JPH06246512A - Cutting tool made of surface coating tungsten carbide-group cemented carbide alloy with excellent abrasion resistance and defect resistance - Google Patents
Cutting tool made of surface coating tungsten carbide-group cemented carbide alloy with excellent abrasion resistance and defect resistanceInfo
- Publication number
- JPH06246512A JPH06246512A JP5063430A JP6343093A JPH06246512A JP H06246512 A JPH06246512 A JP H06246512A JP 5063430 A JP5063430 A JP 5063430A JP 6343093 A JP6343093 A JP 6343093A JP H06246512 A JPH06246512 A JP H06246512A
- Authority
- JP
- Japan
- Prior art keywords
- cemented carbide
- coating layer
- hard coating
- cutting tool
- tungsten carbide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
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- Chemical Vapour Deposition (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】この発明は、すぐれた耐摩耗性と
耐欠損性を有し、特に耐欠損性が要求される、例えば鋼
の高送り切削や高切込み切削などの重切削において、こ
れの高速切削に用いた場合にすぐれた耐摩耗性を発揮す
る表面被覆炭化タングステン(以下、WCで示す)基超
硬合金製切削工具に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention has excellent wear resistance and fracture resistance, and is particularly suitable for heavy cutting such as high feed cutting and high depth cutting of steel which requires fracture resistance. The present invention relates to a surface-coated tungsten carbide (hereinafter referred to as WC) based cemented carbide cutting tool that exhibits excellent wear resistance when used for high speed cutting.
【0002】[0002]
【従来の技術】従来、一般に、例えば鋼の通常条件での
連続切削や断続切削に、重量%で(以下、%は重量%を
示す)、Coおよび/またはNiを主体とする金属結合
相:5〜20%を含有し、残りがWCを主体とする硬質
相からなるWC基超硬合金基体の表面に、化学蒸着法を
用いて、Tiの炭化物、窒化物、炭窒化物、炭酸化物、
窒酸化物、および炭窒酸化物、並びに酸化アルミニウム
(以下、それぞれTiC、TiN、TiCN、TiC
O、TiNO、およびTiCNO、並びにAl2 O3 で
示す)のうちの1種の単層または2種以上の複層からな
る硬質被覆層を1〜15μmの平均層厚で形成してなる
表面被覆WC基超硬合金製切削工具が用いられているこ
とは良く知られるところである。また、例えば特開平2
−254144号公報に記載されるように、耐欠損性を
向上させ、もって例えば鋼の高送り切削や高切込み切削
などの重切削での耐摩耗性を向上させる目的で、上記の
表面被覆WC基超硬合金製切削工具の表面にショットピ
ーニングを施して、これを構成する硬質被覆層中にクラ
ックを積極的に一様に形成してなる表面被覆WC基超硬
合金製切削工具も知られている。2. Description of the Related Art Conventionally, for example, in continuous cutting or interrupted cutting of steel under normal conditions, a metallic binder phase mainly composed of Co and / or Ni in weight% (hereinafter,% means weight%): On the surface of a WC-based cemented carbide substrate containing 5 to 20% and the rest consisting of a hard phase mainly composed of WC, a Ti carbide, a nitride, a carbonitride, or a carbonate of Ti is formed by a chemical vapor deposition method.
Nitride oxide, carbonitride oxide, and aluminum oxide (hereinafter, TiC, TiN, TiCN, TiC, respectively)
O, TiNO, and TiCNO, and Al 2 O 3 ), a surface coating formed by forming a hard coating layer composed of one single layer or two or more multiple layers with an average layer thickness of 1 to 15 μm. It is well known that WC-based cemented carbide cutting tools are used. Also, for example, Japanese Patent Laid-Open No.
As described in JP-A-254144, for the purpose of improving fracture resistance, and thus improving wear resistance in heavy cutting such as high feed cutting and high depth cutting of steel, the above surface-coated WC group is used. A surface-coated WC-based cemented carbide cutting tool is also known in which shot peening is performed on the surface of the cemented carbide cutting tool, and cracks are positively and uniformly formed in the hard coating layer constituting the cutting tool. There is.
