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JPH05331597A - High fatigue strength coil spring - Google Patents

High fatigue strength coil spring

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Publication number
JPH05331597A
JPH05331597A JP16213692A JP16213692A JPH05331597A JP H05331597 A JPH05331597 A JP H05331597A JP 16213692 A JP16213692 A JP 16213692A JP 16213692 A JP16213692 A JP 16213692A JP H05331597 A JPH05331597 A JP H05331597A
Authority
JP
Japan
Prior art keywords
less
coil spring
wire
spring
resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP16213692A
Other languages
Japanese (ja)
Inventor
Teruyuki Murai
照幸 村井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Electric Industries Ltd
Original Assignee
Sumitomo Electric Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Electric Industries Ltd filed Critical Sumitomo Electric Industries Ltd
Priority to JP16213692A priority Critical patent/JPH05331597A/en
Publication of JPH05331597A publication Critical patent/JPH05331597A/en
Pending legal-status Critical Current

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Abstract

(57)【要約】 【目的】 自動車エンジン用弁ばねなどに用いられ、耐
疲労性,耐へたり性に優れたコイルばねを提供する。 【構成】 重量比で、C:0.5〜0.8%、Si:
1.2〜2.5%、Mn:0.4〜0.8%、Cr:
0.7〜1.0%、N:0.005〜0.030%を含
有し、かつV:0.1〜0.6%、Mo:0.05〜
0.50%、W:0.05〜0.50%の2種又は3種
以上を含有して、残部がFe及び不可避的不純物からな
り、不可避的不純物のAl含有量を0.005%以下、
同Ti含有量を0.005%以下とする線材に、パテン
ティング、伸線加工、及び焼入れ焼戻し処理を施し、得
られた鋼線をばね成形したコイルばねで、表面粗さがR
max10μm以下である。
(57) [Summary] [Purpose] To provide a coil spring which is used in a valve spring for an automobile engine and has excellent fatigue resistance and sag resistance. [Structure] C: 0.5-0.8% by weight, Si:
1.2-2.5%, Mn: 0.4-0.8%, Cr:
0.7-1.0%, N: 0.005-0.030%, and V: 0.1-0.6%, Mo: 0.05-
0.50%, W: 0.05 to 0.50% of 2 or 3 types, the balance of Fe and unavoidable impurities, Al content of the unavoidable impurities is 0.005% or less ,
A coil spring obtained by subjecting a wire having the same Ti content of 0.005% or less to patenting, wire drawing, and quenching and tempering, and spring-forming the obtained steel wire.
The maximum is 10 μm or less.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、自動車エンジンの弁ば
ねなどに用いられる、耐疲労性に優れたコイルばねに関
するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coil spring having excellent fatigue resistance, which is used for a valve spring of an automobile engine.

【0002】[0002]

【従来の技術】従来、自動車等のエンジンに使用される
弁ばね用鋼線としては、弁ばね用炭素鋼オイルテンパー
線(JIS SWO-V) 、弁ばね用クロムバナジウム鋼オイルテ
ンパー線線(JIS SWOCV-V) 及び弁ばね用シリコンクロム
鋼オイルテンパー線(JIS SWOSC-V) 等が用いられてい
る。とりわけ、弁ばね用シリコンクロム鋼オイルテンパ
ー線は、耐疲労性,耐熱性の点で優れており、広く使用
されている。しかし、最近のエンジンの高性能化に十分
対応しているとはいえず、これをベースに介在物レベル
をさらに低減したりして耐疲労性の向上を図っている。
2. Description of the Related Art Conventionally, as a steel wire for a valve spring used in an engine of an automobile or the like, a carbon steel oil temper wire for a valve spring (JIS SWO-V), a chrome vanadium steel oil temper wire for a valve spring (JIS SWOCV-V) and silicon chrome steel oil tempered wire for valve springs (JIS SWOSC-V) are used. Above all, the silicon chrome steel oil tempered wire for valve springs is widely used because of its excellent fatigue resistance and heat resistance. However, it cannot be said that it has sufficiently coped with the recent high performance of the engine, and based on this, the level of inclusions is further reduced to improve fatigue resistance.

