JPH0571923A - Ellipsometry method and thin film measuring device - Google Patents
Ellipsometry method and thin film measuring deviceInfo
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- JPH0571923A JPH0571923A JP23304191A JP23304191A JPH0571923A JP H0571923 A JPH0571923 A JP H0571923A JP 23304191 A JP23304191 A JP 23304191A JP 23304191 A JP23304191 A JP 23304191A JP H0571923 A JPH0571923 A JP H0571923A
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- light
- thin film
- polarization
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Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、偏光解析方法および薄
膜測定装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an ellipsometry method and a thin film measuring apparatus.
【0002】[0002]
【従来の技術】一般に被検体の偏光解析法としては、被
検体への照射光の偏光状態に対する被検体からの光の相
対的な偏光状態の変化を検出するものが知られ、いわゆ
る消光法と測光法に大別される。2. Description of the Related Art Generally, as a polarization analysis method for an object, there is known one which detects a change in relative polarization state of light from the object with respect to a polarization state of irradiation light to the object. It is roughly divided into photometric methods.
【0003】この偏光解析は例えば試料面の屈折率測
定、薄膜試料の場合には膜厚測定に用いられる。上記消
光法とは、位相板の回転により楕円偏光を直線偏光に
し、さらに検光子を回転させて消光する事により楕円状
態を求める方法である。また、上記測光法とは、偏光
子、補償子、検光子のいずれか1個を回転させて、少な
くとも3個以上の角度での光量を測光する事により楕円
状態を求める方法である。This polarization analysis is used, for example, to measure the refractive index of the sample surface and, in the case of a thin film sample, to measure the film thickness. The extinction method is a method of obtaining an elliptic state by rotating the phase plate to make the elliptically polarized light into linearly polarized light and further rotating the analyzer to extinguish the light. The photometric method is a method of obtaining an elliptic state by rotating one of a polarizer, a compensator, and an analyzer to measure the amount of light at at least three angles.
【0004】消光法、測光法は以下のような特徴をも
つ。The extinction method and photometric method have the following features.
【0005】消光法の長所としては、どのような偏光状
態についても精度よく測定が可能であり、短所としては
駆動部が多い為、測定時間が長くなり、耐久性の面で問
題がある等が挙げられる。The advantage of the extinction method is that it can accurately measure any polarization state, and the disadvantage is that it has many driving parts and therefore the measurement time is long and there is a problem in terms of durability. Can be mentioned.
【0006】又、測光法の長所としては測定時間が短か
く、光学系の構成が簡便であり、また、短所としては、
偏光状態全域にわたって高精度測定は難しく、そして、
駆動部がある為、安定性に欠ける等が挙げられる。Further, the advantages of the photometric method are that the measurement time is short, the configuration of the optical system is simple, and the disadvantages are that
High precision measurement is difficult over the entire polarization state, and
Since it has a driving part, it lacks stability.
【0007】ところで近年、半導体分野においては、集
積回路の微細化に伴い、絶縁膜等も薄くなりつつある。
従来測定の簡便さ、速度などの点から膜厚の測定には分
光解析方式の膜厚計が主に使われている。しかし、例え
ばSiO2/Siサンプルで100Å(SiO2)以下の
ものに関しては分光解析方式の膜厚計では、安定した測
定は不可能であり、エリプソメータ(偏光解析方式の膜
厚計)による膜厚測定が行われている。特に、半導体分
野では高速かつ高精度の測定が要求される点から、偏光
解析方式とりわけ前述の測光法が有利である。By the way, in recent years, in the field of semiconductors, with the miniaturization of integrated circuits, insulating films and the like are becoming thinner.
Conventionally, a spectroscopic analysis type film thickness meter is mainly used to measure the film thickness in terms of ease of measurement and speed. However, for example, a SiO 2 / Si sample with a thickness of 100 Å (SiO 2 ) or less cannot be stably measured by a spectroscopic analysis film thickness meter, and the film thickness measured by an ellipsometer (polarization analysis film thickness meter) is not possible. Measurements are being taken. Particularly, in the field of semiconductors, the polarization analysis method, especially the above-described photometric method is advantageous because high-speed and highly accurate measurement is required.
【0008】ここで図23に、測光法で最も一般的であ
る回転検光子型の従来例を示す。光源1からの光は集光
レンズ2により試料13上で最小スポットとなるように
結像される。FIG. 23 shows a conventional example of a rotary analyzer type, which is the most general type of photometric method. The light from the light source 1 is imaged by the condenser lens 2 so as to form a minimum spot on the sample 13.
【0009】集光レンズ2を透過後、偏光子3を透過
し、図2の如くx方向の直線偏光21となる。さらに、
図3のようにθH方向に位相を進ませる方向の軸の設定
されたλ/2板4を透過し、その透過光は図3に示すよ
うな方位角θPの直線偏光22となる。次に図4のよう
にθC方向に位相を進ませる方向の軸の設定されたλ/
4板5を透過して、例えば図4のような楕円偏光25と
なる。ここで、θC、θHの角度は、試料13における偏
光状態変化が精度良く測定できる角度に設定されてい
る。それは図5に示すように試料反射後に略円偏光とな
るようにすれば良い。After passing through the condenser lens 2, it passes through the polarizer 3 to become linearly polarized light 21 in the x direction as shown in FIG. further,
As shown in FIG. 3, the light passes through the λ / 2 plate 4 whose axis is set in the direction of advancing the phase in the θ H direction, and the transmitted light becomes the linearly polarized light 22 having the azimuth angle θ P as shown in FIG. Then set the direction for advancing the phase axis theta C direction as shown in FIG. 4 lambda /
The elliptically polarized light 25 as shown in FIG. 4 is transmitted through the four plates 5. Here, the angles of θ C and θ H are set to angles at which changes in the polarization state of the sample 13 can be accurately measured. As shown in FIG. 5, it may be arranged so that it becomes substantially circularly polarized light after the sample is reflected.