【0003】[0003]
【発明が解決しようとする課題】一方、近年の切削加工
のFA化および省力化はめざましく、これに伴ない、切
削工具にも切削条件に影響を受けにくい汎用性が強く望
まれているが、上記の硬質被覆層にショットピーニング
形成クラックが一様に存在する従来表面被覆WC基超硬
合金製切削工具は、通常の条件での重切削ではすぐれた
耐摩耗性を示すものの、これを高速化した場合、摩耗進
行が著しく速くなり、比較的短時間で使用寿命に至るの
が現状である。On the other hand, in recent years FA cutting and labor saving in cutting processing have been remarkable, and along with this, there is a strong demand for versatility of cutting tools that is not easily affected by cutting conditions. The conventional surface-coated WC-based cemented carbide cutting tool in which shot peening-forming cracks are uniformly present in the above hard coating layer has excellent wear resistance in heavy cutting under normal conditions, but has a high speed. In such a case, the progress of wear becomes extremely fast, and the service life is reached in a relatively short time.
【0004】[0004]
【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、上記の硬質被覆層にショットピ
ーニング形成クラックが一様に分布する従来表面被覆W
C基超硬合金製切削工具のもつ問題点を解決すべく研究
を行なった結果、上記の表面被覆WC基超硬合金製切削
工具において、これを構成する硬質被覆層に、表面側上
方部分と基体側下方部分とでクラック分布密度の異るシ
ョットピーニング形成クラックを存在させ、かつ前記ク
ラック分布密度を、前記表面側上方部分に比して前記基
体側下方部分の方を高くすると、この結果の表面被覆W
C基超硬合金製切削工具は、例えば鋼の重切削を高速で
行なってもすぐれた耐摩耗性を示し、著しく長期に亘っ
てすぐれた切削性能を発揮するという研究結果を得たの
である。Therefore, the present inventors have
From the viewpoint as described above, the conventional surface coating W in which the shot peening formation cracks are uniformly distributed in the hard coating layer described above.
As a result of research to solve the problems of the C-based cemented carbide cutting tool, in the above-mentioned surface-coated WC-based cemented carbide cutting tool, the hard coating layer constituting the surface-coated upper part is If shot peening formation cracks having different crack distribution densities are present in the lower part on the substrate side, and the crack distribution density is made higher in the lower part on the substrate side than in the upper part on the surface side, Surface coating W
The research results show that the C-based cemented carbide cutting tool exhibits excellent wear resistance even when heavy cutting of steel is performed at high speed, and exhibits excellent cutting performance for a remarkably long period of time.
【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、Coおよび/またはNiを主体
とする金属結合相:5〜20%を含有し、残りがWCを
主体とする硬質相からなるWC基超硬合金基体の表面
に、TiC、TiN、TiCN、TiCO、TiNO、
TiCNO、およびAl2 O3 のうちの1種の単層また
は2種以上の複層からなる硬質被覆層を1〜15μmの
平均層厚で形成してなる表面被覆WC基超硬合金製切削
工具において、上記硬質被覆層に、表面側上方部分と基
体側下方部分とでクラック分布密度の異るショットピー
ニング形成クラックを存在させ、かつ前記クラック分布
密度を前記表面側上方部分に比して前記基体側下方部分
の方を高くすることにより耐摩耗性と耐欠損性の向上を
はかった表面被覆WC基超硬合金製切削工具に特徴を有
するものである。The present invention has been made based on the above-mentioned research results, and contains a metal binder phase containing Co and / or Ni as a main component: 5 to 20%, and the rest containing WC as a main component. TiC, TiN, TiCN, TiCO, TiNO, on the surface of the WC-based cemented carbide substrate composed of phases,
A surface-coated WC-based cemented carbide cutting tool formed by forming a hard coating layer consisting of one single layer or two or more multiple layers of TiCNO and Al 2 O 3 with an average layer thickness of 1 to 15 μm. In the above hard coating layer, shot peening forming cracks having different crack distribution densities in the upper surface side portion and the lower body side portion are present, and the crack distribution density is higher than that of the surface side upper portion. This is characterized by a surface-coated WC-based cemented carbide cutting tool whose wear resistance and fracture resistance are improved by making the lower side portion higher.