【0003】又、疲労強度を上げる方法として、窒化処
理が広く利用されるようになっている。この方法は、塩
浴中若しくはガス雰囲気中で処理するもので、高温で処
理するほどその効果が大きい。しかし、弁ばねの場合、
高温で処理すると強度の低下を生じる。現行、最も耐熱
性のある弁ばね用シリコンクロムオイルテンパー線で
も、380〜420℃でしか処理できず、これ以上の温
度で窒化処理すると、強度が低下し、耐疲労性や耐へた
り性の低下を招く。
Further, nitriding has been widely used as a method for increasing fatigue strength. This method is carried out in a salt bath or in a gas atmosphere, and the higher the temperature, the greater the effect. But in the case of valve springs,
When treated at high temperature, strength is reduced. Currently, even the most heat-resistant silicon chrome oil tempered wire for valve springs can be processed only at 380 to 420 ° C, and nitriding at a temperature higher than this lowers the strength, resulting in fatigue resistance and sag resistance. Cause decline.

【0004】本発明は、このような技術的背景のもとに
なされたもので、自動車エンジンの高出力化、ばね使用
雰囲気の高温化に対応できるよう、耐疲労性,耐へたり
性に優れたコイルばねを提供することを目的とするもの
である。
The present invention has been made based on such a technical background, and is excellent in fatigue resistance and sag resistance so as to cope with high output of automobile engines and high temperature of atmosphere in which springs are used. It is intended to provide a coil spring.

【0005】[0005]

【発明が解決しようとする課題】この目的を達成するた
めに、本発明コイルばねは、重量比で、C:0.5〜
0.8%、Si:1.2〜2.5%、Mn:0.4〜
0.8%、Cr:0.7〜1.0%、N:0.005〜
0.030%を含有し、かつV:0.1〜0.6%、M
o:0.05〜0.50%、W:0.05〜0.50%
の2種又は3種以上を含有して、残部がFe及び不可避
的不純物からなり、不可避的不純物のAl含有量を0.
005%以下、同Ti含有量を0.005%以下とする
線材に、パテンティング、伸線加工及び焼入れ焼戻し処
理を施し、得られた鋼線をばね成形したもので、表面粗
さがRmax10μm以下であることを特徴とする。
To achieve this object, the coil spring of the present invention has a weight ratio of C: 0.5 to.
0.8%, Si: 1.2 to 2.5%, Mn: 0.4 to
0.8%, Cr: 0.7-1.0%, N: 0.005-
0.030% and V: 0.1-0.6%, M
o: 0.05 to 0.50%, W: 0.05 to 0.50%
2 or 3 or more and the balance consists of Fe and unavoidable impurities, and the Al content of the unavoidable impurities is 0.
A wire rod having a Ti content of 005% or less and a Ti content of 0.005% or less is subjected to patenting, wire drawing and quenching and tempering treatment, and the obtained steel wire is spring-formed. The surface roughness is Rmax 10 μm or less. Is characterized by

【0006】以下に本発明コイルばねの組成限定理由な
どを詳細に説明する。
The reasons for limiting the composition of the coil spring of the present invention will be described in detail below.

【0007】C:0.5〜0.8wt% Cは鋼線の強度を高めるために必須の元素であるが、
0.5%未満では十分な強度が得られず、逆に0.8%
を越えると靱性が低下し、さらに鋼線の疵感受性が増長
するために信頼性が低下するからである。
C: 0.5 to 0.8 wt% C is an essential element for increasing the strength of the steel wire,
If less than 0.5%, sufficient strength cannot be obtained, and conversely 0.8%
If it exceeds 1.0, the toughness decreases, and the susceptibility of the steel wire to defects increases, so that the reliability decreases.

【0008】Si:1.2〜2.5wt% Siはフェライトの強度を向上させ、耐へたり性を向上
させるのに有効な元素である。1.2%未満ではその十
分な効果がなく、逆に2.5%を越える場合は、冷間加
工性を低下させると共に、熱間加工や熱処理による脱炭
を助長するからである。
Si: 1.2 to 2.5 wt% Si is an element effective for improving the strength of ferrite and improving the sag resistance. This is because if it is less than 1.2%, there is no sufficient effect, and if it exceeds 2.5%, cold workability is deteriorated and decarburization by hot working or heat treatment is promoted.

【0009】Mn:0.4〜0.8wt% Mnは、鋼の焼入れ性を向上させ、鋼中のSを固定して
その害を阻止するが、0.4%未満ではその効果がな
い。逆に0.8%を越えると靱性が低下するためであ
る。
Mn: 0.4 to 0.8 wt% Mn improves the hardenability of steel and fixes S in the steel to prevent its damage, but if it is less than 0.4%, it has no effect. On the contrary, if it exceeds 0.8%, the toughness decreases.

