JPH06141747A - Spray composition for capturing small insects - Google Patents
Spray composition for capturing small insectsInfo
- Publication number
- JPH06141747A JPH06141747A JP32364092A JP32364092A JPH06141747A JP H06141747 A JPH06141747 A JP H06141747A JP 32364092 A JP32364092 A JP 32364092A JP 32364092 A JP32364092 A JP 32364092A JP H06141747 A JPH06141747 A JP H06141747A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- small insects
- composition
- present
- spray composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 241000238631 Hexapoda Species 0.000 title claims abstract description 20
- 239000007921 spray Substances 0.000 title claims abstract description 20
- 239000000839 emulsion Substances 0.000 claims abstract description 12
- 239000005667 attractant Substances 0.000 claims abstract description 8
- 230000031902 chemoattractant activity Effects 0.000 claims abstract description 8
- 229920001083 polybutene Polymers 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 abstract description 8
- 230000001070 adhesive effect Effects 0.000 abstract description 8
- 238000005507 spraying Methods 0.000 abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000003380 propellant Substances 0.000 description 5
- 239000005060 rubber Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000011550 stock solution Substances 0.000 description 4
- -1 dodecylbenzene sulfonic acid amine salt Chemical class 0.000 description 3
- 235000012907 honey Nutrition 0.000 description 3
- 229920002367 Polyisobutene Polymers 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229910002014 Aerosil® 130 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- DVQHRBFGRZHMSR-UHFFFAOYSA-N sodium methyl 2,2-dimethyl-4,6-dioxo-5-(N-prop-2-enoxy-C-propylcarbonimidoyl)cyclohexane-1-carboxylate Chemical compound [Na+].C=CCON=C(CCC)[C-]1C(=O)CC(C)(C)C(C(=O)OC)C1=O DVQHRBFGRZHMSR-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
(57)【要約】
【目的】 スプレー、特にエアスプレーによる簡便な操
作で塗布することができる小昆虫捕獲用の粘着剤組成物
を提供する。
【構成】 ポリブテン、水、乳化剤および誘引剤を含有
する水性エマルジョンからなる組成物。(57) [Summary] [Object] To provide an adhesive composition for trapping small insects, which can be applied by a simple operation by spraying, particularly an air spray. A composition comprising an aqueous emulsion containing polybutene, water, an emulsifier and an attractant.
Description
【０００１】[0001]
【産業上の利用分野】本発明は、小昆虫、例えば蝿など
を捕獲するためのスプレー組成物、特にエアスプレーな
どに適した組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a spray composition for trapping small insects such as flies, especially a composition suitable for air spray.
【０００２】[0002]
【従来の技術】従来、一般に小昆虫捕獲用粘着剤は、刷
毛塗りなどの方法により塗布されていたが、このような
方法では塗布作業が煩雑である点に問題があった。2. Description of the Related Art Conventionally, a small insect trapping adhesive has generally been applied by a method such as brush coating, but such a method has a problem in that the application work is complicated.
【０００３】[0003]
【発明が解決しようとする課題】本発明は、スプレー、
特にエアスプレーによる簡便な操作で塗布することがで
きる小昆虫捕獲用の粘着剤組成物を提供することを目的
とする。The present invention is a spray,
In particular, it is an object of the present invention to provide an adhesive composition for trapping small insects, which can be applied by a simple operation by air spray.
【０００４】[0004]
【課題を解決するための手段】本発明は、ポリブテン、
水、乳化剤および誘引剤を含有する水性エマルジョンか
らなる小昆虫捕獲用スプレー組成物を提供するものであ
る。The present invention provides polybutene,
A spray composition for trapping small insects comprising an aqueous emulsion containing water, an emulsifier and an attractant.
