JPH05112435A - Hair cosmetic - Google Patents

Abstract

PURPOSE:To obtain a hair cosmetic providing hair with smoothness and a feeling of tension and rigidity without causing greasiness and drying. CONSTITUTION:A hair cosmetic comprising (A) a cationic surfactant, preferably a quaternary ammonium salt of formula I (at least one of R<3> to R<6> is 8-28C alkyl or alkenyl which may be replaced and the rest is benzyl, 1-5C alkyl or hydroxyalkyl; X1<-> is halogen ion or organic ion) such as stearyltrimethylammonium chloride, (B) fats and oils such as higher alcohols and lanolin derivative and (C) an alkylsaccharide-based surfactant of formula II (R<1> is 8-18C alkyl, alkenyl or alkylphenyl; R<2> is 2-4C alkylene; (m) is 0-10; G is 5-6C reducing sugar; (n) is 1-10) in a ratio of the component A/C=1-20, preferably 2-10 by weight. The cosmetic is preferably mixed with 0.1-10wt.% silicone derivative to improve touch.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair cosmetic such as a hair rinse, a hair conditioner, a hair treatment, a hair cream, etc., which imparts smoothness and firmness to the hair without making the hair sticky or dry.

[0002]

2. Description of the Related Art Conventionally, in order to improve the feel of hair, hair cosmetics have a mono- or di-linear long-chain alkyl quaternary ammonium salt or a mono- or di-branched long-chain alkyl quaternary ammonium salt. Cationic surfactants such as Further, in recent years, for the purpose of imparting suppleness and moisturizing feeling to hair, it has also been carried out to use fats and oils such as higher alcohols, glycerides, liquid paraffin and ester oils in combination with a cationic surfactant.

[0003]

However, this kind of hair cosmetics has insufficient smoothness and moist feeling at the time of finishing, and if the blending amount of the oil agent is increased to improve them, the residual amount of the oil agent remains. When applied to hair that has a feeling of feeling, that is, a greasy and sticky feeling, and is soft and firm and firm, there is a drawback that the feeling of volume is lost and a hairstyle as desired cannot be made.

Therefore, an object of the present invention is to obtain a hair cosmetic composition which is free from stickiness and dryness of the hair and can impart smoothness and firmness to the hair.

[0005]

Under the circumstances, the present inventors have conducted diligent studies to solve the above-mentioned problems, and as a result, as a result of the following general description in hair cosmetics containing a cationic surfactant and oils and fats. It has been found that, when a specific amount of the alkyl saccharide-based surfactant represented by the formula (1) is blended, a hair cosmetic having no greasiness and dryness on the hair and giving the hair smoothness and firmness is obtained. Was completed.

That is, the present invention comprises the following components (A) and (B)
And (C) (A) cationic surfactant (B) oils and fats (C) the following general formula (1) R ¹ —O— (R ² O) _m —G _n (1) (wherein R ¹ Represents a linear or branched alkyl group having 8 to 18 carbon atoms, an alkenyl group, or an alkylphenyl group, R ² represents an alkylene group having 2 to 4 carbon atoms, and m represents a number of 0 to 10, G represents a reducing sugar having 5 to 6 carbon atoms, n represents a number of 1 to 10), and contains (A) / (C) a weight ratio of 1 to 20. The present invention provides hair cosmetics.

Examples of the cationic surfactant as the component (A) used in the present invention include quaternary ammonium salts represented by the following general formula (2) or (3).

[0008]

[Chemical 1]

(In the formula, at least one of R ³ , R ⁴ , R ⁵ and R ⁶ is substituted with an alkoxy group, an alkenyloxy group, an alkanoylamino group or an alkenoylamino group having a total carbon number of 8 to 28). is shown an alkyl or alkenyl group optionally, remainder .R ⁷ showing a benzyl group, alkyl group or hydroxyalkyl group having 1 to 5 carbon atoms is an alkylene group having 2 to 3 carbon atoms, X ₁ ^- And X ₂ ⁻ represents a halogen ion or an organic anion, and v and v ′ are 1 to
An integer of 20 and at least one of R ⁸ and R ⁹ has a total carbon number of 8 to 28 and is an alkyl group which may be substituted with an alkoxy group, an alkenyloxy group, an alkanoylamino group or an alkenoylamino group, or Alkenyl group is shown, and the rest is benzyl group, alkyl group having 1 to 5 carbon atoms or hydroxyalkyl group.) Among such cationic surfactants, the quaternary ammonium salt of the general formula (2) is preferable, and more general Preferred examples of the formula (2) include branched quaternary ammonium salts represented by the following general formulas (4) to (6).