【0006】なお、この発明の切削工具において、これ
を構成する基体の金属結合相の含有量を5〜20%とし
たのは、その含有量が5%未満では焼結性が低下し、基
体に十分な強度を確保することができず、一方その含有
量が20%を越えると硬さが低下し、基体自体の摩耗進
行が急激に加速されるようになるという理由によるもの
である。また、この発明の切削工具を構成する硬質被覆
層の平均層厚を1〜15μmと限定したのは、その平均
層厚が1μm未満では所望の耐摩耗性向上効果が得られ
ず、一方その平均層厚が15μmを越えると、切刃に欠
損やチッピング(微小欠け)が発生するようになるとい
う理由にもとづくものである。In the cutting tool of the present invention, the content of the metallic binder phase in the base material constituting the cutting tool is set to 5 to 20%. If the content is less than 5%, the sinterability is lowered and the base material is However, if the content exceeds 20%, the hardness decreases, and the progress of wear of the substrate itself is rapidly accelerated. Moreover, the average layer thickness of the hard coating layer constituting the cutting tool of the present invention is limited to 1 to 15 μm because the desired wear resistance improving effect cannot be obtained when the average layer thickness is less than 1 μm, while the average value This is based on the reason that when the layer thickness exceeds 15 μm, chipping or chipping (fine chipping) occurs in the cutting edge.
【0007】[0007]
【実施例】つぎに、この発明の表面被覆WC基超硬合金
製切削工具を実施例により具体的に説明する。原料粉末
として、いずれも1〜6μmの範囲内の所定の平均粒径
を有するWC粉末、TiC粉末、TiN粉末、TaC粉
末、NbC粉末、Cr3 C2 粉末、VC粉末、Co粉
末、およびNi粉末を用意し、これら原料粉末を表1に
示される配合組成に配合し、ボールミルで72時間湿式
混合した後、1ton /cm2 の圧力で圧粉体にプレス成形
し、この圧粉体を、10〜100torrの範囲内の所定の
N2 分圧の窒素雰囲気中、1380〜1430℃の範囲
内の所定温度に1時間保持の条件で焼結してISO規格
SNMN432のスローアウェイチップ形状を有するW
C基超硬合金基体A〜Iを形成した。EXAMPLES Next, the surface-coated WC-based cemented carbide cutting tool of the present invention will be specifically described by way of examples. As raw material powders, WC powders, TiC powders, TiN powders, TaC powders, NbC powders, Cr 3 C 2 powders, VC powders, Co powders, and Ni powders each having a predetermined average particle size within the range of 1 to 6 μm Were prepared, and these raw material powders were blended to the blending composition shown in Table 1, wet-mixed for 72 hours in a ball mill, and then press-molded into a green compact at a pressure of 1 ton / cm 2. W having a throwaway tip shape of ISO standard SNMN432 by sintering at a predetermined temperature in the range of 1380 to 1430 ° C. for 1 hour in a nitrogen atmosphere of a predetermined N 2 partial pressure in the range of to 100 torr.
C-based cemented carbide substrates A to I were formed.
【0008】ついで、上記基体A〜Iの表面に、通常の
化学蒸着装置を用いて、まず、高密度クラック分布層を
形成する目的で、表2に示される組成および平均層厚の
単層または複層の硬質被覆層(表2に*印を付す)を形
成した後、 ショット:0.4mmの平均粒径を有する鋳鉄球、 投射速度:80m/sec 、 投射時間:3分、 の条件でショットピーニングを施し、引続いて低密度ク
ラック分布層を形成する目的で、同じく表2に示される
組成および平均層厚を有する単層または複層の硬質被覆
層を形成し、これに、 ショット:0.3mmの平均粒径を有する鋳鉄球、 投射速度:40m/sec 、 投射時間:1分、 の条件でショットピーニングを施すことにより、それぞ
れクラック分布密度は異るが、いずれも硬質被覆層の基
体側下方部分の方が表面側上方部分に比してショットピ
ーニング形成クラックのクラック分布密度が高い本発明
表面被覆WC基超硬合金製切削工具(以下、本発明被覆
切削工具という)1〜13を製造した。Then, for the purpose of forming a high-density crack distribution layer on the surface of the above-mentioned substrates A to I, first, for the purpose of forming a high-density crack distribution layer, a single layer having the composition and average layer thickness shown in Table 2 or After forming a multilayer hard coating layer (marked with * in Table 2), shot: cast iron ball having an average particle size of 0.4 mm, projection speed: 80 m / sec, projection time: 3 minutes For the purpose of performing shot peening and subsequently forming a low-density crack distribution layer, a single-layer or multiple-layer hard coating layer having the same composition and average layer thickness as shown in Table 2 is formed, and shot: Cast iron balls having an average particle size of 0.3 mm, shot speed: 40 m / sec, shot time: 1 minute, shot peening gives different crack distribution densities, but in each case Lower part on the substrate side Surface upper crack distribution density of the shot peening forming cracks than the portion higher present invention surface coating WC-based cemented carbide cutting tool (hereinafter, referred to as the present invention a coated cutting tool) 1 to 13 were prepared.