【0010】例えば試料13がSi基板の時は、θH=
50°(θP=10°)、θC=−1°とすれば良い。こ
の時のλ/4板5からの出射光をFor example, when the sample 13 is a Si substrate, θ H =
It may be set to 50 ° (θ P = 10 °) and θ C = −1 °. The light emitted from the λ / 4 plate 5 at this time is
【0011】[0011]
【外1】 として、[Outer 1] As
【0012】[0012]
【外2】 とすれば、x,y方向の振幅比(tanψ0)、位相差
(Δ0)は、 tanψ0=ay0/ax0 Δ0=φy0−φx0 と表せる。[Outside 2] Then, the amplitude ratio (tan ψ 0 ) and the phase difference (Δ 0 ) in the x and y directions can be expressed as tan ψ 0 = a y0 / a x0 Δ 0 = φ y0 −φ x0 .
【0013】つまり、図4の楕円偏光は(ψ0,Δ0)と
表せる。That is, the elliptically polarized light in FIG. 4 can be expressed as (ψ 0 , Δ 0 ).
【0014】いま波長=780nm、θH=50°、θC
=−1°の時は、ψ0=87.82°、Δ0=94.94
°である。Now, wavelength = 780 nm, θ H = 50 °, θ C
= -1 °, ψ 0 = 87.82 °, Δ 0 = 94.94.
°.
【0015】さらに、試料13の偏光特性を(ψ,Δ)
とおけば、反射光26(図5)の偏光特性(ψ′,
Δ′)は、 tanψ′=tanψ0・tanψ〜1.0(ψ〜10
°、Si基板の時) Δ′=Δ0+Δ〜270°(Δ=170°,Si基板の
時) となり、ほぼ円偏光となる。Further, the polarization characteristic of the sample 13 is (ψ, Δ)
In other words, the polarization characteristic (ψ ′, of the reflected light 26 (FIG. 5),
Delta ') is, tanψ' = tanψ 0 · tanψ ~ 1.0 (ψ ~ 10
°, when Si substrate) Δ ′ = Δ 0 + Δ to 270 ° (Δ = 170 °, when Si substrate), which is almost circularly polarized light.
【0016】さて、図23、図7においてy軸を基準と
して時計回りを正として検光子66の透過軸をθAとす
れば、θA方向のみの成分が検光子66を透過してその
光量Now, in FIGS. 23 and 7, if the transmission axis of the analyzer 66 is θ A and the clockwise direction is positive with the y axis as the reference, the component of only the θ A direction is transmitted through the analyzer 66 and the amount of light thereof is increased.
【0017】[0017]
【外3】 が検出器67により測光される。[Outside 3] Is measured by the detector 67.
【0018】例えば、θA=0,90,45,−45°
とした時の光量をI0,I90,I45,I-45とすれば、次
式のように表わされる。For example, θ A = 0, 90, 45, -45 °
When the light quantity at that time is I 0 , I 90 , I 45 , and I −45 , it is expressed as in the following equation.
【0019】 I0=|vey|2・|ay0|2・tan2ψ・tan2ψ0…(1) I90=|vey|2・|ay0|2…(2) I45=1/2|vey|2・|ay0|2・[tan2ψ・tan2ψ0+1+2t anψ・tanψ0・cos(Δ+Δ0)]…(3) I-45=1/2|vey|2・|ay0|2・[tan2ψ・tan2ψ0+1−2 ・tanψ・tanψ0・cos(Δ+Δ0)]…(4)I 0 = | vey | 2 · | ay 0 | 2 · tan 2 ψ · tan 2 ψ 0 (1) I 90 = | vey | 2 · | ay 0 | 2 (2) I 45 = 1 / 2 | vey | 2 · | ay 0 | 2 · [tan 2 ψ · tan 2 ψ 0 + 1 + 2t an ψ · tan ψ 0 · cos (Δ + Δ 0 )] ... (3) I −45 = 1/2 | vey | 2 · | Ay 0 | 2 · [tan 2 ψ · tan 2 ψ 0 + 1-2 −tan ψ · tan ψ 0 · cos (Δ + Δ 0 )] ... (4)
【0020】(1),(2),(3),(4)よりψ,
Δについてとくと、From (1), (2), (3) and (4), ψ,
As for Δ,
【0021】[0021]
【外4】 [Outside 4]
【0022】従って、検光子66を0°,90°,45
°,−45°に回転させて、その時の光量を測光すれば
ψ0,Δ0は既知であるため式(5),(6)からψ,
Δ、つまり試料での偏光状態の変化を求める事ができ
る。Therefore, the analyzer 66 is set to 0 °, 90 °, 45
If the light amount at that time is measured by rotating it by ø, -45 °, then ψ 0 , Δ 0 are known, so from equations (5) and (6) ψ,
Δ, that is, the change in the polarization state of the sample can be obtained.
【0023】一方、例えば図24の様に基板71上に薄
膜72のついた試料の場合、ψ,Δは薄膜72の屈折率
nと膜厚Dの関数である。従って、ψ,Δが求まれば
n,Dが求まる。ψ,Δからn,Dを求める方法として
は、多くのn,Dについてψ,Δ曲線を求めておき、測
定値(ψ,Δ)に最も近い(n,D)を求める方法等が
ある。On the other hand, in the case of a sample having a thin film 72 on a substrate 71 as shown in FIG. 24, ψ and Δ are functions of the refractive index n and the film thickness D of the thin film 72. Therefore, if ψ and Δ are obtained, then n and D are obtained. As a method of obtaining n, D from ψ, Δ, there is a method of obtaining ψ, Δ curves for many n, D and then obtaining (n, D) closest to the measured value (ψ, Δ).
【0024】[0024]
【発明が解決しようとしている課題】しかしながら、前
述した従来例では、以下のような第1、第2の欠点があ
った。即ち第1の欠点としては測定の際に、例えば検光
子を回転させる必要があり、機械的駆動部があるために
測定時間が長い(消光法に比べれば速いが、分光方式の
膜厚計に比べれば遅い)、又機械的駆動部がある為、安
定性に欠けるということである。However, the above-mentioned conventional example has the following first and second drawbacks. That is, the first drawback is that, for example, the analyzer needs to be rotated at the time of measurement, and the measurement time is long because of the mechanical drive section (it is faster than the extinction method, but it is faster than the spectroscopic film thickness meter). It is slower than that) and lacks stability due to the mechanical drive.
【0025】又、第2の欠点としては偏光解析方式の場
合、測定範囲が小さいということである。The second drawback is that the ellipsometry method has a small measuring range.