【0010】Cr:0.7〜1.0wt% CrはMn同様、鋼の焼入れ性を向上させ、かつ熱間圧
延後のパテンティング処理により靱性を付与し、焼入れ
した後、焼戻し処理時の軟化抵抗性を高め、高強度化す
るのに有効な元素である。0.7%未満ではその効果が
少なく、逆に1.0%を越えると炭化物の固溶を抑制
し、強度の低下を招くと共に、焼入れ性の過度の増大と
なって靱性の低下をもたらすからである。
Cr: 0.7 to 1.0 wt% Cr, like Mn, improves the hardenability of steel, imparts toughness by patenting treatment after hot rolling, and softens during tempering after quenching. It is an element effective in increasing resistance and increasing strength. If it is less than 0.7%, its effect is small. On the contrary, if it exceeds 1.0%, solid solution of carbides is suppressed, strength is lowered, and hardenability is excessively increased, resulting in lower toughness. Is.

【0011】N:0.005〜0.030wt% NはAlと結合して結晶粒の微細化に寄与すると共にフ
ェライトの固溶強化元素として働くが、0.005%未
満ではその効果が不十分であり、0.030%を越える
と靱性の低下を招くからである。
N: 0.005 to 0.030 wt% N combines with Al to contribute to the refinement of crystal grains and acts as a solid solution strengthening element for ferrite, but if less than 0.005%, the effect is insufficient. This is because if it exceeds 0.030%, the toughness is lowered.

【0012】V:0.1〜0.6wt% Vは鋼中において、炭化物を形成し、オーステナイト結
晶粒を微細化し、耐久性を向上させるが、0.1%未満
ではこの効果が得られない。又、0.6%を越えると炭
化物の固溶を抑制する傾向にあり、熱処理悪影響を及ぼ
すからである。
V: 0.1 to 0.6 wt% V forms carbides in steel and refines austenite crystal grains to improve durability, but if less than 0.1%, this effect cannot be obtained. . On the other hand, if it exceeds 0.6%, the solid solution of carbide tends to be suppressed, which adversely affects the heat treatment.

【0013】Mo:0.05〜0.50wt% Moはばねの耐へたり性を向上するのに有効な元素であ
ると共に、焼戻し軟化抵抗を高め、耐久性を付与するも
のである。しかし0.05%未満ではその効果が少な
く、逆に0.50%を越えると伸線加工性の低下を招く
からである。
Mo: 0.05 to 0.50 wt% Mo is an element effective in improving the sag resistance of the spring, and also enhances the temper softening resistance and imparts durability. However, if it is less than 0.05%, its effect is small, and if it exceeds 0.50%, the wire drawability is deteriorated.

【0014】W:0.05〜0.50wt% WはCと結合して炭化物を形成し、結晶粒の微細化を図
ると共に、焼戻し軟化抵抗を高め、耐久性を与えるもの
である。しかし、0.05%未満ではその効果が少な
く、逆に、0.50%を越えても前記効果の向上が望め
ないからである。
W: 0.05 to 0.50 wt% W combines with C to form a carbide, which makes the crystal grains finer and also increases the resistance to temper softening and imparts durability. However, if it is less than 0.05%, the effect is small, and conversely, if it exceeds 0.50%, the improvement of the effect cannot be expected.

【0015】Al,Ti:0.005wt%以下 これらはいずれも高融点介在物であるAl23 ,Ti
Oを生成する。これらの介在物は硬質で、鋼線直下に存
在した場合疲労強度を著しく低下させる。このため、不
可避的な不純物とはいえ、いずれも0.005%以下と
した。原料において、これら不純物濃度が低いものを用
いれば良い。
Al, Ti: 0.005 wt% or less All of these are high melting point inclusions of Al 2 O 3 and Ti.
Generate O. These inclusions are hard and, if present immediately below the steel wire, significantly reduce the fatigue strength. Therefore, although they are unavoidable impurities, the content of each of them is set to 0.005% or less. A raw material having a low concentration of these impurities may be used.