【０００５】さらに本発明を詳細に説明する。本発明の
組成物に用いるポリブテンは、数平均分子量 ２００〜
４,０００の範囲のものが適当である。数平均分子量が
２００未満では、塗布後の組成物の流動性が過大とな
り、一方、上記分子量が４,０００を超えると、 粘度が
高すぎるためにスプレーすることが困難となるほか、初
期粘着力が低下するのでいずれも好ましくない。ポリブ
テンの配合量は、１０〜８０重量％、好ましくは２０〜
５０重量％である。１０重量％より少ないと小昆虫の捕
獲力が低下し、一方８０重量％を越えると粘度が高すぎ
るためにスプレー性が低下して好ましくない。The present invention will be further described in detail. The polybutene used in the composition of the present invention has a number average molecular weight of 200 to
Those in the range of 4,000 are suitable. If the number average molecular weight is less than 200, the fluidity of the composition after coating becomes excessive, while if the molecular weight exceeds 4,000, it becomes difficult to spray because the viscosity is too high and the initial adhesive strength Is decreased, which is not preferable. The content of polybutene is 10 to 80% by weight, preferably 20 to
It is 50% by weight. If it is less than 10% by weight, the trapping power of small insects is lowered, while if it exceeds 80% by weight, the viscosity is too high and the sprayability is lowered, which is not preferable.
【０００６】本発明で使用する水の配合量は、２０〜８
０重量％、好ましくは２５〜７０重量％である。２０重
量％未満では粘度が高くなりすぎるためにスプレー性が
低下し、一方、８０重量％を越えると小昆虫の捕獲力が
低下するためにいずれも好ましくない。The amount of water used in the present invention is 20 to 8
It is 0% by weight, preferably 25 to 70% by weight. If it is less than 20% by weight, the viscosity becomes too high, so that the sprayability is deteriorated. On the other hand, if it exceeds 80% by weight, the trapping power of small insects is deteriorated, which is not preferable.
【０００７】本発明において乳化剤としては任意のもの
を使用することができ、例えば、ポリオキシアルキレン
アルキルフェニルエーテルサルフェートアンモニウム
塩、ドデシルベンゼンスルフォン酸アミン塩などが挙げ
られる。 この配合量は、０.１〜２０重量％が適当であ
る。In the present invention, any emulsifier can be used, and examples thereof include polyoxyalkylene alkylphenyl ether sulfate ammonium salt and dodecylbenzene sulfonic acid amine salt. The appropriate amount of this compound is 0.1 to 20% by weight.
【０００８】誘引剤としては、本発明のスプレー組成物
が対象とする蝿などの小昆虫に対しては、蜂蜜などが適
当である。 その配合量は、０.１〜５重量％が適当であ
る。０.１重量％未満では効果がなく、 ５重量％を越え
るとかえって誘引効果が損なわれるほか、蜂蜜の場合に
は粘度も高くなるために好ましくない。As the attractant, honey or the like is suitable for small insects such as flies targeted by the spray composition of the present invention. The blending amount is suitably 0.1 to 5% by weight. If it is less than 0.1% by weight, no effect is obtained, and if it exceeds 5% by weight, the attractive effect is rather impaired, and in the case of honey, the viscosity becomes high, which is not preferable.
【０００９】なお、小昆虫の捕獲性能を高めるために
は、ゴムを配合することが好ましい。この目的で配合す
るゴムとしては、粘度平均分子量２万から２百万の範囲
のポリイソブチレン、ブチルゴム、またはこれらの混合
物が適当である。ゴムの分子量がこの範囲を外れると、
粘着性が不足して小昆虫の捕獲性能が低下するので好ま
しくない。これらのゴムはポリブテンに対する相溶性が
良好であるため、小昆虫に対する粘着性を向上すること
ができる。ゴムの配合量は、０.１〜２０重量％が適当
である。０.１重量％未満では、捕獲性能向上の効果を
示することが困難であり、一方２０重量％を越えると粘
度が高くなりすぎるためにスプレー性が低下すると共
に、初期粘着力が低下し、小昆虫の捕獲性能が低下する
ためにいずれも好ましくない。In order to enhance the trapping performance of small insects, it is preferable to add rubber. As the rubber compounded for this purpose, polyisobutylene having a viscosity average molecular weight of 20,000 to 2 million, butyl rubber, or a mixture thereof is suitable. If the molecular weight of rubber is out of this range,
It is not preferable because the stickiness is insufficient and the trapping performance of small insects is deteriorated. Since these rubbers have good compatibility with polybutene, the stickiness to small insects can be improved. The appropriate amount of rubber compounded is 0.1 to 20% by weight. If it is less than 0.1% by weight, it is difficult to show the effect of improving the trapping performance, while if it exceeds 20% by weight, the viscosity becomes too high, so that the sprayability is lowered and the initial adhesive strength is lowered. Both are not preferable because the ability to capture small insects is reduced.