【0026】[0026]
【課題を解決するための手段】本発明は上記第1の欠点
を解消すべく、ある偏光状態の光束を試料に入射させ該
試料からの光束を複数の偏光方向で光検出し、若しくは
複数の偏光状態の光束を試料に入射させ該試料からの光
束をある偏光方向で光検出し、前記試料の偏光特性を解
析する偏光解析方法であって、偏光子、位相板、検光子
の内の1つの素子を複数箇、少なくとも3つの異なる偏
光状態を形成するように複数の光路内に固設したことを
特徴とする。In order to solve the above-mentioned first drawback, the present invention makes a light beam of a certain polarization state incident on a sample and detects a light beam from the sample in a plurality of polarization directions, or a plurality of light beams is detected. A polarization analysis method for injecting a light beam in a polarization state into a sample, detecting the light beam from the sample in a certain polarization direction, and analyzing the polarization characteristics of the sample, which is one of a polarizer, a phase plate, and an analyzer. One element is fixed in a plurality of optical paths so as to form a plurality of at least three different polarization states.
【0027】又、本発明は上記第2の欠点を解消すべく
ある偏光状態の光束を薄膜試料に入射させ該薄膜からの
光束の偏光状態を検出する偏光解析方式により薄膜の光
路長情報を測定する手段と、分光反射率方式若しくは白
色干渉方式により薄膜の光路長情報を測定する手段を有
することを特徴とする。Further, according to the present invention, the optical path length information of a thin film is measured by a polarization analysis method in which a light beam having a certain polarization state is incident on a thin film sample to detect the polarization state of the light beam from the thin film in order to solve the second drawback. And a means for measuring optical path length information of the thin film by a spectral reflectance method or a white light interference method.
【0028】[0028]
【作用】上記第1の欠点を解消すべく、例えば第1の実
施例に示す如く機械的駆動部を介さずに偏光子、位相板
を介し試料に楕円偏光を照射し、試料からの反射光を検
光子を介して、少なくとも3つの異なる偏光方向に対応
して個別に光検出する。なお光検出は少なくとも3つの
光検出器で同時に行う若しくは単一の光検出器で順次に
行う。In order to eliminate the above-mentioned first drawback, for example, as shown in the first embodiment, the sample is irradiated with elliptically polarized light through a polarizer and a phase plate without passing through a mechanical driving unit, and reflected light from the sample is reflected. Are individually detected via the analyzer in correspondence with at least three different polarization directions. The light detection is performed by at least three photodetectors simultaneously or sequentially by a single photodetector.
【0029】上記第2の欠点を解消すべく薄膜に関し偏
光解析方式の光路長測定系と、分光反射率方式若しくは
白色干渉方式の光路長測定系を備える。In order to solve the above-mentioned second drawback, a polarization analysis type optical path length measuring system and a spectral reflectance type or white light interference type optical path length measuring system are provided for the thin film.
【0030】[0030]
【実施例】図1に、本発明の第1の実施例を示す。1は
例えば半導体レーザ、He−Neレーザー等の光源、2
は光源の光を集光する為のレンズ、3は偏光子、4はλ
/2板、5はλ/4板、6は光束を2分割する為のビー
ム・スプリッターである。7、8は直交する2方向の振
動成分のみを、一方透過・他方反射させる為の検光子
(偏光プリズム又は偏光ビームスプリッタ)であり、検
光子8は入射光軸のまわりに45°回転変位される。9
〜12はフォトダイオード等の光電検出器、13は試
料、14はビーム・スプリッター6による反射光束、1
5は同じく透過光束である。1 shows a first embodiment of the present invention. 1 is a light source such as a semiconductor laser or He-Ne laser, and 2
Is a lens for collecting the light of the light source, 3 is a polarizer, 4 is λ
/ 2 plate, 5 is a λ / 4 plate, and 6 is a beam splitter for splitting a light beam into two. Reference numerals 7 and 8 denote analyzers (polarizing prisms or polarizing beam splitters) for transmitting and reflecting the vibration components in two orthogonal directions on one side, and the analyzer 8 is rotationally displaced by 45 ° about the incident optical axis. It 9
˜12 is a photoelectric detector such as a photodiode, 13 is a sample, 14 is a luminous flux reflected by the beam splitter 6,
Reference numeral 5 is also a transmitted light flux.
【0031】光源1からの光は集光レンズ2により試料
13上で最小スポットとなるよう結像される。The light from the light source 1 is imaged by the condenser lens 2 so as to form a minimum spot on the sample 13.
【0032】光源1からの光は集光レンズ2を透過後、
偏光子3を透過し図2に示す方向の直線偏光となる。さ
らに図3のようにθH方向にfast軸の設定されたλ
/2板4を透過し、その透過光は図3に示すような方位
角θPの直線偏光22となる。次に図4のようにθC方向
にfast軸の設定されたλ/4板5を透過して、例え
ば図4のような楕円偏光25となる。ここでθC,θHの
角度は、試料13における偏光状態変化が、精度良く測
定できる、即ち反射光量が多く得られる角度に設定され
ている。それは試料反射後に円偏光となるようにすれば
良い。The light from the light source 1 passes through the condenser lens 2,
The light is transmitted through the polarizer 3 and becomes linearly polarized light in the direction shown in FIG. Further, as shown in FIG. 3, λ with the fast axis set in the θ H direction
After passing through the / 2 plate 4, the transmitted light becomes linearly polarized light 22 having an azimuth angle θ P as shown in FIG. Next, as shown in FIG. 4, the light passes through the λ / 4 plate 5 having the fast axis set in the θ C direction, and becomes elliptically polarized light 25 as shown in FIG. 4, for example. Here, the angles θ C and θ H are set so that the change in the polarization state of the sample 13 can be accurately measured, that is, a large amount of reflected light can be obtained. It may be circularly polarized after the sample is reflected.
【0033】例えば、試料13がSi基板の時はθH=
50°(θP=10°)、θC=−1°とすれば良い。For example, when the sample 13 is a Si substrate, θ H =
It may be set to 50 ° (θ P = 10 °) and θ C = −1 °.