[0010]

[Chemical 2]

R ²¹ represents a methyl group or an ethyl group, p represents an integer such that the total number of carbon atoms in the alkyl group is 8 to 16), and (b)

[0012]

[Chemical 3]

S is an integer of 2-14, t is an integer of 3-11
Represents the number such that the sum of s and t is 9 to 21, and X₃ ^-, X_Four ^-Over
And X_Five ^-Represents a halogen ion or an organic anion, R¹⁹
And R ²⁰Is a benzyl group, an alkyl group having 1 to 3 carbon atoms, or
Indicates a hydroxyalkyl group]

The branched quaternary ammonium salt represented by the general formula (4) is usually synthesized by using, for example, an oxo alcohol having 8 to 16 carbon atoms as a raw material, and an example thereof is an alkyl derived from oxo alcohol. Examples thereof include a dialkyldimethylammonium salt having a group, a dialkylmethylhydroxyethylammonium salt, and a dialkylmethylbenzylammonium salt.

In the present invention, the branching ratio of R ^{10 in} the formula (4) is usually 10 to 100%, and particularly 1
It is preferably 0 to 50%. Further, those having a total carbon number of R ¹⁰ of 8 to 16 are used, but those having a constant distribution are preferable, and those having the distribution shown below are particularly preferable. C ₈ ~C _11: 5% or less _{C 12: 10~35% C 13:} 15~40% C 14: 20~45% C 15: 5~30% C 16: 5% or less such branched quaternary ammonium Specific examples of the salt include dialkyldimethylammonium chloride having an alkyl group having 8 to 16 carbon atoms and a branching rate of 10 to 50%. The branched quaternary ammonium salt represented by the general formula (5) is usually a Guerbet alcohol having 8 to 28 carbon atoms.

[0016]

[Chemical 4]

(Wherein R ¹³ and R ¹⁴ have the same meanings as described above), and are synthesized. Preferable examples of the branched quaternary ammonium salt include alkyltrimethylammonium salt having an alkyl group derived from Guerbet alcohol, alkyldimethylbenzylammonium salt, dialkyldimethylammonium salt, dialkylmethylhydroxyethylammonium salt, dialkylmethylbenzylammonium salt. Etc. Further, among these, particularly preferable specific examples include 2-decyltetradecyltrimethylammonium chloride and 2-decyltetradecyltrimethylammonium chloride.
Examples thereof include dodecylhexadecyltrimethylammonium chloride, di-2-hexyldecyldimethylammonium chloride, di-2-octyldodecyldimethylammonium chloride and the like. Examples of the methyl-branched quaternary ammonium salt represented by the general formula (6) include those in which the sum of s and t is 15.

The general formulas (2), (3), (4),
(5) and (6) X is a counterion of the quaternary ammonium salt represented by ₁ ^- to X ₅ ^- Specific examples of chlorine, iodine, halogen ion such as bromine; methosulfate, ethosulfate, methemoglobin Examples thereof include organic anions such as phosphate and ethophosphate.

The cationic surfactant may be used alone or as a mixture of two or more kinds, and the compounding amount thereof is 0.1 to 20% by weight, preferably 0.5 to 15% by weight in the composition. If this amount is less than 0.1% by weight, the effect of the present invention cannot be obtained, and if it exceeds 20.0% by weight, the product becomes sticky and the feel is deteriorated, which is not preferable.