【0016】コイルばねへの成形は、例えば次のような
工程にて行う。先ず、上記のような組成の金属を圧延に
て線材とし、これにパテンティング処理を施して、伸線
加工を施す。次に、A3 点以上の温度に加熱して、オー
ステナイト化し、焼入れ処理を施してマルテンサイト変
態させる。その後適当な温度にて焼戻し処理を行い、ば
ね成形を施す。さらに、ばね成形した後、窒化処理やシ
ョットピーニング処理を施して一層の耐疲労性の向上を
図ることができる。
The coil spring is formed in the following steps, for example. First, a metal having the above composition is rolled into a wire rod, which is subjected to patenting treatment and wire drawing. Next, it is heated to a temperature of A 3 point or higher to form austenite, and is subjected to quenching treatment to transform into martensite. After that, tempering is performed at an appropriate temperature and spring forming is performed. Further, after the spring forming, nitriding treatment or shot peening treatment can be performed to further improve fatigue resistance.

【0017】コイルばねの表面粗さについて コイルばねの表面粗さは、これが平滑であれば一層疲労
強度を向上させることができる。このような観点から、
Rmaxで10μm以下とすることで、疲労強度向上の
著しい向上が見られることが判明した。尚、焼入れ、焼
戻し前の鋼線における表面粗さの調整は、伸線での加工
度を調整することで対応し、必要に応じて、伸線後機械
的研磨を施してもよい。又、コイルばねの表面粗さの調
整に関しては、機械的研磨、ショットピーニング、酸
洗、電解研磨等の方法が用いられる。
Regarding Surface Roughness of Coil Spring If the surface roughness of the coil spring is smooth, the fatigue strength can be further improved. From this perspective,
It was found that when the Rmax is 10 μm or less, the fatigue strength is remarkably improved. The surface roughness of the steel wire before quenching and tempering is adjusted by adjusting the workability in wire drawing, and mechanical polishing may be performed after wire drawing if necessary. For adjusting the surface roughness of the coil spring, methods such as mechanical polishing, shot peening, pickling, and electrolytic polishing are used.

【0018】[0018]

【実施例】【Example】

(実施例1)以下、本発明の一実施例について説明す
る。表1に示す各サンプルを用意し、これを誘導溶解炉
にて溶解して、熱間圧延にて直径6.5mmの線材に加
工した。ここで、F,G,Hは比較例で、F=JIS SWOS
C-V 、G=JIS SWOCV-V 、H=JIS SWO-V である。この
線材を熱処理した後、皮はぎ処理をして直径6.2mm
にし、冷間伸線により直径3.8mmに加工した。さら
に、焼入れ,焼戻し処理を施して表2に示す機械的特性
の鋼線を得た。
(Embodiment 1) An embodiment of the present invention will be described below. Each sample shown in Table 1 was prepared, melted in an induction melting furnace, and hot-rolled into a wire having a diameter of 6.5 mm. Here, F, G, and H are comparative examples, and F = JIS SWOS
CV, G = JIS SWOCV-V, H = JIS SWO-V. After this wire is heat treated, it is peeled off and the diameter is 6.2 mm.
And processed into a diameter of 3.8 mm by cold drawing. Further, quenching and tempering treatments were performed to obtain steel wires having the mechanical properties shown in Table 2.

【0019】[0019]

【表1】 [Table 1]

【0020】[0020]

【表2】 [Table 2]

【0021】このような鋼線を表3に示す諸元のばねに
成形し、これに420℃×30分の歪み取り焼鈍を行
い、460℃×6時間の窒化処理を行った。続いて、直
径0.7mmのカットワイヤ、さらに同0.3mmのス
チールボールを用い、各々30分間のショットピーニン
グ処理を行った。さらに、200℃×20分間の低温焼
鈍を行った。ここでのコイルばねの表面粗さはいずれも
Rmaxで4〜8μmの範囲であった。そして、得られ
たコイルばねについて星型疲労試験機を用いて疲労試験
を行った。
Such a steel wire was formed into a spring having the specifications shown in Table 3, strain relief annealing was carried out at 420 ° C. for 30 minutes, and nitriding treatment was carried out at 460 ° C. for 6 hours. Subsequently, a shot wire with a diameter of 0.7 mm and a steel ball with a diameter of 0.3 mm were used for shot peening treatment for 30 minutes each. Further, low temperature annealing was performed at 200 ° C. for 20 minutes. The surface roughness of the coil springs here was in the range of 4 to 8 μm in Rmax. Then, a fatigue test was performed on the obtained coil spring using a star fatigue tester.

