded products but also foamed products, and moreover, special shaped rubber products and highly foamed products that were difficult to produce. It is also an effective vulcanizer for rubber products.
第1図は第1実施例を示す連続加硫装置の構成図、第2
図はマイクロ波加熱炉の簡略的正面図、第3図は第2図
上のA−A線に沿って切断した簡略断面図、第4図は搬
送ローラ駆動機構の説明図、第5図(a)、(b)は第
2実施例を示す搬送ローラ部の説明図であって、第5図
(a)はスポンジゴムの場合、第5図(b)はソリッド
ゴムの場合を各々示す図、第6図は第3実施例を示す連
続加硫装置の構成図、第7図は従来例を示す連続加硫装
置の構成図、第8図(a)、(b)はスポンジゴムの偏
加熱の影響を説明する図であって、第8図(a)は押出
直後のスポンジゴムの断面図、第8図(b)は偏加熱の
影響を受けた後のスポンジゴムの断面図、第9図
(a)、(b)は摩擦抵抗の影響を説明するための図で
あって、第9図(a)は押出直後の未加硫ゴム成形品の
断面図、第9図(b)は発泡体となった後のスポンジゴ
ムの断面図である。 10……第1実施例の連続加硫装置 11……押出成形機 12……マイクロ波加熱炉 13……NO.1二次加熱炉 14……NO.2二次加熱炉 15……NO.3二次加熱炉 16……連続引取機 22……押出ゴム 23……搬送ローラ 24……マイクロ波発振器 26……加熱室 27……ヒータ 47……第3実施例の連続加硫装置FIG. 1 is a block diagram of a continuous vulcanizer showing the first embodiment, and FIG.
FIG. 3 is a simplified front view of the microwave heating furnace, FIG. 3 is a simplified sectional view taken along the line AA in FIG. 2, FIG. 4 is an explanatory view of a transport roller driving mechanism, and FIG. FIGS. 5 (a) and 5 (b) are explanatory views of a conveying roller portion showing the second embodiment, FIG. 5 (a) showing a case of sponge rubber, and FIG. 5 (b) showing a case of solid rubber. FIG. 6 is a block diagram of a continuous vulcanizing apparatus showing the third embodiment, FIG. 7 is a block diagram of a continuous vulcanizing apparatus showing a conventional example, and FIGS. 8 (a) and 8 (b) are biased sponge rubbers. FIG. 8 (a) is a cross-sectional view of sponge rubber immediately after extrusion, FIG. 8 (b) is a cross-sectional view of sponge rubber after being affected by unbalanced heating, and FIG. 9 (a) and 9 (b) are views for explaining the influence of frictional resistance, and FIG. 9 (a) is a sectional view of an unvulcanized rubber molded product immediately after extrusion, and FIG. 9 (b). Is It is a cross-sectional view of the sponge rubber after a foam. 10 ... Continuous vulcanizing apparatus of the first embodiment 11 ... Extrusion molding machine 12 ... Microwave heating furnace 13 ... NO. 1 Secondary heating furnace 14 ... NO. 2 Secondary heating furnace 15 ... NO. 3 Secondary heating furnace 16 ... Continuous take-up machine 22 ... Extrusion rubber 23 ... Conveying roller 24 ... Microwave oscillator 26 ... Heating chamber 27 ... Heater 47 ... Continuous vulcanizing device of the third embodiment
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 B29K 105:24 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI technical display location B29K 105: 24
Claims (3)
ム押出成形品を連続に加硫、発泡させる装置において、
マイクロ波加熱炉内及び二次加熱炉内に、未加硫ゴムの
押出成形品を搬送させる多数の搬送ローラを搬送方向に
沿って順次所定の間隔で配置すると共に、これら搬送ロ
ーラ各々には各々の加熱炉内でモータ駆動されるチエー
ンまたは歯付ベルトによって一連に回転駆動するスプロ
ケツトを軸支し、未加硫ゴム押出成形品が発泡反応によ
って変形する搬送路部所に位置する搬送ローラをそのス
プロケツトの歯数を変えて回転速度を変える構成とした
ことを特徴とする未加硫ゴム押出成形品の連続加硫装
置。1. An apparatus for continuously vulcanizing and foaming an unvulcanized rubber extruded product by microwave irradiation and hot air,
In the microwave heating furnace and the secondary heating furnace, a large number of conveying rollers for conveying the extruded product of unvulcanized rubber are sequentially arranged at predetermined intervals along the conveying direction, and each of the conveying rollers has a respective one. The sprocket, which is driven to rotate in series by a chain or toothed belt that is driven by a motor in the above-mentioned heating furnace, is rotatably supported by a conveyor roller located at the conveyor path where the unvulcanized rubber extruded product is deformed by the foaming reaction. A continuous vulcanization device for an unvulcanized rubber extruded product, characterized in that the rotational speed is changed by changing the number of teeth of the sprocket.
