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JPH0566094B2 - - Google Patents

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Publication number
JPH0566094B2
JPH0566094B2 JP60075375A JP7537585A JPH0566094B2 JP H0566094 B2 JPH0566094 B2 JP H0566094B2 JP 60075375 A JP60075375 A JP 60075375A JP 7537585 A JP7537585 A JP 7537585A JP H0566094 B2 JPH0566094 B2 JP H0566094B2
Authority
JP
Japan
Prior art keywords
mirin
phytic acid
amount
seasoning
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP60075375A
Other languages
Japanese (ja)
Other versions
JPS61234756A (en
Inventor
Kazuo Tsuzuki
Hiroaki Shimizu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NAKANO SUTEN KK
Original Assignee
NAKANO SUTEN KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NAKANO SUTEN KK filed Critical NAKANO SUTEN KK
Priority to JP60075375A priority Critical patent/JPS61234756A/en
Publication of JPS61234756A publication Critical patent/JPS61234756A/en
Publication of JPH0566094B2 publication Critical patent/JPH0566094B2/ja
Granted legal-status Critical Current

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Description

【発明の詳細な説明】[Detailed description of the invention]

本発明はみりん風調味料の製造法に関し、詳し
くは褐変が有効に防止されたみりん風調味料の製
造法に関する。 ここで、みりん風調味料とほ米等を原料として
発酵により得られた香味液に糖類その他必要に応
じて呈味剤等を加えた一般に市販されているアル
コール分1%未満の甘味系調味料を総称したもの
である。 従来よりみりん風調味料は製造工場から消費者
の手に渡るまでに様々な流通段階を経るため、そ
の間の温度、光等の影響により少しづつ褐変が起
こることは避けられなかつた。このような状況
下、褐変を可及的に抑えて良好な品質を保持した
みりん風調味料が望まれていた。 みりん風調味老の品質向上に関する技術として
特開昭52−99294号、同56−8566号、同56−18567
号、同56−18568号、同59−130163号等があるが、
いずれも防腐性の付与を目的としたものであり、
褐変防止効果を目的としたものは見当らない。 本発明者らは天然物の中からかかる効果を有す
る物質を検索すべく検討を重ね、その過程でフイ
チン酸がすぐれた褐変防止作用を有していること
を見出した。本発明はこの知見に基いて完成され
たものである。 すなわち本発明は、みりん風調味料にフイチン
酸を0.50w/w%以下の割合で添加することを特
徴とするみりん風調味料の製造法である。 本発明においてみりん風調味料としては、前述
したように、甘味系調味料として定義されるもの
を意味し、褐変防止が望まれるすべてのみりん風
調味料が対象とされる。 次に、フイチン酸とは米糖、とうもろこし胚芽
等の天然物から抽出される酸であり、発酵助成
剤、金属封鎖剤、酸化防止剤等の様々な効果が認
められているものであり、通常は50%水溶液とし
て流通している。本発明では50%フイチン酸水溶
液に限定されず、各種のものが使用される。フイ
チン酸の添加量については、みりん風調味料に対
して0.50w/w%以下の割合、通常は0.05〜
0.50w/w%、好ましくは0.15〜0.25w/w%の範
囲である。これはフイチン酸として0.05w/w%
未満の添加量では、十分な褐変防止効果が認めら
れず、一方0.50w/w%を越えると、官能上酸味
が強くなりすぎてしまうからである。 本発明にしたがいフイチン酸を添加することに
より、みりん風調味料は褐変が有効に防止され、
長期間にわたり良好な品質が保持される。 また、みりん風調味料は防カビ効果を発揮させ
るために酢酸または酢酸と酢酸塩を添加すること
が知られているが、このような酢酸等を加えて防
カビ効果を奏する場合、フイチン酸を添加するこ
とにより酢酸の使用量を20〜50%程度減らすこと
ができる。さらに、このみりん風調味料にリン酸
塩を添加して防腐性を付与することも知られてい
るが、この場合もフイチン酸の添加によつて酢酸
等やリン酸塩の使用量を大幅に減らすことが可能
である。通常、酢酸の使用量としては酢の物、ド
レツシング等では1.0〜2.0%前後であるが、他の
食品においては酸味が嫌味にならない程度が望ま
しく、一般に0.3%以下であれば問題がないとさ
れている。また、リン酸塩の使用量はその目的に
より異なり、0.01〜1.0程度の広範囲で使用され
ている現状である。ここで、酢酸とは醸造酢、食
酢、合成酢の総称であり、酢酸塩としては酢酸ナ
トリウム、酢酸カルシウム等がある。また、リン
酸塩とはメタリン酸ナトリウムを主体とした重合
リン酸塩を意味する。 このように、本発明によれば、フイチン酸の所
定量を添加することによつてみりん風調味料の褐
変を防止するとともに、防カビ効果や防腐効果を
向上させるために用いられる酢酸等やリン酸塩の
使用量を節減させることができる。 次に、本発明を実施例により説明する。 実施例 1 下記第1表の処方によつて各種のみりん風調味
料を調製し、透明ビンに充填後、90℃で60分の殺
菌を行ない、冷却して供試料とした。これらの供
試料を室温にて20W螢光灯を平均10時間/日照射
し、3ケ月毎に肉眼観察および420nmにおける
吸光度を測定して比較した。結果を第2表に示
す。
The present invention relates to a method for producing a mirin-like seasoning, and more particularly to a method for producing a mirin-like seasoning in which browning is effectively prevented. Here, we use mirin-style seasoning and a sweet seasoning with an alcohol content of less than 1%, which is generally commercially available and is made by adding sugars and other flavoring agents as necessary to the flavor liquid obtained by fermentation using rice, etc. as raw materials. It is a general term for. Traditionally, mirin-style seasonings go through various stages of distribution from the manufacturing factory to the consumer's hands, so it was inevitable that browning would occur little by little due to the effects of temperature, light, etc. Under these circumstances, a mirin-style seasoning that suppresses browning as much as possible and maintains good quality has been desired. Japanese Patent Application Laid-open Nos. 52-99294, 56-8566, and 56-18567 as techniques for improving the quality of mirin-style seasoned roe.