【0034】この時のλ/4板5からの出射光をThe light emitted from the λ / 4 plate 5 at this time is
【0035】[0035]
【外5】 として、[Outside 5] As
【0036】[0036]
【外6】 とすれば、x,y方向の振幅比(tanψ0)、位相差
(Δ0)、tanψ0=ay0/ax0,Δ0=ay0−ax0と
表せる。[Outside 6] Then, the amplitude ratio (tan ψ 0 ) in the x and y directions, the phase difference (Δ 0 ), tan ψ 0 = a y0 / a x0 , and Δ 0 = a y0 −a x0 can be expressed.
【0037】つまり図4の楕円偏光は(ψ0,Δ0)と表
せる。That is, the elliptically polarized light in FIG. 4 can be expressed as (ψ 0 , Δ 0 ).
【0038】θH=50°,θC=−1°の時はψ0=8
7.82°,Δ0=94.94°である。When θ H = 50 ° and θ C = -1 °, ψ 0 = 8
7.82 ° and Δ 0 = 94.94 °.
【0039】さらに、試料13の偏光特性を(ψ,Δ)
とおけば、図5に示すように反射光26の偏光特性
(ψ′,Δ′)は、 tanψ′=tanψ0・tanψ〜1.0(ψ〜10
°,Si基板の時) Δ′=Δ0+Δ〜270°(Δ=170°、Si基板の
時) となり、ほぼ円偏光となる。Further, the polarization characteristic of the sample 13 is (ψ, Δ)
If you put the polarization characteristics of the reflected light 26 as shown in FIG. 5 (ψ ', Δ') is, tanψ '= tanψ 0 · tanψ ~ 1.0 (ψ ~ 10
°, when Si substrate) Δ ′ = Δ 0 + Δ to 270 ° (Δ = 170 °, when Si substrate), which is almost circularly polarized light.
【0040】次に、円偏光26は、ビーム・スプリッタ
ー6により反射光束14と透過光束15に分けられ、透
過光束15から、検光子7によって図6に示すような方
向の29と30の成分のみを得、反射光束14から、検
光子8によって図7に示すような方向32、33の成分
のみを得ることができる。ここで反射光束14は、透過
光束15は、ビーム・スプリッターの振幅、位相特性の
影響で一般には楕円偏光である。図6、図7における角
度をy軸基準に右回りを正として、θAとすれば、 θA=0°(符号29) 90°(符号30) 45°(符号32) −45°(符号33)であり、 順に、センサ12、センサ11、センサ10、センサ9
によって検出される。各出力I0,I90,I45,I-45と
以下記す。Next, the circularly polarized light 26 is divided into a reflected light beam 14 and a transmitted light beam 15 by the beam splitter 6, and only the components 29 and 30 in the directions shown in FIG. Then, the analyzer 8 can obtain only the components in the directions 32 and 33 as shown in FIG. 7 from the reflected light flux 14. Here, the reflected light beam 14 and the transmitted light beam 15 are generally elliptically polarized light due to the influence of the amplitude and phase characteristics of the beam splitter. 6, the angle as positive a clockwise y axis reference in FIG. 7, if θ A, θ A = 0 ° ( reference numeral 29) 90 ° (reference numeral 30) 45 ° (reference numeral 32) -45 ° (code 33), and sensor 12, sensor 11, sensor 10, sensor 9 in that order.
Detected by. The outputs I 0 , I 90 , I 45 , and I −45 will be described below.
【0041】ここで、ビーム・スプリッター6の特性
を、Here, the characteristics of the beam splitter 6 are
【0042】[0042]
【外7】 とおき、さらに[Outside 7] Toki, further
【0043】[0043]
【外8】 ΔBR=φRP−φRS とおけば各センサー9〜12の出力は、[Outside 8] If we say Δ BR = φ RP −φ RS , the output of each sensor 9-12 is
【0044】[0044]
【外9】 (ここで、K2 A1〜K2 A4は、センサ12、11、10、
9のゲイン感度×各検光子の透過率、Veyは試料13の
S方向の振幅反射率を表わす。)[Outside 9] (Here, K 2 A1 to K 2 A4 are sensors 12, 11, 10,
9 gain sensitivity × transmittance of each analyzer, V ey represents the amplitude reflectance of the sample 13 in the S direction. )
【0045】(A)・(B)・(C)・(D)からψ、
Δについてとくと、From (A), (B), (C), and (D), ψ,
As for Δ,
【0046】[0046]
【外10】 [Outside 10]
【0047】従って、式(E)と(F)において、試料
入射前の特性<ψ0,Δ0>、ビーム・スプリッター特性
<ψBT,ψBR,ΔBR,|TS|,|RS|>、各センサー
の感度×検光子透過率<K2 A1〜K2 A4>を入力しておけ
ば、センサ12、11、10、9の出力I0,I90,I
45,I-45を測定する事により、試料13の特性<ψ,
Δ>を測定する事ができる。Therefore, in the equations (E) and (F), the characteristics <ψ 0 , Δ 0 > before the incidence of the sample, the beam splitter characteristics <ψ BT , ψ BR , Δ BR , | T S |, | RS |>, Sensitivity of each sensor × analyzer transmittance <K 2 A1 to K 2 A4 >, the outputs I 0 , I 90 , I of the sensors 12, 11, 10 , 9 are input.
By measuring 45 and I −45 , the characteristics of sample 13 <ψ,
Δ> can be measured.
【0048】次に図8〜図13に第2の実施例を示す。
実施例1では図6、図7に示すように4方向の偏光成分
を検出していたが、本実施例では図9に示す如く3方向
のみの検出で、Δ,ψを求める。実施例1においても、
4方向の検出を行わなくてもいずれか3方向のみで計算
式を偏光する事により、Δ,ψは求まる。Next, FIGS. 8 to 13 show a second embodiment.
In the first embodiment, the polarization components in four directions are detected as shown in FIGS. 6 and 7, but in the present embodiment, Δ and ψ are obtained by detection in only three directions as shown in FIG. Also in Example 1,
Even if detection in four directions is not performed, Δ and ψ can be obtained by polarizing the calculation formula in only three directions.