【0009】また、比較の目的で、上記の基体A〜Iの
表面に、同じ化学蒸着装置を用い、上記本発明被覆切削
工具1〜13のそれぞれに対応した組成および平均層厚
の硬質被覆層を形成した後、 ショット:0.4mmの平均粒径を有する鋳鉄球、 投射速度:80m/sec 、 投射時間:3分、 の条件でショットピーニングを施して、硬質被覆層に一
様なクラック分布密度のショットピーニング形成クラッ
クを形成することにより従来表面被覆WC基超硬合金製
切削工具(以下、従来被覆切削工具という)1〜13を
それぞれ製造した。For the purpose of comparison, the same chemical vapor deposition apparatus is used on the surfaces of the above-mentioned substrates A to I, and a hard coating layer having a composition and an average layer thickness corresponding to each of the coated cutting tools 1 to 13 of the present invention. After forming, shot: peening iron balls having an average particle diameter of 0.4 mm, shot speed: 80 m / sec, shot time: 3 minutes, shot peening was performed under the following conditions to obtain a uniform crack distribution in the hard coating layer. Conventional surface-coated WC-based cemented carbide cutting tools (hereinafter referred to as conventional coated cutting tools) 1 to 13 were manufactured by forming shot peening formation cracks of high density.
【0010】つぎに、この結果得られた各種の被覆切削
工具について、クラック分布密度を検討するために、そ
の硬質被覆層の縦断面を顕微鏡観察し、これの基体界面
と最表面における長さ:1mm内に存在するクラック本数
を任意5個所について目視測定した。この測定結果を平
均値として表3,4に示した。Next, in order to examine the crack distribution density of the various coated cutting tools obtained as a result, the longitudinal section of the hard coating layer was observed under a microscope, and the lengths at the substrate interface and the outermost surface were: The number of cracks existing within 1 mm was visually measured at arbitrary 5 points. The results of this measurement are shown in Tables 3 and 4 as average values.
【0011】また、上記の各種被覆切削工具について、 被削材:SCM440(硬さ:HB 170)の丸棒、 切削速度:250m/min 、 切込み:4.5mm、 送り:0.3mm/rev.、 切削時間:30分、 の条件での鋼の連続高切込み高速切削試験を行ない、切
刃の逃げ面摩耗幅を測定し、さらに、 被削材:SCM440(硬さ:HB 170)の丸棒、 切削速度:180m/min 、 切込み:4.5mm、 送り:0.3mm/rev.、 切削時間:30分、 の条件での鋼の連続高切込み切削試験を行ない、いずれ
の試験でも切刃の逃げ面摩耗幅を測定した。これらの測
定結果も表3,4に示した。Regarding the above various coated cutting tools, the work material: a round bar of SCM440 (hardness: H B 170), cutting speed: 250 m / min, depth of cut: 4.5 mm, feed: 0.3 mm / rev ., Cutting time: 30 minutes, a continuous high-incision high-speed cutting test of steel was performed, the flank wear width of the cutting edge was measured, and the work material: SCM440 (hardness: H B 170) Round bar, cutting speed: 180 m / min, depth of cut: 4.5 mm, feed: 0.3 mm / rev., Cutting time: 30 minutes. The flank wear width of the blade was measured. The results of these measurements are also shown in Tables 3 and 4.