The fats and oils as the component (B) used in the present invention are not particularly limited as long as they are generally used in hair cosmetics, and have, for example, a linear or branched alkyl group or alkenyl group. Higher alcohols; hydrocarbons such as liquid paraffin, petrolatum and solid paraffin; lanolin derivatives such as liquid lanolin and lanolin fatty acid;

Higher fatty acid esters, higher fatty acids, fats and oils such as long-chain amidoamine having an alkyl group or an alkenyl group; and animal and vegetable fats and oils such as mink oil and olive oil. Among these, monoglycerides derived from saturated or unsaturated linear or branched fatty acids having 12 to 24 carbon atoms and higher alcohols having linear or branched alkyl or alkenyl groups having 12 to 26 carbon atoms are particularly preferable. Preferably, specifically, oleic acid monoglyceride,
Examples thereof include fatty acid monoglycerides such as palmitic acid monoglyceride, behenic acid monoglyceride and isostearic acid monoglyceride, and higher alcohols such as cetyl alcohol, stearyl alcohol, arachin alcohol, behenyl alcohol, caranavir alcohol and ceryl alcohol. These oils and fats may be used alone or as a mixture of two or more kinds, and the blending amount thereof is 0.2 in the composition.
-30% by weight, preferably 0.5-20% by weight.
If this amount is less than 0.2% by weight, the effect of the present invention is not exhibited, and if it exceeds 30% by weight, stickiness may occur, which is not preferable.

The component (C), an alkyl saccharide-based surfactant, is represented by the above general formula (1), in which R ¹ is an alkyl group having 8 to 18 carbon atoms, particularly 8 to 12 carbon atoms (octyl). Groups, decyl groups, lauryl groups, etc.) are preferred. m is the degree of condensation of alkylene oxide and is a number from 0 to 10, but m is 0 to 4, particularly 0.
Are preferred. The reducing sugar represented by G is preferably glucose, galactose or fructose. The average degree of polymerization of the saccharide is n of 1 to 10, but it is particularly preferable that n is 1 to 4. The average degree of polymerization n is desirably selected in consideration of physical properties derived from the hydrophobic group R ^1, For example, R ¹ is an average carbon number 8-11
N is 1.5 to 4. When R ¹ is a hydrophobic group having an average carbon number of 12 to 14, n is 1.5 to 4.
It is preferable to select 0. The average sugar polymerization degree can be determined by proton NMR.

The blending amount of the component (C) is determined by the weight ratio with the component (A). That is, (A) / (C) is a weight ratio of 1 to 20, preferably 2 to 10.
If this ratio exceeds 20, tackiness of the hair will occur and firmness
When it is not possible to give the hair a firm feeling to the hair and it is less than 1,
The softness and slippage of hair in a wet state are inferior, which is not preferable.

The hair cosmetic composition of the present invention may further contain (D) a silicone derivative for improving the feel. Examples of this include:

(A) Dimethylpolysiloxane represented by the formula (7) (CH ₃ ) ₃ SiO [(CH ₃ ) ₂ SiO] _n1 Si (CH ₃ ) ₃ (7) (wherein n ₁ is 3 or more. As the methylpolysiloxane represented by the general formula (2) (indicating an integer), for example, one commercially available from Shin-Etsu Chemical Co., Ltd. under the trade name of KF96 can be used.

(B) Methylphenyl polysiloxane represented by the formula (8)

[0027]

[Chemical 5]

(In the formula, a, b and c are numbers such that their sum is 1 or more. However, when b is 0, c is not 0 and when c is 0, b is not 0) Methylphenyl polysiloxane represented by the formula (8) is also widely known, for example, KF from Shin-Etsu Chemical Co., Ltd.
Commercially available products such as 50 under the trade name can be used.

[0029] (c) amino-modified silicone represented by formula _{(9) (R 'd A} (3-d)) -Si- (OSi (A) 2) n2 - [OSi (A e R' (2-e ₎ )] _n3- OSi (R ′ _d A _(3-d) ) (9) [In the formula, A is a hydrogen atom, a phenyl group, a hydroxyl group, or a carbon number 1
Selected from the group consisting of alkyl groups of ~ 8, d is 0 or an integer of 1 to 3, e is 0 or 1, n ₂
Is 0 or an integer of 1 to 1999, and n ₃ is 1 to 2
000 is an integer, n ₂ + n ₃ is an integer of 1 to 2000, R ′ is a group —C _f H _2f L [where f is 2 to
Is an integer of 8 and L is an expression

[0030]

[Chemical 6]

(In the formula, Z is selected from the group consisting of hydrogen, a phenyl group, a benzyl group, and an alkyl group having 1 to 20 carbon atoms, and B ⁻ represents Cl ⁻ , Br ⁻ , I ⁻ or F ⁻ ) The amino-modified silicone represented by the general formula (9) is commercially available from Toray Dow Corning Silicone Co., Ltd. under the trade name of SF8417, DC536, or an aminoalkyl silicone emulsion. SM
8702C (Toray Dow Corning Silicone Co., Ltd.)
Manufactured) and the like can be used.