【００１０】本発明においては、さらにフロー防止剤を
加えることが好ましい。本発明の組成物を使用する際に
は、スプレー後に水を蒸発させ乾燥した後に粘着性が発
現するが、乾燥状態において傾斜面（垂直面の場合もあ
る）上で粘着剤がフローを起こす場合には、結果的に粘
着剤としての機能を果たすことができない。このような
現象を防止するために、フロー防止剤を添加する。上記
のフロー防止剤としては、親水性の水不溶性無機微粒
子、例えば、微粉末のシリカ、アルミナ、ゼオライト、
有機ベントナイトあるいはタルクなどが例示される。こ
れらのなかでも、親水性微粉末シリカはフロー防止効果
が大きいので好ましい。その配合量は、０.１〜２０重
量％、好ましくは０.５〜１０重量％である。 ０.１重
量％未満では、フロー防止効果を期待し難く、一方２０
重量％を越えるとスプレー性が低下するために好ましく
ない。In the present invention, it is preferable to add an anti-flow agent. When the composition of the present invention is used, the adhesiveness is developed after water is evaporated by spraying and drying is performed. Cannot consequently function as an adhesive. In order to prevent such a phenomenon, an anti-flow agent is added. As the above flow inhibitor, hydrophilic water-insoluble inorganic fine particles, for example, fine powder of silica, alumina, zeolite,
Examples include organic bentonite and talc. Among these, hydrophilic fine powder silica is preferable because it has a large flow prevention effect. The blending amount is 0.1 to 20% by weight, preferably 0.5 to 10% by weight. If it is less than 0.1% by weight, it is difficult to expect the flow-preventing effect.
If it exceeds 5% by weight, the sprayability is deteriorated, which is not preferable.
【００１１】さらに、本発明の組成物には、発明の効果
を損なわない範囲で、任意の成分、例えば防腐剤などを
配合することができる。なお、本発明の水性エマルジョ
ンの製造法については特に制限はなく、公知の方法を用
いることができる。Further, the composition of the present invention may be blended with optional components such as preservatives, etc. within a range that does not impair the effects of the present invention. The method for producing the aqueous emulsion of the present invention is not particularly limited, and a known method can be used.
【００１２】本発明の水性エマルジョンからなる組成物
を塗布するには、スプレーを使用する。スプレーを用い
る方法は特に限定されず、例えばＬＰＧなどの噴射剤を
用いることもできる。しかし、噴射剤としてＬＰＧを使
用する場合には火気に対する安全性が問題となり、また
フロンなどを噴射剤とする場合には環境への安全性が問
題となる。さらに、噴射剤を使用する場合には耐圧容器
を使用する必要があるため高価になる。従って、手動に
よりわずかな空気圧を発生させて容器内圧を上昇させ、
この内圧を利用してスプレーする、いわゆるエアスプレ
ー方法が好ましい。本発明の組成物はエアスプレーを行
うのに最も適したものである。A spray is used to apply the composition comprising the aqueous emulsion of the present invention. The method of using a spray is not particularly limited, and a propellant such as LPG can also be used. However, when LPG is used as a propellant, safety against fire becomes a problem, and when CFC or the like is used as a propellant, environmental safety becomes a problem. Further, when a propellant is used, it is necessary to use a pressure resistant container, which is expensive. Therefore, a small amount of air pressure is manually generated to raise the internal pressure of the container,
A so-called air spray method of spraying by utilizing this internal pressure is preferable. The composition of the present invention is most suitable for air spraying.