【0012】[0012]
【表1】 [Table 1]
【0013】[0013]
【表2】 [Table 2]
【0014】[0014]
【表3】 [Table 3]
【0015】[0015]
【表4】 [Table 4]
【0016】[0016]
【発明の効果】表1〜4に示される結果から、本発明被
覆切削工具1〜13は、いずれもこれを構成する硬質被
覆層におけるショットピーニング形成クラックのクラッ
ク分布密度が表面側上方部分と基体側下方部分とで異
り、かつ表面側上方部分に比して基体側下方部分の方が
高いクラック分布密度を有するのに対して、従来被覆切
削工具1〜13は、いずれも硬質被覆層におけるショッ
トピーニング形成クラックのクラック分布密度が層全体
に亘ってほぼ一様である点で両者は相異し、この結果と
して、前者は鋼の高切込み切削を通常の条件は勿論のこ
と、これを高速で行なっても、すぐれた耐摩耗性と耐欠
損性を示すのに対して、後者は通常の条件では切刃に欠
損やチッピングの発生のない、すぐれた耐欠損性と耐摩
耗性を示すものの、これの高速切削では一段と速い摩耗
進行を示すようになることが明らかである。上述のよう
に、この発明の表面被覆WC基超硬合金製切削工具は、
すぐれた耐摩耗性と耐欠損性を有するので、特に耐欠損
性が要求される、例えば鋼の重切削に用いた場合に、こ
れを高速切削で行なっても摩耗進行が著しく抑制される
ことから、長期に亘ってすぐれた切削性能を発揮するの
である。From the results shown in Tables 1 to 4, in the coated cutting tools 1 to 13 of the present invention, the crack distribution density of the shot peening forming cracks in the hard coating layer constituting the coated cutting tools 1 to 13 is the same as that of the upper portion on the surface side and the substrate. The lower side portion differs from the lower side portion and has a higher crack distribution density in the lower portion on the substrate side than in the upper portion on the surface side, whereas the conventional coated cutting tools 1 to 13 all have a hard coating layer. The two are different in that the crack distribution density of shot peening formation cracks is almost uniform over the entire layer, and as a result, the former requires high-cut cutting of steel under normal conditions as well as high-speed cutting. Although it shows excellent wear resistance and chipping resistance, the latter shows excellent chipping resistance and wear resistance without chipping or chipping of the cutting edge under normal conditions. , It is evident that exhibits a more rapid wear progress in high-speed cutting of les. As described above, the surface-coated WC-based cemented carbide cutting tool of the present invention is
Since it has excellent wear resistance and fracture resistance, especially when it is used for heavy cutting of steel, for example, when it is used for heavy cutting of steel, even if this is done at high speed cutting, wear progress is significantly suppressed , It shows excellent cutting performance over a long period of time.
Claims (1)
属結合相:5〜20重量%を含有し、残りが炭化タング
ステンを主体とする硬質相からなる炭化タングステン基
超硬合金基体の表面に、Tiの炭化物、窒化物、炭窒化
物、炭酸化物、窒酸化物、および炭窒酸化物、並びに酸
化アルミニウムのうちの1種の単層または2種以上の複
層からなる硬質被覆層を1〜15μmの平均層厚で形成
してなる表面被覆炭化タングステン基超硬合金製切削工
具において、 上記硬質被覆層には、表面側上方部分と基体側下方部分
とでクラック分布密度が異るショットピーニング形成ク
ラックが存在し、前記クラック分布密度は、前記表面側
上方部分に比して前記基体側下方部分の方が高いことを
特徴とする耐摩耗性および耐欠損性のすぐれた表面被覆
炭化タングステン基超硬合金製切削工具。1. A metal-bonded phase mainly composed of Co and / or Ni: 5 to 20% by weight, and the balance consisting of a hard phase mainly composed of tungsten carbide on the surface of a tungsten carbide-based cemented carbide substrate, 1 to 1 of a hard coating layer composed of a single layer or two or more multi-layers of Ti carbide, nitride, carbonitride, carbon oxide, oxynitride, and oxycarbonitride, and aluminum oxide. In a surface-coated tungsten carbide-based cemented carbide cutting tool formed with an average layer thickness of 15 μm, in the hard coating layer, shot peening with different crack distribution densities in the upper part on the surface side and the lower part on the substrate side. A surface-coated carbonized material having excellent wear resistance and chipping resistance, characterized in that cracks are present and the crack distribution density is higher in the substrate-side lower portion than in