【0049】次に図10〜図11に第3の実施例を示
す。本実施例は第1実施例の変形であり、4方向の偏光
成分の検出を行っているが、ビーム・スプリッタ41、
42の2つで2回光路を分けた後、検光子43、44、
45の3個を介して光検出器46〜49で4方向の検出
を行う。Next, FIGS. 10 to 11 show a third embodiment. This embodiment is a modification of the first embodiment and detects polarization components in four directions, but the beam splitter 41,
After splitting the optical path twice with the two 42, the analyzers 43, 44,
The photodetectors 46 to 49 detect the light in four directions through the three photosensors 45.
【0050】ここで検光子44、45は入射光軸のまわ
りに各々時計方向、反時計方向に45°回転されてい
る。次に図12〜図13に、第4の実施例を示す。ビー
ム・スプリッタ51の透過光束をビーム・スプリッタ5
2で2光路に分け、一方ビーム・スプリッタ51による
反射光束をビーム・スプリッタ53で2光路に分け、全
部で4光路に分割された光線を検光子54〜57で図1
3に示す如く全て異なる合計8個の偏光成分にして検出
器58〜65で測光する。ここで検光子56、57、5
8は入射光軸のまわりに各々45°回転されている。本
実施例では多成分検出により精度向上をはかることがで
きる。なお第2、3、4の実施例ともに、Δ,ψの計算
式は全て異なるが、第1実施例に示したのと同様の手順
で求める事ができる。Here, the analyzers 44 and 45 are rotated around the incident optical axis by 45 ° in the clockwise and counterclockwise directions, respectively. Next, FIGS. 12 to 13 show a fourth embodiment. The transmitted light flux of the beam splitter 51 is changed to the beam splitter 5
2, the light beam reflected by the beam splitter 51 is split into two optical paths by the beam splitter 53, and the rays split into a total of four optical paths are analyzed by the analyzers 54 to 57.
As shown in FIG. 3, a total of eight polarization components different from each other are formed, and photometry is performed by the detectors 58 to 65. Here the analyzers 56, 57, 5
8 are each rotated by 45 ° about the incident optical axis. In this embodiment, it is possible to improve accuracy by detecting multi-components. Although the formulas for calculating Δ and ψ are different in the second, third, and fourth embodiments, they can be obtained by the same procedure as that shown in the first embodiment.
【0051】さて以上の実施例は検光子を回転変位して
光路中に固設したものであるが、図14〜図16に示す
如く偏光子を回転変位して光路中に固設しても良く、
又、図17〜図18に示す如く位相板を回転変位して光
路中に固設しても良い。即ち図14で偏光子P1,P2の
内、偏光子P1は入射光軸のまわりに45°回転変位さ
れており半導体レーザ等の光源LD1,LD2は各々偏光
子P1を透過、反射して図15の偏光成分が維持され
る。又光源LD3,LD4は各々偏光子P2を反射、透過
して図16の偏光成分が維持される。In the above embodiment, the analyzer is rotationally displaced and fixed in the optical path. However, even if the polarizer is rotationally displaced and fixed in the optical path as shown in FIGS. well,
The phase plate may be rotationally displaced and fixed in the optical path as shown in FIGS. That is, in FIG. 14, among the polarizers P 1 and P 2 , the polarizer P 1 is rotationally displaced by 45 ° around the incident optical axis, and the light sources LD 1 and LD 2 such as a semiconductor laser transmit the polarizer P 1 respectively. , And the polarization component of FIG. 15 is maintained. The light sources LD 3 and LD 4 respectively reflect and transmit the polarizer P 2 to maintain the polarization component of FIG.
【0052】時系列的に順次点滅される光源LD1〜L
D4からの光はビーム・スプリッターBS,λ/4板C
を介し4種類の楕円偏光で試料に入射し、任意の方向に
固設された検光子Aを介して単一の光検出器で略同時に
受光され、順次得られる光検出器の出力をI0,I90,
I45,I-45として検出する。Light sources LD 1 to L which are sequentially blinked in time series
Light from D 4 is beam splitter BS, λ / 4 plate C
Incident on the sample at four elliptically polarized light through the substantially is received simultaneously by a single photodetector via an analyzer A which is fixed in any direction, the output of the sequentially obtained photodetectors I 0 , I 90 ,
It is detected as I 45 and I −45 .
【0053】次に図17に示す実施例では偏光子P1,
P2は共に入射光軸のまわりに回転変位されず、替わり
にλ/4板C1,C2が位相を進ませる方向の軸を入射光
軸のまわりに各々θ1,θ2(θ1とθ2は異なる角度)回
転変位されている。Next, in the embodiment shown in FIG. 17, the polarizers P 1 ,
Both P 2 are not rotationally displaced around the incident optical axis, but instead, the axes of the directions in which the λ / 4 plates C 1 and C 2 advance the phase are θ 1 and θ 2 (θ 1 respectively) around the incident optical axis. And θ 2 are different angles).
【0054】そして図14の実施例と同様に光源LD1
〜LD4からの光は図18に示す偏光成分を有し、λ/
4板C1,C2,ビーム・スプリッターBSを介し4種類
の楕円偏光で試料に入射し、任意の方向に固設された検
光子Aを介して単一の光検出器で略同時に受光され、順
次得られる光検出器の出力をI0,I90,I45,I-45と
して検出する。Then, similarly to the embodiment of FIG. 14, the light source LD 1
Light from LD 4 has a polarization component shown in FIG.
The four types of elliptically polarized light are incident on the sample through the four plates C 1 and C 2 and the beam splitter BS, and are received substantially simultaneously by a single photodetector through an analyzer A fixed in an arbitrary direction. , The outputs of the photodetectors obtained in sequence are detected as I 0 , I 90 , I 45 , and I −45 .
【0055】次に偏光解析方式の他に、特開昭63−4
4106号公報、特開昭62−201304号公報等に
知られる分光反射率方式若しくは特開昭59−1055
08号公報等に知られる白色干渉方式の膜厚測定系を併
せもつ実施例について図19〜図22を基に説明する。
この場合偏光解析方式としては図23に示した如き従来
の回転型でも良く、又図1、図14、図17に示した固
定型でも良い。偏光解析方式の他に、分光反射率方式若
しくは白色干渉方式の膜厚測定系を併せもつ実施例によ
れば偏光解析方式単一の装置に比べ測定範囲が拡大す
る。即ち偏光解析方式で測定できない光路長に対し、分
光反射率方式若しくは白色干渉方式で測定できる。又、
同一被検部を測定する場合に測定スポットのより大きな
偏光解析方式と測定スポットのより小さな分光反射率方
式若しくは白色干渉方式とを切換えて測定することもで
きる。Next, in addition to the polarization analysis method, Japanese Patent Laid-Open No. 63-4
4106, Japanese Patent Laid-Open No. 62-201304, and the like, or the spectral reflectance method, or Japanese Laid-Open Patent Publication No. 59-1055.