(D) Fatty acid-modified polysiloxane represented by the formula (10)

[0033]

[Chemical 7]

[In the formula (10), g, h and i are 1 to 35
0 is a number, j is a number from 0 to 10, and R ²² is a carbon number from 9 to
21 represents an alkyl group]

(E) Formula (11-a) or formula (11-b)
Alcohol-modified silicone represented by

[0036]

[Chemical 8]

[In the formula, k and l represent a number of 1 to 500 (preferably 1 to 200), and R ²³ and R ²³ ′ are C _n4 H _2n4.
(N ₄ represents a number of 0 to 4)]

(F) Aliphatic alcohol-modified silicone represented by the formula (12)

[0039]

[Chemical 9]

[In the formula (12), the sum of m ₁ , o and q ₁ is ₁ to 300, and r is a number of 0 to 5,
R ²⁴ represents C _n5 H _{2n5 + 1} (n ₅ represents a number of 4 to 22).

(G) Polyether-modified silicone represented by the following formulas (13) to (16)

[0042]

[Chemical 10]

(H) Epoxy-modified silicone represented by the formula (17)

[0044]

[Chemical 11]

[In the formula (16), α is a number of 1 to 500 (preferably 1 to 250) and β is a number of 1 to 50 (preferably 1).
To 30), and R ²⁶ represents an alkylene group having 1 to 3 carbon atoms]

(B) Fluorine-modified silicone represented by the formula (18)

[0047]

[Chemical 12]

[In the formula (10), γ represents a number of 1 to 400 (preferably 1 to 250)]

(N) Cyclic silicone represented by the formula (19)

[0050]

[Chemical 13]

[In the formula (11), δ represents a number of 3 to 8,
R ²⁷ represents an alkyl group having 1 to 3 carbon atoms]

(L) Formula (20-a) or Formula (20-b)
Alkyl-modified silicone represented by

[0053]

[Chemical 14]

[In the formula (19-a), ε and η are 1 to 5 respectively.
00 (preferably 1 to 200), R ²⁸ is an alkyl group having 2 to 18 carbon atoms, R ²⁹ is C _n7 H _2n7 (n ₇ is 0 to 0).
4)]

[0055]

[Chemical 15]

[In the formula (20-b), θ and κ are 1 to 5 respectively.
00 (preferably 1 to 200) and R ³⁰ represents an alkyl group having 10 to 16 carbon atoms]

Any of these silicone derivatives can sufficiently exert the effects of the present invention, but from the viewpoint of improving the smoothness and firmness and elasticity of the hair, (a) methylpolysiloxane. , (C) amino-modified silicone, (to) polyether-modified silicone,
It is preferable to use (nu) cyclic silicone.

In the case of (a) methylpolysiloxane, n ₁ in the formula (7) can be selected from 0 to 9000 according to the feeling of finish, but in order to give a sufficient firmness and elasticity to the hair, 1000 or more, Especially 2000-7000
A degree is preferable. (C) Amino-modified silicones are those in which d = 0, e = 1, f = 3 in the formula (9), A is a hydroxyl group and a methyl group, and L is —NHCH ₂ CH ₂ NH ₂ ; The one represented by the name of amodimethicone in the CTFA dictionary is particularly preferably used.

In the present invention, these (D) component silicone derivatives may be used alone or in combination of two or more, and the blending amount thereof is 0.05 to 20% by weight in the hair cosmetic composition, preferably. Is 0.1 to 10% by weight
Is. Further, the hair cosmetic composition of the present invention, if necessary, is usually a component to be blended in cosmetics, pharmaceuticals, foods, etc.,
For example, anti-dandruff agents such as Zpt, bactericides, vitamins, etc .; antiseptics such as parabens; humectants such as propylene glycol, glycerin, diethylene glycol monoethyl ether, sorbitol, panthenol, glycine betaine; Thickeners such as molecules; coloring agents such as dyes and pigments; conditioning agents such as perfluoropolyether and cationic polymers; pearling agents such as glycol esters; chitosan derivatives such as hydroxypropyl chitosan; hair such as acrylic resin liquids. Polymer for set; various fragrances; other Encyclopedia of Conditioning Rinse Ingredients [ENC
YCLOPEDIA OF CONDITIONING
RINSE INGREDIENTS (MICELL
E PRESS 1987)], and the like, may be appropriately blended within a range that does not impair the effects of the present invention.