【００１３】エアスプレーを行うためには、 組成物の
粘度が２５℃において１,０００ｃＰ以下であることが
肝要であり、好ましくは５０〜９００ｃＰ、さらに好ま
しくは２００〜４００ｃＰの範囲である。 上記粘度が
１,０００ｃＰを超えると、たとえ小昆虫の捕獲性能が
高くてもエアスプレー性が低いために好ましくない。本
発明においては、組成物の粘度が上記の範囲になるよ
う、各成分の配合割合を決定する必要がある。通常、エ
マルジョン粘度が低い場合は、エマルジョンの固形分濃
度が低く、必然的に粘着剤の塗布量が少ないと考えら
れ、従って粘着性能、ひいては小昆虫の捕獲性能は低い
ものと予想される。しかしながら、本発明の組成物は、
低粘度であるにもかかわらず、適当な誘引剤を必須成分
としていることなどにより、小昆虫、特に蝿に対する十
分な捕獲性能を有するものである。さらに、本発明の組
成物は、エマルジョンの状態も安定である。In order to perform air spraying, it is essential that the viscosity of the composition is 1,000 cP or less at 25 ° C., preferably 50 to 900 cP, more preferably 200 to 400 cP. If the viscosity exceeds 1,000 cP, the air spray property is low even if the insect trapping performance is high, which is not preferable. In the present invention, it is necessary to determine the blending ratio of each component so that the viscosity of the composition falls within the above range. Usually, when the emulsion viscosity is low, it is considered that the solid content concentration of the emulsion is low and thus the amount of the adhesive applied is necessarily small, and therefore the adhesive performance, and thus the insect trapping performance is expected to be low. However, the composition of the present invention
Despite its low viscosity, it has a sufficient ability to trap small insects, especially flies, by using a suitable attractant as an essential component. Furthermore, the composition of the present invention is stable in the emulsion state.
【００１４】[0014]
【実施例】以下、実施例により本発明を説明する。誘引
剤以外の各種成分を表１の割合で配合し、エマルジョン
原液を調製した。 表 １ 成 分 配合割合(wt％) ポリブテン： 数平均分子量 1,260 ５１.３ ゴ ム： ポリイソブチレン、粘度平均分子量 1,200,000 １.０ フロー防止剤：シリカゲル（商品名：アエロジル 130、日本 アエロジル(株)製） ２.７ 乳 化 剤： ポリオキシエチレンアルキルフェニルエーテル サルフェートアンモニウム塩 ３.６ 乳 化 剤： ドデシルベンゼンスルホン酸アミン塩 １.９ 消 泡 剤： シリコン系（商品名：ＳＮデフォーマー 483、 サンノプコ社製） ０.２ 水： ３９.３ 計 １００.０wt％ 上記エマルジョン原液を水で各種濃度に希釈した後、同
原液および各希釈液に誘引剤として蜂蜜をそれぞれ ０.
５重量％加え、粘度の異なる６種のスプレー組成物の試
料を得た。それらの試料について粘度およびエアスプレ
ー性の適否を調べた結果を、希釈時の原液濃度と共に表
２に示す。 表 ２ 試料番号 濃度（％） 粘度（ｃＰ、２５℃） エアスプレー適否 １ １００ ４,０００ 不適 ２ ９０ ２,０００ 不適 ３ ８０ １,０００ やや不良、使用可 ４ ７０ ４００ 適 ５ ６７ ３００ 適 ６ ５０ ２００ 適 EXAMPLES The present invention will be described below with reference to examples. Various components other than the attractant were mixed in the proportions shown in Table 1 to prepare an emulsion stock solution. Table 1 Composition ratio (wt%) Polybutene: Number average molecular weight 1,260 51.3 Gum: Polyisobutylene, viscosity average molecular weight 1,200,000 1.0 Flow preventer: Silica gel (trade name: Aerosil 130, manufactured by Nippon Aerosil Co., Ltd.) ) 2.7 Emulsifying agent: Polyoxyethylene alkylphenyl ether sulfate ammonium salt 3.6 Emulsifying agent: Dodecylbenzenesulfonic acid amine salt 1.9 Defoaming agent: Silicone (trade name: SN Deformer 483, manufactured by San Nopco) ) 0.2 Water: 39.3 Total 100.0 wt% After diluting the above-mentioned emulsion stock solution with water to various concentrations, honey as an attractant was added to the stock solution and each diluted solution at 0.0% respectively.