ム押出成形品を連続に加硫、発泡させる装置において、
マイクロ波加熱炉内及び二次加熱炉内に、未加硫ゴムの
押出成形品を搬送させる多数の搬送ローラを搬送方向に
沿って順次所定の間隔で配置すると共に、未加硫ゴム押
出成形品が発泡反応によって変形する搬送路部所に位置
する搬送ローラのローラ径を変え、多数の搬送ローラを
同じ回転数で駆動する構成としたことを特徴とする未加
硫ゴム押出成形品の連続加硫装置。2. An apparatus for continuously vulcanizing and foaming an unvulcanized rubber extruded product by microwave irradiation and hot air,
In the microwave heating furnace and the secondary heating furnace, a large number of conveying rollers for conveying the extruded product of unvulcanized rubber are sequentially arranged at predetermined intervals along the conveying direction, and the unvulcanized rubber extruded product Of the unvulcanized rubber extruded product is characterized in that the roller diameter of the conveying roller located in the conveying path portion where is deformed by the foaming reaction is changed, and a large number of conveying rollers are driven at the same rotational speed. Sulfurizer.
ム押出成形品を連続に加硫、発泡させる装置において、
マイクロ波加熱炉内及び二次加熱炉内に、未加硫ゴムの
押出成形品を搬送させる多数の搬送ローラを搬送方向に
沿って順次所定の間隔で配置すると共に、未加硫ゴム押
出成形品の発泡反応による膨張が大きい部所の一定の範
囲に配列された各搬送ローラを搬送方向に沿って順次低
く配置して未加硫ゴム押出成形品の搬送路を水平面より
所定の角度で傾斜させる構成としたことを特徴とする未
加硫ゴム押出成形品の連続加硫装置。3. An apparatus for continuously vulcanizing and foaming an unvulcanized rubber extruded product by microwave irradiation and hot air,
In the microwave heating furnace and the secondary heating furnace, a large number of conveying rollers for conveying the extruded product of unvulcanized rubber are sequentially arranged at predetermined intervals along the conveying direction, and the unvulcanized rubber extruded product The conveyor rollers arranged in a certain range in a portion having a large expansion due to the foaming reaction are sequentially arranged lower along the conveying direction to incline the conveyor path of the unvulcanized rubber extruded product at a predetermined angle from the horizontal plane. A continuous vulcanization device for an unvulcanized rubber extruded product, which has a constitution.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63249104A JPH0659654B2 (en) | 1988-10-04 | 1988-10-04 | Continuous vulcanization equipment for unvulcanized rubber extruded products |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63249104A JPH0659654B2 (en) | 1988-10-04 | 1988-10-04 | Continuous vulcanization equipment for unvulcanized rubber extruded products |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0298411A JPH0298411A (en) | 1990-04-10 |
JPH0659654B2 true JPH0659654B2 (en) | 1994-08-10 |
Family
ID=17188015
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63249104A Expired - Fee Related JPH0659654B2 (en) | 1988-10-04 | 1988-10-04 | Continuous vulcanization equipment for unvulcanized rubber extruded products |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0659654B2 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100383675B1 (en) * | 2000-05-17 | 2003-05-14 | 금호산업주식회사 | A Match Method of Rubber for Continuous Match and System of Rubber Match |
WO2006085696A1 (en) | 2005-02-14 | 2006-08-17 | Canon Kasei Kabushiki Kaisha | Process for producing conductive rubber roller and roller for electrophotographic apparatus |
EP2890219A4 (en) | 2012-08-22 | 2016-06-01 | Otsuka Pharma Co Ltd | Microwave heating device and firing facility |
JP5837870B2 (en) * | 2012-12-11 | 2015-12-24 | 住友ゴム工業株式会社 | Method for manufacturing cylindrical foam rubber, and method for manufacturing conductive roller |
JP5984233B2 (en) * | 2013-07-17 | 2016-09-06 | 日本たばこ産業株式会社 | Rod member extrusion molding system and extrusion molding method thereof |
JP7437141B2 (en) * | 2019-11-20 | 2024-02-22 | 西川ゴム工業株式会社 | Rubber continuous vulcanization system |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2539730A1 (en) * | 1975-09-06 | 1977-03-17 | Bayer Ag | HYDANTOINE MODIFIED WITH CARBONIC ACID ESTER GROUPS |
JPS5940612B2 (en) * | 1980-11-11 | 1984-10-01 | 豊田合成株式会社 | Continuous vulcanization equipment for rubber extrudates with core metal |
-
1988
- 1988-10-04 JP JP63249104A patent/JPH0659654B2/en not_active Expired - Fee Related
Non-Patent Citations (2)
Title |
---|
ラバーダイジュスト昭和58年2月号99〜110頁朝田義雄「マイクロ波加熱によるゴム材料の均一加熱について」 |
架橋設備ハンドブック初版昭和58年3月15日大成社62頁,127〜134頁 |
Also Published As
Publication number | Publication date |
---|---|
JPH0298411A (en) | 1990-04-10 |
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