The hair cosmetic composition of the present invention is manufactured by a conventional method using the above-mentioned components, and after shampooing the hair, the hair cosmetic composition is applied to the hair and rinsed off, for example, hair rinse, hair conditioner, hair treatment. And the like can be suitably used.

The hair cosmetic composition of the present invention can be produced by mixing the above components by a conventional method.

[0062]

EFFECTS OF THE INVENTION The hair cosmetic composition of the present invention is suitable for soft and non-twitch hair because it imparts smoothness and firmness to the hair without causing stickiness and dryness of the hair.

[0063]

The present invention will be described in more detail with reference to examples, but the present invention is not limited thereto. Examples 1 and 2 A hair rinse agent having the composition shown in Table 1 was prepared by the following production method, and its rinse performance was examined by the following sensory evaluation method. The results are shown in Table 1.

Sensory evaluation method: Cold perm ever,
20 g (15 cm in length) of hair (average length of 60 μm, thin hair) of a Japanese woman who has not been subjected to beauty treatment such as bleach is bundled, and for rinse type hair cosmetics, 2 g of the agent is evenly applied to this hair bundle. It was applied, then rinsed with running water for 30 seconds, towel-dried and then dried with a drier. Further, with respect to the hair soot-free type hair cosmetic, a predetermined amount of the agent was applied to this hair bundle and then air-dried. This hair bundle was subjected to a sensory evaluation for its non-greasyness, non-greasiness, smoothness, and firmness / resilience. ◎ was particularly good, ○ was good, △ was normal, and × was poor. As shown. Production method: To (7) heated to 70 ° C, a mixture of components (1) to (6) heated to the same temperature and dissolved is added, stirred to emulsify, cooled to room temperature with stirring, and a hair rinse agent is added. Obtained.

[0065]

[Table 1]

Example 3 Hair conditioners of Example 3 and Comparative Example 3 having the following composition were prepared by the following methods. These performances were evaluated by a pair of comparison methods by 16 female panelists. In addition, the comparison criterion is represented by the number of persons, with +2 being very good, +1 being very good, and 0 when neither can be said. The results are shown in Table 2.

[0067] The composition of the hair conditioner of Example 3: (1) cetostearyl trimethyl ammonium chloride 1 (wt%) (2) dicetyl dimethyl ammonium chloride 0.5 (3) cetanol 4 (4) an alkyl saccharide (C ₁₂ - O- (G) _1.7 ) 0.5 (5) Propylene glycol 5 (6) Perfume 0.4 (7) Water balance (A) component / (C) component ratio 3 Preparation method: heated to 70 ° C (7 ), A mixture of components (1) to (5) dissolved by heating to the same temperature is added, and the mixture is stirred to emulsify, then cooled to 40 ° C. with stirring,
(6) was added, and the mixture was further stirred and cooled to room temperature to obtain a hair conditioner agent.

Composition of hair conditioner of Comparative Example 3: (1) cetostearyltrimethylammonium chloride 1 (wt%) (2) dicetyldimethylammonium chloride 0.5 (3) cetanol 4 (4) propylene glycol 5 (5) Fragrance 0.4 (6) Water balance Preparation method: To (6) heated to 70 ° C., a mixture of components (1) to (4) dissolved by heating to the same temperature was added and stirred to emulsify , Cool to 40 ℃ with stirring,
(5) was added, and the mixture was further stirred and cooled to room temperature to obtain a hair conditioner agent.

[0069]

[Table 2]

Examples 4 to 7 Hair cosmetics having the compositions shown in Tables 3 and 4 were prepared by the following production method, and the rinse performance thereof was examined according to the evaluations of Examples 1 and 2. The results are shown in Tables 3 and 4. Manufacturing method: To a mixture of (6) and (7) heated to 70 ° C.,
The mixture of (1) to (5) heated and dissolved at the same temperature was added and stirred to emulsify, and then cooled to room temperature with further stirring.