【0022】[0022]

【表3】 [Table 3]

【0023】試験条件は、平均応力を637MPaに
し、応力振幅を変化させて5×107回まで繰り返し応
力を付加し、折損しない応力振幅を疲労限とした。試験
結果を表4に示す。
The test conditions were such that the average stress was 637 MPa, the stress amplitude was changed and repeated stress was applied up to 5 × 10 7 times, and the stress amplitude that did not break was the fatigue limit. The test results are shown in Table 4.

【0024】[0024]

【表4】 [Table 4]

【0025】同表に示すように、本発明の実施例(A〜
E)は比較例(F〜H)と比べいずれも優れた疲労特性
を有していることが確認された。さらに、同じコイルば
ねを用い、230℃の温度で686MPaのねじり応力
を96時間加えたときのへたり量を調べてみた。その結
果を残留せん断歪量として表5に示す。
As shown in the table, the embodiments of the present invention (A to
It was confirmed that all of E) had excellent fatigue properties as compared with Comparative Examples (F to H). Further, the same coil spring was used to examine the amount of sag when a torsional stress of 686 MPa was applied at a temperature of 230 ° C. for 96 hours. The results are shown in Table 5 as the residual shear strain amount.

【0026】[0026]

【表5】 [Table 5]

【0027】同表に示すように、本発明実施例は、どの
比較例よりも残留せん断歪量が少なく、優れた耐熱性を
有していることが確認された。
As shown in the table, it was confirmed that the examples of the present invention had less residual shear strain amount than any of the comparative examples and had excellent heat resistance.

【0028】(実施例2)次に、前記サンプルのうちA
及びDに示す組成の鋼線を用い、焼入れ、焼戻し前の鋼
線の表面粗さを調整し、その後実施例1と同様の焼入
れ,焼戻し処理、ばね成形、窒化処理、ショットピーニ
ング処理を行って、表面粗さが約4〜18μmのコイル
ばねを作製した。そして、これらの各々について実施例
1と同様の疲労試験を行った。その結果を表6に示す。
(Embodiment 2) Next, among the above samples, A
And the surface roughness of the steel wire before quenching and tempering was adjusted using the steel wire having the composition shown in D, and then the same quenching, tempering treatment, spring forming, nitriding treatment and shot peening treatment as in Example 1 were performed. A coil spring having a surface roughness of about 4 to 18 μm was produced. Then, a fatigue test similar to that in Example 1 was performed for each of these. The results are shown in Table 6.

【0029】[0029]

【表6】 [Table 6]

【0030】以上の結果より、コイルばねの表面粗さ
は、Rmaxで10μm以下であれば疲労特性に優れる
ことが確認された。
From the above results, it was confirmed that if the surface roughness of the coil spring was 10 μm or less in Rmax, the fatigue characteristics were excellent.

【0031】[0031]

【発明の効果】以上説明したように、組成と表面粗さを
限定することで、優れた疲労特性を持つコイルばねを得
ることができる。又、耐熱性も改善され、高温での窒化
処理が可能となり、一層疲労特性を向上させることがで
きる。従って、近年高性能化の進む自動車エンジンの弁
ばねなどに有効利用することが期待できる。
As described above, the coil spring having excellent fatigue characteristics can be obtained by limiting the composition and the surface roughness. Further, heat resistance is also improved, nitriding treatment can be performed at high temperature, and fatigue characteristics can be further improved. Therefore, it can be expected to be effectively used for valve springs of automobile engines, which have been improved in performance in recent years.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 重量比で、C:0.5〜0.8%、S
i:1.2〜2.5%、Mn:0.4〜0.8%、C
r:0.7〜1.0%、N:0.005〜0.030%
を含有し、かつV:0.1〜0.6%、Mo:0.05
〜0.50%、W:0.05〜0.50%の2種又は3
種以上を含有して、残部がFe及び不可避的不純物から
なり、不可避的不純物のAl含有量を0.005%以
下、同Ti含有量を0.005%以下とする線材に、パ
テンティング、伸線加工、及び焼入れ焼戻し処理を施
し、得られた鋼線をばね成形したもので、表面粗さがR
max10μm以下であることを特徴とする高疲労強度
コイルばね。
1. A weight ratio of C: 0.5 to 0.8%, S
i: 1.2 to 2.5%, Mn: 0.4 to 0.8%, C
r: 0.7 to 1.0%, N: 0.005 to 0.030%
And V: 0.1 to 0.6%, Mo: 0.05
~ 0.50%, W: 0.05 to 0.50% of 2 or 3
A wire rod containing at least one species and the balance consisting of Fe and unavoidable impurities and having an Al content of the unavoidable impurities of 0.005% or less and a Ti content of 0.005% or less is patented and stretched. The steel wire obtained by wire processing and quenching and tempering is spring-formed and has a surface roughness of R.
A high fatigue strength coil spring having a maximum of 10 μm or less.
JP16213692A 1992-05-27 1992-05-27 High fatigue strength coil spring Pending JPH05331597A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16213692A JPH05331597A (en) 1992-05-27 1992-05-27 High fatigue strength coil spring