An embodiment having a film thickness measuring system of a white light interference method known from Japanese Patent Laid-Open No. 08 etc. will be described with reference to FIGS.
In this case, the polarization analysis method may be the conventional rotary type as shown in FIG. 23 or the fixed type as shown in FIGS. 1, 14, and 17. In addition to the polarization analysis method, according to the embodiment having a spectral reflectance method or a white light interference method film thickness measurement system, the measurement range is expanded as compared with a single device of the polarization analysis method. That is, the optical path length that cannot be measured by the polarization analysis method can be measured by the spectral reflectance method or the white light interference method. or,
When measuring the same test portion, it is possible to switch between the polarization analysis method with a larger measurement spot and the spectral reflectance method with a smaller measurement spot, or the white light interference method.
【0056】更には偏光解析方式の測定を行えば前述し
た通り試料の屈折率が実際に測定できるため、予め屈折
率を予想して求める従来例に比べ、該試料に対する分光
反射率方式若しくは白色干渉方式による光路長データか
ら偏光解説方式で求められた屈折率で割ることにより膜
厚を精度良く求めることもできる。Further, since the refractive index of the sample can be actually measured as described above by performing the polarization analysis method, the spectral reflectance method or the white interference with respect to the sample can be compared with the conventional example in which the refractive index is predicted in advance. It is also possible to obtain the film thickness accurately by dividing the optical path length data by the method by the refractive index obtained by the polarization explanation method.
【0057】又別々の装置を備える場合に比べ設置面積
を小さくでき、搬送系も共有できるという利点を備え
る。なお図20、図22はそれぞれ図19、図21の主
要部を示す。Further, compared with the case where separate devices are provided, the installation area can be reduced and the transport system can be shared. 20 and 22 show the main parts of FIGS. 19 and 21, respectively.
【0058】さて図19の101は分光反射率方式に使
用する照明部、102は分光反射率方式及び偏光解析方
式の観察用に使用する対物レンズ、103は分光反射率
方式に使用する分光器、104は顕微鏡鏡筒、105、
106は分光反射率方式及び偏光解析方式の測定位置観
察用として用いるTVカメラとTVモニタ、107は偏
光解析方式の発光部、108は同じく受光部で107、
108の発光部、受光部は一体化して顕微鏡鏡筒と結合
している。109は分光反射率方式、偏光解析方式の機
器を駆動させるコントローラ、110は測定値から膜厚
計算を行い全システムを統括するコンピュータ部、11
1は試料例えばシリコンウエハを自動搬送する搬送部、
112は試料である。測定を行う場合は、まず搬送部1
11によって試料112が測定位置迄搬送され、その試
料上の膜厚の管理値が、数Åから数100Åの場合は、
コンピュータ110からの指示により偏光解析方式にて
測定を行い100Åから30μmの場合は、分光反射率
方式にて測定を行う。分光反射率方式により測定を行う
場合、その被測定膜厚が屈折率を測定できる膜厚の場合
(例えば、Si基板上のSiO膜では500Å程度以
上)測定信頼性を上げる為にあらかじめ偏光解析方式に
より屈折率を測定してからその測定屈折率を用いて分光
反射率方式の方法により測定する。また数千Åの時は分
光反射率方式から測定膜厚値D1を求め、さらに偏光解
析方式により測定膜厚値D′n(n=1,2,…i…n
−1,n)がn個求まるまでD1に近いD′iを決定する
ことができる。In FIG. 19, 101 is an illumination unit used for the spectral reflectance method, 102 is an objective lens used for observation of the spectral reflectance method and polarization analysis method, 103 is a spectroscope used for the spectral reflectance method, 104 is a microscope lens barrel, 105,
Reference numeral 106 is a TV camera and TV monitor used for observing the measurement position of the spectral reflectance method and polarization analysis method, 107 is a light emission section of the polarization analysis method, 108 is also a light reception section 107,
The light emitting portion and the light receiving portion of 108 are integrally connected to the microscope barrel. Reference numeral 109 is a controller for driving a device of the spectral reflectance system and ellipsometry system, 110 is a computer unit for calculating the film thickness from the measured values and controlling the entire system, 11
1 is a transfer unit for automatically transferring a sample, for example, a silicon wafer,
112 is a sample. When performing the measurement, first, the transport unit 1
When the sample 112 is conveyed to the measurement position by 11 and the control value of the film thickness on the sample is several Å to several 100 Å,
According to an instruction from the computer 110, the measurement is performed by the polarization analysis method, and in the case of 100Å to 30 μm, the measurement is performed by the spectral reflectance method. When measuring with the spectral reflectance method, if the film thickness to be measured is a film thickness capable of measuring the refractive index (for example, about 500 Å or more for the SiO film on the Si substrate), the polarization analysis method is used in advance to improve the measurement reliability. Then, the refractive index is measured by using the spectral reflectance method. When the thickness is several thousand Å, the measured film thickness value D 1 is obtained from the spectral reflectance method, and further, the measured film thickness value D ′ n (n = 1, 2, ...
D ′ i close to D 1 can be determined until n−1, n) are obtained.
【0059】図21は他の実施例を示し、106、10
7、108、110、112は前述したTVモニタ、発
光部、受光部、コンピュータ、試料をあらわしている。
109′は白色干渉方式と偏光解析方式の機器を駆動さ
せるコントローラ、113は白色干渉方式の光学部であ
る。光学部の中には観察用のTVカメラが含まれてお
り、偏光解析方式の観察にも使用する。FIG. 21 shows another embodiment, 106 and 10.
Reference numerals 7, 108, 110, and 112 represent the TV monitor, the light emitting unit, the light receiving unit, the computer, and the sample described above.
