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JPH05166717A - Formation of fine pattern - Google Patents

Formation of fine pattern

Info

Publication number
JPH05166717A
JPH05166717A JP33184591A JP33184591A JPH05166717A JP H05166717 A JPH05166717 A JP H05166717A JP 33184591 A JP33184591 A JP 33184591A JP 33184591 A JP33184591 A JP 33184591A JP H05166717 A JPH05166717 A JP H05166717A
Authority
JP
Japan
Prior art keywords
pattern
resist
fine
mixing
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP33184591A
Other languages
Japanese (ja)
Inventor
Hiroyuki Minami
裕之 巳浪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Priority to JP33184591A priority Critical patent/JPH05166717A/en
Publication of JPH05166717A publication Critical patent/JPH05166717A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/40Treatment after imagewise removal, e.g. baking

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)
  • Drying Of Semiconductors (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)

Abstract

PURPOSE:To provide a method of forming a fine omission of pattern with a pattern size smaller than the resolution limit. CONSTITUTION:After a fine omission of pattern is formed on a pattern forming resist 2, a mixing generating resist 3 which mixes itself with the pattern forming resist 2 is coated. Then baking is performed to form a mixing layer 4 and then the mixing generating resist 3 except for the mixing layer 4 is removed. So, developing is performed for obtaining a fine pattern size c which is smaller than a pattern size 'a' of the fine omission of pattern formed on the pattern forming resist 2 by the thickness b of the mixing layer 4.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、半導体装置の製造など
に用いられる微細パターン形成方法に関するものであ
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fine pattern forming method used for manufacturing a semiconductor device.

【0002】[0002]

【従来の技術】図2(a),(b)は従来の微細パター
ン形成方法を示す断面図である。この図において、1は
半導体などの基板、2はこの基板1上に塗布されたパタ
ーン形成用レジストで、aはパターン寸法を示す。
2. Description of the Related Art FIGS. 2A and 2B are sectional views showing a conventional fine pattern forming method. In this figure, 1 is a substrate such as a semiconductor, 2 is a pattern forming resist applied on the substrate 1, and a is a pattern size.

【0003】次に、形成方法について説明する。図2
(a)に示すように、基板1にパターン形成用レジスト
2を塗布形成する。次に、図2(b)に示すように、パ
ターン形成用レジスト2に光学露光、例えば波長365
nmの縮小投影露光法や、電子ビーム(EB)露光法な
どを用いて微細な抜きパターンを形成する。この時の微
細な抜きパターンのパターン寸法aは、それぞれの露光
法により限界があり、光学露光では0.5μm,電子ビ
ーム露光でも0.2μm程度である。
Next, a forming method will be described. Figure 2
As shown in (a), the pattern forming resist 2 is applied and formed on the substrate 1. Next, as shown in FIG. 2B, the pattern forming resist 2 is optically exposed, for example, at a wavelength of 365.
A fine relief pattern is formed by using a reduced projection exposure method of nm, an electron beam (EB) exposure method, or the like. The pattern dimension a of the fine cut pattern at this time has a limit depending on each exposure method, and is 0.5 μm for optical exposure and about 0.2 μm for electron beam exposure.

【0004】[0004]

【発明が解決しようとする課題】従来の微細パターン形
成方法では、使用する露光方法において解像限界があ
り、その限界より微細な抜きパターンを形成することが
できないという問題点があった。
In the conventional fine pattern forming method, there is a problem that the exposure method used has a resolution limit, and it is not possible to form a punched pattern finer than the limit.

【0005】本発明は、上記のような問題点を解消する
ためになされたもので、解像限界以下の微細な抜きパタ
ーンを形成する方法を提供することを目的とする。
The present invention has been made to solve the above problems, and an object of the present invention is to provide a method for forming a fine punching pattern below the resolution limit.

【0006】[0006]

【課題を解決するための手段】本発明に係る微細パター
ン形成方法は、基板上に塗布されたパターン形成用レジ
ストに微細な抜きパターンを形成し、前記パターン形成
用レジストとミキシングを起こすミキシング生成用レジ
ストを塗布し、必要なミキシング層を形成する温度でベ
ークし、ミキシングしていないミキシング生成用レジス
トを除去して前記微細な抜きパターンの寸法より微細な
抜きパターンを形成するものである。
A method for forming a fine pattern according to the present invention is for forming a fine pattern on a resist for pattern formation coated on a substrate, and for generating a mixture for mixing with the resist for pattern formation. A resist is applied and baked at a temperature for forming a required mixing layer, and the unmixed resist for mixing generation is removed to form a punching pattern finer than the size of the fine punching pattern.