5% by weight was added to obtain samples of 6 kinds of spray compositions having different viscosities. The results of investigating the suitability of viscosity and air sprayability of these samples are shown in Table 2 together with the concentration of the stock solution at the time of dilution. Table 2 Sample No. Concentration (%) Viscosity (cP, 25 ° C) Air spray Appropriate 1 100 4,000 Not suitable 2 90 2,000 Not suitable 3 80 1,000 Somewhat poor, usable 4 70 400 Suitable 5 67 300 Suitable 6 50 200 suitable
【００１５】＜捕獲性能実験＞表２の試料番号４、５お
よび６の３試料を、Ｂ４版の台紙にそれぞれエアスプレ
ーにより塗布して塗布シートを得た。１時間放置して乾
燥した後、塗布シートを各２枚ずつ牛舎の壁に貼付して
蝿捕獲性能の試験を行った。３日後に蝿捕獲数を調査し
た結果、各試料の塗布シート２枚の合計はそれぞれ９２
１匹、６５４匹および２７２匹であり、優れた捕獲性能
を示した。<Capture Performance Experiment> The three samples of sample Nos. 4, 5 and 6 in Table 2 were applied to the B4 plate mount by air spray to obtain coated sheets. After left for 1 hour to dry, two application sheets were attached to each wall of the barn to test the fly-capturing performance. As a result of investigating the number of captured flies three days later, the total of two coated sheets for each sample was 92 each.
The number was 1, 654 and 272, which showed excellent capture performance.
【００１６】[0016]
【発明の効果】本発明の小昆虫捕獲用の組成物は、スプ
レー、特にエアスプレーに適するものである。すなわ
ち、ＬＰＧなどの噴射剤を使用せずにスプレーすること
ができるために、安全性が高く、また安価である。The composition for trapping small insects of the present invention is suitable for spraying, particularly for air spraying. That is, since it can be sprayed without using a propellant such as LPG, it is highly safe and inexpensive.
フロントページの続き (72)発明者 世儀 一清 東京都千代田区大手町２−２−１日本曹達 株式会社内 (72)発明者 松田 逵彦 東京都千代田区大手町２−２−１日本曹達 株式会社内Front page continuation (72) Inventor Iksei Seiki 2-2-1 Otemachi, Chiyoda-ku, Tokyo Nippon Soda Co., Ltd. (72) Inventor Tadahiko Matsuda 2-2-1 Otemachi, Chiyoda-ku, Tokyo Nippon Soda Within the corporation
Claims (3)
含有する水性エマルジョンからなる小昆虫捕獲用スプレ
ー組成物。1. A spray composition for trapping small insects, which comprises an aqueous emulsion containing polybutene, water, an emulsifier and an attractant.
において １,０００ｃＰ以下である請求項１に記載の小
昆虫捕獲用スプレー組成物。2. The viscosity of the aqueous emulsion is 25 ° C.
The spray composition for trapping small insects according to claim 1, wherein the spray composition is 1,000 cP or less.
配合割合が、ポリブテン１０〜８０重量％、水２０〜８
０重量％、 乳化剤０.１〜２０重量％および誘引剤 ０.
１〜５重量％である請求項１または２に記載の小昆虫捕
獲用スプレー組成物。3. The blending ratio of each component in the aqueous emulsion is 10 to 80% by weight of polybutene and 20 to 8 of water.
0% by weight, 0.1 to 20% by weight of emulsifier and attractant.
The spray composition for trapping small insects according to claim 1, which is 1 to 5% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32364092A JP3322706B2 (en) | 1992-11-09 | 1992-11-09 | Spray composition for catching small insects |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32364092A JP3322706B2 (en) | 1992-11-09 | 1992-11-09 | Spray composition for catching small insects |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06141747A true JPH06141747A (en) | 1994-05-24 |
| JP3322706B2 JP3322706B2 (en) | 2002-09-09 |
Family
ID=18156984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP32364092A Expired - Fee Related JP3322706B2 (en) | 1992-11-09 | 1992-11-09 | Spray composition for catching small insects |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3322706B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009084394A1 (en) * | 2007-12-28 | 2009-07-09 | Earth Chemical Co., Ltd. | Gel composition for pest insects and gel spray product for pest insects |
-
1992
- 1992-11-09 JP JP32364092A patent/JP3322706B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009084394A1 (en) * | 2007-12-28 | 2009-07-09 | Earth Chemical Co., Ltd. | Gel composition for pest insects and gel spray product for pest insects |
| JP2009161453A (en) * | 2007-12-28 | 2009-07-23 | Earth Chem Corp Ltd | Gel-like composition against harmful insect and gel-like spray product against harmful insect |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3322706B2 (en) | 2002-09-09 |
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