[0071]

[Table 3]

[0072]

[Table 4]

Example 8 Hair Treatment Composition: (1) cetostearyltrimethylammonium chloride 0.8 (wt%) (2) disetostearyldimethylammonium chloride 1.2 (3) cetanol 5.0 (4) alkyl saccharide ( _{C 12 -O- (G) 1.7)} 0.5 (5) squalane 1.0 (6) glycerin 6.0 (7) dimethylpolysiloxane (1000 cs) 0.5 (8) preservative qs (9) dye qs (10) Perfume proper amount (11) Purified water balance (A) component / (C) component ratio 4

Production method: Heat-dissolved in a mixture of (8), (9) and (11) heated to 70 ° C. to the same temperature (1).
After adding the mixture of (6) and stirring to emulsify, cool to 45 ° C. with stirring, add (7) and (10), cool to room temperature with further stirring, and aim. A composition was obtained. This hair treatment was excellent in giving smoothness and firmness to the hair without making it sticky and dry at the time of finishing.

Example 9 Hair rinse Composition: (1) Stearyltrimethylammonium chloride 0.8 (wt%) (2) Dialkyldimethylammonium chloride ^{* 1)} 0.2 (3) Palmitic acid monoglyceride 0.5 (4) Stearyl alcohol 2.5 (5) an alkyl saccharide _{(C 8 -O- (G) 1.4} ) 0.1 (6) Liquid paraffin 0.3 (7) dipropylene glycol 3.0 (8) preservative qs (9) dye qs (10) Perfume proper amount (11) Purified water balance * 1): branched quaternary grade derived from a commercially available oxo-method alcohol having 12 to 15 carbon atoms (equivalent mixture of dovanol 23 and dovanol 45, manufactured by Mitsubishi Petrochemical Co., Ltd.) Ammonium salt,
The branching rate is 20%. Ratio of component (A) / component (C) 10

Manufacturing method: Heat-dissolved in a mixture of (8), (9) and (11) heated to 70 ° C. to the same temperature (1).
After adding the mixture of (7) and stirring to emulsify, cool to 45 ° C. with stirring, add (10) and cool to room temperature with further stirring to obtain the target composition. It was This hair rinse was excellent in imparting smoothness and firmness to the hair without making it sticky and dry at the time of finishing.

[0077] Example 10 Hair Treatment Composition: (1) Stearyl trimethyl ammonium chloride 3.0 (wt%) (2) myristyl alcohol 5.0 (3) oleic acid monoglyceride 2.0 (4) alkyl saccharide (C ₁₂ - O- (G) _2.0 ) 0.2 (5) Isostearic acid 0.5 (6) Glycine betaine 0.5 (7) Diethylene glycol monoethyl ether 10.0 (8) Preservative proper amount (9) Dye proper amount (10) Perfume proper amount (11) Purified water balance (A) component / (C) component ratio 15

Manufacturing method: Heat-dissolved in a mixture of (8), (9) and (11) heated to 70 ° C. to the same temperature (1).
After adding the mixture of (7) and stirring to emulsify, cool to 45 ° C. with stirring, add (10) and cool to room temperature with further stirring to obtain the target composition. It was This hair treatment was excellent in giving smoothness and firmness to the hair without making it sticky and dry at the time of finishing.

Example 11 Hair Conditioner Composition: (1) Cetostearyl dimethyl ammonium chloride 2.5 (wt%) (2) Cetostearyl alcohol 3.0 (3) Alkyl saccharide (C ₁₂ -O- (G) _1.7 ) 0.2 (4) Squalane 1.0 (5) Propylene glycol 5.0 (6) Preservative proper amount (7) Dye proper amount (8) Perfume proper amount (9) Purified water balance (A) component / (C) component Ratio 12.5

Production method: Heat-dissolved in a mixture of (6), (7) and (9) heated to 70 ° C. to the same temperature (1) to
The mixture of (5) was added, and the mixture was stirred to emulsify, then cooled to 45 ° C. with stirring, (8) was added, and further cooled to room temperature with stirring to obtain the target composition. .. When finished, this hair conditioner was excellent in imparting smoothness and firmness to the hair without making it sticky and dry.