No. 56-18568, No. 59-130163, etc.
Both are intended to impart preservative properties,
I have not found anything aimed at preventing browning. The present inventors conducted repeated studies to search for substances having such an effect among natural products, and in the process discovered that phytic acid has an excellent browning prevention effect. The present invention was completed based on this knowledge. That is, the present invention is a method for producing a mirin-like seasoning characterized by adding phytic acid to the mirin-like seasoning at a ratio of 0.50 w/w% or less. In the present invention, mirin-like seasonings refer to those defined as sweet seasonings, as described above, and include all mirin-like seasonings for which prevention of browning is desired. Next, phytic acid is an acid extracted from natural products such as rice sugar and corn germ, and is recognized to have various effects such as a fermentation aid, a sequestering agent, and an antioxidant. is distributed as a 50% aqueous solution. The present invention is not limited to a 50% phytic acid aqueous solution, and various types can be used. The amount of phytic acid added is 0.50w/w% or less relative to mirin-style seasoning, usually 0.05~
It is 0.50 w/w%, preferably in the range of 0.15 to 0.25 w/w%. This is 0.05w/w% as phytic acid
If the amount added is less than 0.50 w/w%, a sufficient browning prevention effect will not be observed, while if it exceeds 0.50 w/w%, the sour taste will become too strong. By adding phytic acid according to the present invention, browning of the mirin-style seasoning can be effectively prevented,
Good quality is maintained for a long period of time. Additionally, it is known that acetic acid or acetic acid and acetate are added to mirin-style seasonings in order to have an anti-mold effect, but when such acetic acid is added to have an anti-mold effect, phytic acid is added. By adding it, the amount of acetic acid used can be reduced by about 20 to 50%. Furthermore, it is known that phosphates are added to this mirin-style seasoning to give it preservative properties, but in this case too, the amount of acetic acid and phosphates used can be significantly reduced by adding phytic acid. It is possible to reduce Normally, the amount of acetic acid used is around 1.0 to 2.0% for vinegared dishes, dressings, etc., but for other foods, it is desirable that the sourness does not become unpleasant, and it is generally considered that there is no problem if it is 0.3% or less. . Furthermore, the amount of phosphate used varies depending on the purpose, and is currently used in a wide range of about 0.01 to 1.0. Here, acetic acid is a general term for brewed vinegar, table vinegar, and synthetic vinegar, and examples of acetate include sodium acetate and calcium acetate. Further, phosphate refers to a polymerized phosphate mainly composed of sodium metaphosphate. As described above, according to the present invention, by adding a predetermined amount of phytic acid, browning of mirin-like seasonings can be prevented, and acetic acid and phosphorus, which are used to improve the antifungal and antiseptic effects, can be added. The amount of acid salt used can be reduced. Next, the present invention will be explained by examples. Example 1 Various mirin-like seasonings were prepared according to the formulations shown in Table 1 below, filled into transparent bottles, sterilized at 90°C for 60 minutes, and cooled to give test samples. These specimens were irradiated with a 20W fluorescent lamp at room temperature for an average of 10 hours/day, and were visually observed and measured for absorbance at 420 nm every 3 months for comparison. The results are shown in Table 2.

