JPH05295576A - Continuous degreasing method for metal strips - Google Patents
Continuous degreasing method for metal stripsInfo
- Publication number
- JPH05295576A JPH05295576A JP9946192A JP9946192A JPH05295576A JP H05295576 A JPH05295576 A JP H05295576A JP 9946192 A JP9946192 A JP 9946192A JP 9946192 A JP9946192 A JP 9946192A JP H05295576 A JPH05295576 A JP H05295576A
- Authority
- JP
- Japan
- Prior art keywords
- degreasing
- strip
- degreasing method
- metal strip
- continuous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G3/00—Apparatus for cleaning or pickling metallic material
- C23G3/02—Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
- C23G3/023—Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously by spraying
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
(57)【要約】
【目的】 連続脱脂方法であって、効率よく、しかも良
好な安定した脱脂効果を得られる方法を提供すること。
【構成】 金属の条材1をスプレーノズル6から噴出す
る洗浄剤水溶液で湿潤させた後、ブラシ3によるブラッ
シングで連続的に脱脂処理する連続脱脂方法において、
ブラッシングされる時点の温度が40℃以上になるよう
に金属条1を加熱しておく金属条1の連続脱脂方法。
(57) [Summary] [Purpose] To provide a continuous degreasing method that is efficient and can obtain a stable degreasing effect. [Constitution] In a continuous degreasing method in which a metal strip 1 is moistened with a cleaning agent aqueous solution ejected from a spray nozzle 6 and then continuously degreased by brushing with a brush 3.
A continuous degreasing method for the metal strip 1 in which the metal strip 1 is heated so that the temperature at the time of brushing is 40 ° C. or higher.
Description
【0001】[0001]
【産業上の利用分野】本発明は銅、銅合金、鉄等の金属
条の連続脱脂方法において、脱脂の効率を向上させる方
法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a continuous degreasing method for metal strips of copper, copper alloys, iron, etc., for improving the efficiency of degreasing.
【0002】[0002]
【従来の技術】銅、銅合金、鉄等の金属条は圧延加工に
より製造されるが、圧延時に加工油として使用される圧
延油が付着するため、必要に応じて脱脂処理が行われ
る。脱脂方法としてはアルカリ水溶液による浸漬脱脂、
水溶液中で金属条を陰極または陽極として通電する電解
脱脂、アルカリ水溶液で金属条を湿潤させてブラッシン
グする方法等各種の方法が使用されている。2. Description of the Related Art Metal strips of copper, copper alloys, iron, etc. are manufactured by rolling, but rolling oil used as working oil during rolling adheres to them, so that degreasing treatment is carried out if necessary. As the degreasing method, immersion degreasing with an alkaline aqueous solution,
Various methods have been used, such as electrolytic degreasing in which an electric current is applied to a metal strip in an aqueous solution as a cathode or an anode, and a method in which the metal strip is wetted with an alkaline aqueous solution and brushed.
【0003】特にアルカリ水溶液で金属条を湿潤させて
ブラッシングする方法は、設備の管理が容易でコストも
低いうえ、効果も比較的高いため脱脂設備や熱処理設備
の脱脂工程等で広く実施されている。Particularly, the method of moistening a metal strip with an alkaline aqueous solution to perform brushing is widely used in the degreasing process of a degreasing facility or a heat treatment facility because the facility management is easy and the cost is low, and the effect is relatively high. .
【0004】ところが、生産性の向上の目的で、金属条
の通板速度が次第に速くなると、設備の脱脂機能が低下
するという問題があった。However, for the purpose of improving productivity, there has been a problem that the degreasing function of the equipment is deteriorated when the speed of passing the metal strip gradually increases.
【0005】すなわち連続脱脂設備では通板する条の厚
み範囲が広く、例えば0.1mmから1.0mmという
広い範囲の厚みの条を通板することが要求される。脱脂
設備を建設する場合も、旧来の設備に比べて通板速度が
高くなることが多く、旧来の設備を使用する場合も通板
速度が次第に高められることが多い。こうした場合に設
備の脱脂能力が低下したり、条の種類により脱脂の程度
がばらつくことがある。That is, in the continuous degreasing equipment, the thickness range of the strip to be passed is wide, and it is required to pass the strip having a wide thickness range of 0.1 mm to 1.0 mm, for example. When constructing a degreasing facility, the strip running speed is often higher than that of the conventional facility, and even when using the legacy facility, the strip running speed is often gradually increased. In such a case, the degreasing ability of the equipment may decrease, and the degree of degreasing may vary depending on the type of strip.
【0006】[0006]
【発明が解決しようとする課題】本発明は銅、銅合金、
鉄等の金属条の連続アルカリブラシ脱脂設備において、
条の種類、通板条件によらず安定して脱脂できる脱脂方
法を提供しようとするものである。DISCLOSURE OF THE INVENTION The present invention relates to copper, copper alloys,
In continuous alkaline brush degreasing equipment for metal strips such as iron,
An object of the present invention is to provide a degreasing method capable of degreasing stably regardless of the type of strip and the threading conditions.