Reference numeral 109 'is a controller for driving a white interference type and polarization analysis type device, and 113 is a white interference type optical unit. A TV camera for observation is included in the optical section, and it is also used for polarization analysis observation.
【0060】図22は偏光解析方式の測定系を示し、1
13は光源、114は偏光子及び位相板、115は検光
子、116は光検出器である。本実施例では試料の搬送
部を除いているが、搬送部を加えたシステムも可能であ
る。FIG. 22 shows a polarization analysis type measurement system.
Reference numeral 13 is a light source, 114 is a polarizer and a phase plate, 115 is an analyzer, and 116 is a photodetector. In the present embodiment, the sample transfer section is excluded, but a system with a transfer section is also possible.
【0061】測定を行うにあたっては、まず試料を測定
位置に置き、その試料上の膜厚の管理値が数Åから数1
00Åの場合はコンピュータ110からの指示により偏
光解析方式にて測定を行い、2μmから30μmの場合
は白色干渉方式で測定を行う。白色干渉方式により測定
を行う場合、その被測定膜厚が屈折率を測定できる膜厚
の場合(例えば、Si基板上のSiO膜では500Å程
度以上)測定信頼性を上げる為に、あらかじめ偏光解析
方式により屈折率を測定してから、その測定屈折率を用
いて白色干渉方式により測定する。In the measurement, the sample is first placed at the measurement position, and the control value of the film thickness on the sample is from several Å to several 1
In the case of 00Å, the measurement is performed by the polarization analysis method according to the instruction from the computer 110, and in the case of 2 μm to 30 μm, the measurement is performed by the white interference method. When performing measurement by the white light interference method, when the film thickness to be measured is a film thickness capable of measuring the refractive index (for example, about 500 Å or more for the SiO film on the Si substrate), the polarization analysis method is used in advance in order to improve the measurement reliability. Then, the refractive index is measured by using the white interference method.
【0062】[0062]
【発明の効果】以上、本発明によれば簡便な偏光解析、
正確な膜厚測定が可能となる。As described above, according to the present invention, simple ellipsometry,
Accurate film thickness measurement is possible.
【図1】複数個の検光子を用いた本発明の第1の実施例
の図である。FIG. 1 is a diagram of a first embodiment of the present invention using a plurality of analyzers.
【図2】偏光子を介した直線偏光を示す図である。FIG. 2 is a diagram showing linearly polarized light passing through a polarizer.
【図3】λ/2板を介した直線偏光を示す図である。FIG. 3 is a diagram showing linearly polarized light through a λ / 2 plate.
【図4】λ/4板を介した楕円偏光を示す図である。FIG. 4 is a diagram showing elliptically polarized light through a λ / 4 plate.
【図5】試料を反射した円偏光を示す図である。FIG. 5 is a diagram showing circularly polarized light reflected from a sample.
【図6】一方の検光子を介した偏光成分を示す図であ
る。FIG. 6 is a diagram showing a polarization component via one analyzer.
【図7】他方の検光子を介した偏光成分を示す図であ
る。FIG. 7 is a diagram showing a polarization component via the other analyzer.
【図8】図1の実施例の変形例を示す図である。FIG. 8 is a diagram showing a modification of the embodiment of FIG.
【図9】図8の変形例の偏光成分を示す図である。9 is a diagram showing polarization components of the modified example of FIG.
【図10】図1の実施例の変形例を示す図である。FIG. 10 is a diagram showing a modification of the embodiment of FIG.
【図11】図10の変形例の偏光成分を示す図である。FIG. 11 is a diagram showing polarization components of the modified example of FIG.
【図12】図1の実施例の変形例を示す図である。FIG. 12 is a diagram showing a modification of the embodiment of FIG.
【図13】図12の変形例の偏光成分を示す図である。FIG. 13 is a diagram showing polarization components of the modified example of FIG.
【図14】複数個の偏光子を用いた本発明の第2の実施
例の図である。FIG. 14 is a diagram of a second embodiment of the present invention using a plurality of polarizers.
【図15】一方の偏光子を介した偏光成分を示す図であ
る。FIG. 15 is a diagram showing a polarization component via one of the polarizers.
【図16】他方の偏光子を介した偏光成分を示す図であ
る。FIG. 16 is a diagram showing a polarization component via the other polarizer.
【図17】複数個の位相板を用いた本発明の第3の実施
例の図である。FIG. 17 is a diagram of a third embodiment of the present invention using a plurality of phase plates.
【図18】位相板に入射する偏光成分を示す図である。FIG. 18 is a diagram showing polarization components incident on a phase plate.
【図19】偏光解析方式の光路長測定系と分光反射率方
式の光路長測定系を併せ持つ実施例の図である。FIG. 19 is a diagram of an embodiment having both a polarization analysis type optical path length measurement system and a spectral reflectance type optical path length measurement system.
【図20】図19の主要部概略図である。20 is a schematic view of a main part of FIG.
【図21】偏光解析方式の光路長測定系と白色干渉方式
の光路長測定系を併せ持つ実施例の図である。FIG. 21 is a diagram of an embodiment having both a polarization analysis type optical path length measurement system and a white light interference type optical path length measurement system.
【図22】図21の偏光解析方式の測定系の主要部概略
図である。22 is a schematic diagram of a main part of the ellipsometry measurement system in FIG. 21. FIG.
【図23】従来例の図である。FIG. 23 is a diagram of a conventional example.
【図24】基板に薄膜のついた試料を示す図である。FIG. 24 is a diagram showing a sample having a thin film on a substrate.