【0007】[0007]

【作用】本発明においては、パターン形成用レジストに
形成した微細な抜きパターンに、前記パターン形成用レ
ジストとミキシングしやすいミキシング生成用レジスト
を塗布し、ベークしてミキシング層を形成した後、前記
ミキシング層以外のミキシング生成用レジストを除去す
ることにより、前記パターン形成用レジストに形成した
微細なレジスト抜きパターンの寸法よりミキシング層の
厚さ分だけ微細なパターンが形成でき、解像限界を向上
できる。
In the present invention, the fine pattern formed on the resist for pattern formation is coated with the resist for forming mixing which is easy to mix with the resist for pattern formation and baked to form a mixing layer, and then the mixture is mixed. By removing the mixing generation resist other than the layers, a finer pattern can be formed by the thickness of the mixing layer than the size of the fine resist removal pattern formed on the pattern forming resist, and the resolution limit can be improved.

【0008】[0008]

【実施例】以下、本発明の一実施例を図1について説明
する。図1(a)〜(e)は本発明の微細パターン形成
方法の一実施例を示す工程断面図である。図1におい
て、1は基板、2はパターン形成用レジスト、3はこの
パターン形成用レジスト2とミキシングを起しやすいミ
キシング生成用レジスト、4はミキシング層、aは前記
パターン形成用レジスト2に形成されたパターン寸法、
bは前記ミキシング層4の厚さ、cは前記ミキシング層
4を形成した後の微細パターン寸法をそれぞれ示す。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT An embodiment of the present invention will be described below with reference to FIG. 1A to 1E are process sectional views showing an embodiment of the fine pattern forming method of the present invention. In FIG. 1, 1 is a substrate, 2 is a pattern forming resist, 3 is a mixing generation resist which easily mixes with the pattern forming resist 2, 4 is a mixing layer, and a is formed on the pattern forming resist 2. Pattern dimensions,
“B” indicates the thickness of the mixing layer 4, and “c” indicates the fine pattern size after the mixing layer 4 is formed.

【0009】以下、図に従い微細パターンの形成工程に
ついて説明する。図1(a)に示すように、基板1上に
パターン形成用レジスト2、例えばPMMA(ポリメタ
クリル酸メチル)を5000Å厚程度に塗布し、ベーク
を180℃30分オーブンでベークして行う。次に、電
子ビーム露光法や光学露光法により露光し、メチルイソ
ブチルケトンなどの有機溶剤を用いて現像し、0.2μ
m程度の微細なパターン寸法aを有する微細な抜きパタ
ーンを形成する(図1(b))。次に、パターン形成用
レジスト2とミキシングを生成するミキシング生成用レ
ジスト3、例えばPMMAなどの溶媒であるエチルセル
ソルブアセテートなどに溶解する通常のフォトレジスト
などを塗布し(図1(c))、そのレジストベーク温度
より低い50〜80℃前後でベークし、ミキシング層4
を100〜500Åの厚みに形成する(図1(d)。そ
して、ミキシング層4以外のミキシング生成用レジスト
3を現像液で除去し、図1(e)のように、図1(b)
のパターン寸法aに比べ(a−2b)となるレジストパ
ターン寸法cの微細な抜きパターンを形成する。例えば
aが0.2μmのパターン寸法で、bが200Å(0.
02μm)の厚みである時、最終的なレジストパターン
寸法cはc=0.2μm−0.02μm×2=0.16
μmとなり、微細な抜きパターンを形成できる。なお、
ミキシング層4の厚さbは、ベーキング温度および時間
に依存する。ベーク時間がある時間になるまで(例えば
15分)は、ミキシング層4の厚さbはベーク時間に比
例し増加するが、それ以上になると増加量が少なくなり
一定の厚さでとまる。また、パターン形成用レジスト2
としては上記以外にノボラック系レジスト、ミキシング
生成用レジスト3としては上記の他クロルメチル化ポリ
スチレン(CMS)等を用いうる。
The steps of forming a fine pattern will be described below with reference to the drawings. As shown in FIG. 1A, a pattern forming resist 2, for example, PMMA (polymethylmethacrylate) is applied on a substrate 1 to a thickness of about 5000Å, and baking is performed in an oven at 180 ° C. for 30 minutes. Next, it is exposed by an electron beam exposure method or an optical exposure method and developed with an organic solvent such as methylisobutylketone to give 0.2 μm.
A fine punched pattern having a fine pattern dimension a of about m is formed (FIG. 1B). Next, a resist 2 for pattern formation and a resist 3 for mixing for generating mixing, for example, a normal photoresist dissolved in ethyl cellosolve acetate which is a solvent such as PMMA are applied (FIG. 1 (c)), Baking is performed at about 50 to 80 ° C., which is lower than the resist baking temperature, and the mixing layer 4
To a thickness of 100 to 500Å (FIG. 1 (d). Then, the mixing generation resist 3 other than the mixing layer 4 is removed with a developing solution, and as shown in FIG. 1 (e), FIG.
A fine punching pattern having a resist pattern size c which is (a-2b) compared with the pattern size a of is formed. For example, a has a pattern size of 0.2 μm and b has a size of 200 Å (0.
When the thickness is 02 μm), the final resist pattern dimension c is c = 0.2 μm−0.02 μm × 2 = 0.16.
Since it becomes μm, a fine pattern can be formed. In addition,
The thickness b of the mixing layer 4 depends on the baking temperature and time. The thickness b of the mixing layer 4 increases in proportion to the bake time until the bake time reaches a certain time (for example, 15 minutes), but when the bake time is longer than that, the increase amount decreases and the thickness b stops at a constant thickness. Also, the pattern forming resist 2
In addition to the above, a novolac-based resist may be used, and as the mixing generation resist 3, other than the above, chloromethylated polystyrene (CMS) or the like may be used.