【表】【table】

【表】 第2表から明らかなように、フイチン酸を添加
することによりみりん風調味料の褐変防止効果は
コントロールおよび他の天然酸化防止剤添加のも
のと比較して明らかにすぐれている。しかも、フ
イチン酸による効果は添加量の多少はあまり影響
がない。なお、吸光度の値について説明すると、
80%と79%では肉眼的には明確な差異を判別し難
いが、73%以下になると容易に肉眼判別が可能と
なり、これらは商品価値が半減したものである。 実施例 2 フイチン酸の添加量が味覚に及ぼす影響につい
て調べるため、実施例1の供試料のうちコントロ
ール、A、DおよびFの4種類についてパネル18
名にて二元配置法による評点法にて官能テストを
行なつた。評点は良い:5点、やや良い:4点、
普通:3点、やや悪い:2点、悪い:1点の5段
階に分類した。結果を第3表に示す。
[Table] As is clear from Table 2, the browning prevention effect of mirin-like seasonings by adding phytic acid is clearly superior compared to the control and those containing other natural antioxidants. Moreover, the effect of phytic acid is not affected much by the amount added. In addition, to explain the absorbance value,
It is difficult to tell a clear difference between 80% and 79% with the naked eye, but it becomes easy to tell with the naked eye when it is 73% or less, which means that the commercial value has been halved. Example 2 In order to investigate the effect of the amount of phytic acid added on taste, panel 18 was prepared for four types of samples of Example 1, control, A, D, and F.
A sensory test was conducted using a scoring method based on the two-way configuration method. Ratings are good: 5 points, moderately good: 4 points,
It was classified into 5 levels: fair: 3 points, somewhat poor: 2 points, and poor: 1 point. The results are shown in Table 3.

【表】 表中の平均点について各試料間の差を検定する
と、コントロール←→F、A←→FおよびD←→F間で
危険率5%で有意差が認められた。この結果よ
り、みりん風調味料の味覚上の見地よりフイチン
酸の添加量は0.5w/w%以下とすることが望ま
しい。 実施例 3 実施例1に示した供試料と同じものを用い、醸
造酢と酢酸ナトリウムの添加による防カビ効果に
対するフイチン酸の影響について検討した。 まず、コントロールを未殺菌のまま30℃の恒温
室に入れて培養し、繁殖したアスペルギルス属と
ペニシリウム属のカビのみを採取して殺菌した前
記供試料に常法により103個/mlの割合で植菌し、
30℃の恒温室に保管してカビの発生を肉眼観察に
より比較した。結果を第4表に示す。
[Table] When the difference between each sample was tested for the average score in the table, a significant difference was observed among control←→F, A←→F, and D←→F at a risk rate of 5%. From this result, it is desirable that the amount of phytic acid added be 0.5 w/w% or less from the taste standpoint of the mirin-style seasoning. Example 3 Using the same sample as shown in Example 1, the influence of phytic acid on the antifungal effect of the addition of brewed vinegar and sodium acetate was investigated. First, the control was cultured in an unsterilized thermostatic chamber at 30°C, and only the grown Aspergillus and Penicillium molds were collected and sterilized. Inoculate and
They were stored in a constant temperature room at 30°C and the growth of mold was compared by visual observation. The results are shown in Table 4.