【0007】[0007]
【課題を解決するための手段】上記課題を解決するため
の本発明の構成は、金属の条材を洗浄剤水溶液で湿潤さ
せてブラッシングして連続的に脱脂処理する連続脱脂方
法において、ブラッシングされる時点の条材の温度が4
0℃以上に加熱されている金属条の連続脱脂方法であ
る。The structure of the present invention for solving the above problems is a continuous degreasing method in which a metal strip is wetted with an aqueous solution of a cleaning agent and continuously brushed for degreasing. Temperature of the strip is 4
This is a continuous degreasing method for metal strips heated to 0 ° C or higher.
【0008】アルカリブラシ方式の連続脱脂設備の一例
を図1を参照して具体的に説明すると、送りロール5、
ブラシ3、バックアップロール4、スプレーノズル6お
よび7を備えた脱脂槽2の中に、金属の条材1を通過さ
せるものである。An example of the alkaline brush type continuous degreasing equipment will be specifically described with reference to FIG.
The metal strip 1 is passed through a degreasing tank 2 equipped with a brush 3, a backup roll 4, and spray nozzles 6 and 7.
【0009】送りロール5の隣に設けられたスプレーノ
ズル7からは洗浄剤水溶液が噴出して金属の条材1の表
面を湿潤させる。表面が洗浄剤水溶液で湿潤した条材1
をバックアップロール4で裏面から支えながら表面をブ
ラシ3で擦り、次に上からバックアップロール4で押え
ながら裏面をブラシ3で擦る。スプレーノズル7と8は
それぞれ条とブラシの間に洗浄剤水溶液を噴出して条表
面を脱脂させるものである。ただし、第1図は、アップ
カット、すなわち条の進行方向とブラシの回転方向が逆
の場合であるため、スプレーがブラシの後方に位置する
が、ブラシの回転方向が逆、すなわちダウンカットの場
合は、スプレーは前方に位置する。こうして脱脂処理さ
れた金属の条材を送りロール6で送り出す。An aqueous cleaning agent solution is jetted from a spray nozzle 7 provided next to the feed roll 5 to wet the surface of the metal strip 1. Strip 1 whose surface is moistened with an aqueous cleaning solution
Is rubbed on the front side with the backup roll 4 while supporting it from the back side, and then rubbed on the back side with the brush 3 while being pressed by the backup roll 4 from above. The spray nozzles 7 and 8 spray a cleaning agent aqueous solution between the strip and the brush to degrease the surface of the strip. However, Fig. 1 shows an upcut, that is, when the direction of travel of the strip and the direction of rotation of the brush are opposite, so the spray is located behind the brush, but when the direction of rotation of the brush is opposite, that is, when the brush is downcut. The spray is located in the front. The metal strip thus degreased is sent out by the feed roll 6.
【0010】このような方法で金属の条材(条)を処理
する場合、通板する条の厚み範囲が広く、例えば0.1
mmから1.0mmという広い範囲の厚みの条を通板す
ることが要求される。脱脂設備を建設する場合も、旧来
の設備に比べて通板速度が高くなることが多く、旧来の
設備を使用する場合も通板速度も次第に高められること
が多い。こうした場合に設備の脱脂能力が低下したり、
条の種類により脱脂の程度がばらつくことがある。その
原因を調査したところ、ブラッシングの際に条の厚みが
厚い場合や通板速度が速い場合は条材の温度が低く、脱
脂液の脱脂効果およびブラッシング効果が不十分である
ことが大きな要因として明らかになった。すなわち、ブ
ラッシングされる前に脱脂液に条を浸漬するか、条に脱
脂液をスプレー等で予めかけて、しかもブラッシングさ
れる時点での条の温度を40℃以上に上げておくこと
が、脱脂効果を高く安定させておく上で重要である。When a metal strip material (strip) is treated by such a method, the thickness range of the strip to be threaded is wide, for example, 0.1.
It is required to pass a strip having a wide range of thickness from mm to 1.0 mm. When constructing a degreasing facility, the strip running speed is often higher than that of the conventional facility, and when using the legacy facility, the strip running speed is often gradually increased. In such a case, the degreasing ability of the equipment will decrease,
The degree of degreasing may vary depending on the type of strip. When investigating the cause, when the thickness of the strip is thick during brushing or the stripping speed is fast, the temperature of the strip is low, and the degreasing effect of the degreasing liquid and the insufficient brushing effect are the major factors. It was revealed. That is, it is necessary to immerse the strip in the degreasing solution before brushing, or to spray the stripping solution with the degreasing solution beforehand and to raise the temperature of the strip at the time of brushing to 40 ° C or higher. It is important to keep the effect high and stable.