【0010】[0010]

【発明の効果】以上説明したように、本発明によれば、
パターン形成用レジストに微細な抜きパターンを形成し
た後、前記パターン形成用レジストとミキシングをおこ
すミキシング生成用レジストを塗布してベークを行って
ミキシング層を生成し、このミキシング層以外のミキシ
ング生成用レジストを除去することにより、はじめの微
細な抜きパターンよりも微細な寸法の抜きパターンを形
成するようにしたので、半導体装置などの微細加工が容
易に行える効果がある。
As described above, according to the present invention,
After forming a fine punched pattern on the pattern forming resist, a mixing generation resist that mixes with the pattern forming resist is applied and baked to form a mixing layer, and a mixing generation resist other than this mixing layer is formed. By removing the above, a punching pattern having a finer dimension than the initial fine punching pattern is formed, so that fine processing of a semiconductor device or the like can be easily performed.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明による微細パターン形成方法の工程断面
図である。
FIG. 1 is a process sectional view of a fine pattern forming method according to the present invention.

【図2】従来の微細パターン形成方法の工程断面図であ
る。
FIG. 2 is a process sectional view of a conventional fine pattern forming method.

【符号の説明】[Explanation of symbols]

1 基板 2 パターン形成用レジスト 3 ミキシング生成用レジスト 4 ミキシング層 a パターン寸法 b ミキシング層の厚さ c 微細パターン寸法 1 substrate 2 pattern forming resist 3 mixing generating resist 4 mixing layer a pattern dimension b mixing layer thickness c fine pattern dimension

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 基板上に塗布したパターン形成用レジス
トに微細な抜きのパターンを形成した後、前記パターン
形成用レジストとミキシングするミキシング生成用レジ
ストを基板全面に塗布し、前記パターン形成用レジスト
とミキシングする温度でベークを行ってミキシング層を
形成し、ミキシングしていない部分の前記ミキシング生
成用レジストを除去して前記微細な抜きパターン寸法よ
り微細な抜きパターンを形成することを特徴とする微細
パターン形成方法。
1. A fine pattern is formed on a pattern forming resist applied on a substrate, and then a mixing generation resist for mixing with the pattern forming resist is applied on the entire surface of the substrate to form the pattern forming resist. A fine pattern characterized by forming a mixing layer by baking at a mixing temperature, and removing the mixing generation resist in a non-mixed portion to form a finer punch pattern than the fine punch pattern size. Forming method.
JP33184591A 1991-12-16 1991-12-16 Formation of fine pattern Pending JPH05166717A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33184591A JPH05166717A (en) 1991-12-16 1991-12-16 Formation of fine pattern

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33184591A JPH05166717A (en) 1991-12-16 1991-12-16 Formation of fine pattern

Publications (1)

Publication Number Publication Date
JPH05166717A true JPH05166717A (en) 1993-07-02

Family

ID=18248301

Family Applications (1)

Application Number Title Priority Date Filing Date
JP33184591A Pending JPH05166717A (en) 1991-12-16 1991-12-16 Formation of fine pattern

Country Status (1)

Country Link
JP (1) JPH05166717A (en)