【表】【table】

【表】 表から明らかなように、フイチン酸は単独では
防カビ効果を有していないが、或程度の防カビ効
果がある供試料(既知の有効使用量の半量とした
もの)にフイチン酸を僅か0.1%添加することに
よつて防カビ効果を著しく向上させることができ
る。すなわち、酢酸等の使用量を半減させても十
分な防カビ効果を奏することができる。 実施例 4 酢酸等のリン酸塩の併用によるみりん風調味料
の防腐効果に対するフイチン酸の影響について検
討した。 まず、実施例3と同様にコントロールを未殺菌
のまま30℃恒温室にて培養して繁殖したアスペル
ギルス属とペニシリウム属のカビを採取し、これ
にチゴサツカロミセス属の酵母を加えて混合し
た。この混合菌を12種類の殺菌した供試料(第5
表参照)に対し常法により103個/mlの割合で植
菌したのち30℃の室に保管し、カビの発生と酵母
の湧きを同時に肉眼観察して比較した。結果を第
6表に示す。
[Table] As is clear from the table, phytic acid alone does not have an antifungal effect, but phytic acid was added to a sample (half of the known effective amount used) that has a certain degree of antifungal effect. The antifungal effect can be significantly improved by adding just 0.1% of . That is, even if the amount of acetic acid used is halved, a sufficient antifungal effect can be achieved. Example 4 The influence of phytic acid on the preservative effect of mirin-like seasonings by the combined use of phosphates such as acetic acid was investigated. First, as in Example 3, molds of the genus Aspergillus and Penicillium that had grown by culturing the control in an unsterilized thermostatic chamber at 30°C were collected, and yeast of the genus Chigosaccharomyces was added and mixed. . This mixed bacteria was sterilized into 12 types of test samples (No. 5
After inoculating the cells (see table) at a rate of 10 3 cells/ml using a conventional method, they were stored in a room at 30°C, and the growth of mold and the emergence of yeast were simultaneously observed and compared with the naked eye. The results are shown in Table 6.

【表】【table】

【表】【table】

【表】 表から明らかなように、酢酸等やリン酸塩を既
知の有効使用量より少ない量で添加しても十分な
防腐効果は得られない(供試料ヘ)が、少量のフ
イチン酸を併用することによつてみりん風調味料
の防腐効果は著しく向上する(供試料ニ、ホ、チ
など)。
[Table] As is clear from the table, a sufficient preservative effect cannot be obtained even if acetic acid or phosphate is added in an amount smaller than the known effective usage amount (for the sample), but a small amount of phytic acid When used together, the preservative effect of mirin-style seasonings is significantly improved (sample samples d, h, chi, etc.).

Claims (1)

【特許請求の範囲】 1 みりん風調味料にフイチン酸を0.50w/w%
以下の割合で添加することを特徴とするみりん風
調味料の製造法。 2 フイチン酸の添加量が0.05〜0.50w/w%で
ある特許請求の範囲第1項記載の方法。 3 みりん風調味料が酢酸と酢酸塩の混合物を含
有するものである特許請求の範囲第1項記載の方
法。 4 みりん風調味料が酢酸と酢酸塩の混合物およ
びリン酸塩を含有するものである特許請求の範囲
第1項記載の方法。
[Claims] 1 0.50w/w% phytic acid in mirin-style seasoning
A method for producing a mirin-style seasoning characterized by adding it in the following proportions. 2. The method according to claim 1, wherein the amount of phytic acid added is 0.05 to 0.50 w/w%. 3. The method according to claim 1, wherein the mirin-like seasoning contains a mixture of acetic acid and acetate. 4. The method according to claim 1, wherein the mirin-like seasoning contains a mixture of acetic acid and acetate, and a phosphate.
JP60075375A 1985-04-11 1985-04-11 Production of mirin-like seasoning Granted JPS61234756A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60075375A JPS61234756A (en) 1985-04-11 1985-04-11 Production of mirin-like seasoning

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60075375A JPS61234756A (en) 1985-04-11 1985-04-11 Production of mirin-like seasoning

Publications (2)

Publication Number Publication Date
JPS61234756A JPS61234756A (en) 1986-10-20
JPH0566094B2 true JPH0566094B2 (en) 1993-09-21

Family

ID=13574394

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60075375A Granted JPS61234756A (en) 1985-04-11 1985-04-11 Production of mirin-like seasoning

Country Status (1)

Country Link
JP (1) JPS61234756A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0661748A1 (en) * 1993-12-28 1995-07-05 Hitachi, Ltd. Semiconductor device

Also Published As

Publication number Publication date
JPS61234756A (en) 1986-10-20

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