【0011】脱脂液は通常、水酸化ナトリウム、炭酸ナ
トリウム、リン酸ナトリウム、ケイ酸ナトリウム等の無
機薬剤に加えて、界面活性剤等を主要成分とするもので
あり、液温が高い方が脱脂効果は高い。通常、目的に応
じ脱脂液の温度は常温〜80℃の範囲で使用されること
が多い。ところが通板速度が速くなると、ブラッシング
時に条の温度が脱脂液の温度まで上がらず、脱脂効果が
低くなる。また、条の厚みが厚い場合も同様に条の温度
が上がりにくいために、脱脂効果が低下する。そこで通
板速度および板厚を考慮して、浸漬法スプレー法によら
ず、脱脂液により条を予め加熱し、ブラッシング時に条
の温度が所定の脱脂液温度になるようにすることによっ
て、脱脂効果を高くすることができる。The degreasing liquid usually contains an inorganic chemical such as sodium hydroxide, sodium carbonate, sodium phosphate, sodium silicate, etc., and a surfactant as a main component. The effect is high. Usually, the temperature of the degreasing liquid is often in the range of normal temperature to 80 ° C. depending on the purpose. However, when the sheet passing speed is increased, the temperature of the strip does not rise to the temperature of the degreasing liquid during brushing, and the degreasing effect is reduced. Also, when the thickness of the strip is large, the temperature of the strip is unlikely to rise and the degreasing effect is reduced. Therefore, taking into account the stripping speed and plate thickness, the degreasing effect can be obtained by preheating the strips with a degreasing liquid so that the temperature of the strips reaches the specified degreasing liquid temperature during brushing instead of using the dipping method or spraying method. Can be higher.
【0012】[0012]
【実施例】以下、実施例および比較例によって本発明を
具体的に説明する。EXAMPLES The present invention will be specifically described below with reference to Examples and Comparative Examples.
【0013】図1に示す条のアルカリブラシ脱脂設備
に、幅600mm、板厚0.1〜0.8mmの銅の条材
を通板速度を変えて通板し、脱脂前後の条表面の油分を
測定した。その際、脱脂液の予備スプレーの流量および
予備スプレーとブラシとの距離を調節して、ブラッシン
グ時の条の温度を調節した。A strip of copper having a width of 600 mm and a thickness of 0.1 to 0.8 mm is passed through the strip of alkaline brush degreasing equipment shown in FIG. Was measured. At that time, the flow rate of the preliminary spray of the degreasing liquid and the distance between the preliminary spray and the brush were adjusted to control the temperature of the strip during brushing.
【0014】それらの具体的条件と結果を表1に示す。Table 1 shows the specific conditions and the results.
【0015】[0015]
【表1】 [Table 1]
【0016】[0016]
【発明の効果】以上説明したように、本発明の方法によ
れば、連続脱脂方法を効率よく行い、しかも良好な安定
した脱脂効果を得ることができる。As described above, according to the method of the present invention, the continuous degreasing method can be efficiently performed, and a good and stable degreasing effect can be obtained.
【図1】本発明を実施する具体例の説明図である。FIG. 1 is an explanatory diagram of a specific example for carrying out the present invention.
【符号の説明】 1 金属の条材 2 脱脂槽 3 ブラシ 4 バックアップロール 5,6 送りロール 7,8 スプレーノズル[Explanation of symbols] 1 metal strip 2 degreasing tank 3 brush 4 backup roll 5,6 feed roll 7,8 spray nozzle
Claims (1)
ブラッシングして連続的に脱脂処理する連続脱脂方法に
おいて、ブラッシングされる時点の条材の温度が40℃
以上に加熱されていることを特徴とする金属条の連続脱
脂方法。1. In a continuous degreasing method in which a metal strip is moistened with a cleaning solution and brushed continuously to degrease, the temperature of the strip at the time of brushing is 40 ° C.
A continuous degreasing method for a metal strip, which is characterized by being heated above.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9946192A JPH05295576A (en) | 1992-04-20 | 1992-04-20 | Continuous degreasing method for metal strips |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9946192A JPH05295576A (en) | 1992-04-20 | 1992-04-20 | Continuous degreasing method for metal strips |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH05295576A true JPH05295576A (en) | 1993-11-09 |
Family
ID=14247958
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9946192A Pending JPH05295576A (en) | 1992-04-20 | 1992-04-20 | Continuous degreasing method for metal strips |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH05295576A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006144072A (en) * | 2004-11-19 | 2006-06-08 | Sanbo Copper Alloy Co Ltd | Removal treatment method for silicon-containing copper alloy material |
-
1992
- 1992-04-20 JP JP9946192A patent/JPH05295576A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006144072A (en) * | 2004-11-19 | 2006-06-08 | Sanbo Copper Alloy Co Ltd | Removal treatment method for silicon-containing copper alloy material |
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