Example 12 Hair Conditioner Composition: (1) Cetostearyltrimethylammonium chloride 0.7 (wt%) (2) 2-dodecylhexadecyltrimethylammonium chloride 0.4 (3) Cetanol 3.0 (4) Alkyl saccharide _{(C 8 -O- (G) 1.4} ) 1.1 (5) Liquid paraffin 0.5 (6) dimethylpolysiloxane (500 cs) 0.2 (7) 2-octyldodecanol 0.5 (8) propylene Glycol 5.0 (9) Hydroxyethyl cellulose 0.1 (10) Preservative proper amount (11) Dye proper amount (12) Perfume proper amount (13) Purified water balance Ratio of (A) component / (C) component 1

Manufacturing method: (9) and (1) heated to 70 ° C.
To the mixture of (0), (11) and (13), the mixture of (1) to (8) heated and dissolved to the same temperature was added, and the mixture was stirred to emulsify, then cooled to 45 ° C. with stirring, ( 12)
Was added, and the mixture was further cooled to room temperature with stirring to obtain the target composition. When finished, this hair conditioner was excellent in imparting smoothness and firmness to the hair without making it sticky and dry.

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[Procedure amendment]

[Submission date] June 5, 1992

[Procedure Amendment 1]

[Document name to be amended] Statement

[Correction target item name] 0012

[Correction method] Change

[Correction content]

[0012]

[Chemical 3] A mixture of groups, the branching ratio of which is (a) / [(a) + (b)]
Represents a group of 10 to 100%, R ¹¹ and R ¹² represent a benzyl group, an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group, and R ¹³ and R ¹⁴ represent 2 to 12 carbon atoms.
It indicates an alkyl ^{group, R 15} is And R ¹⁷ represents a benzyl group, an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group. Shows the radical

[Procedure Amendment 2]

[Document name to be amended] Statement

[Correction target item name] 0016

[Correction method] Change

[Correction content]

[0016]

[Chemical 4]

[Procedure 3]

[Document name to be amended] Statement

[Name of item to be corrected] 0022

[Correction method] Change

[Correction content]

The component (C), which is an alkyl saccharide-based surfactant, is represented by the above general formula (1), in which R ¹ is an alkyl group having 8 to 18 carbon atoms, particularly 8 to 12 carbon atoms (octyl). Groups, decyl groups, lauryl groups, etc.) are preferred. m is the degree of condensation of alkylene oxide and is a number from 0 to 10, but m is 0 to 4, particularly 0.
Are preferred. The reducing sugar represented by G is preferably glucose, galactose or fructose. The average degree of polymerization n of the saccharide is 1 to 10,
It is preferably 1-4 especially. It is desirable to select the average degree of polymerization n in consideration of the physical properties derived from the R ¹ hydrophobic group. For example, when R ¹ is a hydrophobic group having an average carbon number of 8 to 11, n is 1 to 1.4. , R ¹ has an average carbon number of 12 to ¹
When it is a hydrophobic group of 4, n is preferably selected from 1.5 to 4.0. The average sugar polymerization degree can be determined by proton NMR.

[Procedure amendment 4]

[Document name to be amended] Statement

[Name of item to be corrected] 0025

[Correction method] Change

[Correction content]

(A) Dimethylpolysiloxane represented by the formula (7): (CH ₃ ) ₃ SiO [(CH ₃ ) ₂ SiO] _n1 Si (CH ₃ ) ₃ (7) (wherein n ₁ is 3 or more. an integer) as the di-methyl polysiloxane represented by the general formula (7), for example, can be used such as those available under the trade name KF96 from Shin-Etsu chemical Co., Ltd..

[Procedure Amendment 5]

[Document name to be amended] Statement

[Name of item to be corrected] 0029

[Correction method] Change

[Correction content]

The amino-modified silicone represented by formula (iii) below _{(9) (R 'd)} (A 3-d) SiO- [Si (A 2) O] n2 - [Si (Ae) (R' 2-e _{) O] n3 -Si (R '} d) (A 3-d) (9) wherein, A represents a hydrogen atom, a phenyl group, a hydroxyl group, C 1 -C
Selected from the group consisting of alkyl groups of 8 to 8, d is an integer of 0 to 3 , e is 0 or 1, and n ₂ is 0 to 19
Shows an integer of 99 , n ₃ shows an integer of 1 to 2000,
n ₂ + _{n 3} represents an integer of 1 - 2000, R 'is the group -C
_f H _2f L [ where f is an integer of 2 to 8 and L
Is an expression