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5583063A (en) * 1993-11-30 1996-12-10 Nec Corporation Method of forming T-shaped, cross-sectional pattern using two layered masks
US5858620A (en) * 1996-07-05 1999-01-12 Mitsubishi Denki Kabushiki Kaisha Semiconductor device and method for manufacturing the same
US6180528B1 (en) 1998-08-07 2001-01-30 Murata Manufacturing Co., Ltd. Method for forming a minute resist pattern and method for forming a gate electrode
US6319853B1 (en) 1998-01-09 2001-11-20 Mitsubishi Denki Kabushiki Kaisha Method of manufacturing a semiconductor device using a minute resist pattern, and a semiconductor device manufactured thereby
JP2002334830A (en) * 2000-06-12 2002-11-22 Nec Kagoshima Ltd Method for forming pattern, and manufacturing method for display using the same
US6566040B1 (en) 1998-08-06 2003-05-20 Mitsubishi Denki Kabushiki Kaisha Method of manufacturing a semiconductor device and semiconductor device manufactured by the method
US6579657B1 (en) 1997-03-31 2003-06-17 Mitsubishi Denki Kabushiki Kaisha Material for forming a fine pattern and method for manufacturing a semiconductor device using the same
US6811817B2 (en) 2001-07-05 2004-11-02 Tokyo Ohka Kogyo Co., Ltd. Method for reducing pattern dimension in photoresist layer
US7189499B2 (en) 2002-06-26 2007-03-13 Tokyo Ohka Kogyo Co., Ltd. Method of forming fine patterns
US7235345B2 (en) 2001-11-05 2007-06-26 Tokyo Ohka Kogyo Co., Ltd. Agent for forming coating for narrowing patterns and method for forming fine pattern using the same
US7316885B2 (en) 2002-12-02 2008-01-08 Tokyo Ohka Kogyo Co., Ltd Method of forming resist pattern, positive resist composition, and layered product
WO2008136499A1 (en) 2007-05-01 2008-11-13 Az Electronic Materials (Japan)K.K. Water-soluble resin composition for the formation of micropatterns and process for the formation of micropatterns with the same
WO2009035087A1 (en) 2007-09-12 2009-03-19 Az Electronic Materials (Japan) K.K. Composition for forming silicon-containing fine pattern and method for forming fine pattern using the same
JP2009130170A (en) * 2007-11-26 2009-06-11 Fujitsu Ltd Semiconductor device manufacturing method and mask manufacturing method
US7553610B2 (en) 2002-10-10 2009-06-30 Tokyo Ohka Kogyo Co., Ltd. Method of forming fine patterns
US7579138B2 (en) 2006-07-19 2009-08-25 Tokyo Ohka Kogyo Co., Ltd. Method for forming micropattern
US7745077B2 (en) 2008-06-18 2010-06-29 Az Electronic Materials Usa Corp. Composition for coating over a photoresist pattern
US7923200B2 (en) 2007-04-09 2011-04-12 Az Electronic Materials Usa Corp. Composition for coating over a photoresist pattern comprising a lactam
US8043798B2 (en) 2002-08-21 2011-10-25 Tokyo Ohka Kogyo Co., Ltd. Method of forming fine patterns
US8124318B2 (en) 2002-06-28 2012-02-28 Tokyo Ohka Kogyo Co., Ltd. Over-coating agent for forming fine patterns and a method of forming fine patterns using such agent
US8142980B2 (en) 2004-04-30 2012-03-27 Tokyo Ohka Kogyo Co., Ltd. Over-coating agent for forming fine patterns and a method of forming fine patterns using such agent
US8187798B2 (en) 2002-10-25 2012-05-29 Tokyo Ohka Kogyo Co., Ltd. Method of forming fine patterns
WO2013121797A1 (en) * 2012-02-15 2013-08-22 Jsr Corporation Pattern-forming method
US8617653B2 (en) 2006-08-23 2013-12-31 Tokyo Ohka Okgyo Co., Ltd. Over-coating agent for forming fine patterns and a method of forming fine patterns using such agent

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02156244A (en) * 1988-12-08 1990-06-15 Oki Electric Ind Co Ltd Pattern forming method

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02156244A (en) * 1988-12-08 1990-06-15 Oki Electric Ind Co Ltd Pattern forming method