the surface-side upper portion. Cutting tool made of Nungsten base cemented carbide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP05063430A JP3087503B2 (en) | 1993-02-26 | 1993-02-26 | Manufacturing method of surface-coated tungsten carbide based cemented carbide cutting tools with excellent wear and fracture resistance |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP05063430A JP3087503B2 (en) | 1993-02-26 | 1993-02-26 | Manufacturing method of surface-coated tungsten carbide based cemented carbide cutting tools with excellent wear and fracture resistance |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH06246512A true JPH06246512A (en) | 1994-09-06 |
JP3087503B2 JP3087503B2 (en) | 2000-09-11 |
Family
ID=13229057
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP05063430A Expired - Fee Related JP3087503B2 (en) | 1993-02-26 | 1993-02-26 | Manufacturing method of surface-coated tungsten carbide based cemented carbide cutting tools with excellent wear and fracture resistance |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999024198A1 (en) * | 1997-11-06 | 1999-05-20 | Sumitomo Electric Industries, Ltd. | Coated tool of cemented carbide |
US20100150677A1 (en) * | 2006-01-17 | 2010-06-17 | Hitoshi Yamaguchi | Rotary Cutting Tool and Method For Manufacturing Such a Rotary Cutting Tool |
CN102581323A (en) * | 2011-01-11 | 2012-07-18 | 三菱综合材料株式会社 | Surface-coated cutting tool with hard-coated layer possessing knife broken resistance and abrasion resistance |
JP2012161847A (en) * | 2011-02-03 | 2012-08-30 | Mitsubishi Materials Corp | Surface coated cutting tool with hard coating layer having excellent chipping resistance and defect resistance |
WO2015025903A1 (en) | 2013-08-21 | 2015-02-26 | 株式会社タンガロイ | Coated cutting tool |
JP2015182169A (en) * | 2014-03-24 | 2015-10-22 | 三菱マテリアル株式会社 | Surface coated cutting tool |
JP2017013211A (en) * | 2015-07-06 | 2017-01-19 | 三菱マテリアル株式会社 | Surface coating and cutting tool |
-
1993
- 1993-02-26 JP JP05063430A patent/JP3087503B2/en not_active Expired - Fee Related
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999024198A1 (en) * | 1997-11-06 | 1999-05-20 | Sumitomo Electric Industries, Ltd. | Coated tool of cemented carbide |
US6187421B1 (en) | 1997-11-06 | 2001-02-13 | Sumitomo Electric Industries, Ltd. | Coated tool of cemented carbide |
US20100150677A1 (en) * | 2006-01-17 | 2010-06-17 | Hitoshi Yamaguchi | Rotary Cutting Tool and Method For Manufacturing Such a Rotary Cutting Tool |
US8215881B2 (en) * | 2006-01-17 | 2012-07-10 | Sakai Threading Tool Co., Ltd. | Rotary cutting tool and method for manufacturing such a rotary cutting tool |
CN102581323A (en) * | 2011-01-11 | 2012-07-18 | 三菱综合材料株式会社 | Surface-coated cutting tool with hard-coated layer possessing knife broken resistance and abrasion resistance |
JP2012161847A (en) * | 2011-02-03 | 2012-08-30 | Mitsubishi Materials Corp | Surface coated cutting tool with hard coating layer having excellent chipping resistance and defect resistance |
WO2015025903A1 (en) | 2013-08-21 | 2015-02-26 | 株式会社タンガロイ | Coated cutting tool |
KR20160029853A (en) | 2013-08-21 | 2016-03-15 | 가부시키가이샤 탕가로이 | Coated cutting tool |
RU2635055C2 (en) * | 2013-08-21 | 2017-11-08 | Тунгалой Корпорейшн | Coated cutting tool |
JP2015182169A (en) * | 2014-03-24 | 2015-10-22 | 三菱マテリアル株式会社 | Surface coated cutting tool |
JP2017013211A (en) * | 2015-07-06 | 2017-01-19 | 三菱マテリアル株式会社 | Surface coating and cutting tool |
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