[Procedure correction 6]

[Document name to be amended] Statement

[Correction target item name] 0034

[Correction method] Change

[Correction content]

[In the formula , g, h, and i are numbers 1 to 350, j is a number 0 to 10, and R ²² is a carbon number 9 to 21.
The alkyl group of

[Procedure Amendment 7]

[Document name to be amended] Statement

[Correction target item name] 0036

[Correction method] Change

[Correction content]

[0036]

[Chemical 8]

[Procedure Amendment 8]

[Document name to be amended] Statement

[Item name to be corrected] 0040

[Correction method] Change

[Correction content]

[0040] wherein, _m 1, o and _{q 1} is the sum of them 1 to 300, and, r is the number of 0 to ^{5, R 24}
_Represents C _n5 H _{2n5 + 1} (n ₅ represents a number of 4 to 22)]

[Procedure Amendment 9]

[Document name to be amended] Statement

[Name of item to be corrected] 0045

[Correction method] Change

[Correction content]

[0045] wherein, alpha 1 to 500 (preferably 1 to
250), β is 1 to 50 (preferably 1 to 30)
And R ²⁶ represents an alkylene group having 1 to 3 carbon atoms]

[Procedure Amendment 10]

[Document name to be amended] Statement

[Correction target item name] 0048

[Correction method] Change

[Correction content]

[0048] wherein, gamma is 1 to 400 (preferably 1 to
250)]]

[Procedure Amendment 11]

[Document name to be amended] Statement

[Correction target item name] 0051

[Correction method] Change

[Correction content]

[0051] wherein, [delta] is a number of 3 to ^{8, R 27} represents an alkyl group having 1 to 3 carbon atoms]

[Procedure Amendment 12]

[Document name to be amended] Statement

[Correction target item name] 0054

[Correction method] Change

[Correction content]

[In the formula , ε and η each represent a number of 1 to 500 (preferably 1 to 200), and R ²⁸ has 2 to 18 carbon atoms.
R ²⁹ is C _n7 H _2n7 (n ₇ is 0 to 0).
4)]

[Procedure Amendment 13]

[Document name to be amended] Statement

[Correction target item name] 0056

[Correction method] Change

[Correction content]

[0056] wherein, theta, kappa each represent a number of 1 to 500 (preferably 1 to ^{200), R 30} is a carbon number between 1:10
6 represents an alkyl group]

[Procedure Amendment 14]

[Document name to be amended] Statement

[Correction target item name] 0057

[Correction method] Change

[Correction content]

[0057] From the standpoint these silicone derivatives, using either, but can be sufficiently exhibit the effect of the present invention, to improve the smoothness and firmness strained feeling of hair, (b) di methylpoly Siloxane, (C) amino modified silicone, (G) polyether modified silicone,
It is preferable to use (nu) cyclic silicone.

[Procedure Amendment 15]

[Document name to be amended] Statement

[Correction target item name] 0058

[Correction method] Change

[Correction content]

[0058] The (b) _{n 1} in the formula (7) In di-methyl polysiloxane in accordance with the finish feeling 3-9000
Although it can be selected up to 1000, in order to give a firm and firm feeling to the hair, 1000 or more, particularly 2000 to 700
About 0 is preferable. (C) Amino-modified silicones, wherein d = 0, e = 1, f = 3 in the formula (9), A is a hydroxyl group and a methyl group, and L is —NHCH ₂ CH ₂ NH ₂ ; The one represented by the name of amodimethicone in the CTFA dictionary is particularly preferably used.

Claims (2)

[Claims] 1. The following components (A), (B) and (C) (A) cationic surfactant (B) oils and fats (C) the following general formula (1) R ¹ —O— (R ² O) _m -G _n (1) (In the formula, R ¹ represents a linear or branched alkyl group having 8 to 18 carbon atoms, an alkenyl group, or an alkylphenyl group, and R ² has 2 to 4 carbon atoms. Represents an alkylene group, m represents a number of 0 to 10, G represents a reducing sugar having a carbon number of 5 to 6, and n represents a number of 1 to 10). , (A) / (C) in a weight ratio of 1 to 20. 2. The hair cosmetic composition according to claim 1, further comprising (D) a silicone derivative.