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5583063A (en) * 1993-11-30 1996-12-10 Nec Corporation Method of forming T-shaped, cross-sectional pattern using two layered masks
US5858620A (en) * 1996-07-05 1999-01-12 Mitsubishi Denki Kabushiki Kaisha Semiconductor device and method for manufacturing the same
US6579657B1 (en) 1997-03-31 2003-06-17 Mitsubishi Denki Kabushiki Kaisha Material for forming a fine pattern and method for manufacturing a semiconductor device using the same
US6319853B1 (en) 1998-01-09 2001-11-20 Mitsubishi Denki Kabushiki Kaisha Method of manufacturing a semiconductor device using a minute resist pattern, and a semiconductor device manufactured thereby
US6566040B1 (en) 1998-08-06 2003-05-20 Mitsubishi Denki Kabushiki Kaisha Method of manufacturing a semiconductor device and semiconductor device manufactured by the method
EP0978869A3 (en) * 1998-08-07 2002-01-16 Murata Manufacturing Co., Ltd. Method for forming a minute resist pattern and method for forming a gate electrode
US6180528B1 (en) 1998-08-07 2001-01-30 Murata Manufacturing Co., Ltd. Method for forming a minute resist pattern and method for forming a gate electrode
JP2002334830A (en) * 2000-06-12 2002-11-22 Nec Kagoshima Ltd Method for forming pattern, and manufacturing method for display using the same
US6811817B2 (en) 2001-07-05 2004-11-02 Tokyo Ohka Kogyo Co., Ltd. Method for reducing pattern dimension in photoresist layer
EP1942376A2 (en) 2001-07-05 2008-07-09 Tokyo Ohka Kogyo Co., Ltd. Method for reducing pattern dimension in a photoresist layer
US7235345B2 (en) 2001-11-05 2007-06-26 Tokyo Ohka Kogyo Co., Ltd. Agent for forming coating for narrowing patterns and method for forming fine pattern using the same
US7189499B2 (en) 2002-06-26 2007-03-13 Tokyo Ohka Kogyo Co., Ltd. Method of forming fine patterns
US8124318B2 (en) 2002-06-28 2012-02-28 Tokyo Ohka Kogyo Co., Ltd. Over-coating agent for forming fine patterns and a method of forming fine patterns using such agent
US8043798B2 (en) 2002-08-21 2011-10-25 Tokyo Ohka Kogyo Co., Ltd. Method of forming fine patterns
US7553610B2 (en) 2002-10-10 2009-06-30 Tokyo Ohka Kogyo Co., Ltd. Method of forming fine patterns
US8187798B2 (en) 2002-10-25 2012-05-29 Tokyo Ohka Kogyo Co., Ltd. Method of forming fine patterns
US7316885B2 (en) 2002-12-02 2008-01-08 Tokyo Ohka Kogyo Co., Ltd Method of forming resist pattern, positive resist composition, and layered product
US8142980B2 (en) 2004-04-30 2012-03-27 Tokyo Ohka Kogyo Co., Ltd. Over-coating agent for forming fine patterns and a method of forming fine patterns using such agent
US7579138B2 (en) 2006-07-19 2009-08-25 Tokyo Ohka Kogyo Co., Ltd. Method for forming micropattern
US8617653B2 (en) 2006-08-23 2013-12-31 Tokyo Ohka Okgyo Co., Ltd. Over-coating agent for forming fine patterns and a method of forming fine patterns using such agent
US7923200B2 (en) 2007-04-09 2011-04-12 Az Electronic Materials Usa Corp. Composition for coating over a photoresist pattern comprising a lactam
WO2008136499A1 (en) 2007-05-01 2008-11-13 Az Electronic Materials (Japan)K.K. Water-soluble resin composition for the formation of micropatterns and process for the formation of micropatterns with the same
EP2199861A4 (en) * 2007-09-12 2011-01-19 Az Electronic Materials Usa Composition for forming silicon-containing fine pattern and method for forming fine pattern using the same
WO2009035087A1 (en) 2007-09-12 2009-03-19 Az Electronic Materials (Japan) K.K. Composition for forming silicon-containing fine pattern and method for forming fine pattern using the same
US8663906B2 (en) 2007-09-12 2014-03-04 Az Electronic Materials Usa Corp. Silicon-containing composition for fine pattern formation and method for fine pattern formation using the same
KR101438384B1 (en) * 2007-09-12 2014-09-05 에이제토 엘렉토로닉 마티리알즈 아이피 (재팬) 가부시키가이샤 Composition for forming silicon-containing fine pattern and method for forming fine pattern using the same
JP2009130170A (en) * 2007-11-26 2009-06-11 Fujitsu Ltd Semiconductor device manufacturing method and mask manufacturing method
US7745077B2 (en) 2008-06-18 2010-06-29 Az Electronic Materials Usa Corp. Composition for coating over a photoresist pattern
WO2013121797A1 (en) * 2012-02-15 2013-08-22 Jsr Corporation Pattern-forming method
US8968586B2 (en) 2012-02-15 2015-03-03 Jsr Corporation Pattern-forming method

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