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16213692A JPH05331597A (en) 1992-05-27 1992-05-27 High fatigue strength coil spring

Publications (1)

Publication Number Publication Date
JPH05331597A true JPH05331597A (en) 1993-12-14

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP16213692A Pending JPH05331597A (en) 1992-05-27 1992-05-27 High fatigue strength coil spring

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Country Link
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002050327A1 (en) * 2000-12-20 2002-06-27 Nippon Steel Corporation High-strength spring steel and spring steel wire
EP1361289A4 (en) * 2001-02-07 2004-08-25 Nippon Steel Corp THERMALLY TREATED STEEL WIRE FOR HIGH STRENGTH SPRING
WO2007114490A1 (en) * 2006-03-31 2007-10-11 Nippon Steel Corporation Heat-treatment steel for high-strength spring
WO2007114491A1 (en) * 2006-03-31 2007-10-11 Nippon Steel Corporation Heat-treatment steel for high-strength spring
JP2008261055A (en) * 2008-05-26 2008-10-30 Kobe Steel Ltd High-toughness martensitic steel
KR100954788B1 (en) * 2002-12-23 2010-04-28 재단법인 포항산업과학연구원 Coil spring for sliding gate with excellent high temperature strain resistance
JP2015163735A (en) * 2014-01-29 2015-09-10 株式会社神戸製鋼所 Spring steel wire material excellent in fatigue characteristic and spring

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7789974B2 (en) 2000-12-20 2010-09-07 Nippon Steel Corporation High-strength spring steel wire
WO2002050327A1 (en) * 2000-12-20 2002-06-27 Nippon Steel Corporation High-strength spring steel and spring steel wire
US7575646B2 (en) 2001-02-07 2009-08-18 Nippon Steel Corporation Heat-treated steel wire for high strength spring
EP1361289A4 (en) * 2001-02-07 2004-08-25 Nippon Steel Corp THERMALLY TREATED STEEL WIRE FOR HIGH STRENGTH SPRING
KR100954788B1 (en) * 2002-12-23 2010-04-28 재단법인 포항산업과학연구원 Coil spring for sliding gate with excellent high temperature strain resistance
WO2007114491A1 (en) * 2006-03-31 2007-10-11 Nippon Steel Corporation Heat-treatment steel for high-strength spring
WO2007114490A1 (en) * 2006-03-31 2007-10-11 Nippon Steel Corporation Heat-treatment steel for high-strength spring
JP5114665B2 (en) * 2006-03-31 2013-01-09 新日鐵住金株式会社 Heat-treated steel for high-strength springs
JP5200540B2 (en) * 2006-03-31 2013-06-05 新日鐵住金株式会社 Heat-treated steel for high-strength springs
EP2003223A4 (en) * 2006-03-31 2014-08-20 Nippon Steel & Sumitomo Metal Corp THERMAL TREATMENT STEEL FOR HIGH RESISTANCE SPRING
US8845825B2 (en) 2006-03-31 2014-09-30 Nippon Steel & Sumitomo Metal Corporation High strength spring-use heat treated steel
JP2008261055A (en) * 2008-05-26 2008-10-30 Kobe Steel Ltd High-toughness martensitic steel
JP2015163735A (en) * 2014-01-29 2015-09-10 株式会社神戸製鋼所 Spring steel wire material excellent in fatigue characteristic and spring
JP2018193615A (en) * 2014-01-29 2018-12-06 株式会社神戸製鋼所 Spring steel wire excellent in fatigue characteristic and spring

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