1 光源 3 偏光子 4 λ/2板 5 λ/4板 6 ビームスプリッタ 7,8 検光子 9,10,11,12 光電検出器 101 分光反射率方式に使用する照明部 103 分光器 105 TVカメラ 106 TVモニタ 107 偏光解析方式の発光部 108 偏光解析方式の受光部 109,109′ コントローラ 111 搬送部 112 試料 113 白色干渉方式の光学部 1 Light Source 3 Polarizer 4 λ / 2 Plate 5 λ / 4 Plate 6 Beam Splitter 7, 8 Analyzer 9, 10, 11, 12 Photoelectric Detector 101 Illuminator Used for Spectral Reflectance Method 103 Spectroscope 105 TV Camera 106 TV monitor 107 Polarization analysis light emitting unit 108 Polarization analysis light receiving unit 109, 109 ′ Controller 111 Transport unit 112 Sample 113 White interference type optical unit
Claims (9)
試料からの光束を複数の偏光方向で光検出し、若しくは
複数の偏光状態の光束を試料に入射させ該試料からの光
束をある偏光方向で光検出し、前記試料の偏光特性を解
析する偏光解析方法であって、 偏光子、位相板、検光子の内の1つの素子を複数箇、少
なくとも3つの異なる偏光状態を形成するように複数の
光路内に固設したことを特徴とする偏光解析方法。1. A light beam having a certain polarization state is made incident on a sample, and light beams from the sample are detected in a plurality of polarization directions, or light beams having a plurality of polarization states are made incident on the sample and the light beam from the sample is made into a certain polarization. A polarization analysis method for detecting light in a specific direction and analyzing the polarization characteristics of the sample, wherein a plurality of elements of one of a polarizer, a phase plate, and an analyzer are formed to form at least three different polarization states. An ellipsometry method characterized by being fixed in a plurality of optical paths.
る直線偏光を形成するように複数の光路内に固設し、少
なくとも3つの異なる偏光方向に対応して光検出を同時
に行う請求項1記載の偏光解析方法。2. A plurality of analyzers are fixed in a plurality of optical paths so as to form at least three different linearly polarized lights, and light detection is simultaneously performed corresponding to at least three different polarization directions. Polarization analysis method.
も3つの異なる楕円偏光を形成するように複数の光路内
に固設し、対応する各光源を順次点灯し、検光子を介し
てある偏光方向で順次光検出する請求項1記載の偏光解
析方法。3. A plurality of polarization or phase plates, fixed in a plurality of optical paths so as to form at least three different elliptically polarized lights, sequentially turn on the corresponding light sources, and a polarization direction via an analyzer. The polarization analysis method according to claim 1, wherein the light detection is sequentially performed by.
せ該薄膜からの光束の偏光状態を検出する偏光解析方式
により薄膜の光路長情報を測定する手段と、 分光反射率方式若しくは白色干渉方式により薄膜の光路
長情報を測定する手段を有することを特徴とする薄膜測
定装置。4. A means for measuring optical path length information of a thin film by a polarization analysis method in which a light beam having a certain polarization state is made incident on a thin film sample and the polarization state of the light beam from the thin film is detected; and a spectral reflectance method or a white light interference method. A thin film measuring apparatus having means for measuring optical path length information of the thin film.
の屈折率、及び前記分光反射率方式若しくは白色干渉方
式により検出される薄膜の光路長を基に薄膜の膜厚を演
算する手段を備える請求項4記載の薄膜測定装置。5. A means for calculating the thickness of the thin film based on the refractive index of the thin film detected by the polarization analysis method and the optical path length of the thin film detected by the spectral reflectance method or the white light interference method. Item 4. The thin film measurement apparatus according to item 4.
報を測定する手段は、偏光子、位相板、検光子の内の1
つの素子を複数箇、少なくとも3つの異なる偏光状態を
形成するように複数の光路内に固設した請求項4記載の
薄膜測定装置。6. The means for measuring the optical path length information of the thin film by the polarization analysis method is one of a polarizer, a phase plate and an analyzer.
The thin film measuring apparatus according to claim 4, wherein a plurality of elements are fixed in the plurality of optical paths so as to form at least three different polarization states.
を備え且つ薄膜からの反射光路に光分割手段を備え、該
光分割手段で分割された各光路に複数の検光子を固設
し、該検光子を介して少なくとも3つの光検出器を有し
異なる偏光方向に対応して前記少なくとも3つの光検出
器で同時検出する請求項6記載の薄膜測定装置。7. A single light source and a polarizer are provided in the incident light path to the thin film, a light splitting means is provided in the reflection light path from the thin film, and a plurality of analyzers are fixed in each light path split by the light splitting means. 7. The thin film measuring apparatus according to claim 6, wherein the thin film measuring apparatus is provided with at least three photodetectors through the analyzer, and the at least three photodetectors simultaneously detect corresponding polarization directions.
該光分割手段で分割された光源側の各光路に複数の光
源、複数の偏光子若しくは位相板を固設して少なくとも
3つの異なる楕円偏光を形成し、薄膜からの反射光路に
ある単一の検光子、光検出器を介して異なる楕円偏光に
対応して順次各光源を点灯して前記単一の光検出器で順
次検出する請求項6記載の薄膜測定装置。8. A light splitting means is provided in an optical path incident on the thin film,
A plurality of light sources, a plurality of polarizers or a phase plate are fixedly provided in each light path on the light source side divided by the light splitting means to form at least three different elliptically polarized lights, and a single light path in a reflection light path from the thin film is formed. 7. The thin film measuring apparatus according to claim 6, wherein each light source is sequentially turned on corresponding to different elliptically polarized lights through an analyzer and a photodetector, and the single photodetector sequentially detects.
報を測定する手段は、前記光束分割手段又は前記光検出
器の特性を入力して薄膜の光路長情報を測定する請求項
7若しくは請求項8記載の薄膜測定装置。9. The method for measuring optical path length information of a thin film by the polarization analysis method, wherein the optical path length information of the thin film is measured by inputting characteristics of the light beam splitting means or the photodetector. 8. The thin film measuring device according to 8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23304191A JPH0571923A (en) | 1991-09-12 | 1991-09-12 | Ellipsometry method and thin film measuring device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23304191A JPH0571923A (en) | 1991-09-12 | 1991-09-12 | Ellipsometry method and thin film measuring device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0571923A true JPH0571923A (en) | 1993-03-23 |
Family
ID=16948878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23304191A Pending JPH0571923A (en) | 1991-09-12 | 1991-09-12 | Ellipsometry method and thin film measuring device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0571923A (en) |
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|---|---|---|---|---|
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| US5596406A (en) * | 1993-07-16 | 1997-01-21 | Therma-Wave, Inc. | Sample characteristic analysis utilizing multi wavelength and multi angle polarization and magnitude change detection |
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1991
- 1991-09-12 JP JP23304191A patent/JPH0571923A/en active Pending
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|---|---|---|---|---|
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